• Title/Summary/Keyword: Quasi steady state

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Plasma nitridation of atomic layer deposition-Al2O3 by NH3 in PECVD

  • Cha, Ham cho rom;Cho, Young Joon;Chang, Hyo Sik
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.304.1-304.1
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    • 2016
  • We have investigated the effect of plasma nitridation of atomic layer deposited-Al2O3 films of monocrystalline Si wafers and the thermal properties of nitridated Al2O3 films. Nitridation was performed on Al2O3 to form aluminum oxynitride (AlON) using NH3 plasma treatment in a plasma-enhanced chemical vapor deposition and it was conducted at temperature of $400^{\circ}C$ with various plasma power condition. After nitridation, we performed firing and forming gas annealing (FGA). For each step, we have observed the minority carrier lifetime and the implied Voc by using quasi-Steady-State photoconductance (QSSPC). We confirmed a tendency to increase the minority carrier lifetime and the implied Voc after the nitridation. On the other hand, the minority carrier lifetime and the implied Voc was decreased after Firing and forming gas annealing (FGA). To get more information, we studied properties of the plasma treated Al2O3 films by using Secondary Ion Mass Spectroscopy (SIMS) and X-ray Photoelectron Spectroscopy (XPS).

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Effects of Friction Pressure on Bonding Strength and a Characteristic of Fracture in Friction Welding of Cu to Cu-W Sintered Alloy (동-텅스텐 소결합금(Cu-W)과 동(Cu)의 마찰용접에서 마찰압력이 접합강도와 파단특성에 미치는 영향)

  • 강성보;민택기
    • Journal of Welding and Joining
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    • v.15 no.4
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    • pp.90-98
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    • 1997
  • A copper-tungsten sintered alloy(Cu-W) has been friction welded to a tough pitch copper in order to investigate the effect of friction pressure on bonding strength and a charicteristic of fracture. The tensile strength of the friction welded joint was increased up to 90% of the Cu base metal under the condition of friction time 1.2 sec, friction pressure 4.5kgf/$\textrm{mm}^2$ and upset pressure 10kgf/$\textrm{mm}^2$. From the results of fracture surface analysis, the increase of friction pressure could remarkably decrease the force and the time to be normally acted on weld interface. The W particles which were included in the plastic zone of Cu side could induce fracture adjacent to the weld interface because their existance in Cu induces a decrease in available section area and an increase in notch effect. Therefore, the tensile strength was decreased at high friction pressure (6kgf/$\textrm{mm}^2$) because the destruction of W was increased by an increase in mechanical force and crack was formed at weld interface.

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Zero Voltage Soft Switching PWM High-Frequency Inverter with Active Inductor Snubber for Induction Heated Roller in New Type Copy Machine

  • Muraoka S.;Feng Y.L.;Kunimoto H.;Chandhaket S.;Okuno A.;Nakaoka M.
    • Proceedings of the KIPE Conference
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    • 2001.10a
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    • pp.75-79
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    • 2001
  • This paper presents a novel version of an active voltage clamped ZVS-PWM high frequency inverter using IGBTs for electromagnetic induction eddy current-based rolling drum heating in new generation copy and printing machines in consumer business use. The operating principle of this inverter circuit and unique features are described herein. Its constant frequency duty cycle (asymmetrical PWM) controlled voltage source quasi-resonant soft switching high frequency inverter employing IGBTs is proposed, which is capable of achieving stable and efficient zero voltage soft switching commutation over a widely specified power regulation range from full power to low power. The operating performances in a steady state of this inverter is discussed and evaluated on basis of simulation and experimental results as an induction heated roller in new generation copy machine.

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Hydraulic Model Experiment on Circulation in Sagami Bay, Japan (IV) -Time-Varying States of Flow Pattern and Water Exchange in Baroclinic Rotating Model-

  • Choo, Hyo-Sang;Takasige Sugimoto
    • Environmental Sciences Bulletin of The Korean Environmental Sciences Society
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    • v.3 no.1
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    • pp.57-73
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    • 1999
  • Baroclinic hydraulic model experiments on the time-varying states of the flow pattern and water exchange in Sagami Bay were carried out based on quasi-steady state experiments on the flow pattern. For the model experiments, density changes as well as time changes in the volume transport of the upper layer were executed to investigate the flow response of the bay in the case of a sudden inflow of low density water and variable volume transport into the Sagami Bay. The results of the model experiments showed that when the volume transport was increased frontal eddies or frontal wave streamers from the Kuroshio Through Flow were transferred to the inner part of the bay along with cyclonic circulation in the bay. In addition, density boundary currents appeared and flowed along the eastern boundary of the bay. As the upper layer density decreased, frontal eddies, frontal streamers and coastal boundary density currents occurred and proceeded along the eastern boundary of the bay at a high speed.

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Instantaneous Speed Variation of Crankshaft on a Low Speed Marine Diesel Engine (저속박용디젤기관의 순간회전속도 변동에 관한 연구)

  • Choi, Jae-Sung;Lee, Jin-Uk;Lee, Sang-Dug;Cho, Kwon-Hae
    • Journal of Advanced Marine Engineering and Technology
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    • v.31 no.2
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    • pp.138-144
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    • 2007
  • The variation of the crankshaft speed in a multi-cylinder engine is determined by the resultant gas pressure torque and the torsional deformation of the crankshaft. Under steady state operation, the crankshaft speed has a quasi-periodic variation. For the diagnosis the engine instantaneous speed versus crankshaft angle is utilized. This paper describes a simple measurement method of the engine instantaneous speed versus crankshaft angle using the teeth on the flywheel of the crankshaft. Two non-contacting magnetic pickup combinations detect the crank angle and TDC position for the data acquisition. The results from experiments on a 6 cylinder marine diesel engine demonstrate that the crankshaft speed variation are detected with good resolution. And the crankshaft speed variation is investigated according to the operation conditions. Also, it is confirmed that the engine output measured by EMS can be evaluated larger than the actual value due to TDC position error caused by instantaneous speed variation.

Hydrogen production by catalytic decomposition of methane over carbon black catalyst in a fluidized bed (카본블랙 촉매를 이용한 유동층 반응기에서 메탄의 직접 열 분해에 의한 수소생산 연구)

  • Jung, Jae-Uk;Nam, Woo-Seok;Yun, Ki-Jun;Lee, Dong-Hyun;Han, Gui-Young
    • 한국신재생에너지학회:학술대회논문집
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    • 2005.06a
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    • pp.284-287
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    • 2005
  • A fluidized bed reactor made of quartz with 0.055 m I.D. and 1.0 m in height was employed for the thermocatalytic decomposition of methane to produce $CO_2 - free$ hydrogen. The fluidized bed was proposed for the continuous withdraw of product carbons from the reactor. The methane decomposition rate with the carbon black N330 catalyst was quickly reached a quasi-steady state rate and remained for several hour. The methane decomposition reaction was carried out at the temperature range of $850-925^{\circ}C$, methane gas velocity of $1.0U_{mf}\;3.0U_{mf}$ and the operating pressure of 1.0 atm. Effect of operating parameters such as reaction temperature, gas velocity on the reaction rates was investigated. The produced carbon by the methane decomposition was deposited on the surfaces of carbon catalysts and the morphology was observed by SEM image.

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Small-Signal Modeling and Control of Three-Phase Bridge Boost Rectifiers under Non-Sinusoidal Conditions

  • Chang, Yuan;Jinjun, Liu;Xiaoyu, Wang;Zhaoan, Wang
    • Journal of Power Electronics
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    • v.9 no.5
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    • pp.757-771
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    • 2009
  • This paper proposes a systematic approach to the modeling of the small-signal characteristics of three-phase bridge boost rectifiers under non-sinusoidal conditions. The main obstacle to the conventional synchronous d-q frame modeling approach is that it is unable to identify a steady-state under non-sinusoidal conditions. However, for most applications under non-sinusoidal conditions, the current loops of boost rectifiers are designed to have a bandwidth that is much higher than typical harmonics frequencies in order to achieve good current control for these harmonic components. Therefore a quasi-static method is applied to the proposed modeling approach. The converter small-signal characteristics developed from conventional synchronous frame modeling under different operating points are investigated and a worst case point is then located for the current loop design. Both qualitative and quantitative analyses are presented. It is observed that operating points influence the converter low frequency characteristics but hardly affect the dominant poles. The relationship between power stage parameters, system poles and zeroes is also presented which offers good support for the system design. Both the simulation and experimental results verified the analysis and proposed modeling approach. Finally, the practical case of a parallel active power filter is studied to present the modeling approach and the resultant regulator design procedure. The system performance further verifies the whole analysis.

Hydrogen production by catalytic decomposition of methane over carbon black catalyst in a fluidized bed on pressurized bench-scale condition (가압유동층 반응기에서 카본블랙 촉매를 이용한 메탄의 촉매분해에 의한 수소제조)

  • Seo, Hyung-Jae;Lee, Seung-Chul;Lee, Gang-In;Han, Gui-Young
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.06a
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    • pp.791-793
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    • 2009
  • Hydrogen has been recognized of the energy source for the future, in terms of the most environmentally acceptable energy source. A pressurized fluidized bed reactor made of carbon steel with 0.076 m I.D. and 1.0 m in height was employed for the thermocatalytic decomposition of methane to produce amount of $CO_2$ - free hydrogen with validity from a commercial point of view. The fluidized bed was proposed for withdrawing of product carbons from the reactor continuously. The methane decomposition rate with the carbon black N330 catalyst was rapidly reached a quasi-steady state and remained for several hour. The methane thermocatalytic decomposition reaction was carried out at the temperature range of 850 - 950 $^{\circ}C$, methane gas velocity of 2.0 $U_{mf}$ and the operating pressure of 1.0 -3.0 bar. Effect of operating parameters such as reaction temperature, pressure on the reaction rates was investigated and predicted the effect of a change in conditions on a chemical equilibrium thermodynamically, according to Le Chatelier's principle.

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Passivation Quality of ALD $Al_2O_3$ Thin Film via Silicon Oxide Interfacial Layer for Crystalline Silicon Solar Cells (실리콘 산화막의 두께에 따른 ALD $Al_2O_3$ 박막의 passivation 효과)

  • Kim, Young-Do;Park, Sung-Eun;Tark, Sung-Ju;Kang, Min-Gu;Kwon, Soon-Woo;Yoon, Se-Wang;Kim, Dong-Hwan
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.06a
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    • pp.93-93
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    • 2009
  • 실리콘 태양전지의 효율 향상을 위한 노력의 일환으로 결정질 실리콘 웨이퍼 표면passivation 물질 중 Atomic Layer Deposition (ALD)을 이용하여 증착한 $Al_2O_3$ 박막에 대한 관심이 증가하고 있다. 본 연구에서는 $Al_2O_3$ 박막의 증착 전 실리콘 웨이퍼의 산화막 두께에 따른 passivation 효과에 대해서 연구하였다. 실리콘 산화막은 $HNO_3$ 용액을 사용하여 화학적으로 생성시켰으며 $HNO_3$ 용액과의 반응 시간을 조절하여 실리콘 산화막의 두께를 조절하였다. 실리콘 산화막 생성 후 ALD로 $Al_2O_3$ 박막을 증착하였으며 증착 후 $N_2$ 분위기에서 annealing 하였다. Annealing 후 passivation 효과는 Quasi-Steady-State Photo Conductance를 사용하여 minority carrier의 lifetime을 측정하였다. Capacitance-Voltage measurement, Transmission Electron Microscopy, Ellipsometry를 사용하여 실리콘 산화막의 두께에 따른 $Al_2O_3$ 박막의 passivation 효과를 분석하였다.

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A study of rear surface passivation by $Al_2O_3$ thin film for ultra thin silicon solar cells (초박형 태양전지를 위한 후면 패시베이션 막의 특성 연구)

  • Park, Sung-Eun;Kim, Young-Do;Tark, Sung-Ju;Kang, Min-Gu;Kwon, Soon-Woo;Yoon, Se-Wang;Kim, Dong-Hwan
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.06a
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    • pp.94-94
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    • 2009
  • 최근 실리콘 태양전지는 점점 얇아 지는 추세에 있다. 실리콘 태양전지에 있어 실리콘의 두께를 감소시키는 것은 실리콘 소모량을 줄이는데 있어 필수적인 조건이 되었다. 이에 따라 실리콘 표면의 passivation도 더욱 중요하게 여겨지고 있다. 실리콘 태양전지의 passivation막의 한 종류인 $Al_2O_3$는 다른 산화막 물질들과는 달리 negative fixed charge를 가지고 있고 charge의 양이 다른 산화막의 density보다 높아 p-type 실리콘의 경우 후면 passivation막으로 이용이 고려되고 있다. 본 연구에서는 atomic layer deposition으로 $Al_2O_3$막을 실리콘 위에 증착하여 열처리에 따른 그 특성을 비교하고 태양전지를 제작하였다. $Al_2O_3$막을 rapid thermal annealing을 통해 서로 다른 분위기에서 열처리 한 결과를 capacitance-voltage를 통해 측정하여 비교, 분석하였고 ellipsomety 분석을 통해 광학적 특성을 비교하였다. 또한 열처리 온도의 변화에 따른 $Al_2O_3$내에 charge에 변화가 있다는 것을 관찰하였다. 이러한 charge의 변화가 태양전지의 passivation에 영향을 주는지 관찰하기 위해 Quasi-steady state photoconductace를 통해 lifetime의 변화를 관찰 하였다. 이러한 실험결과로부터 열처리 분위기와 온도를 최적화 하여 태양전지 passivation 특성을 증가시킬 수 있었다.

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