• 방사선산업학회지
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• 제8권1호
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• pp.53-57
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• 2014

The kenaf is quickly developing as a renewable resource. Kenaf can be grown under a wide range of weather conditions. Modification of kenaf fiber by graft polymerization provides a significant route to alter the chemical properties, including surface hydrophilicity or hydrophobicity. In this study, kenaf fiber surfaces were grafted with acrylic acid as a hydrophilic group using electron beam irradiation. The grafting rate increased with an increase in grafting time. The FT-IR results confirmed that acrylic acid was successfully grafted onto the kenaf fibers. The wettability of the kenaf fiber was increased, accompanied by acylic acid grafting on the fiber surface. According to the permeability test result, it was found that acrylic acid grafted kenaf fiber reinforced cement composite was more reduced than non-grafted kenaf fiber reinforced cement composite.

• 방사선산업학회지
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• 제7권1호
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• pp.23-28
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• 2013

In this study, we fabricated high density polyethylene (HDPE) composites filled with antioxidants and UV stabilizers. The electron beam irradiation on the fabricated composites was carried out over a range of absorbed doses from 50 to 200 kGy to confirm the changes of discoloration. The changes of discoloration were characterized using a color difference meter and FT-IR for confirming the changes of the color difference and structural change. It was observed that the color difference of IRGANOX 1010-, IRGAFOS 168-, and TINUVIN 328- added HDPE was higher than that of the control HDPE by electron beam irradiation. The melting temperature of UV stabilizer-added HDPE was not significantly changed by electron beam irradiation. However, the melting temperature of phenol-containing antioxidant-added HDPE was increased with increasing the absorbed dose. And the melting temperature of phosphorus-containing antioxidant-added composite was decreased with increasing the absorbed dose.

• 방사선산업학회지
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• 제5권4호
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• pp.353-357
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• 2011

Degradation of p-nitrophenol has been carried out using only gamma irradiation or gamma irradiation with $H_2O_2$ or $Na_2S_2O_8$. Effects of different operating parameters such as initial concentration ($50mg\;l^{-1}$, $100mg\;l^{-1}$, $200mg\;l^{-1}$, $300mg\;l^{-1}$, $400mg\;l^{-1}$, $500mg\;l^{-1}$ and $600mg\;l^{-1}$) on the extent of degradation has been investigated. At 5 kGy, $50mg\;l^{-1}$ p-nitrophenol was completely degraded, and the radiolytic degradation of p-nitrophenol was described by the pseudo-first-order kinetic model. The combination of gamma irradiation with $H_2O_2$ or $Na_2S_2O_8$ leads to an enhanced effect, which remarkably increased the degradation efficiency of p-nitrophenol and TOC removal. However, at high $H_2O_2$ concentration, the efficacy of p-nitrophenol degradation is reduced because ${\cdot}OH$ radicals are scavenged by $H_2O_2$ and $Na_2S_2O_8$.

• 방사선산업학회지
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• 제6권4호
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• pp.317-322
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• 2012

In this study, the preparation of a temperature-responsive poly(N-isopropylacrylamide) (PNIPAAm)-grafted surface was performed using an eco-friendly and biocompatible ion beam-induced surface graft polymerization. The surface of a perfluoroalkoxy (PFA) film was activated by ion implantation and N-isopropylacrylamide (NIPAAm) was then graft polymerized selectively onto the activated regions of the PFA surfaces. Based on the results of the peroxide concentration and grafting degree measurements, the amount of the peroxide groups formed on the implanted surface was dependant on the fluence, which affected the grafting degree. The results of the FT-IR-ATR, XPS, and SEM confirmed that the NIPAAm was successfully grafted onto the implanted PFA. Moreover, the contact angle measurement at different temperatures revealed that the surface of the PNIPAAm-grafted PFA film was temperature-responsive.

• 폴리머
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• 제31권6호
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• pp.512-517
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• 2007

[ $Co_{60}\;{\gamma}-ray$ ] 방사선 조사법을 이용하여 kapok 섬유에 styrene, glycidylmethacrylate(GMA) 또는 acrylic acid(AAc)를 그래프트 공중합 반응하여 합성한 공중합체의 그래프트율은 단량체의 농도와 방사선 조사량에 따라 증가하는 것으로 나타났으며, 또한 합성된 이온교환 섬유의 도입된 관능기를 확인하고 이온교환 능을 측정하였으며, SEM과 FT-IR을 통하여 이온교환 섬유의 표면과 구조를 분석하였다.

• 폴리머
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• 제34권1호
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• pp.74-78
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• 2010

본 연구에서는 다양한 전류조건하에 전자선 조사로 가교된 리튬 이차전지용 폴리에틸렌 분리막을 제조하였다. 제조된 폴리에틸렌 분리막의 가교율은 조사량이 증가할수록 그리고 빔 전류가 낮을수록 증가하여 최대 71%까지 증가하였다. 낮은 빔 전류에서 조사된 폴리에틸렌 분리막은 상용 분리막 보다 우수한 열수축률(51%) 및 기계적 특성을 보여주었다. 가교된 분리막의 이온전도도는 $1.01{\times}10^{-3}\;S/cm$와 전해액 함침률(275%)은 조사되지 않은 분리막과 거의 동일하였다.

• 방사선산업학회지
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• 제6권1호
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• pp.11-15
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• 2012

This study confirmed the cytotoxicity and anti-inflammatory activities of natural herbal extracts (HE) including Eucommia ulimoides and Ulmus davidiana against human mast cell (HMC-1). HE was extracted with distilled water (at $75^{\circ}C$) and then freeze-dried for 5 days. Finally, the HE was sterilized by gamma radiation with $^{60}Co$ ${\gamma}$ source at room temperature. Cytotoxicity of the HE against HMC-1 cell was measured using cell counting kit-8 (CCK-8) assay. In addition, inflammatory cytokines such as $TNF-{\alpha}$, IL-6 and IL-8 were evaluated by ELISA kit on the HMC-1 cells with calcimycin A23187 and phorbol 12-myristate 13-acetate (PMA). The results showed that HE had no toxicity and reduced $TNF-{\alpha}$, IL-6, IL-8 response on HMC-1 cells.

• 방사선산업학회지
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• 제4권3호
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• pp.259-263
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• 2010

Carbon fibers are used as a reinforcement material in an epoxy matrix in advanced composites due to their high mechanical strength, rigidity and low specific density. An important aspect of the mechanical properties of composites is associated to the adhesion between the surface of the carbon fiber and the epoxy matrix. This paper aimed to evaluate the effects of electron beam irradiation on the physicochemical properties of carbon fibers to obtain better adhesion properties in resultant composite. Chemical structure and surface elements of carbon fiber were determined by FT-IR, elemental analysis and X-ray photoelectron spectroscopy, which indicated that the oxygen content increased significantly with increasing the radiation dose. Thermal stability of the carbon fibers was studied via the thermalgravimetric analysis. Surface morphology of carbon fiber was analyzed by scanning electron microscope. It was found that the degree of surface roughness was increased by electron beam irradiation.

• 방사선산업학회지
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• 제5권1호
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• pp.69-73
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• 2011

Polyamide 66 (PA66) nanofibers with Triallyl cyanurate (TAC) were obtained by electrospinning of formic acid and chloroform solution. Electron beam irradiation of PA66 nanofiber with and without TAC was carried out over a range of absorbed doses (20~100 kGy) in nitrogen. The characterization of the irradiated PA66 nanofibers and PA66 nanofibers with TAC was done by scanning electron microscopy (SEM), nuclear magnetic resonance (NMR), thermogravimetric analysis (TGA) and universal testing machine (UTM). The results of the SEM image analysis confirmed that the morphology of PA66 nanofibers was not altered by electron beam. The amount of TAC in PA66 nanofiber with TAC was identified by $^1H-NMR$ analysis. The degradation temperature of PA66 nanofibers with TAC at an absorbed dose of 20~100 kGy was higher than the irradiated PA66 nanofiber without TAC. On the other hand, the decreasing rate of modulus of irradiated PA66 nanofibers with TAC was less than PA66 nanofibers.

• 방사선산업학회지
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• 제4권3호
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• pp.271-276
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• 2010

Epoxy resin has wide application in various industrial fields because of their good mechanical strength, superiority adhesion and low shrinkage etc. And the typical curing method for epoxy resins is thermal and press compaction. However, a curing method was used electron beam process in this study. Epoxy acrylate was fabricated from mixture of epoxy, acrylic acid, tetraphenylporphyrin (TPP) and hydroquinone monomethyl ether (MEHQ) with mole ratios. Then electron beam irradiation effect on the curing of the epoxy acrylate resin was investigated various absorption dose in nitrogen atmospheres at room temperature. The dynamic mechanical and thermal properties of the irradiated epoxy acrylate resins were characterized using dynamic mechanical analysis (DMA) and thermogravimetric analyzer (TGA). And the tensile and flexural strength were measured by an universal tensile machine (UTM).