• Title/Summary/Keyword: Pulp paper

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Bleaching of Kraft Bagasse Pulp in Presence of Polyoxometalate Catalyst

  • Ibrahim A. A.;El-Sakhawy Mohamed;Kamel Samir
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.37 no.5 s.113
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    • pp.56-62
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    • 2005
  • The catalytic effect of molybdovandophosphate heteropolyanion (HPAs) on the delignification of kraft bagasse pulp by hydrogen peroxide has been investigated. Very small amounts of the catalyst (0.05 0.3 mM/l) gave convenient results. Partial reduction of the catalyst was also studied. The effect of reaction medium (water, ethyl alcohol and acetone) on the bleaching was also studied. The results obtained show that the optimum condition for bleaching in presence of polyoxometalate were 0.05 mM/l catalyst concentration at $70^{\circ}C$ reaction temperature and $7\%$ consistency at pH 2 in aqueous medium. The ratio of water to solvent of 60:40 from acetone gives higher brightness than ethyl alcohol. The catalyst solution can be reused for 5 times without any reduction in brightness. ESR for the blank and exhausted solutions under different conditions was also carried out to find the relation between reduced metals and pulp brightness.

Hanji Manufacturing from Bast Fibers of Kenaf, Hibiscus cannabinus (양마의 인피섬유를 이용한 한지제조)

  • Cho, Nam-Seok
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.40 no.4
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    • pp.1-9
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    • 2008
  • The utilization of non-woody fibers with the fast growing annual plants has occurred in the paper industry to replace wood and preserve environment of the earth. The non-woody fibers generally used for papermaking are paper mulberry, gampi, manila hemp, rice straw, bamboo, and coton linter etc.. Recently Kenaf has been spot-lighted for the same application. Kenaf is an annual plant of Hibiscus species of Malvaceae family. Kenaf, a rapid growing and high harvesting non-woody fiber plant, was identified as one of the promising fiber sources for the production of paper pulp. This study was carried out to investigate the pulping characteristics of Kenaf bast fiber for Hanji (traditional Korean paper) manufacturing by different pulping methods, such as alkali, alkali-peroxide and sulfomethylated pulpings. It was possible to make superior grade of Hanji. Especially sulfomethylated pulping was resulted in superior pulp in terms of higher yields and qualities in comparison to those of the other pulping methods. Hanji from sulfomethylated pulp was shown the highest brightness of over 60% and higher sheet strength. In addition, the morphological features of pulp fibers (pulp compositions) affect to the sheet properties. Therefore the effect of fiber distribution index(FDI) which was calculated from the data of Confocal laser scanning microscopy(CLSM) on the sheet properties of Kenaf Hanji was also discussed.

Enzymatic Deinking of Mixed Office Waste Paper(2) -Paper properties and utilization of DIP- (혼합사무용지의 효소 탈묵(2) -효소처리 혼합사무용지의 물성 및 용도-)

  • Park, Soung-Bae;Yoon, Kyung-Dong;Yoon, Byung-Tae;Eom, Tae-Jin
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.37 no.1 s.109
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    • pp.53-60
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    • 2005
  • The mechanical properties of deinked mixed office waste paper in relation to sorts and dosage of enzymes were investigated for successful enzymatic deinking of mixed office waste paper. The increasing of $\Delta$. freeness was most predominant in pulp of Denimax treated pulp. The tensile and burst properties are decreased with enzyme dosage while $\Delta$. freeness were increased. The fine content in disintegrated pulp was decreased with enzyme dosage of $0.4\%$ on the dried weight of paper. The water absorption of handsheets of enzyme deinked pulp was like as that of market roll tissue papers and the mechanical properties of handsheets of enzyme deinked pulp were improved with enzyme treatment comparing of market roll tissue papers.

Comparison of the soda-anthraquinone pulping properties between imported Eucalyptus mixture chips and domestic yellow poplar (Liriodendron tulipifera)chips (수입산 혼합 유칼립투스 칩과 국내산 백합 나무 (Liriodendron tulipifera) 칩의 소다-안트라퀴논 (soda-anthraquinone) 펄핑 특성 비교)

  • Sung, Yong-Joo;Lee, Joon-Woo;Kim, Se-Bin;Shin, Soo-Jeong
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.42 no.3
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    • pp.22-27
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    • 2010
  • Pulping properties of the imported mixed eucalyptus chips and the domestic yellow poplar chips were investigated for comparing two chips as the raw materials for the hardwood chemical pulp. Soda-AQ (anthraquinone) pulping was applied for this study. The pulp from yellow poplar showed higher pulp yield than pulp from mixed eucalyptus, which comes from the lower hot-water soluble extractives and the higher polysaccharides in yellow poplar chips than those of the mixed eucalyptus chips. The yellow poplar pulp had higher average fiber length and fiber width than those of the mixed eucalyptus pulp, which led to the better respond to beating and the higher tear strength than those of the pulp from the mixed eucalyptus chips.

Nitric-Acid Pulping of Municipal Wastepapers and its Spent-Liquor Utilization for Fertilizers(I) -Study on the Nitric-Acid Pulping Conditions of OCC Pulp- (도시 폐휴지의 질산 펄프제조와 펄프폐액의 입상 비료화 기술개발(I) -폐골판지 상자(OCC)의 질산 펄프제조 조건-)

  • 임기표;위승곤;김창래;양정훈
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.32 no.4
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    • pp.74-80
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    • 2000
  • A series of studies on nitric-acid pulping of municipal recycled waste papers were carried out to substitute the bleached chemical pulp imported for producing printing paper as well as to use its solidified spent-liquor as fertilizer. The first experiment was carried out to find the optimum treatment conditions such as pulp consistency, nitric acid charge and temperature in $HNO_3$-alkali pulping process. The results obtained were as follows: 1. Some selective delignification of OCC pulp was conducted by $HNO_3$-alkali process. The higher the temperature and concentration of nitric acid, the lower the pulp yield and kappa number of treated pulp. while its brightness was increased. 2. The higher consistency required the stronger mixing in case of more than 5% pulp. 3. In the laboratory, the suitable $HNO_3$-treating condition seemed to be less than 6% consistency, lower than 500% $HNO_3$charge on pulp and lower than $100^{\circ}C$ in cooking temperature. 4. The spent liquor with 1.77% N-content seemed to be slow-release nitrogen fertilizer suitable for agriculture.

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Changes in the Process Efficiency and Product Properties of Pulp Mold by the Application of Oil Palm EFB (오일팜 EFB 섬유 적용에 따른 펄프몰드 공정효율 및 제품품질 변화)

  • Kim, Dong-Seop;Sung, Yong Joo;Kim, Chul-Hwan;Kim, Se-Bin
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.48 no.1
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    • pp.67-74
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    • 2016
  • The demand of environmental friendly packaging materials such as pulp mold has been increased. The application of the oil palm biomass, EFB (Empty Fruit Bunch) fiber as natural raw materials to the pulp mold could increase the usability of the pulp mold by the reduced production cost brought from the relatively low cost of EFB. The effects of the EFB(Empty Fruit Bunch) fibers on the properties of pulp mold and on the process efficiency were evaluated in this study. The pulp mold samples were prepared with mixture ONP (Old news paper) and EFB by using laboratory wet pulp molder. The changes in the drying efficiency were measured with the changes in the solid contents of pulp mold samples during drying process. The efficiency of the surface coating treatment on the pulp mold depending on the condition of the pulp mold samples were also evaluated in order to improve the water resistance properties of pulp mold. The addition of EFB increased the drying efficiency by providing the bulkier structure and the higher water contact angle, which indicated the better water resistance properties. The water resistance were improved by the surface coating treatments and the application of surface coating on the pulp mold at the higher moisture contents resulted in the higher improvement in the water resistance. The bulkier structure originated from the application of EFB fiber reduced the effects of the surface coating, which could be overcome by the control of surface coating process.

Evaluation of Refining Strategies for Combined use of Softwood and Eucalyptus Pulps in Papermaking

  • Manfredi, Vail
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 2006.06a
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    • pp.37-42
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    • 2006
  • The paper discusses the combined use of softwood and eucalyptus kraft pulps in the production of printing and writing papers. Looking for process and paper quality optimization, refining pilot plant trails were carried to identify the effects of refining type (mixed or separate) and intensities (specific edge load), and also furnish composition (amount of each pulp in mixture) on final paper quality and process costs. The basic effects on pulp fibers were evaluated against paper quality properties, such as physical strengths, bulk, vessel picking, opacity and porosity, as well as the interactions with papermaking process, such as estimates of paper machine runnability, paper breaks and industrial refining control. The results show that the furnish composition and the type of refining has a significant effect on properties related with both final paper quality and total costs. The best alternative for printing and writing papers was identified for mixed refining, under the lowest refining intensity, and with the highest dosage of eucalyptus pulp.

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Reduction of Fluorine, Boron and Heavy Metals Leaching from Coal Ash by Adding Fixation Chemicals

  • Iwasaki, Makoto;Inoue, Kaori;Ikeshima, Kazuya;Ishizuka, Tadashi
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 2006.06a
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    • pp.105-110
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    • 2006
  • In order to utilize coal fly ash (hereafter : coal ash ) discharged from coal boiler as a material for civil engineering usage such as snow melter or soil improver, we have to prevent leaching hazardous elements such as fluorine boron and heavy metals from the coal ash because the leaching concentrations of some elements in the ash exceed the Japanese standards for environmental soil quality. Through the laboratory experiments and mill trials we confirmed that the leaching concentrations of fluorine, boron and heavy metals were maintained below their environmental standards by mixing with fixation chemicals and curing for a short time.

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Environmental Features and Actions of Pulp & Paper Industry (펄프.제지산업의 환경적 특성과 대책)

  • Cho, Jun-Hyung
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.41 no.3
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    • pp.13-21
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    • 2009
  • Pulp and paper industry is a typical plant industry which usually consume lots of water and energy. Recently, environmental issues have become more important due to climate changes around the world, and reinforcement in the regulatory content in transfer and management of chemical material and that in environmental regulations for waste water and air. Paper industry is a source material recycle industry which recycle or reuse waste paper, recyclable wood, planned plantation or lumber from thinning and waste wood. Hence it can be said that paper industry is the representative industry for earth environment and of 21th century.

A Physico-chemical Change of Dissolving Pulp by Dry Milling and Fractionation (건식분쇄와 분급에 의한 용해용 펄프의 특성변화)

  • Kim, Taeyoung;Lee, Songmin;Heo, Yongdae;Kim, Jinyoung;Joung, Yangjin
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.47 no.5
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    • pp.23-32
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    • 2015
  • In this study, chemical and physical changes of dissolving pulps which have similar viscosity by dry milling and fractionation were investigated. We used two types of dissolving pulp made from wood and cotton linter fiber, respectively. Dry milling was executed by knife cutter and pulp powders were fractionated by sieve shaker into 4 grades. We analyzed fiber properties, crystallinity index, viscosity, molecular weight of pulp sheet and powders. It was found that poly-dispersity index of cotton linter pulp was smaller than that of wood pulp, meaning that cotton pulp has more narrow molecular weight distribution. It was assumed that these were related to exposure times to chemical treatment which cut cellulose chains not evenly. At least 4 times of chemical treatments for wood pulp were executed and only two times of chemical treatments for cotton linter pulp were done. After dry milling average molecular weight and crystallinity index of cotton linter pulp powders were reduced and these were related to fines content and shape of pulp powders.