• Title/Summary/Keyword: Quaternary structure

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Rising of Integrated Ocean Drilling Program (IODP) and its Scientific Achievement on Earth Science and Role of Korea Integrated Ocean Drilling Program (K-IODP) (국제공동 해양 시추사업(IODP)의 등장과 지구과학에의 학술적 성과 및 한국프로그램(K-IODP)의 역할)

  • Hyun, Sang-Min;Chang, Se-Won;Lee, Young-Joo
    • The Korean Journal of Quaternary Research
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    • v.25 no.2
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    • pp.1-15
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    • 2011
  • The ODP (Ocean Drilling Program) has been greatly contributed to the progress of Earth Science through the strong international cooperation with its name changed from DSDP DSDP(Deep Sea Drilling Program), IPOD (International Phase of Ocean Drilling) to IODP (Integrated Ocean Drilling Program). The IODP program which was launched about ten years ago will continue to develop toward the 2nd phase of scientific targets through the tight international cooperation. Distinguished scientific results from the various expedition as well as new phase of IODP structure and its important role that enhance the new scientific fields are summarized in this study. In particular, Arctic Expedition and deep-biosphere and high resolution climatic study that was not performed in previous ODP stages, will be extensively conducted in coming new 2nd IODP stages. Likewise, through strong international cooperation, it is expected that IODP would play an important role in Earth Science developments.

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A Study on Volcanic Stratigraphy and Fault of Ulleung-do, Korea (울릉도의 화산층서와 단층에 대한 연구)

  • Kim, Ki-Beom;Lee, Gi-Dong
    • The Journal of Engineering Geology
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    • v.18 no.3
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    • pp.321-330
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    • 2008
  • This study, geological survey was carried out in order to study on the geology, geological structure and volcanic activity of the Ulleung-do volcano body. Ulleung-do is the volcano body of about 3,000m heights from the East Sea seabed. The geology of Ulleung-do is divided into basaltic agglomerate, trachytic agglomerate, trachyte, trachytic pumice and trachyandesite in ascending orders. The faults in caldera of Nari Basin came to make the reverse triangle style in compliance with sinking. The faults in circumference of Nari Basin are ranging with northeast-southwest direction and northwest-southeast direction. The Quaternary volcanic activities in the Ulleung-do are divided into 5 activity period. The engineering geologists and the applied geologists were not easy to apply because complicated geology of Ulleung-do. Therefore, this study supplied simple geology of Ulleung-do for them.

Effect of KCN Treatment on Cu-Se Secondary Phase of One-step Sputter-deposited CIGS Thin Films Using Quaternary Target

  • Jung, Sung Hee;Choi, Ji Hyun;Chung, Chee Won
    • Current Photovoltaic Research
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    • v.2 no.3
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    • pp.88-94
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    • 2014
  • The structural, optical and electrical properties of sputter-deposited CIGS films were directly influenced by the sputtering process parameters such as substrate temperature, working pressure, RF power and distance between target and substrate. CIGS thin films deposited by using a quaternary target revealed to be Se deficient due to Se low vapor pressure. This Se deficiency affected the overall stoichiometry of the films, causing the films to be Cu-rich. Current tends to pass through the Cu-Se channels which act as the shunting path increasing the film conductivity. The crystal structure of CIGS thin films depends on the substrate orientation due to the influence of surface morphology, grain size and stress of Mo substrate. The excess of Cu was removed from the CIGS films by KCN treatment, achieving a suitable Cu concentration (referred as Cu-poor) for the fabrication of solar cell. Due to high Cu concentrations on the CIGS film surface induced by Cu-Se phases after CIGS film deposition, KCN treatment proved to be necessary for the fabrication of high efficiency solar cells. Also during KCN treatment, dislocation density and lattice parameter decreased as excess Cu was removed, resulting in increase of bandgap and the decrease of conductivity of CIGS films. It was revealed that Cu-Se secondary phase could be removed by KCN wet etching of CIGS films, allowing the fabrication of high efficiency absorber layer.

Qualitative Identification of Surfactants by Spectroscopic Method (분광학적 방법에 의한 계면활성제의 확인)

  • An, Chong-Il;Cho, Jong-Hoi;Park, Shin-Ja;Kim, Jong-Kil;Jeon, Ji-Hye;Lee, Jung-Bock;Park, Hong-Soo
    • Journal of the Korean Applied Science and Technology
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    • v.18 no.4
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    • pp.306-315
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    • 2001
  • Our study is aimed at proposal of systematic verification method of molecular structure using measuring method of selective ionic determination and spectrometry on 34 kinds of surfactants such as sodium dodecyl sulfate(SDS) which are most widely used today. In the IR spectrum, unsaturated fatty acids reveal themselves by HC= at $3000{\sim}3020cm^{-1}$, and intensity of $720cm^{-1}$ depends on carbon length of alkyl group. Also ethylene oxide(EO) adducts exhibit weak characteristic bands by $-CH_{2}-CH_{2}-O$ at 1350, 1100 and $950cm^{-1}$. Isethionate can be distinguished from diester succinate by intensity ratio of 1740 and $1200cm^{-1}$ spectrums, the ratio of latter is close to 1 due to 2 carboxylate radical in diester succinate. Quaternary ammonium salts exhibit characteristic band of $C_{4}N^{+}$ at $1000-900㎝^{-1}$. In the case of dialkyl dimethyl ammonium salts in quaternary ammonium surfactants, the spectrum of $3000cm^{-1}$ by $N-CH_{3}$ collapses to a very weak band at $3020cm^{-1}$. In ammonium heterocyclic derivatives, pyridinium salts show characteristic bands at 1640 and $1460cm^{-1}$, while imidazolinium salts exhibit characteristic band at $1620-1610cm^{-1}$. In the characteristic spectrum at $1080-1050cm^{-1}$ on OH radicals of the alkyl esters, primary alcohol appears as weak band and the 2 bands show in almost same intensity when primary and secondary alcohols exist together in one molecule. Also, alkyl ester of polyhydric alcohols appears as various broad band.

Fast Inter CU Partitioning Algorithm using MAE-based Prediction Accuracy Functions for VVC (MAE 기반 예측 정확도 함수를 이용한 VVC의 고속 화면간 CU 분할 알고리즘)

  • Won, Dong-Jae;Moon, Joo-Hee
    • Journal of Broadcast Engineering
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    • v.27 no.3
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    • pp.361-368
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    • 2022
  • Quaternary tree plus multi-type tree (QT+MTT) structure was adopted in the Versatile Video Coding (VVC) standard as a block partitioning tool. QT+MTT provides excellent coding gain; however, it has huge encoding complexity due to the flexibility of the binary tree (BT) and ternary tree (TT) splits. This paper proposes a fast inter coding unit (CU) partitioning algorithm for BT and TT split types based on prediction accuracy functions using the mean of the absolute error (MAE). The MAE-based decision model was established to achieve a consistent time-saving encoding with stable coding loss for a practical low complexity VVC encoder. Experimental results under random access test configuration showed that the proposed algorithm achieved the encoding time saving from 24.0% to 31.7% with increasing luminance Bjontegaard delta (BD) rate from 1.0% to 2.1%.

Membrane Containing Biocidal Material for Reduced Biofilm Formation: A Review (미생물막 형성을 막기 위한 살균 물질 함유 막: 총설)

  • Son, Soohyun;Patel, Rajkumar
    • Membrane Journal
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    • v.32 no.1
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    • pp.23-32
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    • 2022
  • Bacteria grow biofilm on various surface such as separation membrane, food packaging film and biomedical device. Growth of biofilm is associated with the formation of a complex structure of exopolysaccharides. Effect of antibacterial effect reduce drastically once the biofilm developed due to the difficulties in mass transport of antimicrobial agent. In order to enhance the antibacterial activity, surface of the membrane is modified, coated or immobilized with functional materials with biocidal properties. One of the idea is to introduce positive charge on the membrane surface by the presence of quaternary ammonium group which might displace divalent metal ion such as magnesium or calcium present in the bacteria cell wall. Efficacy of cell membrane disruption depends on the mobility of the agents available directly on the surface environment. In this review, various biocidal agents like quaternary ammonium group, helamine or zwitter ion containing membrane are discussed.

Microbial Tansformatin of $\gamma$-Butyrobetaine into L-Carnitine by Achromobacter cylcoclast (Achromobacter cycloclast에 의한 $\gamma$-Butyrobetaine의 L-Carnitine에로의 생물전환)

  • 이은구;이인영;박영훈
    • KSBB Journal
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    • v.14 no.2
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    • pp.205-211
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    • 1999
  • We investigated optimal conditions for the microbial transformation of $\gamma$-butyrobetaine into L-carnitine by using Achromobacter cycloclast ATCC 21921. When the cells were cultivated in the medium containing $\gamma$-butyrobetaine as the sole carbon source for both cell growth and L-carnitine production, the maximum L-carnitine production was 2.9 g/L and the conversion yield from $\gamma$-butyrobetaine to L-carnitine was as low as 30.9 mol%. In order to enhance the L-carnitine production and the conversion yield, various carbon sources were added to the $\gamma$-butyronetaine containing basal medium. In the medium supplemented with glycerol, L-carnitine production was as high as 4.6 g/L and the conversion yield was 88.2 mol%, showing a significant improvement in L-carnitine synthesis compared to those in the medium without glycerol. We also examined the additional effect of quaternary ammonium compounds such as betaine and choline, which are similar in structure to $\gamma$-butyrobetaine and L-carnitien. It was observed that in the presence of those quaternary ammonium compounds, both the L-carnitine production rate and the conversion yield increased. In addition, we found that cell growth was inhibited by a $\gamma$-butyrobetaine concentration of more than 3%, while L-carnitine production was efficient at the $\gamma$-butyrobetaine concentration of 2-3%. By cultivating the cells in the optimal medium containing glycerol and choline, we obtained an L-carnitine concentration of 7.2 g/L with the conversion yield of 98.7 mol% in 4 days.

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Morphological Correlation and Chronology of Lower Terrace Formations of Southeastern Coast of Korea (한국 남동해안 저위단구 퇴적층의 지형대비 및 형성시기 고찰)

  • Choi, Weon-Hack;Kim, Ju-Yong
    • Proceedings of the Korean Quaternary Association Conference
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    • 2005.10a
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    • pp.48-54
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    • 2005
  • Terrace morphology is so conspicuous in the south eastern coastal areas. Coastal terraces can be divided into 5 main surfaces, including beach and coastal alluvial plain(AP, $4{\sim}5m$), Low Terrace(LT, 8 $^{\sim}$ 25m), Middle Terrace(MT, 36 $^{\sim}$ 55m), High Terrace(HT, 63 $^{\sim}$ 86m) and upper High Terrace(uHT, above 90m). Among them Lower Terrace Formation is distributed between 8m and 20m in altitude. Both Tephra deposited of LT2 formation and OSL datings of sand layers in LT 2 and LT 3 Formations support the age of the LT 2 formation is MIS 5d or 5e, most probably 5e. The age of LT 3 is interpreted MIS 5a, based on tephra production in organic mud layers and OSL dating of sand deposits just above the beach pebbles of the LT 3. Particularly the transgression, possibly equivalent to the well-known Monastirrian episode in the Mediterranean Sea.

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The Experimental Study on Hydration Properties of Quaternary Component Blended High Fluidity Concrete with CO2 Reduction (탄소저감형 4성분계 고유동 콘크리트의 수화 특성에 관한 연구)

  • Choi, Yun-Wang;Oh, Sung-Rok;Jo, Jun-Hee;Kang, Hyun-Jin
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.5 no.4
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    • pp.403-413
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    • 2017
  • In this paper, to increase the use of industrial byproducts for $CO_2$ reduction and to improve construction performance, it was manufactured that $CO_2$ reduction type quaternary component high fluidity concrete (QC-HFC) with Reduced cement usage by more than 80% and its quality and hydration characteristics were evaluated. QC-HFC was found to satisfy the target performance, and the flow and mechanical properties were similar to those of conventional concrete. The drying shrinkage of QC-HFC decreased about twice compared with the conventional blend, and the hydration heat decreased about 36%. As a result, it can be concluded that the amount of cracks can be reduced by reducing temperature stress due to hydration heat reduction effect and reducing deformation due to relatively small temperature difference between inside and outside. Also, As a result of the simulation of the mass structure, the temperature cracking index of QC-HFC is 1.1 or more, and the cracking probability is reduced by about 35%, so that the crack due to temperature can be reduced.

Influence of Selenization Pressure on Properties of CIGS Absorber Layer Prepared by RF Sputtering

  • Jung, Sung Hee;Choi, Ji Hyun;Chung, Chee Won
    • Current Photovoltaic Research
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    • v.4 no.3
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    • pp.87-92
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    • 2016
  • The effects of selenization pressure on the structural, optical and electrical properties of the CIGS thin films prepared by RF magnetron sputtering using a single quaternary target were investigated. At selenization pressures lower than atmospheric pressure, CIGS thin films formed non-stoichiometric compounds due to deficiencies of Se vapor. In contrast, when selenization process was conducted at above atmospheric pressure, the residence time of Se vapor inside the tube increased so that the Se element could be incorporated within vacant sites of the CIGS structure, resulting in the formation of stoichiometric CIGS thin films. High quality CIGS thin films could be obtained when the selenization process was performed at pressures greater than atmospheric and $550^{\circ}C$.