• Proceedings of the KSME Conference
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• 2001.06a
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• pp.383-388
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• 2001

Effects of particle property variation of cone crack shape according to impact velocity in silicon carbide materials were investigated. The damage induced by spherical impact having different material and size was different according to materials. The size of ring cracks induced on the surface of specimen increased with increase of impact velocity within elastic contact conditions. The impact of steel particle produced larger ring cracks than that of SiC particle. In case of high impact velocity, the impact of SiC particle produced radial cracks by the elastic-plastic deformation at impact regions. Also percussion cone was formed from the back surface of specimen when particle size become large and its impact velocity exceeded a critical value. Increasing impact velocity, zenithal angle of cone cracks in SiC material was linearly decreasing not effect of impact particle size. An empirical equation, $\theta=\theta_{st}-\upsilon_p(180-\theta_{st})(\rho_p/\rho_s)^{1/2}/415$, was obtained from the test data as a function of quasi-static zenithal angle of cone crack($\theta_{st}$), the density of impact particle(${\rho}_p$) and specimen(${\rho}_s$). Applying this equation to the another materials, the variation of zenithal angle of cone crack could be predicted from the particle impact velocity.

• The Journal of Korean Institute of Communications and Information Sciences
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• v.24 no.12A
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• pp.1960-1965
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• 1999

In this paper, we propose a new method of erased concatenated code with RS-convolutional code. In the method, we make use of erasure for undecoded information when we have some errors in RS decoding. For decoding with erasure, the method is processed inner decoding and outer decoding again. After the erasure decoding, if the decoding result is better than the previous one, then we use this result. If not, use the previous one. In this paper, we use concatenated RS(63,31)-convolutional(4.1/2) code. Simulation result is compared with calculation result for performance analysis. According to the result, the proposed method has better performance than the others without erasure such that 2dB when 0.5$\leq\rho\leq$1 and 4dB when $\rho\leq$0.3.

• YAKHAK HOEJI
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• v.55 no.2
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• pp.138-144
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• 2011

The aim of present study was to investigate the possible influence and related mechanism of resveratrol on U-46619 (high concentration)-induced vasoconstriction. Agonist-induced vascular smooth muscle contractions involve the activation of thick or thin filament pathway. However, there are no reports addressing the question whether this pathway is involved in resveratrol-induced relaxation in rat aortae contracted with high U-46619. We hypothesized that MEK or Rho-kinase inhibition plays a role in vascular relaxation evoked by resveratrol in rat aortae. Endothelium-denuded arterial rings from male Sprague-Dawley rats were used and isometric contractions were recorded using a computerized data acquisition system. Resveratrol fully inhibited U-46619 in low concentration-induced contraction regardless of endothelial function. However, resveratrol partially decreased U-46619 in high concentration-induced contraction regardless of endothelial function. Interestingly, only in U-46619 (high concentration)-induced contraction, no significant decrease was observed in phospho-ERK1/2 levels and slight decrease in phospho-MYPT1 levels suggesting that additional pathways different from them or endothelial nitric oxide synthesis might be involved in the vasorelaxation. In conclusion, in high U-46619-contracted rat aortae, resveratrol showed relaxation response regardless of endothelial function significantly but slightly decreasing MYPT1 phosphorylation rather than ERK1/2 phosphorylation.

• Journal of the Korean Chemical Society
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• v.34 no.3
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• pp.227-231
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• 1990

Kinetic studies on the nucleophilic reactions of p-substituted benzylnitrates with substituted anilines have been conductometically carried out in 50-100% $CH_3CN-CH_3OH$ mixtures. From the kinetic data, Hammett ${\rho}_C$ and ${\rho}_N$ values, Bronsted $\beta$ values, and solvatochromic coefficients were determined in order to examine the transition state variations caused by changes in substituents and solvent properties. It is concluded that the reaction proceeds via a synchronous $S_N2$ mechanism in which bond formation is more advanced than bond cleavage.

• Journal of the Korean Chemical Society
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• v.36 no.4
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• pp.517-522
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• 1992

The reaction of ${\beta}$-picoline with substituted benzoyl chlorides has been studied by means of conductometry under various pressures in acetonitrile. From the values of pseudo-first order and second order rate constants, the activation parameters (${\Delta}V{\neq}$, ${\Delta}{\beta}{\neq}$, ${\Delta}H{\neq}$, ${\Delta}S{\neq}$ and ${\Delta}G{\neq}$) and the pressure dependence of Hammett ${\rho}$ value were studied. The activation volume, the activation compressibility coefficient and the activation entropy were all negative. By increasing pressure the rate constant and Hammett ${\rho}$ value were increased, and the reaction mechanism was proceed in bond formation favored.

• Bulletin of the Korean Chemical Society
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• v.35 no.2
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• pp.483-488
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• 2014

The nucleophilic substitution reactions of Y-aryl methyl (8) and Y-aryl propyl (10) chlorothiophosphates with X-pyridines are studied kinetically in acetonitrile at $35.0^{\circ}C$. The Hammett and Bronsted plots with X in the nucleophiles for both substrates exhibit biphasic concave upwards with a break region between X = 3-Me and H. The obtained values of the cross-interaction constants (${\rho}_{XY}$) are negative with 8 while positive with 10 despite the same free energy correlations with X for both substrates. A stepwise mechanism with a rate-limiting bond formation is proposed with 8, whereas a stepwise mechanism with a rate-limiting leaving group departure from the intermediate is proposed with 10 based on the sign of ${\rho}_{XY}$, negative and positive with 8 and 10, respectively. A frontside nucleophilic attack is proposed with strongly basic pyridines based on the considerably great magnitudes of ${\rho}_X$ and ${\beta}_X$ values while a backside attack is proposed with weakly basic pyridines based on the relatively small magnitudes of ${\rho}_X$ and ${\beta}_X$ for both substrates.

• Nuclear Engineering and Technology
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• v.3 no.1
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• pp.21-31
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• 1971

The part of the work of plastic deformation of metal goes into the changes in the total surface free energy. This contribution is dependent on the specific surface free energy, which is affected by the environment. Based on thermodynamical approach, volume constancy requirement and adsorption induced two distinct dislocation interaction mechanisms for strengthening or weakening of metals at surface, theoretical derivation has been made to show that the environmental contribution on the strain hardening, the stress and the energy required for plastic deformation can be expressed in terms of solid surface tension in vacuum (${\gamma}$$_{s}$), interfacial tension (${\gamma}$$_{se}$ ), surface dislocation density ($\rho$$_{s}$), internal dislocation density ($\rho$$_{i}$) and fraction of surface site uncoverage (f). On the basis of theoretical derivation, the various mechanical behaviours under different environments are predicted.d.d.

• Journal of the Korea institute for structural maintenance and inspection
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• v.9 no.1
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• pp.205-215
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• 2005

The main objective of this study is to investigate the behavior of NSC and HSC beams with stirrups. Main variables were the concrete compressive strength and amount of vertical stirrups. A total of 24 beams was tested; 4 beams without web reinforcement and 20 beams with web reinforcement in the form of vertical stirrups. Main variables were 2 different compressive strengths of concrete of 26.9MPa and 63.5MPa, 5 different spacing of stirrups of 200, 150, 120, 100 and 90mm. Therefore, the results were compared with the strengths predicted by the equations of ACI code 318-99 and other researchers. The shear reinforcement ratio, where the test beams were failed simultaneously under flexure and shear, were $0.63{\rho}_{vmax}$ for NSC beams and $0.53{\rho}_{vmax}$ for HSC beams, respectively. The ACI code equation was found to be very conservative for shear design.

• Journal of the Korean institute of surface engineering
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• v.32 no.1
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• pp.3-9
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• 1999

Pt thin film of about 7000$\AA$ thickness was deposited on the alumina substrate using DC Magnetron Sputter and the characteristics of the film for temperature sensor were investigated. When film of about 7000$\AA$ thickness was deposited at working gas pressure of $2.0{\times}10^{-3}$torr, sputtering power of 50W, substrate temperature of $350^{\circ}C$(Ts), sheet resistance(Rs), resistivity($\rho$) and temperature coefficient of resistivity(TCR) of the film were respectively 0.39$\Omega$/$\square$, 27.60$\mu\Omega$-cm and $3350 ppm/^{\circ}C$. When the film was annealed at $1000^{\circ}C$ for 240min in hydrogen ambient, Rs, $\rho$ and TCR were respectively 0.236$\Omega$/$\square$, 15.18$\mu\Omega$-cm and 3716 ppm/$3716 ppm/^{\circ}C$. When working gas of 15sccm oxygen and 100sccm Argon were used, Rs, $\rho$ and TCR were respectively 0.335$\Omega$/$\square$, 22.45$\mu\Omega$-cm and $3427 ppm/^{\circ}C$. When the film was annealed at $1000^{\circ}C$ for 240min, Rs, $\rho$and TCR were respectively 0.224/$\Omega$$\square$, 14$\mu\Omega$-cm and $3760 ppm/^{\circ}C$ and the characteristics of the film were much improved.

• Bulletin of the Korean Chemical Society
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• v.22 no.9
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• pp.953-957
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• 2001

The specificity of conjugation site for coating ligands was investigated using toluene-bovine serum albumin (BSA) conjugates in which BSA was conjugated at the position of o-, m-, and ${\rho}-toluic$ acid. Toluene-BSA conjugated at ${\rho}-position$ showed a binding activity of about 89-95%, whereas, those conjugated at o- and m-position of toluene exhibited a binding activity of 5 and 11%, respectively. On the basis of the above result, coating ligands with various proteins (OVA, BSA, KLH) were compared by conjugating with $\rho-toluic$ acid, and toluene-KLH was considered as the best coating ligand for this ELISA. Indirect competitive ELISA method was developed using anti-toluene antibody and $\rho-position$ conjugated toluene-KLH. The dose-response curve constructed after kinetic and optimization studies showed a 1${\times}$10-4 - 1${\times}$102 mM detectable response range with 0.1 ${\mu}M$ detectability. In specificity test of the antibody, the binding capabilities of aromatic compounds substituted with nitro-, alkyl-, chloro-, and hydroxyl group were larger rather than those of aromatic compounds (benzene, toluene and xylene) themselves. Also, tests with soil and water samples that had been spiked with toluene resulted in 102.7-113.7% recovery.