• Title/Summary/Keyword: PtMn

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INVESTIGATION ON FERROMAGNETIC $Mn_{1-x}Co_{x}Pt_{3}$ ORDERED ALLOYS

  • Kaneko, T.;Fujimori, H.;Yoshida, H.;Watanabe, K.;Abe, S.;Matsumoto, M.;Yoshida, T.;Kanomata, T.
    • Journal of the Korean Magnetics Society
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    • v.5 no.5
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    • pp.758-761
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    • 1995
  • The magnetization of $Mn_{1-x}Co_{x}Pt_{3}$ ordered alloys was measured at various temperatures and the pressure effect on $T_{c}$ for X=0.25, 0.5 and 0.6 was examined. The X dependence of $T_{c}$ determined by Arott plot has a minimum near X=0.6. The field-cooling effect measurement for X=0.5 shows a reentrant spin glass behavior. It is found that there is a concentration showing no pressure dependence of $T_{c}$ between X=0.25 and 0.5. These magnetic properties are discussed with a rigid band model.

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Photocatalytic Decomposition of Gaseous Acetaldehyde by Metal Loaded $TiO_2$ with Ozonation

  • Cho, Ki-Chul;Yeo, Hyun-Gu
    • Journal of Korean Society for Atmospheric Environment
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    • v.22 no.E1
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    • pp.19-26
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    • 2006
  • The decomposition of gaseous $CH_3CHO$ was investigated by metal loaded $TiO_2$ (pure $TiO_2,\;Pt/TiO_2,\;Pd/TiO_2,\;Mn/TiO_2\;and\;Ag/TiO_2$) with $UV/TiO_2$ process and $UV/TiO_2/O_3$ process at room temperature and atmospheric pressure. Metal loaded $TiO_2$ was prepared by photodeposition. Decomposition of $CH_3CHO$ was carried out in a flow-type photochemical reaction system using three 10W black light lamps ($300{\sim}400nm$) as a light source. The experimental results showed that the degradation rate of $CH_3CHO$ was increased with Pt and Ag on $TiO_2$ compared to pure $TiO_2$, but decreased with depositing Pd and Mn on pure $TiO_2$. The considerable increase in the degradation efficiency of the $CH_3CHO$ was found by a combination of photocatalysis and ozonation as compared to only by ozonation or photocatalysis. Loading of Pt on $TiO_2$ promoted conversion of gaseous ozone. The degradation rate of gaseous $CH_3CHO$ decreased with an increase of water vapor in the feed stream for the both $UV/TiO_2\;and\;UV/TiO_2/O_3$ processes. The pure $TiO_2$ was more affected by the water vapor than Pt loaded $TiO_2$.

Effects of ${Y_2}{O_3}$Buffer Layer on Ferroelectric Properties of $YMnO_3$Thin Films Fabricated on Pt/$TiO_2$/$SiO_2$/Si Substrate (Pt/$TiO_2$/$SiO_2$/Si 기판 위에 제조된 $YMnO_3$박막의 강유전 특성에 미치는 ${Y_2}{O_3}$버퍼층의 영향)

  • 김제헌;강승구;은희태
    • Journal of the Korean Ceramic Society
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    • v.37 no.11
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    • pp.1097-1104
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    • 2000
  • MOD(Metal-Organic-Decomposition)법에 의해 $Y_2$O$_3$버퍼층에 Pt/TiO$_2$/SiO$_2$/Si 기판 위에 제조한 후, 그 표면 위에 졸-겔 방법으로 YMnO$_3$박막을 형성하였다. 기판의 종류와 수화조건 변화가 YMnO$_3$박막의 결정화 거동에 미치는 영향을 고찰하였으며, 또한 $Y_2$O$_3$버퍼층 유.무에 따른 Mn의 산화상태를 확인하고 이에 따른 유전특성 변화를 연구하였다. $Y_2$O$_3$버퍼층을 삽입하지 않고 직접 기판 위에 형성한 YMnO$_3$박막의 결정상은 기판의 종류 및 Rw 변화에 관계없이 orthorhombic 구조임이 확인되었다. 반면, $Y_2$O$_3$버퍼층 위에 형성된 YMnO$_3$박막의 경우에는 Rw($H_2O$/alkoxide mole ratio)가 0~6 범위 내에서 낮아질술고 hexagonal 결정상 성장에 유리하였으며, 또한 Pt(111)/TiO$_2$/SiO$_2$/Si 기판이 Ptd(200)/TiO$_2$/SiO$_2$/Si에 비하여 결정상 형성에 용이하였다. $Y_2$O$_3$버퍼층은 YMnO$_3$결정상 내에서 $Mn^{4+}$ 이온형성을 억제함으로써 누설전류밀도가 크게 감소되는 효과를 주었으며, 동시에 강유전 특성을 지닌 hexagonal 결정상 형성에 유리하게 작용하였다. 결론적으로, $Y_2$O$_3$는 Pt가 코팅된 Si 기판 위에 YMnO$_3$박막 제조시 그 강유전 특성을 향상시켜주는 우수한 버퍼층 재료임을 확인하였다.

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The effects of conductivity and CNT cathode on electricity generation in air-cathode microbial fuel cell (공기양극 미생물연료전지 시스템에서 전력발생특성에 미치는 전기전도도와 CNT 양극의 영향)

  • Yoo, Kyu-Seon;Park, Hyun-Soo;Song, Young-Chae;Woo, Jung-Hui;Lee, Chae-Young;Chung, Jae-Woo
    • Journal of Korean Society of Water and Wastewater
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    • v.26 no.3
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    • pp.355-360
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    • 2012
  • The characteristics of power generation were investigated by changing the electrical conductivity from 10 to 40mS/cm using air-cathode microbial fuel cell, which had graphite fiber fabric(GFF) anode. There were three kinds of cathode used: one was carbon cloth cathode coated with Pt, another was carbon nanotube(CNT) cathode with non-precious catalyst of Fe-Cu-Mn, and the other was carbon nanotube(CNT) cathode without any catalyst. When it was operated in batch mode, power density of 1369.5mW/$m^2$ was achieved at conductivity of 20mS/cm. Power density from MFC with CNT cathode coated with multi-catalyst of Fe-Cu-Mn was shown about 985.55mW/$m^2$, which was 75.1% compared the power density of carbon cloth coated with Pt. This meant that CNT cathode coated with multi-catalyst of Fe-Cu-Mn could be an alternative of carbon cloth cathode.

Preparation of Ferroelectric $YMnO_3$ Thin Films by Metal-Organic Decomposition Process and their Characterization (Metal-Organic Decomposition법에 의한 강유전성 $YMnO_3$ 박막의 제조 및 특성)

  • 김제헌;강승구;김응수;김유택;심광보
    • Journal of the Korean Ceramic Society
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    • v.37 no.7
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    • pp.665-672
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    • 2000
  • The ferroelectric YMnO3 thin films were prepared by MOD(metal-organic decomposition) method with Y- and Mn-acetylacetonate as starting materials. Thin films were grown on various substrates by spin-coating technique. The crystalline phases of the thin films were identified by X-ray diffractometer as a function of heat-treatment temperature, pH of coating solution and substrate. In addition, the effect of Mn/Y molar ratio(0.8~1.2) on the formation of hexagonal-YMnO3 phase was investigated. In forming highly c-axisoriented hexagonal-YMnO3 single phase, the Pt coated Si substrate was more effective than the bare Si substrate, and the optimum heat-treatment condition was at 82$0^{\circ}C$ for 30 min. Higher Mn/Y molar ratio within 0.8~1.2 and pH of YMnO3 precursor solution within 0.5~2.5 favored formation of ferroelectric hexagonal phase rather than orthorhombic phase. Leakage current density of the hexagonal-YMnO3 thin film formed on Pt(111)/TiO2/SiO2/Si substrate was low enough as 0.4~4.0$\times$10-8(A/$\textrm{cm}^2$) at 5 V and its remanent polarization(Pr), calculated from the P-E hysteresis loop, was 3 nC/$\textrm{cm}^2$.

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Fiber optic interferometric electric field sensor with La-doped PMN/PT PMN/PT[0.9 Pb$(Mg_{1/3}Nb_{2/3})O_3-0.1\;PbTiO_3$] electrostrictive ceramics (PMN/PT[0.9 Pb$(Mg_{1/3}Nb_{2/3})O_3-0.1\;PbTiO_3$에 La이 첨가된 광섬유 전왜변환기를 이용한 간섭계형 광섬유 전계센서의 특성분석)

  • 강원석;이영탁;강현서;정래성;이경식;장현명
    • Korean Journal of Optics and Photonics
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    • v.7 no.2
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    • pp.162-166
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    • 1996
  • We report a fiber optic interferometric electric field sensor that utilizes electrostrictive ceramics-1%, 2%, 3%, La-doped 0.9MN/0.1PT, respectively-as the transducing elements. It is also experimentally observed that 3% La-doped PMN/PT among the three elements has the largest electrostrictive coefficient $M=3.87{\times}10^ {-16}(m/V)^2$ at 3.38 kHz and displays small hysteresis. The optical fiber sensor with the 3% La-doped PMN/PT exhibits minimum detectable field of 2.08(V/m)/ $\sqrt{Hz}$ and has a good linearity over the dynamic range 40 dB.

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Microstructure of the Oriented Hexagonal HoMnO3 Thin Films by PLD

  • Choi, Dong-Hyeok;Shim, In-Bo;Kouh, Tae-Joon;Kim, Chul-Sung
    • Journal of Magnetics
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    • v.12 no.4
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    • pp.141-143
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    • 2007
  • We have fabricated (0001) oriented hexagonal $HoMnO_3$ thin films with thickness of 300 nm using Pulsed Laser Deposition (PLD) technique on $Pt(111)/Ti/SiO_2/Si$ substrates. The XRD $\theta-2\theta$ pattern shows only (0002), (0004), and (0008) reflection of a hexagonal phase, and the full width at half maximum (FWHM) of (0004) peak is under $1.6^{\circ}$. The chemical state of Mn from XPS spectra of the films reveals the presence of $Mn^{3+}$ only. The temperature dependence of dielectric constant shows a weak anomaly at magnetic $N\acute{e}el$ temperature $(T_N)$, which is about 70 K.

Fabrication of 3-Dimensional LiMn2O4 Thin Film

  • Park, Bo-Gun;Ryu, Jea Hyeok;Choi, Won Youl;Park, Yong-Joon
    • Bulletin of the Korean Chemical Society
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    • v.30 no.3
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    • pp.653-656
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    • 2009
  • 3-Dimensionally ordered macroporous $LiMn_2O_4$ thin film was prepared by a sol-gel and dip coating method on Pt/Ti/$SiO_2$/Si substrate. An opal structure consisting of mono dispersed polystyrene beads (300 nm) was used as a template. After solution containing Mn and Li precursors was coated on the template-deposited substrate, the template and organic materials in the precursors was removed by calcination at 400 ${^{\circ}C}$. And then the 3-dimensional $LiMn_2O_4$ thin film with spinel structure was fabricated by heat treatment at 700 ${^{\circ}C}$. The structural and electrochemical property was investigated by XRD, SEM and charge-discharge cycler.