• Title/Summary/Keyword: Quaternary structure

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Study on the Alkaloids from Thalictrum fauriei

  • Chen, Chung-Hsiung
    • Korean Journal of Pharmacognosy
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    • v.17 no.1
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    • pp.49-54
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    • 1986
  • To explore the biological activities of Thalictrum alkaloids, a study was initiated to investigate the alkaloidal constituents from T. fauriei, a species indigenous to Taiwan. Extensive fractionation of the ethanolic extract provided three known aporphines, (+)-oconovine (Ia), (+)-isocorydine (Ib), and (+)-corydine (Ic) from nonphenolic tertiary base fraction. From quaternary base fraction two new protoberberinium salts, thalifaurine (IIa), dehydrodiscretine (IIb), in addition to magnoflorine (III), were isolated. The structure of both new compounds were confirmed by total syntheses. Fractionation of phenolic bases yielded a dihydromorphinandienone, (-)-ocobotrine (IV), as well as a novel aporphine-pavine dimer, tentatively named EP-10. The structure of EP-10 was established by means of 2D NMR studies. Preliminary study indicated a weak activity of lyzing Hela cells, in vitro, for EP-10.

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TEM Observations on the Blue-green Laser Diode (청녹색 레이저 다이오드 구조에 관한 TEM 관찰)

  • Lee, Hwack-Joo;Ryu, Hyun;Park, Hae-Sung;Kim, Tae-Il
    • Applied Microscopy
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    • v.27 no.3
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    • pp.257-263
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    • 1997
  • Microstructural characterizations of II-VI blue laser diodes which consist of quaternary $Zn_{1-x}Mg_xS_ySe_{l-y}$ cladding layer, ternary $ZnS_ySe_{l-y}$ guiding layer and $Zn_{0.8}Cd_{0.2}Se$ quantum well as active layer were carried out using the transmission electron microscope working at 300 kV. Even though the entire structure is pseudomorphic to GaAs substrate, the structure had contained numerous extended stacking faults and dislocations which had created at ZnSe/GaAs interfaces and then further grown to the top of the epilayers. These faults might be expected to cause the degradation and shortening the lifetime of laser devices.

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Structural Characteristics of NiSOD from Streptomyces seoulensis

  • Lee, Jin-Won;Wuerges, Jochen;Carugo, Kristina Djinovic;Kang, Sa-Ouk
    • Proceedings of the Korean Biophysical Society Conference
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    • 2002.06b
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    • pp.50-50
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    • 2002
  • The heterologous expression of sodN gene from Streptomyces seoulensis in Streptomyces lividans together with the gel filtration and sedimentation equilibrim data indicated that the quaternary structure of NiSOD is homohexamer, which is novel among SODs, not the previously reported homotetramer. The EPR spectrum of $^{61}$ Ni (I = 3/2) substituted NiSOD showed a clear resolved hyperfine structure at g=2.016, unambiguously identifying that the EPR signal from NiSOD is due to Ni.(omitted)

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The microstructure and adhesive characteristics of Ti-Al-V-N films prepared by reactive magnetron sputtering (반응성 마그네트론 스퍼터링법으로 제조한 Ti-Al-V-N 박막의 미세조직 및 부착특성에 관한 연구)

  • Sohn, Yong-Un;Lee, Young-Ki
    • Journal of the Korean Society for Heat Treatment
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    • v.12 no.3
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    • pp.199-205
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    • 1999
  • The quaternary Ti-Al-V-N films have been grown on glass substrates by reactive dc and rf magnetron sputter deposition from a Ti-6Al-4V target in mixed Ar-$N_2$ discharges. The Ti-Al-V-N films were investigated by means of X-ray diffraction(XRD), electron probe microanalysis(EPMA) and scratch tester. Both XRD and EPMA results indicated that the Ti-Al-V-N films were of single B1 NaCl phase having columnar structure with the (111) preferred orientation. Scratch tester results showed that the adhesion strength of Ti-Al-V-N films which treated with substrate heating and vacuum annealing was superior to that of as-deposited film. The good adhesion strength was also achieved in the double-layer structure of Ti-Al-V-N/Ti-Al-V/Glass.

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Attachment of Silver Nanoparticles to the Wool Fiber Using Glycidyltrimethylammonium Chloride(GTAC) (Glycidyltrimethylammonium Chloride(GTAC)를 이용한 양모 섬유 표면의 Silver Nanoparticle 부착)

  • Lee, Seungyoung;Sul, In Hwan;Lee, Jaewoong
    • Textile Coloration and Finishing
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    • v.28 no.2
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    • pp.70-76
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    • 2016
  • Silver nanoparticles(AgNPs) were attached to wool fibers using glycidyltrimethylammonium chloride(GTAC), which is a type of quaternary ammonium salt. GTAC, which contains an epoxy functional group that, under high temperatures, generates a ring-opening reaction with wool fibers, which contain the amine group. Then, the AgNPs are attached to the surface of the GTAC-treated wool fibers by treatment with a silver colloidal solution. The process involves the following procedures: (1) The wool fibers are immersed in the GTAC solution, followed by pre-drying at $80^{\circ}C$ and curing at $180^{\circ}C$ to induce an alteration in the chemical structure; and (2) The wool fibers treated with GTAC are immersed in the silver colloid at $40^{\circ}C$ for 120 min to chemically induce a strong attachment of the AgNPs to the wool fibers. Scanning electron microscopy was used to analyze the influence of the concentrations of GTAC and the silver colloid, as well as the influence of the applied temperature of the silver colloid on the wool fibers, and the influence of the morphological changes in the wool fiber surfaces. As a result, the enhanced concentrations of GTAC and the silver colloid together with an elevated applied temperature of silver colloid have a tendency to increase in Ag atomic%.

Global Warming Effects on the Cambial Growth of Larix leptolepis in Central Korea : Predictions from Simulation Modeling (지구온난화에 따른 중부 한국 낙엽송의 형성층 생장 예측: 시뮬레이션 모델링)

  • Won-Kyu Park;Eugene Vaganov;Maria Arbatskaya;Jeong-Wook Seo;Je-Su Kim
    • The Korean Journal of Quaternary Research
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    • v.14 no.1
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    • pp.57-63
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    • 2000
  • A simulation model was used to examine the effects of climate variation on the tree-ring structure of Larix leptolepis trees growing at a plantation plot in Worak National Park in central Korea. The model uses mathematical equations to simulate processes affecting cell(tracheid) size variations for individual rings using daily precipitation and temperature measurements. Limiting conditions are estimated from temperature, day length and a calculated water balance. The results indicate that the seasonal growth is mostly limited by the soil moisture content and precipitation income during April and May. The April-May temperature also inversely influences the growth by increasing water losses from soil. The global climate-change scenario which includes regional warming(increasing temperature in spring-summer periods) appears to decrease the duration of optimal growths. Consequently, the model estimated that Larix leptolepis would lose the total production of xylem by 25%.

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Synthesis of Hydroxy-terminated Poly(propylene carbonate) (Hydroxy-terminated Poly(propylene carbonate)의 합성)

  • Jung, S.M.;Moon, J.Y.;Park, D.W.;Park, S.W.;Lee, J.K.
    • Applied Chemistry for Engineering
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    • v.9 no.2
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    • pp.273-277
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    • 1998
  • The synthesis of hydroxy-terminated poly(propylene carbonate)(HTPPC) was performed by the reaction of propylene carbonate(PC) with alcohol initiator using metal alkoxides, crown ethers and quaternary onium salts as catalysts. The effects of catalyst structure, types and concentration of alcohol, and solvent were investigated. Among the alkoxide catalysts tested, the ones with higher Lewis acidity and with more nucleophilic alkoxide anion showed higher catalytic activity. Mixed catalysts of metal alkoxied and crown ether showed higher conversion of PC than metal alkoxide alone. Quaternary onium salts of bulky cation exhibited higher catalytic activity. High polar solvent showed higher yield of HTPPC and the yield increased with the decrease of [PC]/[Initiator] ratio.

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Climate Change Concerns in Mongolia

  • Dagvadorj, D.;Gomboluudev, P.;Natsagdorj, L.
    • The Korean Journal of Quaternary Research
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    • v.17 no.2
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    • pp.47-54
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    • 2003
  • Climate of Mongolia is a driven force on natural conditions as well as socio-economic development of the country. Due to the precariousness of climate conditions and traditional economic structure, natural disasters, specially disasters of meteorological and hydrological origin, have substantial effect upon the natural resources and socio-economic sectors of Mongolia. Mongolia's climate is characterized by high variability of weather parameters, and high frequency and magnitude of extreme climate and weather events. During the last few decades, climate of the country is changing significantly under the global warning. The annual mean air temperature for the whole territory of the country has increased by $1.56^{\circ}C$ during the last 60 years,. The winter temperature has increased by $1.56^{\circ}C$. These changes in temperature are spatially variable: winter warming is more pronounced in the high mountains and wide valleys between the mountains, and less so in the steppe and Gobi regions. There is a slight trend of increased precipitation during the last 60 years. The average precipitation rate is increased during 1940-1998 by 6%. This trend is not seasonally consistent: while summer precipitation increased by 11 %, spring precipitation decreased by 17. The climate change studies in Mongolia show that climate change will have a significant impact on natural resources such as water resources, natural rangeland, land use, snow cover, permafrost as well as major economic activities of arable farming, livestock, and society (i.e. human health, living standards, etc.) of Mongolia. Therefore, in new century, sustainable development of the country is defined by mitigating and adaptation policies of climate change. The objective of the presentation is to contribute one's idea in the how to reflect the changes in climate system and weather extreme events in the country's sustainable development concept.

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Design of paraleel adder with carry look-ahead using current-mode CMOS Multivalued Logic (전류 모드 CMOS MVL을 이용한 CLA 방식의 병렬 가산기 설계)

  • 김종오;박동영;김흥수
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.18 no.3
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    • pp.397-409
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    • 1993
  • This paper proposed the design methodology of the 8 bit binary parallel adder with carry book-ahead scheme via current-mode CMOS multivalued logic and simulated the proposed adder under $5{\mu}m$ standard IC process technology. The threshold conditions of $G_K$ and $P_K$ which are needed for m-valued parallel adder with CLA are evaluated and adopted for quaternary logic. The design of quaternary CMOS logic circuits, encoder, decoder, mod-4 adder, $G_K$ and $P_K$ detecting circuit and current-voltage converter is proposed and is simulated to prove the operations. These circuits are necessary for binary arithmetic using multivalued logic. By comparing with the conventional binary adder and the CCD-MVL adder, We show that the proposed adder cab be designed one look-ahead carry generator with 1-level structure under standard CMOS technology and confirm the usefulness of the proposed adder.

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Half-metallicity and Magnetism at the (001) Surfaces of the Quaternary Heusler Alloys CoFeCrZ (Z = Ga, Ge): A First-principles Study (4원 호이슬러 합금 CoFeCrZ(Z = Ga, Ge)의 (001) 표면에서의 자성과 반쪽금속성: 제일원리 계산 연구)

  • Kim, Dong-Chul;Lee, Jae Il
    • Journal of the Korean Magnetics Society
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    • v.25 no.2
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    • pp.31-38
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    • 2015
  • Recently, a first-principles study led to a prediction that quaternary Heusler compounds, CoFeCrZ (Z = Ga, Ge) are excellent half-metallic ferromagnets. In this study, we investigate the electronic and the magnetic properties at the (001) surfaces of CoFeCrGa and CoFeCrGe by means of the full-potential linearized augmented plane wave (FLAPW) method within generalized gradient approximation. We considered two types of surface termination: CoFe-terminated and CrZ-terminated surfaces, Z being either Ga or Ge. From the calculated total magnetic moments and the local density of states, we found that half-metallicity is not preserved for all the surfaces. But the calculated atomic density of states showed that CrGa-terminated surface of the CoFeCrGa is almost half-metallic. The magnetic moment of the Co, Fe, or Cr atoms at the surface or subsurface layers in each system had very different values.