• Transactions of the Korean hydrogen and new energy society
• /
• v.28 no.1
• /
• pp.63-69
• /
• 2017

In this work, two different platinum (Pt) counter electrodes have been prepared by spin coating a Pt solution and screen printing a Pt paste on fluorine doped tin oxide (FTO) glass substrate followed by sintering at $380^{\circ}C$ for 30 min. Linear sweep voltammetry (LSV) and electrochemical impedance spectroscopy (EIS) analyses of the Pt electrodes showed that the spin coated electrode was catalytically more active than the screen printed electrode. The above result agrees well with the surface morphology of the electrodes studied by atomic force microscopy (AFM) and the photovoltaic performance of the dye-sensitized solar cells (DSSCs) fabricated with the Pt electrodes. Moreover, calculation of current density-voltage (j-V) curves according to diode model with the parameters obtained from the experimental j-V curves and the EIS data of the DSSCs provided a quantitative insight about how the catalytic activity of the counter electrodes affected the photovoltaic performance of the cells. Even though the experimental situations involved in this work are trivial, the method of analyses outlined here gives a strong insight about how the catalytic activity of a counter electrode affects the photovoltaic performance of a DSSC. This work, also, demonstrates how the photovoltaic performance of DSSCs can be improved by tuning the performance of counter electrode materials.

• Transactions of the Korean Society of Mechanical Engineers B
• /
• v.28 no.4
• /
• pp.441-448
• /
• 2004

A numerical study was conducted to show the effect of aspect ratio on the analogy of the developing laminar flows between in orthogonally rotating straight duct and in a stationary curved duct of rectangular cross-section. In order. to clarify the similarity of two nows, dimensionless parameters (equation omitted) and Rossby Ro= $w_{m}$$\Omega$ $d_{h}$, in a rotating straight duct were used as a set corresponding to Dean number, (equation omitted), and curvature ratio, λ=R/ $d_{h}$, in a stationary curved duct. Four. different aspect ratios A=0.25, 0.5, 2 and 4 were considered. Under the condition that the magnitudes of Ro and λ were large enough to satisfy the 'asymptotic invariance property' and the aspect ratio was larger than 1, there were strong quantitative similarities between the two flows such as flow patterns, friction factors, and maximum axial velocity magnitudes fur the same values of $K_{LR}$ and $K_{LC}$ . On the other hand, as the aspect ratio decreased below 1 (A=0.25 and 0.5), the difference of the secondary flow intensity between these two flows was enhanced and therefore the analogy of two flows was not so evident as that of the larger aspect ratio (A=2 and 4). 4).nd 4).

• Economic and Environmental Geology
• /
• v.45 no.2
• /
• pp.181-188
• /
• 2012

The 1M and $2M_1$ stacking sequences are the most frequently encountered in the illite species among the possible 6 polytypes. The $1M_d$, derived from the 1M polytype which exhibits a variable degree of disorder in the stacking sequence, is also observed in illite samples. In this paper, the author introduces and reviews the theoretical background of the quantitative analysis method of illite polytypes, and considers the possibility to determine the fault age and its reactivation age using K/Ar age-dating based on the quantification of illite polytypes in the fault system. For the increase of the accuracy and precision of the illite age analysis method, the occurrence, identification, and mineralogical characterization of illite polytypes should be defined in detail. The broadening effect of (hkl) reflections, due to disordering of 1M polytype and the presence of I/S minerals with expandability, are also considered as the main parameters controlling the quantification of illite polytypes using the WILDFIRE(C)simulation.

• Analytical Science and Technology
• /
• v.30 no.4
• /
• pp.174-181
• /
• 2017

Bio-liquid is a liquid by-product of the hydrothermal carbonization (HTC) reaction, converting wet biomass into solid hydrochar, bio-liquid, and bio-gas. Since bio-liquid contains various compounds, it requires efficient sampling method to extract the target compounds from bio-liquid. In this research, fatty acid methyl ester (FAME) in bio-liquid was extracted based on hollow fiber supported liquid phase microextraction (HF-LPME) and determined by Gas Chromatography-Flame Ionization Detector (GC-FID) and Gas Chromatography/Mass Spectrometry (GC/MS). The well-known major components of biodiesel, including methyl myristate, palmitate, methyl palmitoleate, methyl stearate, methyl oleate, and methyl linoleate had been selected as standard materials for FAME analysis using HF-LPME. Physicochemical properties of bio-liquid was measured that the acidity was 3.30 (${\pm}0.01$) and the moisture content was 100.84 (${\pm}3.02$)%. The optimization of HF-LPME method had been investigated by varying the experimental parameters such as extraction solvent, extraction time, stirring speed, and the length of HF at the fixed concentration of NaCl salt. As a result, optimal conditions of HF-LPME for FAMEs were; n-octanol for extraction solvent, 30 min for extraction time, 1200 rpm for stirring speed, 20 mm for the HF length, and 0.5 w/v% for the concentration of NaCl. Validation of HF-LPME was performed with limit of detection (LOD), limit of quantitation (LOQ), dynamic range, reproducibility, and recovery. The results obtained from this study indicated that HF-LPME was suitable for the preconcentration method and the quantitative analysis to characterize FAMEs in bio-liquid generated from food waste via HTC reaction.

• Journal of the Korean Society for Aeronautical & Space Sciences
• /
• v.30 no.4
• /
• pp.114-122
• /
• 2002

The integration of the landing gear system is a complex relationship between the many conflicting parameters of shock absorption, minimum stow area, complexity, weight and cost. Especially ground impact load and dynamic behaviors greatly influence design load of landing gear components as well as load carrying structural attachment. This study investigates ground impact load and dynamic behaviors of the T-50 landing gear system using ADAMS. Taking into account for various operational/environmental conditions, an analysis of shock absorbing characteristics at ground impact is performed with experience derived from a wide range of proprietary designs. Analytical results are presented for discussing the effects of aircraft horizontal and vertical speed, landing attitudes, shock absorbing efficiency. This analysis leads us to the conclusion that the proposed program is shown to be a better quantitative one that apply to a new development and troubleshooting of the landing gear system.

• Journal of the Korean Society for Nondestructive Testing
• /
• v.20 no.1
• /
• pp.10-17
• /
• 2000

In boiler high-temperature pipelines such as main steam pipe, header and steam drum in fossil power plants, conventional measurement techniques(replica method, electric resistance method, and hardness test method) for measuring creep damage have such disadvantages as complex preparation and measurement procedures, too many control parameters. And also, these techniques have low practicality and applied only to component surfaces with good accessibility. It needs to apply a reliable and quantitative ultrasonic nondestructive evaluation method that can be replaced for these equipment. In this study, both artificial creep degradation test using life prediction formula and frequency analysis by ultrasonic tests for crept specimens were carried out for the purpose of nondestructive evaluation for creep damage. As a result of ultrasonic tests for crept specimens, we conformed that the high frequency side spectra decrease and central frequency components shift to low frequency band, and also their bandwidth decreases as increasing creep damage in backwall echos.

• Journal of the Korean Society for Nondestructive Testing
• /
• v.20 no.1
• /
• pp.18-26
• /
• 2000

Boiler high-temperature pipelines such as main steam pipe, header and steam drum in fossil power plants are degraded by creep damage due to severe operating conditions such as high temperature and high pressure for an extended period time. Conventional measurement techniques(replica method, electric resistance method, and hardness test method) for measuring creep damage have such disadvantages as complex preparation and measurement procedures, too many control parameters. And also these techniques have low practicality and applied only to component surfaces with good accessibility. In this paper, artificial creep degradation test and ultrasonic measurement for their creep degraded specimens(Cr-Mo alloy steels) were carried out for the purpose of evaluation for creep damage. Absolute measuring method of quantitative ultrasonic measurement for material degradation was established, and long term creep degradation tests using life prediction formula were carried out. As a result of ultrasonic tests for crept specimens. we conformed that both the sound velocity decreased and attenuation coefficient linearly increased in proportion to the Increase of creep life fraction($\Phi$c).

• Journal of radiological science and technology
• /
• v.40 no.2
• /
• pp.237-243
• /
• 2017

This study evaluated the applicability of computer-aided diagnosis by retrospective analysis of GLCM algorithm based on cytopathological diagnosis of normal and malignant nodules in thyroid ultrasound images. In the experiment, the recognition rate and ROC curve of thyroid malignant nodule were analyzed using 6 parameters of GLCM algorithm. Experimental results showed 97% energy, 93% contrast, 92% correlation, 92% homogeneity, 100% entropy and 100% variance. Statistical analysis showed that the area under the curve of each parameter was more than 0.947 (p = 0.001) in the ROC curve, which was significant in the recognition of thyroid malignant nodules. In the GLCM, the cut-off value of each parameter can be used to predict the disease through analysis of quantitative computer-aided diagnosis.

• Korean Journal of Remote Sensing
• /
• v.27 no.6
• /
• pp.703-715
• /
• 2011

Forests have been considered one of the most important ecosystems on the earth, affecting the lives and environment. The sustainable forest management requires accurate and timely information of forest and tree parameters. Appropriately interpreted remotely sensed imagery can provide quantitative data for deriving forest information temporally and spatially. Especially, analysis of individual tree detection and crown delineation is significant issue, because individual trees are basic units for forest management. Individual trees in aerial imagery have reflectance characteristics according to tree species, crown shape and hierarchical status. This study suggested a method that identified individual trees and delineated crown boundaries through adopting gradient method algorithm to amplified greenness data using red and green band of aerial imagery. The amplification of specific band value improved possibility of detecting individual trees, and gradient method algorithm was performed to apply to identify individual tree tops. Additionally, tree crown boundaries were explored using spectral intensity pattern created by geometric characteristic of tree crown shape. Finally, accuracy of result derived from this method was evaluated by comparing with the reference data about individual tree location, number and crown boundary acquired by visual interpretation. The accuracy ($\hat{K}$) of suggested method to identify individual trees was 0.89 and adequate window size for delineating crown boundaries was $19{\times}19$ window size (maximum crown size: 9.4m) with accuracy ($\hat{K}$) at 0.80.

• Journal of the Korean Society of Tobacco Science
• /
• v.30 no.2
• /
• pp.117-124
• /
• 2008

A solid phase microextraction (SPME) method in combination with gas chromatography/mass spectrometric techniques was used for the extraction and quantification of 12 selected agrochemical residues in tobacco. The parameters such as the type of SPME fiber, adsorption/desorption time and the extraction temperature affecting the precision and accuracy of the SPME method were investigated and optimized. Among three types of fibers investigated, polyacrylate (PA), polydimethylsiloxane (PDMS) and polydimethylsiloxane-divinylbenzene (PDMS-DVB), PDMS fiber was selected for the extractions of the agrochemicals. The SPME device was automated and on-line coupled to a gas chromatograph with a mass spectrometer. Mass spectrometry (MS) was used and two different instruments, a quadrupole MS and triple quadrupole MS-MS mode, were compared. The performances of the two GC-MS instruments were comparable in terms of linearity (in the range of 0.01$\sim$0.5 $\mu$g/mL) and sensitivity (limits of detection were in the low ng/mL range). The triple quadrupole MS-MS instrument gave better precision than that of quadrupole MS system, but generally the relative standard deviations for replicates were acceptable for both instruments (< 15%). The LODs was fully satisfied the requirements of the CORESTA GRL. Recoveries of 12 selected agrochemicals in tobacco yielded more than 80% and reproducibility was found to be better than 10% RSD so that SPME procedure could be applied to the quantitative analysis of agrochemical residues in tobacco.