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Effect of Anodizing Current Density on Anti-Corrosion Characteristics for Al2O3 Oxide Film (Al2O3 산화 피막의 내식성에 미치는 양극산화 전류밀도의 영향)

  • Lee, Seung-Jun;Jang, Seok-Gi;Kim, Seong-Jong
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2016.11a
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    • pp.153-153
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    • 2016
  • Aluminum alloys have poor corrosion resistance compared to the pure aluminum due to the additive elements. Thus, anodizing technology artificially generating thick oxide films are widely applied nowadays in order to improve corrosion resistance. Anodizing is one of the surface modification techniques, which is commercially applicable to a large surface at a low price. However, most studies up to now have focused on its commercialization with hardly any research on the assessment and improvement of the physical characteristics of the anodized films. Therefore, this study aims to select the optimum temperature of sulfuric electrolyte to perform excellent corrosion resistance in the harsh marine environment through electrochemical experiment in the sea water upon generating porous films by variating the temperatures of sulfuric electrolyte. To fabricate uniform porous film of 5083 aluminum alloy, we conducted electro-polishing under the 25 V at $5^{\circ}C$ condition for three minutes using mixed solution of ethanol (95 %) and perchloric (70 %) acid with volume ratio of 4:1. Afterward, the first step surface modification was performed using sulfuric acid as an electrolyte where the electrolyte concentration was maintained at 10 vol.% by using a jacketed beaker. For anode, 5083 aluminum alloy with thickness of 5 mm and size of $2cm{\times}2cm$ was used, while platinum electrode was used for cathode. The distance between the two was maintained at 3 cm. Afterward, the irregular oxide film that was created in the first step surface modification was removed. For the second step surface modification process (identical to the step 1), etching was performed using mixture of chromic acid (1.8 wt.%) and phosphoric acid (6 wt.%) at $60^{\circ}C$ temperature for 30 minutes. Anodic polarization test was performed at scan rate of 2 mV/s up to +3.0 V vs open circuit potential in natural seawater. Surface morphology was compared using 3D analysis microscope to observe the damage behavior. As a result, the case of surface modification presented a significantly lower corrosion current density than that without modification, indicating excellent corrosion resistance.

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Bar effects on the central SF and AGN activities in the SDSS galaxy sample

  • Kim, Minbae;Choi, Yun-Yung;Kim, Sungsoo S.
    • The Bulletin of The Korean Astronomical Society
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    • v.41 no.1
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    • pp.35.3-36
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    • 2016
  • We explore the role of bars in AGN-galaxy co-evolution using a volume-limited face-on late-type galaxy sample with $M_r$ < -19.5 and 0.02 < z < 0.055 selected from SDSS DR7. In this study, we investigate how $SFR_{fib}$ as a proxy of gas contents at galactic center (over 1~1.5 kpc bulge scale) and central stellar velocity dispersion, ${\sigma}$, of host galaxies are connected to the bar presence and AGN activity. We find that galaxies are distributed in three distinct regions over the $SFR_{fib}-{\sigma}$ space and the behaviors of their bar fraction ($f_{Bar}$) are clearly different for each region. Galaxies at the AGN dominant region tend to be gas-deficient as $f_{Bar}$ increases and bars are more frequently found in fully-quenched late-type galaxies at the quiescent region, suggesting that bars speed up of the consumption of gas by SF and lead a sudden decline in the central gas. Overall, the bar effects on the AGN activity are positive over the same space except for quiescent galaxies with ${\sigma}$ > $170km\;s^{-1}$. Most significant bar effect on the AGN activity occurs in the less massive galaxies having sufficient gas, whereas the effect on galaxies at the AGN dominant region with higher the AGN fraction is relatively small. We suggest that the bar affect both central SF and AGN activities, but differently for central gas amount and BH (or bulge) mass of galaxies. We also investigate the AGN-bar connection with only pure AGNs and then confirm that they give marginally the same results.

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Effect of Serpentine as Soil Conditioner on Growth of Turfgrass (토양 개량재로서 사문석이 잔디의 생육에 미치는 영향)

  • 태현숙;고석구;김용선
    • Journal of the Korean Institute of Landscape Architecture
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    • v.30 no.3
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    • pp.86-93
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    • 2002
  • The objectives of this research were to investigate the effect of serpentine as a new soil conditioner for growth of turfgrass. To achieve the goal, pure sand or mixtures of sand and serpentine with various ratios were tested for soil physical properties and the growth effects of perennial ryegrass and zoysiagrass growth were compared. Major results of this research are summarized as follows; 1) Hydraulic conductivity of 10~30% serpentine mixtures were observed within the range of 1010~901mm/h which is good for USGA recommendation. Experimental results of pH and EC for various mixtures indicated that the 10% serpentine mixture was the most suitable for turfgrass growth. 2) Perennial ryegass treated with 10% serpentine mixture showed the highest visual quality(p<0.01) among all treatments. And serpentine treatment was more effective to improve visual quality of perennial ryegrass than that of zoysiagrass. The treatment of 10% serpentine had better visual qualities than that of 20% in both of zoysiagrass and perennial ryegrass. Treatment with the right amount of serpentine extends green period for one to two weeks during early winter in both zoysiagrass and perennial ryegrass. 3) In perennial ryegrass, the treatment of 10% serpentine resulted in an increase of total dry weight compare with those of zeolite or barley stone, and also dramatically promoted the dry weight by 15% compared with sand 100%(control). Total dry weight of zoysiagrass treated with 10% serpentine was 9% higher than that of san. These results indicated that serpentine can be a good soil conditioner for both zoysiagrass and perennial ryegrass when it is blended with sand within a range of 10 to 20% by volume.

NOx Formation Characteristics with Oxygen Enrichment in Nonpremixed Counterflow Flames (비예혼합 대향류화염에서 산소부화에 따른 NOx 생성특성)

  • Lee, Chang-Eon;Hwang, Cheol-Hong;Yoo, Byung-Hun;Han, Ji-Woong
    • Journal of the Korean Institute of Gas
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    • v.11 no.4
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    • pp.17-22
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    • 2007
  • The NOx emission characteristics with oxygen enrichment in non-premixed counterflow flames were investigated numerically. To consider systematically the situation of inevitable $N_2$ contamination by air infiltration in the process of pure-oxygen combustion, the volume ratio of $O_2$ in an oxidizer was changed from 21% to 100%. As a result the NO emission index $(EI_{NO})$ has the highest value under condition of 75% oxygen enrichment. This result can be explained by the change of $N_2$ destruction rate with oxygen enrichment rather than flame temperature, flame thickness and residence time. In particular, it was found that the reaction of N+NO=$N_2+O$ has the largest contribution on NOx production in oxygen-enrichment flames.

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Synthesis and Properties of PEGMA/Na-MMT with Acrylic Monomer by Free-Radical Polymerization (Free Radical 중합에 의한 PEGMA/Na-MMT와 아크릴단량체의 합성 및 물성)

  • Joo, Hong Hee;Park, Chan Young;Kim, Tae Kyoon;Chun, Jae Hwan;Lee, Won Kee;Oh, Sang Taek
    • Journal of Adhesion and Interface
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    • v.11 no.3
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    • pp.106-111
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    • 2010
  • Na-MMT intercalated with PEGMA macromer was prepared using an EtAc/acetone mixture (1/1 by volume) as a solvent. PEGMA/(Na-MMT)-co-MMA/MA nanocomposites was synthesized by copolymerizing intercalated compound with MMA and MA, and then characterization was performed. The results of X-ray diffraction (XRD) showed that in the case of Na-MMT intercalated with PEGMA macromer the d-spacings of silicate of Na-MMT increased with increasing of Na-MMT loading. As the Na-MMT loading increases Tg showed increasing trend through the DSC measurement. TGA result showed that thermal stability of PEGMA/(Na-MMT)-co-MMA/MA nanocomposites improved a little more than the pure PEGMA-co-MMA/MA.

Study on the Oil Seal Application Using Polytetrafluoroethylene Composites (Polytetrafluoroethylene 복합재료를 이용한 오일씰 응용에 관한 연구)

  • Ha, Ki-Ryong;Lee, Jong-Cheol;Lee, Young-Seok
    • Elastomers and Composites
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    • v.45 no.1
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    • pp.32-39
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    • 2010
  • The mechanical properties of PTFE 100%, PTFT 90% + carbon black 10%, PTFE 85% + glass fiber 15%, PTFE 80% + glass fiber 15% + molybdenum disulfide ($MoS_2$) 5%, PTFE 75% + glass fiber 25%, and PTFE 75% + carbon black 18% + graphite 7% composites were investigated in this study. The differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA) were used to examine the heat of fusion(${\Delta}H_f$) and thermal stability of the composites. Also, the wear surface and wear volume of PTFE lip seal were examined using the durability test. Wear surface was observed using scanning electron microscope (SEM). It was found that the hardness, wear resistance and durability were enhanced by adding glass fiber and molybdenum disulfide into pure PTFE, but tensile strength and elongation were decreased. According to the experimental results, the composite (PTFE + 15% glass fiber + 5% molybdenum disulfide) showed the best properties for applying to oil-seal among six types of PTFE composites.

Rheological Properties of Dough Added with Barley Bran (보리등겨 첨가 반죽의 물성변화)

  • Choi, Ung-Kyu;Yoo, Byung-Hyuk;Son, Dong-Hwa;Kwon, Dae-Jun;Kim, Mi-Hyang;Kim, Young-Ho
    • Korean Journal of Food Science and Technology
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    • v.37 no.5
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    • pp.751-756
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    • 2005
  • Effect of barley bran flour on bread quality was investigated. With addition of barley bran flour, crude protein and ash contents of bread increased, and color of crumb and crust became darker than control group made with pure wheat flour. Content of dietary fiber in bread made with 5% barley bran flour was twofold higher than that of control group. Hardness of bread increased and volume decreased in proportion to bran content. Sensory qualities of 5% barley bran flour-added group and control group were not significantly different, but decreased in 10 and 15% barley bran flour-added groups, revealing optimal content of barley bran flour to be 5%.

The Intumescent Flame Retardant Mechanism of Red-phosphorus Containing Ortho-Cresol Novolac / Biphenyl Epoxy Composites (적인을 포함한 Ortho-Cresol Novolac/Biphenyl 에폭시 복합재료의 발포성 난연 기구)

  • 김윤진;강신우;유제홍;김익흠;서광석
    • Polymer(Korea)
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    • v.26 no.5
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    • pp.623-633
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    • 2002
  • The flame retardant and thermal properties of ortho-cresol novolac (OCN) and biphenyl epoxy blends containing red-phosphorus were investigated. For five types of compounds designed with the volume ratio of OCN and biphenyl epoxy, thermal properties were analysed by TGA or DTC, and flame retardancy effectiveness was estimated through UL-94V test. While the flame retardant and thermal properties were improved with the content of filler and red-phosphorus, the excessive amount of red-phosphorus caused to deteriorate those properties. Using the blends of OCN/biphenyl rather than pure OCN or biphenyl epoxy as a matrix the flame retardancy of composites could be improved by the synergic effects of high thermal resistance of OCN and intumescent property of biphenyl. The flame retardant me chanism of epoxy compound containing red-phosphorus could be thought of the heat-insulating effect of intumescent char-layer formed in the surface of composites.

Fabrication of High Density BZN-PVDF Composite Film by Aerosol Deposition for High Energy Storage Properties (상온분말분사공정을 이용한 고밀도 폴리머-세라믹 혼합 코팅층 제조 및 에너지 저장 특성 향상)

  • Lim, Ji-Ho;Kim, Jin-Woo;Lee, Seung Hee;Park, Chun-kil;Ryu, Jungho;Choi, Doo hyun;Jeong, Dae-Yong
    • Korean Journal of Materials Research
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    • v.29 no.3
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    • pp.175-182
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    • 2019
  • This study examines paraelectric $Bi_{1.5}Zn_{1.0}Nb_{1.5}O_7$ (BZN), which has no hysteresis and high dielectric strength, for energy density capacitor applications. To increase the breakdown dielectric strength of the BZN film further, poly(vinylidene fluoride) BZN-PVDF composite film is fabricated by aerosol deposition. The volume ratio of each composition is calculated using dielectric constant of each composition, and we find that it was 12:88 vol% (BZN:PVDF). To modulate the structure and dielectric properties of the ferroelectric polymer PVDF, the composite film is heat-treated at $200^{\circ}C$ for 5 and 30 minutes following quenching. The amount of ${\alpha}-phase$ in the PVDF increases with an increasing annealing time, which in turn decreases the dielectric constant and dielectric loss. The breakdown dielectric strength of the BZN film increases by mixing PVDF. However, the breakdown field decreases with an increasing annealing time. The BZN-PVDF composite film has the energy density of $4.9J/cm^3$, which is larger than that of the pure BZN film of $3.6J/cm^3$.

Orbital wall restoring surgery with resorbable mesh plate

  • Joo, Jae Doo;Kang, Dong Hee;Kim, Hyon Surk
    • Archives of Craniofacial Surgery
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    • v.19 no.4
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    • pp.264-269
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    • 2018
  • Background: Orbital resorbable mesh plates are adequate to use for isolated floor and medial wall fractures with an intact bony buttress, but are not recommended to use for large orbital wall fractures that need load bearing support. The author previously reported an orbital wall restoring surgery that restored the orbital floor to its prior position through the transnasal approach and maintained temporary extraorbital support with a balloon in the maxillary sinus. Extraorbital support could reduce the load applied on the orbital implants in orbital wall restoring surgery and the use of resorbable implants was considered appropriate for the author's orbital wall restoring technique. Methods: A retrospective review was conducted of 31 patients with pure unilateral orbital floor fractures between May 2014 and May 2018. The patients underwent transnasal restoration of the orbital floor through insertion of a resorbable mesh plate and maintenance of temporary balloon support. The surgical results were evaluated by the Hertel scale and a comparison of preoperative and postoperative orbital volume ratio (OVR) values. Results: The OVR decreased significantly, by an average of 6.01% (p<0.05) and the preoperative and postoperative Hertel scale measurements decreased by an average of 0.34 mm with statistical significance (p<0.05). No complications such as buckling or sagging of the implant occurred among the 31 patients. Conclusion: The use of resorbable mesh plate in orbital floor restoration surgery is an effective and safe technique that can reduce implant deformation or complications deriving from the residual permanent implant.