• 제목/요약/키워드: Radiation stability

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In Situ X-ray Photoemission Spectroscopy Study of Atomic Layer Deposition of $TiO_2$ on Silicon Substrate

  • Lee, Seung-Youb;Jeon, Cheol-ho;Kim, Yoo-Seok;Kim, Seok-Hwan;An, Ki-Seok;Park, Chong-Yun
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.08a
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    • pp.222-222
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    • 2011
  • Titanium dioxide (TiO2) has a number of applications in optics and electronics due to its superior properties, such as physical and chemical stability, high refractive index, good transmission in vis and NIR regions, and high dielectric constant. Atomic layer deposition (ALD), also called atomic layer epitaxy, can be regarded as a special modification of the chemical vapor deposition method. ALD is a pulsed method in which the reactant vapors are alternately supplied onto the substrate. During each pulse, the precursors chemisorb or react with the surface groups. When the process conditions are suitably chosen, the film growth proceeds by alternate saturative surface reactions and is thus self-limiting. This makes it possible to cover even complex shaped objects with a uniform film. It is also possible to control the film thickness accurately simply by controlling the number of pulsing cycles repeated. We have investigated the ALD of TiO2 at 100$^{\circ}C$ using precursors titanium tetra-isopropoxide (TTIP) and H2O on -O, -OH terminated Si surface by in situ X-ray photoemission spectroscopy. ALD reactions with TTIP were performed on the H2O-dosed Si substrate at 100$^{\circ}C$, where one cycle was completed. The number of ALD cycles was increased by repeated deposition of H2O and TTIP at 100$^{\circ}C$. After precursor exposure, the samples were transferred under vacuum from the reaction chamber to the UHV chamber at room temperature for in situ XPS analysis. The XPS instrument included a hemispherical analyzer (ALPHA 110) and a monochromatic X-ray source generated by exciting Al K${\alpha}$ radiation (h${\nu}$=1486.6 eV).

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A Study on the Shielding Analysis in Vitrification Facility of Low-and Intermediate Level Radioactive Wastes ($\cdot$저준위 방사성폐기물 유리화 시설의 차폐해석에 관한 연구)

  • 이창민;이건재;지평국;박종길;하종현;송명재
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2003.11a
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    • pp.524-531
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    • 2003
  • The usefulness of vitrification technology for low- and intermediate- level radioactive wastes was demonstrated because of high volume reduction, mechanical and chemical stability of final waste forms. Thus, a construction of the commercial vitrification plant Is currently promoted. Due to the high radiation level of the waste, shielding analysis has to be carried out for safe design in a vitrification facility. Because there has been no experience in the construction and operation of the vitrification facility in Korea, in this study, in order to get some information for help the detailed design and plan for operation in vitrification facility, shielding analysis for each facility in pilot plant is carried out by using source term from established study. For the selection of the shielding material, concrete was chosen compared to the lead because of economic advantage, weight consideration, and thermal resistance.

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Nitrogen을 도핑시킨 Ge-Sb-Te 박막의 광전자 및 광흡수 분광학 연구

  • Sin, Hyeon-Jun;Jeong, Min-Cheol;Kim, Min-Gyu;Lee, Yeong-Mi;Kim, Gi-Hong;Jeong, Jae-Gwan;Song, Se-An;Sun, Zhimei
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.02a
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    • pp.186-186
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    • 2013
  • Nitrogen doped Ge-Sb-Te (N-GST) thin films for phase change random access memory (PRAM) applications were investigated by synchrotron-radiation-based x-ray photoelectron spectroscopy and absorption spectroscopy. Nitrogen doping in GST resulted in more favorable N atoms' bonding with Ge atoms rather than with Sb and Te atoms [1,2], which explains the higher phase change transition temperature than that of undoped Ge-Sb-Te thin film. Surprisingly, it was noticed that N atoms also existed in the form of molecular nitrogen, $N_2$, which is detrimental to the stability of the GST performance [3]. N-doped GST experimental features were also supported by ab-initio molecular dynamic calculations [2]. References [1] M.-C. Jung, Y. M. Lee, H.-D. Kim, M. G. Kim, and H. J. Shin, K. H. Kim, S. A. Song, H. S. Jeong, C. H. Ko, and M. Han, "Ge nitride formation in N-doped amorphous Ge2Sb2Te5", Appl. Phys. Lett. 91, 083514 (2007). [2] Zhimei Sun, Jian Zhou, Hyun-Joon Shin, Andreas Blomqvist, and Rajeev Ahuja, "Stable nitride complex and molecular nitrogen in N doped amorphous Ge2Sb2Te5", Appl. Phys. Lett. 93, 241908 (2008). [3] Kihong Kim, Ju-Chul Park, Jae-Gwan Chung, and Se Ahn Song, Min-Cherl Jung, Young Mi Lee, Hyun-Joon Shin, Bongjin Kuh, Yongho Ha, Jin-Seo Noh, "Observation of molecular nitrogen in N-doped Ge2Sb2Te5", Appl. Phys. Lett. 89, 243520 (2006).

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Design and Fabrication of the Antenna for Wibro and WLAN Communications Using CPWG Structure (CPWG 구조를 이용한 Wibro 및 WLAN 통신용 안테나 설계 및 제작)

  • Lee, Seung-Woo;Kim, Nam;Rhee, Seung-Yeop
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.19 no.10
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    • pp.1086-1095
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    • 2008
  • In this paper, we designed and fabricated the trapezoidal antenna using the CPWG structure for Wibro and WLAN communications. This antenna has broadband characteristics using the basic trapezoidal antenna, and an H-shaped parasitic patch is making an expansion of resonance bandwidth and bringing stability of impedance matching. Especially, CPWG structure is combined two kinds of the structure which of a monopole antenna and a coplanar waveguide antenna. They make up for the weak point of the CPW which is variation of impedance matching according to varying the gap or size of the feed line and the ground. The designed antenna has occurred resonances of which the band of 2.2 GHz to 4.6 GHz(70.5 %) below the return loss of -10 dB($VSWR{\leq}2$) obtained in measurement, and it has an omnidirectional radiation pattern of H-plane. In addition, the changes of impedance matching appear slightly caused by the effects of the ground plane and the feed line.

The study on oriental and western medicine of esophagitis (식도염(食道炎)에 대(對)한 동서의학적(東西醫學的) 고찰(考察))

  • Choi, Chang-woo;Son, Chang-gyu;Cho, Chong-kwan
    • Journal of Haehwa Medicine
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    • v.10 no.2
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    • pp.91-96
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    • 2002
  • We arrived at the following conclusions after we have studied esophagitis through the literatures of oriental and western medicine. 1. The western medical causes of acute esophagitis are corrosiveness chemical material, esophageal or gastric disease, trauma, blister stomatitis, filamentous fungus infection and uremia of chronic patient etc, and the oriental medical causes are qi and blood stagnation, blood stasis and stagnation, stagnant phlegm by coldness, heating, dyspepsia and food poisoning etc. 2. The western medical causes of chronic esophagitis are malfunction of lower esophageal sphincter, esophageal tom chink and hernia, increase of gastric pressure by overeating, fatness, pregnancy and ascites etc, and the oriental medical causes are asthenic cardiac qi, hepatic qi attacking stomach by seven kinds of depression, cold-damp stagnation and insufficiency of gastric qi by overeating, excessive drinking and sexual indulgence etc. 3. The main symptoms of acute esophagitis are severe chest pain, instantly vomiting, swallowing pain etc, and chronic esophagitis are occasionally light chest pain, heart bum, anorexia, dysphagia, dizziness, general body weakness etc. These symptoms are come under thoracic obstruction, acid regurgitation, vomiting and chest pain of oriental medicine. 4. The western medical diagnoses of acute and chronic esophagitis have used radiation test, esophageal endoscopy, esophageal pressure test and biopsy etc, and the oriental medical diagnoses have used syndrome differentiation by four examination of inspection, listening and smelling examination, inquiring, pulse-taking and palpitation. 5. The western medical treatments of acute esophagitis have regarded preservation stability of esophagus as a principle, and the oriental medical treatments mainly have used expelling pathogen of expelling cold and regulating qi, cooling and removing stasis, promoting blood circulation to remove blood stasis, eliminating phlegm and regulating qi. 6. The western medical treatments of chronic esophagitis have regarded decrease flowing backward of gastric juice as a purpose, and the oriental medical treatments mainly have used strengthening body resistance of replenishing and strengthening cardioqi, dispersing stagnated hepatoqi, expelling cold and dehygrosis, invigorating stomach and nourishing qi.

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Radiation Technology in the Preparation of Polyethylene Oxide Hydrophilic Gels and Immobilization of Proteases for Use in Medical Practice

  • E.I.Vereschagin;Han, Do-Hung;A.W.Troitsky;O.V.Grishin;S.E.Petrov;E.P.Gulyaeva;L.A.Bogdanova;M.V.Korobeinikov;V.L.Auslender
    • Archives of Pharmacal Research
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    • v.24 no.3
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    • pp.229-233
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    • 2001
  • This Paper deals with the development of a technology for making a hydrophilic gel of Polyethylene oxide reception in which radiating ability is employed to cause cross-linking of Polymers in a water solution. The gel of polyethylene oxide was shown to be nontoxic contain 5-50% of polymer and be useful in composite medicinal forms along with biologically active substances including Bac. subtilis proteases. Proteases immobilized in the gel possess high thermal stability and proteolytic activity and are readily applied in medicine. The effect of immobilized proteolytic and glucolytic enzymes of Bac. subtillis (Immozimase) on the warm ischemia-reperfusion (I/R) which can cause hepatic and jejunum injury was also studied. These enzymes were immobilized on water-soluble polymer polyethylene glycol by means of an electron beam. The number of degraanulated mast cells as well as serum ALT after I/R in the group with Immozimase was decreased to almost half as compared with the control group. Pretreatment with Immozimase resulted in significant reduction of hepatic and gut neutrophil accumulation as compared with control animals. It was concluded that Immozimase has a protective effect for hepatic and gut ischemia/reperfusion, and this effect seems to be associated with prevention of leukocyte accumulation .

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A New Evaluation Method of UV Curing Process by Using Electrical Properties (전기적 특성을 이용한 UV 경화 프로세스에 대한 새로운 평가방법)

  • Lee, Mun-Hag;Kim, Sung-Bin;Son, Se-Mo;Cheon, Jae-Kee
    • Korean Chemical Engineering Research
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    • v.43 no.3
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    • pp.393-400
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    • 2005
  • A novel evaluation method was investigated for measuring the ability of acid amplification of acid amplifier. The method was based on the measurement of conductivity change by the acid generation according to UV radiation. It was found that the decrease of conductivity was caused by photopolymerization of epoxy monomer during UV curing process of ink film and by the rate of UV curing. In this paper, the novel acid amplifiers were synthesized and measured thermal stability by means of DSC. It was found that mono-type acid amplifiers were more stable than di-type. It was possible to make the dynamical evaluation of the curing rate of UV curable ink in curing process by this method.

Development of a Fast Neutron Detector (속중성자 탐지용 반도체 소자 개발)

  • 이남호;김승호;김양모
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.52 no.12
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    • pp.545-552
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    • 2003
  • When a Si PIN diode is exposed to fast neutrons, it results in displacement damage to the Si lattice structure of the diode. Defects induced from structural dislocation become effective recombination centers for carriers which pass through the base of a PIN diode. Hence, increasing the resistivity of the diode decreases the current for the applied forward voltage. This paper involves the development of a neutron sensor based on the phenomena of the displacement effect damaged by neutron exposure. The neutron effect on the semiconductor was analyzed. Several PIN diode arrays with various thickness and cross-section area of the intrinsic layer(I layer) were fabricated. Under irradiation tests with a neutron beam, the manufactured diodes have a good linearity to neutron dose and show that the increase of thickness of I layer and the decrease of cross-section of PIN diodes improve the sensitivity. Newly developed PIN diodes with thicker I layer and various cross section, were retested and then showed the best neutron sensitivity at the condition that the I layer thickness was similar to a side length. On the basis of two test results, final discrete PIN diodes with a rectangular shape were manufactured and the characteristics as neutron detectors were analyzed through the neutron beam test using on-line electronic dosimetry system. Developed PIN diode shows a good linearity as dosimetry in the range of 0 to 1,000cGy(Tissue) and its neutron sensitivity is 13mV/cGy at constant current of 5mA, that is three times higher than that of commercially available neutron detectors. And the device shows little dependency on the orientation of the neutron beam and a considerable stability in annealing test for a long period.

Study on Pre-treatment Method for Vitrification of Concentrated Wastes (농축폐기물 유리화를 위한 전처리 방안 연구)

  • Cho, Hyun-Je;Kim, Deuk-Man;Park, Jong-Kil
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.8 no.3
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    • pp.221-227
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    • 2010
  • The solidification methods for powder wastes dried at CWDS(Concentrate Waste Drying System) in PWR have been studied in a variety of ways both at home and abroad. The solidification for these wastes has been performed using stabilization agents such as cement, paraffin and polymer. The applicability studies to maximize the reduction ratio of wastes and operational effectiveness for wastes treatment have been carried out, recently. It is necessary to pretreat the powder wastes before feeding wastes to vitrification facility because the fines flying brings about clogging of feeding pipes and off-gas treatment system or workers' exposure to radiation during maintenance. This paper describes an effective method for treatment of powder wastes to improve safety and stability of vitrification facilities.

Characterization of Rhizophora SPP. particleboards with SOY protein isolate modified with NaOH/IA-PAE adhesive for use as phantom material at photon energies of 16.59-25.26 keV

  • Samson, Damilola Oluwafemi;Shukri, Ahmad;Mat Jafri, Mohd Zubir;Hashim, Rokiah;Sulaiman, Othman;Aziz, Mohd Zahri Abdul;Yusof, Mohd Fahmi Mohd
    • Nuclear Engineering and Technology
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    • v.53 no.1
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    • pp.216-233
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    • 2021
  • In this work, Rhizophora spp. particleboard phantoms were made using SPI-based adhesives, modified with sodium hydroxide and itaconic acid polyamidoamine-epichlorohydrin (0, 5, 10, and 15 wt%). An X-ray computed tomography (CT) imaging system was used to ascertain the CT numbers and density distribution profiles of the particleboards. The SPI-based/NaOH/IA-PAE/Rhizophora spp. particleboard phantoms with 15 wt% IA-PAE addition level had the highest solid content, flexural strength, flexural modulus, and internal bonding strength of 36.06 ± 1.08%, 18.61 ± 0.38 Nmm-2, 7605.76 ± 0.89 Nmm-2, and 0.463 ± 0.053 Nmm-2, respectively. The moisture content, mass density, water absorption, and dimensional stability were 6.93 ± 0.27%, 0.962 ± 0.037 gcm-3, 22.36 ± 2.47%, and 10.90 ± 0.86%, respectively. The results revealed that the mass attenuation coefficients and effective atomic number values within the 16.59-25.26 keV photon energy region, were close to the calculated XCOM values in water, with a p-value of 0.077. Moreover, the CT images showed that the dissimilarities in the discrepancy of the profile density decreased as the IA-PAE concentrations increased. Therefore, these results support the appropriateness of the SPI-based/NaOH/IA-PAE/Rhizophora spp. particleboard with 15 wt% IA-PAE adhesive as a suitable tissue-equivalent phantom material for medical health applications.