• 폴리머
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• 제27권5호
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• pp.470-476
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• 2003

고굴절률을 갖는 플라스틱 재료를 얻기 위하여 1,2-에틸렌디설파닐비스(2-머캅토메틸-1-에탄티올) (ESTT)을 1,2-에틸렌디설파닐비스(2-브로모메틸-1-에탄티올) (ESTB)과 티오우레아의 반응과 암모니아 용액으로 가수분해 반응을 해서 높은 수율로 새로이 합성하였고, $^1$H-NMR, $^{13}$C-NMR, FT-IR및 Mass Specooscopy 등에 의해 1.7 ppm에서 -SH, 28.4 ppm에서 -CH$_2$SH, 2540 $cm^{-1}$ /에서 -SH등의 관능기 구조를 확인하였다. 이어서, 폴리티오우레탄 (PTU)들은 디부틸틴 디라울레이트 존재하에서 ESTT와 4,4＇-메틸렌비스(페놀이소시아네이트) (MDI), 톨릴렌 2,4-디이소시아네이트 (TDI), 이소포론 디이소시아네이트 (IPDI), m-자일렌디이소시아네이트 (XDI) 및 1,6-디이소시아네이토헥산 (HMDI) 등을 일정한 틀에 넣고 주형중합을 하고, FT-IR로 N=C=O의 존재를 확인하였다. 이어서, PTU 수지들의 열적, 기계적 및 광학적 성질을 살펴보기 위하여 열주사분석 (DSC)과 열중량분석 (TGA), 경도 및 굴절률 측정 등을 행하여, PTU 시편들이 DSC상에서 융점이 없고 XRD상으로 무정형임을 관찰하였다. 또, 110 $^{\circ}C$ 이상의 유리 전이 온도를 갖는 PTU 수지들은 86∼89 범위의 양호한 경도 (Shore D)를 나타냈으며, 방향족 고리를 함유하는 디이소시아네이트와 ESTT를 원료로 했던 PTU수지들의 내열성이 특별히 양호하였다. 무정형 PTU 수지들은 400∼600 m 범위의 UV-vis 광원에 의한 광투과율 들도 양호하게 나타났다. PTU 수지들은 1.60 이상의 굴절률을 보였으며, 황함량이 증가하면 굴절률도 점차 증가하는 것이 관찰되었다.

• 한국산학기술학회논문지
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• 제18권12호
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• pp.793-798
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• 2017

현대의 함정에서는 추진 기관에서 생성된 고온의 폐기가스와 가열된 폐기관의 금속표면온도를 저감하기 위해 적외선 신호저감 장치(Infra-red Signature Suppression system, IRSS)를 설치하고 있다. 국내 함정에 탑재된 일반적인 IRSS는 이덕터, 믹싱튜브 그리고 디퓨져로 구성되며, 이 중 디퓨져는 금속표면에 내기 외기의 압력차에 의한 공기 막을 생성시켜 온도를 저감시키는 역할을 한다. 본 연구에서는 국외 선진 기술사에서 설계한 IRSS의 디퓨져 형상을 분석하여 설계 변수를 선정하였으며, 분석 조건을 줄이면서 설계 변수의 특성을 효과적으로 파악 할 수 있는 다구치 실험계획법을 통해 IRSS 디퓨져의 성능에 영향을 미치는 설계 변수의 특성을 검토하였다. 디퓨져의 성능분석에는 선행 연구에서 정립한 열 유동해석 기술을 활용하였다. IRSS의 성능평가에는 함정 적외선 신호의 세기와 직접적으로 관련되는 디퓨져 출구에서의 폐기가스 온도와 금속표면온도의 면적평균 값을 기준으로 하였으며, 폐기가스의 온도는 디퓨져 출구의 직경 변화에 크게 영향을 받고, 디퓨져 금속표면의 온도는 디퓨져 링의 개수 변화에 크게 영향 받음을 확인하였다.

• 한국산림과학회지
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• 제65권1호
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• pp.48-53
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• 1984

과거(過去)에 솔잎혹파리 피해(被害)를 받은 바 있는 충청남도(忠淸南道) 서천군(舒川郡) 비인(庇仁)과 피해(被害)를 받지 않은 충청남도(忠淸南道) 홍성군(洪城郡) 장곡(長谷) 자생(自生)하고 있는 13년생내외(年生內外) 소나무의 연륜(年輪)을 Duff와 Nolan(1953)의 방법(方法)으로 비교(比較)한 바 다음과 같은 결과(結果)를 얻었다. 1) 건전(健全)한 소나무연륜(年輪)의 사선계열(斜線系列)에서 하나의 생장(生長) Pattern이 발견(發見)된다. 그러나 수선계열(垂線系列)을 위시(爲始)한 각(各) 계열(系列)에서 나무가 성장(成長)함에 따라 연륜폭(年輪幅)이 점차 증가(增加)하는 경향(傾向)도 볼 수 있었다. 2) 솔잎혹파리로 인(因)한 연륜생장저해(年輪生長沮害)는 수간기부(樹幹基部)의 수평선계열(水平線系列)에서는 발견(發見)되지 않았으나 기타계열(其他系列)에서는 모두 쉽게 식별(識別)해낼 수 있었다. 3) 경미(輕微)한 피해(被害)를 받았을 때나 생장저해(生長沮害)가 발생(發生)하는 초년도(初年度)를 판단(判斷)하기 위하여는 사선계열(斜線系列)이 가장 유용(有用)할 것으로 고찰(考察)되었다.

• 보존과학회지
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• 제30권1호
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• pp.95-101
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• 2014

은제품은 대기의 아황산가스나 황화수소 등과 반응하여 검게 변색된다. 검은 변색은 표면에 황화은이 형성되는 것으로 보존처리시 제거하는 것이 일반적이다. 황화은을 제거하는 방법은 화학적, 전기화학적, 미세마모법 등을 사용하지만 모두 은의 손실을 초래한다. 따라서 본 연구는 표면 오염물만을 선택적으로 제거할 수 있는 레이저클리닝을 은시편에 실험하여 안전하고 효율적인 레이저 조건을 알아보고자 하였다. 먼저 부식되지 않은 순수한 은에 레이저를 조사하여 안전한 레이저에너지밀도 범위를 확인하였다. 실험 결과 은은 1064nm $4.00J/cm^2$ 이하, 532nm $2.39J/cm^2$ 이하 레이저에너지밀도 범위에서 안전하였다. 인공적으로 부식시킨 은판의 부식층(황화은)은 레이저조건 1064nm $2.39J/cm^2$로 약 5~10회, 532nm $1.19J/cm^2$로 5~10회 조사하였을 때 제거되었다. AES를 이용하여 레이저 펄스당 제거되는 부식층 두께를 확인한 결과 약 13 ~ 25nm이다. 은 시편의 레이저클리닝 조건을 은제품에 적용한 결과 표면의 검은 부식층이 제거되었으며 은 광택도 유지되었다. 이를 통해 은제품의 레이저클리닝 적용 가능성을 확인하였다.

• The Korean Journal of Physiology and Pharmacology
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• 제4권6호
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• pp.471-477
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• 2000

In the rabbit renal artery, acetylcholine $(ACh,\;1\;nM{\sim}10\;{\mu}M)$ induced endothelium-dependent relaxation of arterial rings precontracted with norepinephrine $(NE,\;1\;{\mu}M)$ in a dose-dependent manner. $N^G-nitro- L-arginine$ (L-NAME, 0.1 mM), an inhibitor of NO synthase, or ODQ $(1\;{\mu}M),$ a soluble guanylate cyclase inhibitor, partially inhibited the ACh-induced endothelium-dependent relaxation. The ACh-induced relaxation was abolished in the presence of 25 mM KCl and L-NAME. The cytochrome P450 inhibitors, 7- ethoxyresorufin $(7-ER,\;10\;{\mu}M),$ miconazole $(10\;{\mu}M),$ or 17-octadecynoic acid $(17-ODYA,\;10\;{\mu}M),$ failed to inhibit the ACh-induced relaxation in the presence of L-NAME. 11,12-epoxyeicosatrienoic acid $(11,12-EET,\;10\;{\mu}M)$ had no relaxant effect. The ACh-induced relaxation observed in the presence of L-NAME was significantly reduced by a combination of iberiotoxin $(0.3\;{\mu}M)$ and apamin $(1\;{\mu}M),$ and almost completely blocked by 4-aminopyridine (5 mM). The ACh-induced relaxation was antagonized by $P_{2Y}$ receptor antagonist, cibacron blue $(10\;and\;100\;{\mu}M),$ in a dose-dependent manner. Furthermore, 2-methylthio-ATP (2MeSATP), a potent $P_{2Y}$ agonist, induced the endothelium-dependent relaxation, and this relaxation was markedly reduced by either the combination of iberiotoxin and apamin or by cibacron blue. In conclusion, in renal arteries isolated from rabbit, ACh produced non-NO relaxation that is mediated by an EDHF. The results also suggest that ACh may activate the release of ATP from endothelial cells, which in turn activates $P_{2Y}$ receptor on the endothelial cells. Activation of endothelial $P_{2Y}$ receptors induces a release of EDHF resulting in a vasorelaxation via a mechanism that involves activation of both the voltage-gated $K^+$ channels and the $Ca^{2+}-activated\;K^+\;channels$. The results further suggest that EDHF does not appear to be a cytochrome P450 metabolite.

• Journal of the Korean Wood Science and Technology
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• 제18권4호
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• pp.65-78
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• 1990

For the purpose of Improving the sounding boards for the conventional GAYAKUM, I was making approximately 202 specimens of radial board, 371 specimens of tangential board by cutting along the grain and the part of stem and 31 specimens of the disjointed traditional GAYAKUM made in Paulownia coreana. And it was conducted to measure specific gravity, dynamic Young's modulus, internal friction, resonant frequency, velosity of sound and width of annual ring by the method of the frexural vibration in a free-free bar in the audio frequency range. And it confirmed the juvenile wood by measuring wood fiber length of specimens. It was also conducted to investigate dynamic properties and moisture absorption by various heat-treatment and to test dynamic Young's modulus and internal friction for the disjointed conventional GAYAKUM. The results obtained were summarized as follow: 1. The Juvenile wood is located within about 7 annual rings from the pith in Paulownia coreana. 2. As increased with the specific gravity, the dynamic Young's modulus had more and more increased, but the internal friction had slightly decreased. 3. I think that radial board would be good for sounding board wood. because radial board is higher than tangential board in dynamic Young's mudulus and internal friction is lower than tangential board. 4. The value of mean dynamic Young's modulus on the conventional GAYAKUM, radial board and tangential board of 604 samples is $0.4283\pm0.037(\times10^{11}dyne/cm^2)$, $0.4316\pm(\times10^{11}dyne/cm^2)$ and $0.4234\pm0.112(\times10^{11}dyne/cm^2)$ respectively. The value of the radial board showed little higher than that of conventional GAYAKUM, but It had a similar tendency between conventional GAYAKUM and tangential board. 5. The annual ring width by four aspect is more narrow in north and west than that of others. 6. The values of specific gravity and dynamic Young's modulus in the mature wood showed higher than those of juvenile wood. 7. As the grain angle in the butt wood more increased to bark from pith, the dynamic Young's modulus were low. Then it was not good for sounding board. 8. It appeared that the heat-treatment for sounding board wood had a more effect to do the treatment of hotiron on surface after heat-treatment during 24 hours in $60^{\circ}C$ temperature. 9. As increased with the temperature, the rate of moisture absorption of heat-treatment wood had decreased. In conclusion, I thought that the sounding board wood for GAYAKUM would had the most effect to do the treatment of hotiron on surface after heat-treatment during 24 hours in $60^{\circ}C$ temperature using the radial board of mature wood.

• Archives of Reconstructive Microsurgery
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• 제3권1호
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• pp.45-53
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• 1994

Suture microvascular anastomosis is time-consuming and tedious and demands long and continuous training. Techinique of anastomosis of microvessel was presented interrupted suture and continuous suture. Recently the unilink instrument system is created as a fast and simple method to achieve high patency rates without long and continuous training in the anastomosis of small vessels. The author experimentally studied the femoral artery of 20 mice(0.5-1.0mm, av. 0.7mm), the femoral vein of 20 mice(0.8-1.6mm, av. 1.2mm) after anastomosis with interrupted suture in 20 cases and continuous sutre in 20 cases. For the unilink apparatus we used the carotid arteries of 15 cases in 14 rabbits(1.0-1.6mm, av. 1.3mm) and facial veins of 12 cases in 14 rabbits(0.9mm-2.2mm, av. 1.5mm). A total of 27 arterial and venous anastomoses were performed. We examined the postoperative patency at immediate, 2 weeks, and 8 weeks. The results were as followings, 1. In the arterial anastomosis the rate of patency was 90%(18/20) in interrupted suture, 90%(18/20) in continuous suture and 93%(13/15) in unilink apparatus. In the venous anastomosis the rate of patency was 90%(18/20) in interrupted suture, 80%(16/20) in continuous suture and 100%(9/9) in unilink apparatus. 2. The mean time for completion of the arterial anastomosis were 12.2 minutes in interrupted suture group, 10.3 minutes in continouous suture group and 8.5 minutes in unillnk apparatus group. The mean time for completion of the venous anastomosis were 13.6 minutes in interrupted suture group, 11.0 minutes in continuous suture group and 6.2 minutes in unilink apparatus group. 3. At the histological examination of suture group, hyperplastic reaction of middle layer and subintimal hyperplasia were observed. In unilink apparatus group, the endothelium layer was continued and the thickness of vessel wall was decreased due to moderate atrophy of the media and mild degree of nonspecific chronic inflammation were seen around the unilink apparatus. 4. No significants was noticied in foreign body reaction among the interrupted, continuous and unilink apparatus group. 5. A case of the arterial anastomosis was released with acting out at 15 minutes after operation. 6. The important factors in the technical problems were accurate apposition of the cut vessel edges in suture group and the proper selection of the ring size and optimal fitting between two rings in unilink apparatus group. Even though the outer diamater of vessel in suture group was different from that in unilink apparatus group the unilink method provides a very safe, fast, and simple way to perform microvascular anastomoses especially in anastomosis of vein. But howerver suture was needed in vessels below 1 mm outer diamater. In that situation continuous suture was benefit than the interrupted suture in operation time.

• 식물병연구
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• 제14권3호
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• pp.214-218
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• 2008

국립산림과학원에서 표본실에 보관되어 있는 잣나무 잎녹병 건조표본에 대하여 광학현미경과 주사형 전자현미경으로 녹병정자기와 녹포자기의 형태 및 크기, 호막세포의 모양, 크기 및 표면구조, 녹포자의 모양, 크기 및 표면구조(돌기의 형태, 크기, 수/$100\;{\mu}m^2$)등 녹포자세대의 분류형질에 대한 형태학적 특징을 조사하고 기존 연구결과와 비교한 결과, 9개의 건조표본이 국내 미기록 녹병균인 Coleosporium neocacaliae의 녹포자세대로 동정되었다. 우리나라에서 잣나무에서 유일하게 보고되어 있던 C. eupatorii와 형태적 특징을 비교하였을 때, 특히 녹포자의 크기에서 상대적으로 큰 차이를 보여 구분이 가능하였다. 기존 문헌에는 광학현미경 관찰에서 녹포자의 표면구조가 단순히 "verrucose"로 기재되어 있으나, 주사전자현미경으로 관찰한 결과, 사마귀형 돌기는 3-4개의 고리를 가진 환상형 돌기로 밝혀졌다. 우리나라에서 C. neocacaliae의 녹포자세대는 경기도, 전라북도, 강원도 등의 한반도 중부지역에 광범위하게 분포하면서 해발 약 1,000 m내외의 고산지역에서도 발생하고 있었으며, 녹포자세대의 출현 시기는 4월 중순부터 6월 초순이었다.

• 한국소성가공학회:학술대회논문집
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• 한국소성가공학회 2005년도 추계학술대회 논문집
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• pp.167-170
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• 2005

The two-dimensional (2D) and three-dimensional (3D) diamond-like carbon (DLC) stamps for ultraviolet nanoimprint lithography (UV-NIL) were fabricated using two kinds of methods, which were a DLC coating process followed by the focused ion beam (FIB) lithography and the two-photon polymerization (TPP) patterning followed by nano-scale thick DLC coating. We fabricated 70 nm deep lines with a width of 100 nm and 70 nm deep lines with a width of 150 nm on 100 nm thick DLC layers coated on quartz substrates using the FIB lithography. 200 nm wide lines, 3D rings with a diameter of $1.35\;{\mu}m$ and a height of $1.97\;{\mu}m$, and a 3D cone with a bottom diameter of $2.88\;{\mu}m$ and a height of $1.97\;{\mu}m$ were successfully fabricated using the TPP patterning and DLC coating process. The wafers were successfully printed on an UV-NIL using the DLC stamp. We could see the excellent correlation between the dimensions of features of stamp and the corresponding imprinted features.

• 동의생리병리학회지
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• 제21권2호
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• pp.408-413
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• 2007

Vascular tone plays an important role in the regulation of blood pressure. In the present study, the methanol extract of Rosae multiflora Radix (MRM) induced dose-dependent relaxation of phenylephrine-precontracted aorta, which was abolished by removal of functional endothelium. Pretreatment of the endothelium-intact aortic tissues with $N^G$-nitro-L-arginine methly ester (L-NAME) or 1H-[1,2,4]-oxadiazole-[4,3-${\alpha}$]-quinoxalin-1-one (ODQ) inhibited the relaxation induced by MRM, respectively. But, the relaxation effect of MRM was not blocked by indomethacine, glibenclamide, tetraethylammonium (TEA), verapamil, diltiazem, atropine, and propranolol, respectively. Moreover, incubation of endothelium-intact aortic rings with MRM increased the production of cGMP. Taken together, the present results suggest that MRM relaxes vascular smooth muscle via endothelium-dependent nitric oxide/cGMP signaling. These results would be useful for further study to MRM on animal models with cardiovascular diseases.