• 제목/요약/키워드: Raman Scattering

검색결과 312건 처리시간 0.021초

O VI Raman spectroscopy of the S-type symbiotic star V455 Sco

  • Heo, Jeong-Eun;Lee, Hee-Won;Lee, Ho-Gyu
    • 천문학회보
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    • 제40권1호
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    • pp.90.2-90.2
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    • 2015
  • We present the high-resolution spectrum of the S-type symbiotic star V455 Sco obtained with the Dupont telescope in 2014 June. We note that the Raman-scattered O VI ${\lambda}1032$ at $6825{\AA}$ exhibits a triple-peak profile. Adopting an accretion disk model with an additional contribution from a collimated bipolar outflow, we attempt to fit the profile. We propose that the blue and central peaks are formed via Raman-scattering of O VI line photons from the accretion flow and that the bipolar flow is responsible for the remaining red peak. It is also noted that V455 Sco exhibits the Raman-scattered He II features blueward of $H{\alpha}$ and $H{\beta}$.

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Preparation and Characterization of Silica-coated Gold Nanoflowers (AuNFs) with Raman Dye Encoding

  • Yoo, Jihye;Lee, Sang-Wha
    • Bulletin of the Korean Chemical Society
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    • 제35권9호
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    • pp.2765-2768
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    • 2014
  • Flower-like Au nanoparticles, so-called Au nanoflowers (AuNFs), were synthesized by simply adding ascorbic acid to a gold acid solution in the presence of a chitosan biopolymer. The chitosan-entangled AuNFs exhibited strong plasmon absorption in the near-infrared (NIR) wavelength due to the aggregation of primary Au nanoparticles. The chitosan-entangled AuNFs were preferentially adsorbed by Raman-active 2-chlorothiophenol (CTP) molecules, and the CTP-encoded AuNFs (AuNF-CTPs) were subsequently coated with a thin silica layer by a sol-gel reaction with Si alkoxides. The silica-coated AuNFs (AuNF-CTPs@silica) exhibited the distinct Raman signals of adsorbed CTP molecules, as a potential nanoprobe with surface-enhanced Raman scattering (SERS).

SERS Immunoassay Using Microcontact Printing for Application of Sensitive Biosensors

  • Hong, Won-Jin;Seo, Hyeong-Kuyn;Jung, Young-Mee
    • Bulletin of the Korean Chemical Society
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    • 제32권12호
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    • pp.4281-4285
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    • 2011
  • We introduced a promising patterned substrate by using a microcontact printing method that can be used for SERS immunoassays based on antigen-antibody binding. SERS spectrum of the Raman reporter with antibody, which is rhodamine 6G (R6G) adsorbed on colloidal gold nanoparticles, was observed only for the surfaces in which prostate-specific antigen (PSA) is present on the substrate that is attached to an immobilized layer of antibody on the gold nanoparticles layer of the patterned substrate. Raman mapping images clearly showed that the antibodies on the Raman reporter were successfully and selectively conjugated with the antigen on the patterned substrate. This method could be potentially extended to multi-protein detections and ultrasensitive biosensors.

Raman Scattered Ne $VII{\lambda}4881$ in the Symbiotic Star V1016 Cygni

  • Lee, Hee-Won;Heo, Jeong-Eun;Lee, Byeongcheol
    • 천문학회보
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    • 제39권1호
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    • pp.83.2-83.2
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    • 2014
  • We present the two high resolution spectra of the symbiotic star V1016 Cygni obtained with the Bohyunsan Optical Echelle Spectrograph in 2003 and 2005, from which we note the existence of the broad emission feature at 4881 ${\AA}$. We propose that this broad feature is formed from Raman scattering of Ne $VII{\lambda}973$ by atomic hydrogen. Thus far, the detection of Raman scattered lines by atomic hydrogen is limited to O $VI{\lambda\lambda}1032$, 1038 and He $II{\lambda\lambda}940$, 972 and 1025. We perform Monte Carlo simulations to fit the Raman scattered Ne $VII{\lambda}4881$ to investigate the basic spectroscopic properties concerning Ne $VII{\lambda}973$.

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Ge$O_2$-doped 다중모드 파이버에서 유도라만산한의 스토크스 펄스의 발생 (Evolution of stokes pulses of stimulated Raman scattering in a Ge$O_2$-doped multimode fiber)

  • Yi, Yong-Woo;Hwang, In-Duk
    • 한국정보통신학회:학술대회논문집
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    • 한국해양정보통신학회 2002년도 추계종합학술대회
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    • pp.529-532
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    • 2002
  • 본 논문은 1064 nm의 Q-스위칭 Nd:YAG로 펌핑된 단일통과 라만레이저에서 nano-초의 스토크스 펄스발생에 관한 연구이며, 라만 매질로는 GeO$_2$로 도핑된 grad index형 다중모드 파이버 220 m를 사용하였다. 실험 결과에서 펌핑 에너지의 변화에 따라 1.5~2.7 nano 초의 펄스폭을 갖는 스토크스 펄스 트레인 성분이 효율적으로 발생함을 알 수 있었다.

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비접촉식 지표면 화학 오염 탐지용 라만 분광시스템 설계 및 성능확인 (The Design and Test of the Stand-off Surface Chemical Contaminant Detection System based on Raman Spectroscopy)

  • 고영진
    • 한국군사과학기술학회지
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    • 제22권3호
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    • pp.433-440
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    • 2019
  • In order to detect toxic chemical spread on field ground, we developed stand-off Raman spectrometer system which employed a deep UV laser. In this paper, the design and specification of various components in the spectrometer system are described. Some results when the detection system was tested on the outdoor roads are shown, which may help researching stand-off chemical detectors based on Raman spectroscopy.

A New Grid-Based Monte Carlo Code for Raman Scattered He II: Preliminary Results

  • Chang, Seok-Jun;Choi, Bo-Eun;Lee, Hee-Won
    • 천문학회보
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    • 제44권1호
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    • pp.85.2-85.2
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    • 2019
  • We developed a new grid-based Monte Carlo code to trace far UV He II line photons that are incident on a thick H I region and subsequently transferred through Rayleigh and Raman scattering with atomic hydrogen. In particular, we consider a neutral region that is moving away from the He II emission source which is either monochromatic or is described by a Gaussian profile. The resultant Raman scattered He II line profiles from a monochromatic source are characterized by a double peaked core part with an extended Raman red tail that is attributed to multiple re-entry events. Complicated behaviors are observed in the case of a Gaussian He II source including the formation of a secondary red peak near the Balmer center dependent on the H I column density. A preliminary application of our results to the CFHT data of the planetary nebula IC 5117 is presented.

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대기 온도 측정용 회전 라만 라이다 시스템의 설계 (Designing of Rotational Raman Lidar system measuring Atmospheric Temperature)

  • 김덕현;차형기;이종민
    • 한국광학회:학술대회논문집
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    • 한국광학회 2000년도 하계학술발표회
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    • pp.208-209
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    • 2000
  • 라이다 방법을 이용한 대기의 온도 측정은 크게 1) DIAL 방법을 이용하는 방법 2) 공기분자의 밀도를 측정하는 진동 라만 산란을 이용하는 방법 3)공기분자의 회전 라만 산란을 이용하는 방법 4) Rayleigh 산란의 선폭을 이용하는 방법 등으로 나누어진다. 이 중에서 대류권의 온도 측정에 적용가능한 방법은 3 번째의 방법으로 질소나 산소의 회전 라만 산란(RRS:Rotational Raman Scattering)이 가장 흔히 사용되는 기술이다. 질소와 산소의 회전 라만 신호를 이용한 온도 측정 기술은 Cohen$^1$ 등에 의하여 처음 시도되었으며, 그 후 많은 사람들에 의하여 검증되었다.$^2$ (중략)

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Adsorption of 2-Cyanonaphthalene on Silver Sol Investigated by Raman Spectroscopy$^\dag$

  • 박성현;이은아;장두전;김명수;김관
    • Bulletin of the Korean Chemical Society
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    • 제16권2호
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    • pp.130-134
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    • 1995
  • Surface-enhanced Raman (SER) scattering of 2-cyanonaphthalene (2-CN) has been investigated in silver sol. Addition of halide ions was needed to obtain authentic SER spectra of the molecule. The SER spectra thus obtained exhibited a slight but noticeable dependence on the kind of halide ions used. This halide-dependent spectral variation was attributed to the orientational change of molecule on silver sol surface. A possible mechanism for such an orientational change is proposed in terms of the competitive adsorption of 2-CN with halide ions on the so-called halide-specific sites.

Raman Spectroscopic Study of Benzonitrile on Silver Surface

  • Boo, Doo-Wan;Kim, Kwan;Kim, Myung-Soo
    • Bulletin of the Korean Chemical Society
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    • 제8권4호
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    • pp.251-254
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    • 1987
  • The surface-enhanced Raman scattering(SERS) of benzonitrile in a silver sol was investigated. It was concluded that the molecule adsorbed onto the silver surface via the nitrogen lone pair electrons. Using the surface selection rule, the orientation of the benzene ring with respect to the surface plane could not be determined conclusively. However, it seemed likely that benzonitrile is adsorbed edge-on to the surface. It was demonstrated that the SERS technique provides a useful method for detailed characterization of the chemisorbed layer.