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Chemical Stabilization Study for Sulfonylurea Herbicides (Sulfonylurea계(系) 제초제(除草劑)의 화학적(化學的) 안정성(安定性))

  • Chen, Chia-Chung
    • Korean Journal of Weed Science
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    • v.17 no.2
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    • pp.135-138
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    • 1997
  • Sulfonylureas are highly active herbicides which can be applied at very low rate(10-50g/ha) to control broadleaf weeds. The nature of this category of compound is, however, very unstable toward hydrolysis. Therefore, the preparation of these compounds as liquid formulation was not possible. Most of the current formulations of sulfonylurea are in dry forms such as water dispersible granule or wettable powder. Even in these dry forms, the active ingredients also encounter significant chemical decomposition. This study involves the preparation of the sulfonylurea salts by reacting the parent compound with base such as sodium hydroxide. The salt becomes stable toward hydrolysis and it turns soluble when diluted with water. This discovery makes the preparation for liquid formulation or soluble granule of sulfonylurea possible. The stoichiometry of base added to the neutral sulfonylurea is controlled quite precisely. The base has to be added enough to quench the acidic impurities in the technical material and to convert the active ingredient into salt. However, the base should not be overused to cause further saponification of the sulfonylurea salts. The chemical nature of these compounds is presented and the chemical reaction is described. New soluble liquid formulation and solid granule formulation of sulfonylurea are suggested.

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Operational Characteristics of Transformer-Type SFCL with or without Neutral Line between the Secondary windings and Superconducting units (2차 권선과 초전도 사이의 중성선 유무에 따른 변압기형 초전도 한류기의 동작특성)

  • Cho, Yong-Sun;Choi, Hyo-Sang;Go, Sung-Pil
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.60 no.6
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    • pp.1268-1273
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    • 2011
  • The study on power capacity increase of superconducting fault current limiter (SFCL) is one of the most important researches to apply a SFCL in the power system. To achieve this, we thought that the unbalanced quenching problem generated in series connection of superconducting units should be solved. In this paper, we investigated the quenching characteristics of superconducting units in the transformer-type SFCL with or without the neutral line between secondary windings and superconducting units. In case of transformer-type SFCL without neutral line, the connection structure of superconducting units is identical to that of the resistive-type SFCL connected in series. Therefore, the unbalanced quenching was occurred by difference of critical current between superconducting units. However, in case of transformer-type SFCL with neutral line, the superconducting units with different critical current were simultaneously quenched. It was because the currents induced by secondary winding were separately flowed through the superconducting units. By these results, we confirmed that the resistances and consumption powers of the superconducting units were equally generated.

Current Limiting and Voltage Sag Suppressing Characteristics of Flux-lock Type SFCL According to Variations of Turn Number's Ratio (자속구속형 초전도전류제한기의 권선비 변화에 따른 전류제한 및 전압강하 보상 특성)

  • Han, Tae-Hee;Lim, Sung-Hun
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.24 no.5
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    • pp.410-415
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    • 2011
  • In this paper, we investigated the fault current limiting and the load voltage sag suppressing characteristics of the flux-lock type SFCL, designed with the additive polarity winding, according to the variations of turn number's ratio and the comparative analysis between the resistive type and the flux-lock type SFCLs were performed as well. From the analysis for the short-circuit tests, the flux-lock type SFCL designed with the larger turn number's ratio was shown to perform more effective fault current limiting and load voltage sag suppressing operations compared to the flux-lock type SFCL designed with the lower turn number's ratio through the fast quench occurrence of the high-$T_C$ superconducting (HTSC) element comprising the flux-lock type SFCL. In addition, the recovery time of the flux-lock type SFCL after the fault removed could be confirmed to be shorter in case of the flux-lock type SFCL designed with the lower turn number ratio.

Analysis on Current Limiting Characteristics of Flux-Lock Type SFCL Using a Transformer Winding (변압기 권선을 이용한 자속구속형 초전도 전류제한기의 전류제한 특성 분석)

  • Han, Tae-Hee;Lim, Sung-Hun
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.24 no.2
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    • pp.136-140
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    • 2011
  • The fault current limiting characteristics of the flux-lock type superconducting fault current limiter (SFCL) using a transformer winding were investigated. The suggested flux-lock type SFCL consists of two parallel connected coils on an iron core and the transformer winding connected in series with one of two coils. In this SFCL, the high-TC superconducting (HTSC) element was connected with the secondary side of the transformer. The short-circuit experimental devices to analyze the fault current limiting characteristics of the flux-lock type SFCL using the transformer winding were constructed. Through the short-circuit tests, the flux-lock type SFCL using transformer winding was shown to perform more effective fault current limiting operation compared to the previous flux-lock type SFCL without the transformer winding from the viewpoint of the quench occurrence and the recovery time of the HTSC element.

Analysis on Recovery in Au/YBCO thin Film Meander Lines (Au/YBCO 박막 곡선에서의 회복 분석)

  • Kim, H.R.;Yim, S.W.;Oh, S.Y.;Hyun, O.B.
    • Progress in Superconductivity
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    • v.9 no.1
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    • pp.119-125
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    • 2007
  • We investigated recovery in $Au/YBa_2Cu_3O_7$ (YBCO) thin film meander lines on sapphire substrates. The meander lines were fabricated by patterning YBCO films coated with gold layers. The lines were subjected to simulated AC fault current and then small current was applied for recovery measurements. The samples were immersed in liquid nitrogen during the experiment. After the fault, the resistance decreased linearly, first slowly and then fast to zero. The initial slow decrease was due to the decrease of the meander line temperature, whereas the fast decrease was originated from the transition from the normal state to the superconducting state. The recovery speed depended on the size of samples, and was faster in the smaller samples during the whole period of recovery. The experimental results were analyzed quantitatively with the concept of heat transfer within the sample and to the surrounding liquid nitrogen. A heat balance equation was solved for the initial phase of recovery, and an expression for the time dependence of resistance was obtained. The result agreed with data well.

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Characteristics of Matrix Type SFCL with $2{\times}3$ Array According to the Trigger Coil and Shunt Resistance ($2{\times}3$구조의 매트릭스형 초전도 한류기의 트리거 코일 및 션트 저항에 따른 특성)

  • Jung, Byung-Ik;Choi, Hyo-Sang
    • The Transactions of the Korean Institute of Electrical Engineers P
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    • v.58 no.1
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    • pp.85-89
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    • 2009
  • We investigated the quench characteristics in accordance with increase of turns number of trigger coil and shunt resistance of matrix-type superconducting fault current limiter (SFCL) with $2{\times}3$ array. The matrix-type SFCL consists of the trigger part to apply magnetic field and the current-limiting part to limit fault current. The fault current limiting characteristics according to the increase of magnetic field and applied voltage were nearly same. This is because the application of magnetic field hasn't an affect on total impedance of the SFCL. When turns number of a reactor increased, the voltage difference between two superconducting units in the current-limiting part according was decreased. The resistance difference generated in two superconducting units was also decreased. Therefore, we confirmed that the differences of the critical behaviors between superconducting units were reduced by application of magnetic field. By this results, we could decide the optimum turns number of reactor to apply magnetic field.

RTDS-based Model Component Development of a Tri-axial HTS Power Cable and Transient Characteristic Analysis

  • Ha, Sun-Kyoung;Kim, Sung-Kyu;Kim, Jin-Geun;Park, Minwon;Yu, In-Keun;Lee, Sangjin;Kim, Jae-Ho;Sim, Kideok
    • Journal of Electrical Engineering and Technology
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    • v.10 no.5
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    • pp.2083-2088
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    • 2015
  • The transient characteristics of the tri-axial High Temperature Superconducting (HTS) power cable are different from those of a conventional power cable depending on whether the cable is under a steady or transient state due to the quench. Verification using simulation tools is required to confirm both the characteristics of the cable and the effect of the cable when it is applied to a real utility. However, a component for the cable has not been provided in simulation tools; thus the RTDS-based model component of the tri-axial HTS power cable was developed, and a simulation was performed under the transient state. The considered properties of model component include resistance, reactance and temperature. Simulation results indicate the variation of HTS power cable condition. The results are used for the transient characteristic analysis and stability verification of the tri-axial HTS power cable. In the future, the RTDS-based model component of the cable will be used to implement the hardware-in-the-loop simulation with a protection device.

Design of Heater-trigger HTS Switch through 3-Dimensional Thermal Characteristic Analysis (3차원 열특성해석을 통한 히터트리거 고온초전도 스위치의 설계)

  • Ahn, Min-Cheol;Yoon, Yong-Soo;Kim, Ho-Min;Kim, Tae-Joong;Kim, Yeong-Sik;Bae, Duck-Kwon;Lee, Sang-Jin;Han, Tae-Su;Ko, Tae-Kuk
    • Proceedings of the KIEE Conference
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    • 2001.07b
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    • pp.714-716
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    • 2001
  • This paper is about the characteristic analysis of a heater-trigger HTS switch. It is composed of a BSCCO tape wire and a heater as a thermal quench source. To minimize the heat flow to the liquid nitrigen, the epoxy was used around them. The heater-trigger switch operates in the process that the HTS tape is thermally quenched by the current flowing through the heater. Since the switch works in coolant, it needs to be designed by the accurate thermal characteristic analysis. Here, we focus on FEM for it.

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Fabrication and test of heater triggered persistent current switch using coated conductor tapes (Coated conductor를 이용한 히터트리거 방식의 영구전류 스위치의 제작과 실험)

  • Kim, Young-Jae;Yang, Seong-Eun;Park, Dong-Keun;Ahn, Min-Cheol;Yoon, Yong-Soo;Ko, Tae-Huk
    • Proceedings of the KIEE Conference
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    • 2006.07d
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    • pp.2039-2040
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    • 2006
  • Persistent current switch (PCS) system in NMR, MRI, MAGLEV and SMES has many advantages, such as uniformity and durability of magnetic field and reducing a thermal loss, which enable many superconducting application to operate effectively. This paper deals with fabrication and test of heater trigger persistent current switch using coated conductor (CC) which has high n-index, critical current independency from external magnetic field and adaptable selectivity of stabilizer. PCS system consists of magnet power supply for energizing current to a magnet, heater, switch and magnet using coated conductor tape. Finite element method (FEM) is used to simulate thermal quench (switching) characteristic and design heater trigger. With FEM simulation, optimal length of heater is calculated by temperature and time analysis. Fabrication of PCS system and test of heater trigger characteristic were performed and compared with simulation result. This paper would be the foundation of researches of superconducting switching application.

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A Study on the Power System Application of High-Tc Superconducting Fault Current Limiter (고온초전도 한류기의 전력계통 적용에 관한 연구)

  • Bae, Hyeong-Thaek;Yu, In-Keun
    • Proceedings of the KIEE Conference
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    • 2006.07a
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    • pp.115-116
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    • 2006
  • Since the discovery of the high-temperature superconductors, many researches have been performed for the practical applications of superconductivity technologies in various fields. As results, significant progress has been achieved. Especially, Superconducting Fault Current Limiter (SFCL) offers an attractive means to limit fault current in power systems. The SFCLS, in contrast to current limiting reactors or high impedance transformers, are capable of limiting short circuit currents without adding considerable voltage drop and energy loss to power systems during normal operation. Under fault conditions, a resistance is automatically inserted into the power grid to limit the peak short-circuit current by transition from the superconducting state to the normal state, the quench. The advantages, like fail safe operation and quick recovery, make SFCL very attractive, especially for rapidly growing power systems with higher short-circuit capacities. In order to verify the effectiveness of the SFCL, in this paper, the analysis of fault current and voltage stability assessment in a sample distribution system and a transmission system are performed by the PSCAD/EMTDC based simulation method. Through the simulation, the advantage of SFCL application is shown, and the effective parameters of the SFCL are also recommended for both distribution and transmission systems. A resistive type component of SFCL is adopted in the analysis. The simulation results demonstrate not only the effectiveness of the proposed simulation scheme but also SFCL parameter assessment technique.

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