• Title/Summary/Keyword: R- phase

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Effect of and R Phase on the Pitting Corrosion in Super Duplex Stainless Steel (슈퍼 2상 스테인리스강의 공식에 미치는 R상의 영향)

  • Lee, Byung-Chan;Oh, Eun-Ji;Kang, Chang-Yong
    • Korean Journal of Materials Research
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    • v.24 no.11
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    • pp.610-616
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    • 2014
  • In this study, we investigated the precipitation behavior of the R-phase precipitated at the initial stage of aging and its effect on the pitting corrosion of 25%Cr-7%Ni-4%Mo super duplex stainless steel. The R-phase in super duplex stainless steel was mainly precipitated at the interface of ferrite/austenite phases and inside of the ferrite phase during the initial stage of aging, and it was transformed into the ${\sigma}$-phase with an increase in aging time. The ferrite phase was decomposed into a new austenite phase and ${\sigma}$-phase. The R phase was an intermetallic compound, which represented a lower Ni and higher Mo than the matrix, and also had a higher Mo and Cr concentration than the ${\sigma}$ phase. With an increasing aging time, the pitting potential $E_p$ was increased slowly by the precipitation of the R-phase, and it was then steeply decreased by the precipitation of the ${\sigma}$-phase. The R-phase was decreased the pitting potential, but its effect was smaller than effect of ${\sigma}$-phase.

Effect of R Phase Formation on the Mechanical Properties of 25Cr-7Ni-2Mo-4W Super Duplex Stainless Steel (25Cr-7Ni-2Mo-4W 슈퍼 2상 스테인리스강의 기계적 성질에 미치는 R상의 영향)

  • Lee, Byung-Chan;Kang, Chang-Yong
    • Korean Journal of Materials Research
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    • v.24 no.8
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    • pp.401-406
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    • 2014
  • In this study, we investigated the precipitation behavior of the R-phase precipitated at the initial stage of aging and its effects on the mechanical properties of 25%Cr-7%Ni-2%Mo-4%W super duplex stainless steel. The R-phase was mainly precipitated at the interface of ferrite/austenite phases and inside of the ferrite phase during the initial stage of aging. It was transformed into the ${\sigma}$-phase with an increase of the aging time. The ferrite phase was decomposed into a new austenite(${\gamma}_2$)phase and the ${\sigma}$-phase by an aging treatment. The R phase was an intermetallic compound showing higher molybdenum and tungsten concentrations than the matrix and also showed higher molybdenum and tungsten concentrations than the ${\sigma}$ phase. In the initial stage of aging, precipitation of the R-phase did not change the hardness, the strength and the elongation. The hardness and the strength increased upon a longer aging time, but the elongation rapidly decreased. These results show that the R-phase did not significantly affect the hardness and the strength, though it did influence the elongation.

Experimental measurements of R-22 two-phase friction factor in plate heat exchangers (판형열교환기에서 R-22 냉매의 이상 압력 손실계수 평가)

  • Yoo, Sang-Roon;Jeong, Ji-Rwan
    • Proceedings of the KSME Conference
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    • 2007.05b
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    • pp.2273-2278
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    • 2007
  • Brazed Plate Heat Exchanger (BPHE) is a type of compact plate heat exchanger with parallel corrugated plates which are brazed together in series. Each plate hascorrugation called herringbone pattern. Inside a BPHE, hot fluid and cold fluid alternate its flow direction to establish counter current flow configuration. Two-phase flow heat transfer and pressure drop of R-22 in BPHE were experimentally measured in this study. In the present experiments, single-phase region and two-phase region coexist in a BPHE. Therefore, the inside of a BPHE have to be divided into single phase region and two phase region and analyzed accordingly. The results from the single phase flow analysis are then extended to the two phase flow analysis to correlate the condensation and evaporation heat transfer and pressure drop for the refrigerant R-22 in the BPHEs. Previous models for two- phase friction factor have been compared with the present experimental results.

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A Study on the Phase Identification of Dental Amalgams (의과용 아말감의 합금상 판별에 관한 연구)

  • 이규환;신명철
    • Journal of Biomedical Engineering Research
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    • v.2 no.1
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    • pp.39-46
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    • 1981
  • Microstructural phases of the dental amalgams have been studied by optical microscope, scanning electron microprobe and X-ray diffractometer. r1 ($Ag_2Hg_3$) phase and r2 ($Sn_{7-8}Hg$) phase are found on conventional compositioned alloys. On high copper single compositioned alloy, rl ($Ag_2Hg_3$) phase and V ($Cu_6Sn_5$) phase are found but brittle r2 ($Sn_(7-8)Hg$) phase.

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Syntheses and Characteristics of R-P Phase $Ln_{1-x}Sr_{2-x}Mn_2O_7$(Ln=La, Pr, Gd, Eu, Er, Nd, Sm) (R-P Phase $Ln_{1-x}Sr_{2-x}Mn_2O_7$(Ln=La, Pr, Gd, Eu, Er, Nd, Sm)의 합성 및 특성연구)

  • 송민석;서상일;이재열
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1999.05a
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    • pp.337-340
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    • 1999
  • Since the first reports of CMR(colossal magnetoresistance) effects in some single crystal R-P Phase Ln$_{1-x}$ Sr$_{2-x}$Mn$_{2}$O$_{7}$ 1996. many researches have been carried out to find optimum compositions and processing conditions in this system. In this study, layered perovskite R-P Phase Ln$_{1-x}$ Sr$_{2-x}$Mn$_{2}$O$_{7}$ (x=0.4, Ln=-La, Eu, Gd, Nd, Pr, Sm) phases were synthesized by solid state reaction and their structures were refined by Rietveld method. Electrical and magnetic properties were measured drown to 20K and compare with those of R-P Phase Ln$_{1-x}$ Sr$_{2-x}$Mn$_{2}$O$_{7}$ Phases.es.es.es.es.es.

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Effects of Mo Content on Surface Characteristics of Dental Ni-Ti Alloys (치과용 Ni-Ti합금의 표면특성에 미치는 Mo함량의 영향)

  • Han-Cheol Choe;Jae-Un Kim;Sun-Kyun ark
    • Corrosion Science and Technology
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    • v.22 no.1
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    • pp.64-72
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    • 2023
  • Ni-Ti shape memory alloy for dental nerve treatment devices was prepared by adding Mo to Ni-Ti alloy to improve flexibility and fatigue fracture characteristics and simultaneously increase corrosion resistance. Surface properties of the alloy were evaluated. Microstructure analysis of the Ni-Ti-xMo alloy revealed that the amount of needle-like structure increased with increasing Mo content. The shape of the precipitate showed a pattern in which a long needle-like structure gradually disappeared and changed into a small spherical shape. As a result of XRD analysis of the Ni-Ti-xMo alloy, R-phase structure appeared as Mo was added. R-phase and B2 structure were mainly observed. As a result of DSC analysis, phase transformation of the Ti-Ni-Mo alloy showed a two-step phase change of B2-R-B19' transformation with two exothermic peaks and one endothermic peak. As Mo content increased, R-phase formation temperature gradually decreased. As a result of measuring surface hardness of the Ti-Ni-Mo alloy, change in hardness value due to the phase change tended to decrease with increasing Mo content. As a result of the corrosion test, the corrosion potential and pitting potential increased while the current density tended to decrease with increasing Mo content.

Measurement of a Phase Plate Simulates Atmospheric Turbulence Depending on Laser Power (레이저 출력에 따른 난류 모사 위상판 측정)

  • Han-Gyol Oh;Pilseong Kang;Jaehyun Lee;Hyug-Gyo Rhee;Young-Sik Ghim
    • Korean Journal of Optics and Photonics
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    • v.34 no.3
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    • pp.99-105
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    • 2023
  • The performance of astronomical telescopes can be negatively affected by atmospheric turbulence. To address this issue, techniques for atmospheric turbulence correction have been developed, requiring the simulation of atmospheric turbulence in the laboratory. The most practical way to simulate atmospheric turbulence is to use a phase plate. When measuring a phase plate that simulates strong turbulence, a Shack-Hartmann wave-front sensor is commonly used. However, the laser power decreases as it passes through the phase plate, potentially leading to a weak laser signal at the sensor. This paper investigates the need to control the laser power when measuring a phase plate that simulates strong atmospheric turbulence, and examines the effects of the laser power on the measured wavefront. For phase plates with relatively high Fried parameter r0, the laser power causes a variation of over 10% in r0. For phase plates with relatively low r0, the laser power causes a variation of less than 5%, which means that the influence of the laser power is negligible for phase plates that simulate strong atmospheric turbulence. Based on the system described in this paper, a phase plate simulating strong atmospheric turbulence can be measured at a laser power of 5 mW or higher. Therefore, controlling the laser's output power is necessary when measuring a phase plate for simulating atmospheric turbulence, especially for phase plates with low r0 values.

A Study on $90^{\cire}$ Constant Phase Shifter (전송선형 $90^{\cire}$ 정위상기에 관한 연구)

  • 이충웅
    • Journal of the Korean Institute of Telematics and Electronics
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    • v.13 no.6
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    • pp.12-15
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    • 1976
  • This paper presents the realization method of 90$^{\circ}$ constant phase shifter in the VHF band, constructed by the entirely differens idea from the conventional method of the realization of constant phase shifter in the audio frequency range. The construction of 90$^{\circ}$ constant phase shifter is. simple and can be easily realized by using the distributed constant element, transmission line, and the lumped constant elements, R,C,L.

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Applying Aqueous Two Phase Systems to Multi-layer Cosmetics (다중 층 화장료에서 수성 이상계의 응용)

  • Hong, Junki;You, Jaewon;Yoo, Jangyung;Nam, Seungok;Lee, Sanggil;Pyo, Hyeongbae
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.39 no.2
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    • pp.83-88
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    • 2013
  • The aqueous two phase system has biocompatibility, because it is physically separated into an immiscible liquid multi-layer induced by incompatibility among hydrophilic components dissolved in the water phase. we have applied this principle to aqueous multi-layer liquid cosmetics and select two representative systems. What it was experimentally obtained was the phase diagrams including a binodal curve, a critical point, tie lines of concentration and tie curves of phase separating volume ratio and phase separating time. From the phase diagrams, we were able to observe existence of the optimum condition to prepare the aqueous multi-layer cosmetics for the systems.