• Clean Technology
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• v.28 no.3
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• pp.218-226
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• 2022

As a result of the recent social transformation towards a hydrogen economy and carbon-neutrality, the demands for hydrogen energy have been increasing rapidly worldwide. As such, eco-friendly hydrogen production technologies that do not produce carbon dioxide (CO₂) emissions are being focused on. Among them, ammonia (NH₃) is an economical hydrogen carrier that can easily produce hydrogen (H₂). In this study, Ru/Al₂O₃ catalyst coated onmetallic monolith for hydrogen production from ammonia was prepared by a dip-coating method using a catalyst slurry mixture composed of Ru/Al₂O₃ catalyst, inorganic binder (alumina sol) and organic binder (methyl cellulose). At the optimized 1:1:0.1 weight ratio of catalyst/inorganic binder/organic binder, the amount of catalyst coated on the metallic monolith after one cycle coating was about 61.6 g L^-1. The uniform thickness (about 42 ㎛) and crystal structure of the catalyst coated on the metallic monolith surface were confirmed through scanning electron microscopy (SEM) and X-ray diffraction (XRD) analysis. Also, a numerical optimization regression equation for NH3 conversion according to the independent variables of reaction temperature (400-600 ℃) and gas hourly space velocity (1,000-5,000 h^-1) was calculated by response surface methodology (RSM). This model indicated a determination coefficient (R²) of 0.991 and had statistically significant predictors. This regression model could contribute to the commercial process design of hydrogen production by ammonia decomposition.

• Journal of the Korean Institute of Gas
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• v.17 no.5
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• pp.58-63
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• 2013

LNG(Liquefied Natural Gas) has been considered as the green energy. Thus, the demand of natural gas is keep increasing around the world, and various studies are actively under progress about the LNG storage tank. To calculate the seismic forces of actual LNG storage tank, FEM model has to include inner tank, outer tank, pile and soil to implement the interaction between structure and ground. So, this paper is represent the study about inner tank model of three cases using Malhotra method in EN 1998-4(European Standard). The results of calculation were compared, and the most suitable to inner tank model was suggested.

• The Korean Journal of Food And Nutrition
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• v.1 no.2
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• pp.86-94
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• 1988

In view of the national health, the health of women during their childbearing age is Important. This survey was conducted for the purpose of pratice of nutrition education the dietary intakes, and the means of daily food intakes was investigated by food habit for 100 students and two day records of 75 women students of Junior on Dept. of Food and Nutrition in a college in November 1987. The results obtained are summarized as follows. 1) Average food habit score was only 4.67 out of possible 10.0 points. And 41% of the subjects belonged "poor food habit" group. 2) Their diets were found to be lacking in total amount of food intake (915$\pm$74gm)and in such foods as cereals, potatoes, green and yellow vegetables, oils and fats. But animal food Intakes were sufficient in such foods as fishes, meats and eggs. The percentage of animal protein to total protein was 43.8% in subjects. 3) The average calorie intake(1535$\pm$ 512kcal) was insufficient against R.0.A.(2000kcal), the other lacking nutrients were protein, Fats and oils, Ca, these percentages of R.D.A. were 98.2%, 64.0% and 89.6%. They showed that each person was depended upon more the chief meals than side dishes in intakes of energy.of energy.

• Current Photovoltaic Research
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• v.3 no.3
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• pp.80-84
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• 2015

We suggest new emitter formation method using solid-phase epitaxy (SPE); solid-phase epitaxy emitter (SEE). This method expect simplification and cost reduction of process compared with furnace process (POCl3 or BBr3). The solid-phase epitaxy emitter (SEE) deposited a-Si:H layer by radio-frequency plasma-enhanced chemical vapor deposition (RF-PECVD) on substrate (c-Si), then thin layer growth solid-phase epitaxy (SPE) using rapid thermal process (RTP). This is possible in various emitter profile formation through dopant gas ($PH_3$) control at deposited a-Si:H layer. We fabricated solar cell to apply solid-phase epitaxy emitter (SEE). Its performance have an effect on crystallinity of phase transition layer (a-Si to c-Si). We confirmed crystallinity of this with a-Si:H layer thickness and annealing temperature by using raman spectroscopy, spectroscopic ellipsometry and transmission electron microscope. The crystallinity is excellent as the thickness of a-Si layer is thin (~50 nm) and annealing temperature is high (<$900^{\circ}C$). We fabricated a 16.7% solid-phase epitaxy emitter (SEE) cell. We anticipate its performance improvement applying thin tunnel oxide (<2nm).

• Advances in Energy Research
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• v.5 no.3
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• pp.227-237
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• 2017

The continuous increase of emission rates of green house gases and the effects on global warming added a new dimension to the problem of substituting the petroleum and its derivatives by environment friendly and sustainable energy sources for the world. Solar and wind energy appear at the top of the list of renewable of high potential, widely available, of dominated technology and well accepted. Brazil is one of the few countries in the world that receives number hours of sunshine exceeding 3,000 hours per year with a daily average of 4.5 to 6 kWh. However, this potential is largely unexplored and poorly tapped. The number of renewable systems implanted in Brazil has grown in recent years, but still insignificant when compared, for example, with Germany and Spain among others. This paper presents the results of an optical study on small concentration solar collector with evacuated tube enveloping the absorber and internal reflective surface fixed on the bottom part of the evacuated tube. The designed collector has a 2D geometrical concentration ratio between 2.455 and 4.91. The orientation of the solar collector, the ratio of the radius of the receiver to the radius of the absorber, the incidence angle for each period of the year, the collector inclination angle, the aperture angle of the reflective surface, concentration and optical efficiency were determined. The ray traces and flux distribution on the absorber of the evacuated tube solar collector were determined by using the program Ray Optics Simulation. The optical efficiency varies during the year according to the solar declination. For the periods were the solar declination is close to zero the efficiencies are maximum, and the variation during the day is around 25.88% and 99.9%. For the periods were the solar declination is maximum the efficiencies are minimum, and the variation during the day is around 23.78% and 91.79%.

• Economic and Environmental Geology
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• v.55 no.6
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• pp.661-669
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• 2022

The need for miniaturization, high efficiency, and green energy resources as an energy storage device through the development of various electronic device has emerged. Accordingly, nanomaterials with excellent electrochemical properties, such as graphene and graphene hybrids, are attracting attention as promising materials. In particular, in the electric vehicle industry, cost reduction of secondary batteries is a key factor that can determine the spread of related industries, and it is most important to analyze R&D trends for battery material technology and respond to future technological development directions. Therefore, in this study, we tried to suggest a direction for R&D activities in the future by analyzing patent trends for graphene anode material technology for secondary batteries and deriving implications. As a result, in the case of anode material technology, the proportion of foreigners in the US and European patent markets was higher than in the Korean and Japanese patent markets, which means that the US and European marketability is high. In addition, Japanese applicants are filing high-level applications not only in the Japanese patent market but also in other countries suggests that Japan is leading the technology in this field. Lastly, the proportion of research institutes in the patent market of Korea and the US remains high compared to that of Japan and Europe, indicating that the commercialization of technology is still slow in those countries. Therefore research institutes and companies in Korea will have to establish their own strategies for developing and securing materials using the results of patent trends in major countries and major companies analyzed in this study.

• Journal of the Korean Home Economics Association
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• v.18 no.1
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• pp.47-52
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• 1980

In view of the nationel health, the health of women during their childbearing age is important. In Korean, several studies reported that incidence of anemic case was high among these group. The present study was conducted to investigate the dietetic life and dietetic problems among college women during their child-earing age. One hundred thirty seven college women (Age ranges 18.5 to 21.8) who lived in Gwangju area were randomly selected and were practiced dietary survey by three day records in November 1979. Also, hemoglobin level was determined. The result are summarized as follows; their diets were found to be lacking I total amounts of food it takes (878.6$\pm$266.9 gm) and in such foods as cereals, potatoes, beans, green and yellow vegetables, oils and fats and small fishes. but animal food intakes were sufficient in such foods as fishes, meats and eggs. The average calorie intake (1729.3$\pm$437.0kcal) was insufficient against R.D.A (2000kcal) and the daily energy expenditure (2024.7kcal). Lacking nutrients were Fe and Vitamin A these percentages of R.D.A. were 75.61% and 80.14% The mean body height (16.1$\pm$8.1cm) was higher tendency compared to other studies, but the mean body weight (49.8$\pm$4.1kg) was lighter. The average Hb level was 12.75$\pm$2.94gm%, and 13.64% of the subjects was anemic (12gm% below) The differences of each nutrient intake between the anemic and the healthy group not noted statistically significant.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.15 no.2
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• pp.666-671
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• 2014

Using positive temperature coefficient (PTC) heater as supplementary heating for diesel engine vehicles with low heat source is a good method to enhance the heating performance during cold start. In this study, the PTC elements were made by using screen printing process for forming ohmic contact layer, and prototype of PTC heater was designed and made for a diesel engine vehicle. In process of designing the PTC heater, the thermal flow analysis of PTC element modules was conducted for verifying the effect of the shapes of contact surface between each of the components (cooling fin, insulator, ceramic element). We also investigated the performance characteristic (heating capacity, energy efficiency, pressure drop) of the PTC heater through the experiments. Therefore, the experimental results indicated that prototype of PTC heater had satisfactory performance. This study will be basis for improving the manufacturing process and increasing the performance of the PTC element and heater.

• Journal of Microbiology and Biotechnology
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• v.16 no.2
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• pp.226-231
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• 2006

Several white-rot fungi are able to produce extracellular lignin-degrading enzymes such as manganese peroxidase (MnP), lignin peroxidase (LiP), and laccase. In order to enhance the production of laccase and MnP using Trametes versicolor KCTC 16781 in suspension culture, the effects of major medium ingredients, such as carbon and nitrogen sources, on the production of the enzymes were investigated. The decolorization mechanism in terms of biodegradation and biosorption was also investigated. Among the carbon sources used, glucose showed the highest potential for the production of laccase and MnP. Ammonium tartrate was a good nitrogen source for the enzyme production. No significant difference in the laccase production was observed, when glucose concentration was varied between 5 g/l and 30 g/l. As the concentration of nitrogen source increased, a lower MnP activity was observed. The optimal C/N ratio was 25 for the production of laccase and MnP. When the concentrations of glucose and ammonium tartrate were simultaneously increased, the laccase and MnP activities increased dramatically. The maximum laccase and MnP activities were 33.7 U/ml at 72 h and 475 U/ml at 96 h, respectively, in the optimal condition. In this condition, over 90% decolorization efficiency was observed.

• Korean Chemical Engineering Research
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• v.62 no.1
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• pp.36-43
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• 2024

Fishing net waste (FNW) constitutes over half of all marine plastic waste and is a major contributor to the degradation of marine ecosystems. While current treatment options for FNW include incineration, landfilling, and mechanical recycling, these methods often result in low-value products and pollutant emissions. Importantly, FNWs, comprised of plastic polymers, can be converted into valuable resources like syngas and pyrolysis oil through pyrolysis. Thus, this study presents a process for generating high-purity hydrogen (H₂) by catalytically pyrolyzing FNW in a CO₂ environment. The proposed process comprises of three stages: First, the pretreated FNW undergoes Ni/SiO₂ catalytic pyrolysis under CO₂ conditions to produce syngas and pyrolysis oil. Second, the produced pyrolysis oil is incinerated and repurposed as an energy source for the pyrolysis reaction. Lastly, the syngas is transformed into high-purity H₂ via the Water-Gas-Shift (WGS) reaction and Pressure Swing Adsorption (PSA). This study compares the results of the proposed process with those of traditional pyrolysis conducted under N₂ conditions. Simulation results show that pyrolyzing 500 kg/h of FNW produced 2.933 kmol/h of high-purity H₂ under N₂ conditions and 3.605 kmol/h of high-purity H₂ under CO₂ conditions. Furthermore, pyrolysis under CO₂ conditions improved CO production, increasing H₂ output. Additionally, the CO₂ emissions were reduced by 89.8% compared to N₂ conditions due to the capture and utilization of CO₂ released during the process. Therefore, the proposed process under CO₂ conditions can efficiently recycle FNW and generate eco-friendly hydrogen product.