• Title/Summary/Keyword: Q 계수

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Application of Two Centre Huckel Method for Basicity of the Polydentate Amine Ligands (여러자리 아민리간드의 염기도에 대한 이중심 Huckel 법의 응용)

  • Kim, Ja Hong;Lee Kae Soo
    • Journal of the Korean Chemical Society
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    • v.22 no.5
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    • pp.317-319
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    • 1978
  • The change of the electron densities of polydentate amine ligands in the reaction of protonation are discussed on the basis of the calculation by Two Center Huckel method. From results, such as ${\Delta}E_{\sigma}$, $q_N,\;q_H$ , and observed pKb, it is concluded that the stabilities of polydentate amine ligands are in the order of trien > en > gly > dien.

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Analysis on Character and Ability of In -Plane Permeability of Geotextiles Used for Darainage (배수용 Geotextlle의 평면투수 성능분석)

  • 이상호
    • Geotechnical Engineering
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    • v.8 no.3
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    • pp.61-74
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    • 1992
  • In order to provide fundamental data for the design of geotextile drains, the in-plane permeability coefficients were determined by tests and permeable cllaracteristics were investigated, mainly on domestic nonwoven and composite getextile products used for drainage purpose. The results obtained are as follows, The thickness, the in-plane permeability coefficient and the transmissivity with the in- crease of compressive stress are found to be remarkably decreased when the compressive stress is lass than about 10KN/m2. The inflane permeability of filament nonwovens are found to be lower than that of composites or staple-fiher nonwovens, and the compressibility of the geotextile shown to be larger for the polyester nonwovens than for the polypropylene nonwovens. The relation of compressive stress, q and compressibility, Cr is expressed as Cr=13.37 In q+23.28 and that of compressibility on the basis of 2KN /m2, Cr' and decrease ratio of in-plane permeability coefficient is followed Pr: 1.25Cr'

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Experimental Investigation of the Combined Effects of Heat Exchanger Geometries on Nucleate Pool Boiling Heat Transfer in a Scaled IRWST (열교환기 형상이 축소한 IRWST 내부의 풀핵비등에 미치는 복합적인 영향에 대한 실험적 연구)

  • Kang, Myeong-Gie;Chun, Moon-Hyun
    • Nuclear Engineering and Technology
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    • v.28 no.1
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    • pp.1-16
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    • 1996
  • In an effort to determine the combined effects of major parameters of heat exchanger tubes on the nucleate pool boiling heat transfer in the scaled in-containment refueling water storage tank (IRWST), a total of 1,966 data for q'quot; versus ${\Delta}T$ has been obtained using various combinations of tube diameters, surface roughness, and tube orientations. The experimental results show that (1) increased surface roughness enhances heat transfer for both horizontal and vertical tubes, (2) the two heat transfer mechanisms, i.e.,enhanced heat transfer for both horizontal and vertical tubes, (2) the two heat transfer mechanisms, i.e., enhanced heat transfer due to liquid agitation by bubbles generated and reduced heat transfer by the formation of large vapor slugs and bubble coalescence are different in two regions of low heat fluxes (q'quot; $\leq$50kW/$m^2)$ and high heat fluxes (q'quot; $\geq$50kW/$m^2)$ depending on the orientation of tubes and the degree of surface roughness, and (3) the heat transfer rate decreases as the tube diameter is increased for both horizontal and vertical tubes, but the effect of tube diameter on the nucleate pool boiling heat transfer for vertical tubes is greater than that for horizontal tubes. Two empirical heat transfer correlations for q'quot;, one for horizontal tubes and the other for vertical tubes, are obtained in terms of surface roughness $({\varepsilon})$ and tube diameter (D). In addition, a simple empirical correlation for nucleate pool boiling heat transfer coefficient $(h_b)$ is obtained as a function of heat flux (q'quot;) only.ucleate pool boiling heat transfer coefficient $(h_b)$ is obtained as a function of heat flux (q'quot;) only.

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Cr:YAG 포화 흡수체를 이용한 Nd:YVO$_4$ 레이저의 수동형 Q-switching 특성

  • 이희철;김규욱;김칠민
    • Proceedings of the Optical Society of Korea Conference
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    • 2001.02a
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    • pp.42-43
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    • 2001
  • Nd:YVO$_4$ 결정은 들뜬 상태의 발광 평균 수명이 90-100 $\mu\textrm{s}$로 아주 짧아서 Nd:YAG나 Nd:YLF 레이저 매질에 비해 짧은 펄스폭과 빠른 반복율을 가진 펄스들을 만들어 내는 Q-switching에 적합한 레이저 매질이다. 또한 Nd:YAG 결정에 비해 아주 큰 흡수 계수 및 이득 단면적을 지니고 있어 반도체 레이저로 펌핑하는 고체 레이저에 아주 적합한 레이저 이득 매질이다. (중략)

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A Study on the Characteristics of Rock Mass by GSI in Limestone Mine (석회석 광산에서의 GSI 분류법에 의한 암반특성연구)

  • ;Kaynnam U. M. Rao
    • Tunnel and Underground Space
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    • v.14 no.2
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    • pp.86-96
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    • 2004
  • Rock mass classification methods such as RMR, Q system and GSl have been widely adopted with certain modifications for the design of mine openings. The GSI system is the only rock mass classification system that is related to Mohr-Coulomb and Hoek-Brown strength parameters and gives a simple method to calculate the engineering properties of rock masses which can be useful input parameters for a numerical analysis. A detailed surveying for GSI mapping as well as far calculating RMR values was undertaken at Daesung and Pyunghae underground limestone mining sites. RQD values were determined for row locations in these two mining sites. Based on GSI values and intact rock strength properties, the rock mass strength modulus of elasticity as well as the Mohr-Coulomb strength parameter c$_{m}$ and $\phi$$_{m}$ were determined. GSI and RMR are correlated.

Microwave Dielectric Properties of CaTiO$_3$and CaTiO$_3$-TiO$_2$Ceramics (CaTiO$_3$및 CaTiO$_3$-TiO$_2$세라믹스의 마이크로파 유전특성)

  • 홍석경;윤중락;김경용
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.18 no.8
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    • pp.1102-1107
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    • 1993
  • Microwave dielectric properties of CaTiO3 and CaTiO3-TiO2 ceramics for the composition range between 40 and 50 mol% CaO in CaO-TiO2 binary system were investigated. CaTiO3 ceramics with50 mol% CaO showed the dielectric constant (e,) of 178, the temperature coefficient of resonant frequency(c,) of+1000 ppm/'c and the qualify factor Q of 2760 (f0=2.7 GHz ). Dielectric constant and temperature coefficient of resonant frequency of ceramics with dual phases of CaTiO3 and TiO2 decreased gradually from those of CaTiO3 as the CaO content decreased. Q value and density were found to have minimum at the composition of 47 mol% CaO. The degradation of Q value and density in dual phase ceramics seems to be caused by the large pores at grain boundaries and/or within grains remained after rapid growth of CaTiO3 grains as TiO2 Phase decreased.

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Evaluation of Cementation Effect of Sand Using CPT and DMT (CPT와 DMT에 의한 사질토 고결영향 평가)

  • Lee, Moon-Joo;Choi, Sung-Kun;Hong, Sung-Jin;Lee, Woo-Jin
    • Journal of the Korean Geotechnical Society
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    • v.25 no.2
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    • pp.67-77
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    • 2009
  • In this study, the relations of cone tip resistances (qc) and DMT indices of cemented sand are analyzed from a series of calibration chamber tests. The experimental results show that, with increasing the cementation level, three DMT indices also increase. The CPT and DMT do not appear to properly reflect the cementation effect of sand, since the penetration induces the damage of cementation. Nevertheless, the DMT is more sensitive to deformation characteristics of cemented sand than CPT. It is also observed that the $E_D/q_c$ ratio of cemented sand is larger than that of uncemented sand. However, the $K_D-q_c/{\sigma}_v'$ relation is independant of cementation, unlike the result of previous study. In addition, this study evaluates the constrained modulus and cohesion intercept of cemented sand using the relation between cone resistance and dilatometer constrained modulus ($M_D$).

Validation of Stem-loop RT-qPCR Method on the Pharmacokinetic Analysis of siRNA Therapeutics (Stem-loop RT-qPCR 분석법을 이용한 siRNA 치료제의 생체시료 분석법 검증 및 약물 동태학적 분석)

  • Kim, Hye Jeong;Kim, Taek Min;Kim, Hong Joong;Jung, Hun Soon;Lee, Seung Ho
    • Journal of Life Science
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    • v.29 no.6
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    • pp.653-661
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    • 2019
  • The first small interfering RNA (siRNA) therapeutics have recently been approved by the Food and Drug Administration in the U.S., and the demand for a new RNA therapeutics bioanalysis method-which is essential for pharmacokinetics, including the absorption, distribution, metabolism, and excretion of siRNA therapeutics-is rapidly increasing. The stem-loop real-time qPCR (RT-qPCR) assay is a useful molecular technique for the identification and quantification of small RNA (e.g., micro RNA and siRNA) and can be applied for the bioanalysis of siRNA therapeutics. When the anti-HPV E6/E7 siRNA therapeutic was used in preclinical trials, the established stem-loop RT-qPCR assay was validated. The limit of detection was sensitive up to 10 fM and the lower limit of quantification up to 100 fM. In fact, the reliability of the established test method was further validated in three intra assays. Here, the correlation coefficient of $R^2$>0.99, the slope of -3.10 ~ -3.40, and the recovery rate within ${\pm}20%$ of the siRNA standard curve confirm its excellent robustness. Finally, the circulation profiles of siRNAs were demonstrated in rat serum, and the pharmacokinetic properties of the anti-HPV E6/E7 siRNA therapeutic were characterized using a stem-loop RT-qPCR assay. Therefore, the stemloop RT-qPCR assay enables accurate, precise, and sensitive siRNA duplex quantification and is suitable for the quantification of small RNA therapeutics using small volumes of biological samples.

Effect of the Application of Temporal Mask Map on the Relationship between NDVI and Rice Yield (시계열 마스크 맵이 논벼 NDVI와 단수와의 관계에 미치는 영향)

  • Na, Sang-il;Ahn, Ho-yong;Park, Chan-won;Hong, Suk-young;So, Kyu-ho;Lee, Kyung-do
    • Korean Journal of Remote Sensing
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    • v.36 no.5_1
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    • pp.725-733
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    • 2020
  • The objectives of this study were (1) to develop a temporal mask map using MCD12Q1 data, and (2) to extract the annual variations in paddy, (3) to investigate the correlation analysis between MYD13Q1 NDVI and rice yield, and (4) to review its applicability. For these purposes, the temporal mask map was created using annual MCD12Q1 PFT data from 2002 to 2019, and compared with the fixed mask map. As a result, it found that the temporal mask map well reflected the variations of the paddy area. In addition, the correlation coefficient between NDVI and rice yield was also high significant as compared to the fixed mask map. Therefore, the temporal mask map will be useful for NDVI extraction, crop monitoring, and estimation of rice yield.

Bearing Capacity Characteristics of Shallow Foundation by Three Dimension FEM (3차원 유한요소해석에 의한 얕은 기초의 지지력 특성)

  • Park, Choon-Sik;Kim, Jong-Hwan
    • Journal of the Korean Geotechnical Society
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    • v.35 no.3
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    • pp.17-24
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    • 2019
  • The purpose of this study is to understand the characteristics of bearing capacity of shallow foundation on the grounds. We made a comparative study of existing bearing capacity theory, based on the three-dimensional finite element analysis with a variety of conditions such as ground condition, foundation scale and foundation shape. In the finite element analysis, the ultimate bearing capacity showed a gradual convergence in the form of exponential function or logarithm function according to the foundation scale. Although the shear strength increased, the bearing capacity tended not to increase but change linearly. In the results of comparative study of existing bearing capacity theory, bearing capacity ratio ($q_{u(FEA)}/q_{u(theory)}$) of pure sand has the outcome closest to those of the Terzaghi method. Pure clay turned out to be about 0.4~0.6 while normal soil was changed in a range of 0.3~1.3. As shear strength is increased, the results turned out to be less than 1.0. Bearing capacity ratio ($q_u/q_{u(1.0)}$), normalized at 1.0m bearing capacity, was about 35%, 15% and 5% of theoretical formula under the condition of ${\phi}=25^{\circ}$, $30^{\circ}$ and $35^{\circ}$ of pure sand; no scale effect was found with pure clay and the normal soil with lower soil strength level showed less than 10% of the theoretical formula of pure sand. Bearing capacity ratio of each case, in accordance with, the shear strength increase, was largely influenced by the internal friction angle. Shape factor of bearing capacity ratios classified by foundation shapes have different results according to the shapes; the shape factor of circular foundation is 1.50, square foundation is 1.30, rectangular and continuous foundations are 1.1~1.0.