• Title/Summary/Keyword: Purity measurement

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Gamma-ray Full Spectrum Analysis for Environmental Radioactivity by HPGe Detector

  • Jeong, Meeyoung;Lee, Kyeong Beom;Kim, Kyeong Ja;Lee, Min-Kie;Han, Ju-Bong
    • Journal of Astronomy and Space Sciences
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    • v.31 no.4
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    • pp.317-323
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    • 2014
  • Odyssey, one of the NASA's Mars exploration program and SELENE (Kaguya), a Japanese lunar orbiting spacecraft have a payload of Gamma-Ray Spectrometer (GRS) for analyzing radioactive chemical elements of the atmosphere and the surface. In these days, gamma-ray spectroscopy with a High-Purity Germanium (HPGe) detector has been widely used for the activity measurements of natural radionuclides contained in the soil of the Earth. The energy spectra obtained by the HPGe detectors have been generally analyzed by means of the Window Analysis (WA) method. In this method, activity concentrations are determined by using the net counts of energy window around individual peaks. Meanwhile, an alternative method, the so-called Full Spectrum Analysis (FSA) method uses count numbers not only from full-absorption peaks but from the contributions of Compton scattering due to gamma-rays. Consequently, while it takes a substantial time to obtain a statistically significant result in the WA method, the FSA method requires a much shorter time to reach the same level of the statistical significance. This study shows the validation results of FSA method. We have compared the concentration of radioactivity of $^{40}K$, $^{232}Th$ and $^{238}U$ in the soil measured by the WA method and the FSA method, respectively. The gamma-ray spectrum of reference materials (RGU and RGTh, KCl) and soil samples were measured by the 120% HPGe detector with cosmic muon veto detector. According to the comparison result of activity concentrations between the FSA and the WA, we could conclude that FSA method is validated against the WA method. This study implies that the FSA method can be used in a harsh measurement environment, such as the gamma-ray measurement in the Moon, in which the level of statistical significance is usually required in a much shorter data acquisition time than the WA method.

Effect of Carbon dioxide in Fuel on the Performance of PEM Fuel Cell (연료중의 이산화탄소 불순물에 의한 연료전지 성능변화 연구)

  • Seo, Jung-Geun;Kwon, Jung-Taek;Kim, Jun-Bom
    • 한국신재생에너지학회:학술대회논문집
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    • 2007.11a
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    • pp.184-187
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    • 2007
  • Hydrogen could be produced from any substance containing hydrogen atoms, such as water, hydrocarbon (HC) fuels, acids or bases. Hydrocarbon fuels couold be converted to hydrogen-rich gas through reforming process for hydrogen production. Even though fuel cell have high efficiency with pure hydrogen from gas tank, it is more beneficial to generate hydrogen from city gas (mainly methane) in residential application such as domestic or office environments. Thus hydrogen is generated by reforming process using hydrocarbon. Unfortunately, the reforming process for hydrogen production is accompanied with unavoidable impurities. Impurities such as CO, $CO_2$, $H_2S$, $NH_3$, and $CH_4$ in hydrogen could cause negative effects on fuel cell performance. Those effects are kinetic losses due to poisoning of electrode catalysts, ohmic losses due to proton conductivity reduction including membrane and catalyst ionomer layers, and mass transport losses due to degrading catalyst layer structure and hydrophobic property. Hydrogen produced from reformer eventually contains around 73% of $H_2$, 20% or less of $CO_2$, 5.8% of less of $N_2$, or 2% less of $CH_4$, and 10ppm or less of CO. Most impurities are removed using pressure swing adsorption (PSA) process to get high purity hydrogen. However, high purity hydrogen production requires high operation cost of reforming process. The effect of carbon dioxide on fuel cell performance was investigated in this experiment. The performance of PEM fuel cell was investigated using current vs. potential experiment, long run (10 hr) test, and electrochemical impedance measurement when the concentrations of carbon dioxide were 10%, 20% and 30%. Also, the concentration of impurity supplied to the fuel cell was verified by gas chromatography (GC).

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Fabrication and Evaluation Properties of Titanium Sintered-body for a Sputtering Target by Spark Plasma Sintering Process (방전플라즈마 소결 공정을 이용한 스퍼터링 타겟용 타이타늄 소결체 제조 및 특성 평가)

  • Lee, Seung-Min;Park, Hyun-Kuk;Youn, Hee-Jun;Yang, Jun-Mo;Woo, Kee-Do;Oh, Ik-Hyun
    • Korean Journal of Metals and Materials
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    • v.49 no.11
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    • pp.845-852
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    • 2011
  • The Spark Plasma Sintering(SPS) method offers a means of fabricating a sintered-body having high density without grain growth through short sintering time and a one-step process. A titanium compact having high density and purity was fabricated by the SPS process. It can be used to fabricate a Ti sputtering target with controlled parameters such as sintering temperature, heating rate, and pressure to establish the optimized processing conditions. The compact/target(?) has a diameter of ${\Phi}150{\times}6.35mm$. The density, purity, phase transformation, and microstructure of the Ti compact were analyzed by Archimedes, ICP, XRD and FE-SEM. A Ti thin-film fabricated on a $Si/SiO_2$ substrate by a sputtering device (SRN-100) was analyzed by XRD, TEM, and SIMS. Density and grain size were up to 99% and below $40{\mu}m$, respectively. The specific resistivity of the optimized Ti target was $8.63{\times}10^{-6}{\Omega}{\cdot}cm$.

Evaluation of Radioactive Substance and Measurement of Harmfulness in Drinking Water (먹는 샘물의 방사성물질 측정 및 유해성 평가)

  • Jo, Jungwon;Lee, Sangbok;Nam, Johyeon;Noh, Eunjeong;Beak, Hyunwoo;Lee, Yejin;Lee, Joonse;Choi, Jiwon;Kim, Sungchul
    • Journal of radiological science and technology
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    • v.44 no.3
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    • pp.247-252
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    • 2021
  • As the number of single-person households increases, the consumption of bottled water is increasing. In addition, as the public's interest in radioactivity increases, interest in the field of living radioactivity is also increasing. Since drinking water is an essential element in our daily life, it must be safe from radioactivity. In this study, gamma radiation of drinking spring water was measured and internal exposure dose evaluation was performed to determine its harmfulness. K-40 and uranium-based radioactivity analysis was performed through a high-purity germanium detector, and as a result, drinking water was detected somewhat higher than that of mixing water. Since there is no regulation on the natural radioactivity concentration in Korea, it was compared with the U.S. Environmental Protection Agency Drinking Water Regulations and World Health Organization standard. As a result, there were some items that exceeded standards. Internal exposure was evaluated according to the effective dose formula of ICRP 119. As the result was derived that a maximum of 1.17 mSv per year could be received. This result means that the dose limit for the general public may be exceeded, and it was judged that it is necessary to set an appropriate standard value and present a recommendation value through continuous monitoring in the future.

The Growth and Energy Gap Measurement of $ZnGa_2S_4 and Zn$a_2S_4$: Co Crystals ($ZnGa_2S_4 및 Zn$a_2S_4$ : Co 결정의 합성과 Energy Gap 측정)

  • Kim, Hyung-Gon
    • Journal of the Korean Institute of Telematics and Electronics
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    • v.26 no.11
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    • pp.1814-1818
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    • 1989
  • The crystals of ZnGa2S4 and ZnGa2S4:Co(2mole%) were synthesized from high-purity (99.999%) elements of Zinc, Gallium, and sulfur. The crystal structure of these crystals belong to a tetragonal system with layer type and the lattice constants are a =5.35\ulcorner c=10.43\ulcornerfor ZnGa2S4: Co(2 mole%) crystal at 298\ulcorner. The optical absorption spectra of these compounds were obtained through reflectance measurements using a 60 mm diameter intergrating sphere. The optical energy gaps are 3.18eV for ZnGa2S4 and 2.60eVfor ZnGa2S4:L Co(2mole%)at 298\ulcorner, respectively.

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Polarization Diversity Antenna for Receiving Traffic Information Contents in WiBro System (교통정보 컨텐츠 수신을 위한 WiBro용 편파 다이버시티 안테나)

  • Jung, Byung-Woon
    • The Journal of The Korea Institute of Intelligent Transport Systems
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    • v.7 no.2
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    • pp.56-61
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    • 2008
  • Diversity antenna system against multi-fading environment is strongly required for WiBro service of vehicle. In general, high isolation performance between antennas leads to good diversity gain. In this paper, a polarization diversity antenna is presented, which has orthogonal polarizations and good isolation characteristic. In addition, by simulation and measurement, it is certified that HWLLA (Half Wave Length Loaded Antenna) improves polarization purity on common ground. In isolation between two antennas, HWLLA can provide better isolation over 12dB than conventional PIFA (Planar Inverted F Antenna).

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A Study on the Measurement of the Concentration and the Size Distribution of Inclusions in the Molten Aluminum (용융 알루미늄내에서 개재물의 크기분포 및 농도측정에 관한 연구)

  • An, Jeong;Moon, Kwang-Ho;Lee, Kwang-Hak
    • Journal of Korea Foundry Society
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    • v.14 no.1
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    • pp.62-74
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    • 1994
  • The concentration and particle size distribution of non-metallic inclusions which suspended in the molten aluminum at $700^{\circ}C$ were measured by using LiMCA apparatus. The result revealed that the number of inclusions increased with increasing the applied current or decreasing the orifice diameter, while decreased with increasing the purity of aluminum. And also, it was found that the number of inclusions increased with increasing the amount of boron added to molten aluminum. This was found to be attributed to the formation of the inclusions of TiB and $V_3B_2$. It was investigated that the average concentration of inclusions in a constant volume of 20ml of molten aluminum was increased in the order of pure molten aluminum, molten aluminum containing 20ppm of boron and molten aluminum used repeatly in the experimental casting in this study.

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Characteristics and Formation of Thermal Oxidative Film Silicon Carbide for MOS Devices (MOS 소자용 Silicon Carbide의 열산화막 생성 및 특징)

  • O, Gyeong-Yeong;Lee, Gye-Hong;Lee, Gye-Hong;Jang, Seong-Ju
    • Korean Journal of Materials Research
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    • v.12 no.5
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    • pp.327-333
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    • 2002
  • In order to obtain the oxidation layer for SiC MOS, the oxide layers by thermal oxidation process with dry and wet method were deposited and characterized. Deposition temperature for oxidation layer was $1100^{\circ}C$~130$0^{\circ}C$ by $O_2$ and Ar atmosphere. The oxide thickness, surface morphology, and interface characteristic of deposited oxide layers were measurement by ellipsometer, SEM, TEM, AFM, and SIMS. Thickness of oxidation layer was confirmed 50nm and 90nm to with deposition temperature at $1150^{\circ}C$ and $1200{\circ}C$ for dry 4 hours and wet 1 hour, respectively. For the high purity oxidation layer, the necessity of sacrificial oxidation which is etched for the removal of the defeats on the wafer after quickly thermal oxidation was confirmed.

A Study on the Analysis of Safety Standard and Evaluation of Safety Performance for the 5 Nm3 /hr Class Alkaline Water Electrolysis System (5 Nm3 /hr급 알카라인 수전해 시스템 안전기준 분석 및 안전성능 평가에 관한 연구)

  • Kim, Ji-Hye;Lee, Eun-Kyung;Kim, Min-Woo;Oh, Gun-Woo;Lee, Jung-Woon;Kim, Woo-Seop
    • Journal of the Korean Institute of Gas
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    • v.22 no.6
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    • pp.65-75
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    • 2018
  • The wind energy produced at night is being discarded because of the excess power generated at night compared to daytime. To solve this problem, In this study, we analyzed the evaluation contents for evaluation of domestic and overseas water electrolysis systems and drew contents for safety performance contents test of the water electrolysis system based on the evaluation contents. The test contents produced the efficiency measurement test, the hydrogen generated pressure test, and the hydrogen purity test. And the safety performance evaluation of the alkaline water electrolysis system of $5Nm^3/hr$ was performed based on the results. As a result, the hydrogen generation was calculated as $5.10Nm^3/hr$ and the stack efficiency was $4.97kWh/Nm^3$. The purity of the hydrogen generated was 99.993% and it was confirmed that it produced high purity hydrogen. I think will help us assess and build safety performance of water electrolysis systems in the future.

Error factors and uncertainty measurement for determinations of amino acid in beef bone extract (사골농축액 시료 중에 함유된 아미노산 정량분석에 대한 오차 요인 및 측정불확도 추정)

  • Kim, Young-Jun;Kim, Ji-Young;Jung, Min-Yu;Shin, Young-Jae
    • Analytical Science and Technology
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    • v.26 no.2
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    • pp.125-134
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    • 2013
  • This study was demonstrated to estimate the measurement uncertainty of 23 multiple-component amino acids from beef bone extract by high performance liquid chromatography (HPLC). The sources of measurement uncertainty (i.e. sample weight, final volume, standard weight, purity, standard solution, calibration curve, recovery and repeatability) in associated with the analysis of amino acids were evaluated. The estimation of uncertainty obtained on the GUM (Guide to the expression of uncertainty in measurement) and EURACHEM document with mathematical calculation and statistical analysis. The content of total amino acids from beef bone extract was 36.18 g/100 g and the expanded uncertainty by multiplying coverage factor (k, 2.05~2.36) was 3.81 g/100 g at a 95% confidence level. The major contributors to the measurement uncertainty were identified in the order of recovery and repeatability (25.2%), sample pretreatment (24.5%), calibration-curve (24.0%) and weight of the reference material (10.4%). Therefore, more careful experiments are required in these steps to reduce uncertainties of amino acids analysis with a better personal proficiency improvement.