• Bulletin of the Korean Chemical Society
• /
• v.34 no.12
• /
• pp.3847-3850
• /
• 2013

• Journal of the Korean Society of Safety
• /
• v.6 no.4
• /
• pp.13-20
• /
• 1991

Ion-selective electrode responsive to the thiocynate ion prepared by using the quaternary ammonium salts as a active material and PVC as a membrane matrix. The effect of chemical structure and composition of active material, and the membrane thickness on the linear response. the detection limit, and Nernstian slope of the electrode studied. Under the above optimum conditions of membrane, the effect of pH and the selectivity coefficients to various interfering anions were compared and investigated. It was concluded that the functions of thiocynate ion-selective electrode(ISE) were closely related to the chemical structure of the quaternary ammonium salts. The linear response, and the detection limit of the electrode potential increased with the increase of the carbon chain length of the alkyl group in the quaternary ammonium salts in the ascending order of Aliquat 336T, TOAT, TDAT, and TDDAT. The optimum membrane thickness was 0.3mm. The electrode characteristics was better with the decrease of the concentration of active material, and the best concentration was 3 weight percent. The membrane potential was independent of the pH variation in the region from pH 2 to 12. The order of the selectivity coefficients is as follows：Cl $O_4$$^{[-10]}$ ＞ $I^{[-10]}$ ＞N $O_3$$^{[-10]}$ ＞B $r^{[-10]}$ ＞ $F^{[-10]}$ ＞C $l^{[-10]}$ ＞O $A_{c}$ $^{[-10]}$ 〓S $O_4$$^{2-}$.

• The Korean Journal of Quaternary Research
• /
• v.22 no.2
• /
• pp.1-5
• /
• 2008

Some reverse fault lines pass through the alluvial fans and west hill slope of Bulguksa mountains including Mt. Toham in the directions of N-S and NW-SE. The study area is known as relatively unstable, because of active faults. Assuming the record of earthquake in the Samguksagi, the architects in the construction of the Bulguksa temple should have recognized the possibility of breakdown from the earthquakes and the need for an unique structure against at that time. Against earthquakes, Greavee technique, a stonework construction technique following woothe one and use of Chushouok (Dongtleouok or Chumchaouok) were applied for the construction of Bulguksa temple. By designing the foundation stone with hole, a structure is prevented from motiff Ction that pillarsakdcede from a foundation stone in spite of horizontal load of earthquake while woot construction isaktrong frame at earthquake. The Bulguksa-temple isausually evaluated to be a beautiful architecture from the appeaultces like the weight balltced structure with unique decoration. ampressive architectures are beautiful in balance and harmony coming from the important and specific rolls in its own way by each part of whole structure. This beauty comes from the science.

• Journal of the Society of Cosmetic Scientists of Korea
• /
• v.14 no.1
• /
• pp.16-37
• /
• 1988

A new quaternary ammonium compound, hydrolyzed ginseng-sapoin quaternary (HGSQ), from hydrolyzed Korean ginseng-saponin and 2, 3-epoxypropyltrimethyl ammonium chloride has been developed as a conditioning agent for hair care products. This structure has the hydrophilic group from the introduced cationic and the hydrophobic group from the aglycone of ginseng saponin. Its properties: surface tension, conductivity, critical micelle concentration, eye irritation, sorption onto hair, force reduction (%) for 20% extension and moisture retention effect comparing with the commercial standards. Also half-head tests of HGSQ-containing shampoo were carried out to compare the conditioning effects in shampoos.

• The Korean Journal of Quaternary Research
• /
• v.13 no.1
• /
• pp.79-89
• /
• 1999

Three deep borings to obtain vertical continuous samples including weathered basement soils (KP-1, KP-2 and KP-3) were carried out in the reclaimed Kimpo tidal flat with purposes to establish late Quaternary stratigraphy. On the basis of detailed observations and descriptions on color, sedimentary structure and textural composition of cored sediments, four lithostratigraphic units are classified. From the stratigraphic top to bottom, they are Holocene tidal sand and muddy deposit (Unit I), early Holocene freshwater marsh muddy deposit (Unit II), late Pleistocene tidal sand and muddy deposit (Unit III) and late Pleistocene basal fluvial gravel deposit (Unit IV). In particular, Unit III is divided into two parts: the upper part-weathered and cryoturbated part during the Last Glacial Maximum (Unit III-a) and the lower part-unweathered tidal sand and muddy deposit (Unit III-b).

• Journal of Powder Materials
• /
• v.12 no.4 s.51
• /
• pp.303-308
• /
• 2005

Various kinds of Mg-Zn-Ca base alloys were rapidly quenched via melt spinning process. The meltspun ternary and quaternary alloy ribbons were heat-treated, and then the effects of additional elements on age hardening behavior and phase change of precipitates were investigated using Vickers hardness tester, XRD, and TEM equipped with EDS system. In ternary alloys, age hardening was mostly due to the distribution of $Mg_6Ca_2Zn_3$ and $Mg_2Ca$. The stable phases of precipitates were varied according to the aging temperature and the alloy composition. With the increase of Ca content, $Mg_2Ca$ precipitates were detected more than $Mg_6Ca_2Zn_3$ precipitates. In quaternary alloys, the precipitates taken from Mg-Zn-Ca-Co were identified as new quaternary phase, whereas those taken from Mg-Zn-Ca-Zr as MgZnCa containing Zr. In general, the ternary alloy showed higher peak hardness and thermal stability than the quaternary considering the total amounts of the solutes. It implies that the structure of precipitate should be controlled to have the coherent interface with the Mg matrix.

• The Korean Journal of Quaternary Research
• /
• v.11 no.1
• /
• pp.25-38
• /
• 1997

한국서남해안에 위치한 해남만의 조수 퇴적층(체)에 관한 층서 설정이 제4기후기 (late Quaternary)의 시간범위로 가능하였다. 즉 현재의 해남만에 분포하고 있는 조간대층은 지난 중기와 후기 현세(middle to late Holocene)동안에 형성된 퇴적지층단위(depositional sequence unit)이며 이 지층단위는 선현세(late Pleistocene)조간대 퇴적지층단위 disconformity 의 부정합 관계로 피복하고 있다 본연구에서는 전자를 Unit I(8-10m 내외의 두께)이라 칭하고 후자를 Unit II(10m 내외의 두께)라고 구분 명명하였다, 그런데 Unit II는 암상(lithofacies)의 특징에 근거하여 상부(upper part)와 하부(lower part)로 나누어진다. 상 부는 약 3-4m 의 두께를 가지고 있으며 황갈색을 분명히 나타내며 게 구멍 화석과 동토구 조(cryogenic structure)그리고 매우 높은 값의 전단응력을 나타낸다, 그러나 하부는 회색을 띄며 낮은 전단응력 값을 나타내 상부와 뚜렷이 구분된다 이러한 Unit II의 상부가 나타내 는 암상적 특징은 지난 간빙하기(Eemian interglacial time)에 형성된 오늘과 같은 조간대층 이 18,000년 전후의 최대 빙하기(last glacial maximum : LGM) 동안의 지배하에 노출되었 고 오랜동안 토양형성 과정이 풍화작용을 받은 증거를 나타내고 있다, 따라서 이지층의 층 서학적 단위 설정과 부정합 (disconformity) 적인 경계의미는 우리나라 제4기 층서(late Quaternary stratigraphy)를 규정하는데 매우 중요하다고 제안하는 바이다.

• Journal of the Korean Regional Science Association
• /
• v.6 no.2
• /
• pp.107-121
• /
• 1990

The structural change of occupational composition with the coming of post-industrial society is most evidently observed in the developed country. Specially representative of social changes is the emergence of new occupational sectors, such as the so-called quaternary and quinary sectors, which are based on the use of information technology and managerial skills. The paper raises the question of how and in what this chage of occupational components in a mtro area affects the existing residential structure over the period. In order to extend the discussion of the question, the related hypothetical statements on urban spatial impact due to transformation of the society have xtnsively considered and identified a possible multicenter structure concentration and deconcentration of new jobs and population over the metro area. For further examination, the renowned high tech city of Minneaplis -St. Paul has been selected and the occupational labour forces data for 1960 and 1980 analyzed. As a whole, this area has experienced a dispersal and reconcentration of population in new patterns which have resulted from changes in the occupational structure. In particular, the residential area of white-coller workers(the quaternary / quinary or information workers) has expanded into the city from a suburban core area. In this process, a large proportion of the manual-worker's residential areas in the central city either disappeared or diminished. Consequently, other isolated centers created by the manualworker residents are emerging in both the central city and suburbs. Thus, the development of mulitple centers or cores based on the distribution of occupational characteristics can be considered as a typical ongoing pattern of metro areas in the Unite States.

• The Korean Journal of Quaternary Research
• /
• v.9 no.1
• /
• pp.43-60
• /
• 1995

The Kanweoldo Deposit in the Cheonsoo Bay western coast of Korean Peninsula is considered to be influenced by severe freezing condition under cold humid environment of the last glacial age. The evidence of severe freezing in the some upper part of the fine-grained Kanweoldo Deposit is characteristically irregular wavy la-mellar structure with the interval of 2∼8mm. In particular lamina show very compacted fabrics composed of rounded or spheroidal discrete aggregates covered by silt caps. Such laminar structure and associated micro-fabrics might owe to soil freezing such as ice segregation in lens form cryophoresis pressure from growing ice and disturbance by frost-creep. Furthermore pedogenesis of cold-humid type such as gleyzation or peseudo-gleyzation also might af-fect the kanweoldo Deposit in the priod of severe cold-humid cli-mate of the Wrm. The Kanweoldo sediment and organic remnant(16,708 B.P. with error limit of 250 years) affected by severe cryogenic activities sug-gest that the paleoclimate of Late Wrm in Korea might be so cold and humid as to engender the cryogenic structure in subaerial silty and sandy silt deposits.

• The Korean Journal of Quaternary Research
• /
• v.17 no.2
• /
• pp.13-14
• /
• 2003

It is generally well known that Quaternary is characteristic geologically in terms of glacial and interglacial repeats and their associated unconformity formation. This paper deals with the first finding of the characteristic and significant meaningful unconformity between Holocene and late Pleistocene, which implies submergence and emergence of the tidal sedimentary basin along the western coastal zone of Korea during interglacial stage(IOS-5e) and glacial time(IOS-2). The stratigraphy of intertidal deposits in the Haenam Bay, western coast of Korea shows two depositional sequence units (Unit I of Holocene and Unit II of late Pleistocene) bounded by an erosional surface of disconformity. The disconformity is related to the latest Pleistocene sea-level lowstands (probably during the LGM). The Unit II is interpreted as intertidal deposit showing tidal sedimentary structures and crab burrow ichnology and has two parts (the upper part and the lower part) showing different lithology and character. The upper part of Unit II shows characteristic subaerial exposure features (emergence) and its related lithology. Such subaerially exposed upper part (more or less 4m to 5m in thickness) is characterized by yellow-brownish sediment color, cryoturbat-ed structure, crab burrow ichnofacies and high value of shear strength. Geochemical and clay mineral analyses of the upper part sediments also indicate subaerial exposure and weathering. In particular, very high value of magnetic susceptibility of the upper part in comparison to that of the lower part is interpreted as pedogenetic weathering during the subaerial exposure period.