• 제목/요약/키워드: Pt-Pd

검색결과 434건 처리시간 0.024초

Synthesis and Characterization of Metal (Pt, Pd and Fe)-graphene Composites

  • Chen, Ming-Liang;Park, Chong-Yeon;Choi, Jong-Geun;Oh, Won-Chun
    • 한국세라믹학회지
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    • 제48권2호
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    • pp.147-151
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    • 2011
  • In this study, we prepared graphene by using the modified Hummers-Offeman method and then introduced the metals (Pt, Pd and Fe) for dispersion on the surface of the graphene for synthesis of metal-graphene composites. The characterization of the prepared graphene and metal-graphene composites was performed by X-ray diffraction (XRD), scanning electron microscopy (SEM) with energy dispersive X-ray (EDX) analysis and transmission electron microscopy (TEM). According to the results, it can be observed that the prepared graphene consists of thin stacked flakes of shapes having a well-defined multilayered structure at the edge. And the metal particles are dispersed uniformly on the surface of the graphene with an average particle size of 20 nm.

천연가스 자동차의 Emission 배출특성 및 저감법 (Emission characteristics of Natural Gas Fueled Vehicl and its Purification Technologies)

  • 최병철;이지연;손건석;이귀영
    • 한국자동차공학회논문집
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    • 제5권2호
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    • pp.127-135
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    • 1997
  • Experiments have been conducted to investigate emission characteristics of compressed natural gas fueled vehicle(CNGV) by the FTP 75 mode test. Its purification technologies were also investigated. It was found that CNGV was operated on the rich A/F condition by comparison with gasoline vehicle. The Pd catalyst was higher in methane purification performance than Pt and Pd/Pt/Rh catalysts. Up to 60% portion of the accumulative HC emissions(that contains above 80% methane) form CNGV occurs during the first phase of the FTP 75 mode. CO that is exhausted at rich conditions of the air-fuel ratio more than lean conditions should be used for the catalytic reduction of NOX, because the methane is not the effective reduction for NOX in the CNGV with 3-way catalyst system.

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Ni 단층이 삽입된 비자성 4d 및 5d 전이금속 Rh, Pd 과 Pt 박막에서 자기모멘트 진동에 관한 제1원리 연구 (A First-principles Study on the Oscillation of Magnetic Moments in the Nonmagnetic 4d and 5d Transition Metal (Rh, Pd, and Pt) Thin Films with an Inserted Ni Monolayer)

  • 김인기;김선희;위선미;이재일;이상조
    • 한국자기학회:학술대회 개요집
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    • 한국자기학회 2002년도 동계연구발표회 논문개요집
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    • pp.192-193
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    • 2002
  • 비자성 금속에 자성 불순물이 첨가되었을 경우 비자성 전이금속의 전도전자들이 불순물에서 멀어지면서 감쇠 진동하는 형태로 스핀분극 된다는 사실은 매우 잘 알려져 있으며, 그 진동주기는 Fermi 파동벡터 크기(k$_{F}$ )의 역수의 절반이다[1]. 비자성 금속 내의 자성 불순물사이의 상호작용은 전도성 전자의 감쇠 진동하는 스핀 분극에 바탕을 둔 RKKY 교환 상호작용[2]으로 잘 기술된다. (중략)

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고농도의 Mg가 도핑된 GaN층을 이용한 GaN계 청자색 레이저다이오드의 동작 전압 감소 (Reduction of Operating Voltage of GaN-based Blue-violet Laser Diode by using Highly Mg Doped GaN Layer)

  • 곽준섭
    • 한국전기전자재료학회논문지
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    • 제17권7호
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    • pp.764-769
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    • 2004
  • In order to reduce operating voltage of the GaN based blue-violet laser diodes, the effect of highly Mg doped GaN layer, which was grown below ohmic contact metals, on contact resistivity as well as operating voltage has been investigated. The addition of the highly Mg doped GaN layer greatly reduced contact resistivity of Pd/Pt/Au ohmic contacts from $5.2 \times {10}^-2 \Omegaㆍ$\textrm{cm}^2$ to 7.5 \times {10}^-4 \Omegaㆍ$\textrm{cm}^2$$. In addition, it also decreased device voltage at 20 mA by more than 3 V. Temperature- dependent sheet resistivity of the highly Mg doped GaN layer suggested that the reduction of the contact resistivity could be attributed to predominant current flow at the interface between the Pd/Pt/Au contacts and p-GaN through a deep level defect band, rather than the valence band.

Determination of Pd(II) and Pt(II) Metal Cyano Complexes Using Capillary Electrophoresis

  • Lee, Hue-Jin;Lee, Sang-Ho;Chung, Koo-Soon;Lee, Kwang-Woo
    • Bulletin of the Korean Chemical Society
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    • 제15권11호
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    • pp.945-949
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    • 1994
  • Mixtures of cyano complexes of palladium(II) and platinum(II) were separated by capillary electrophoresis using a fused silica capillary as a separation column and 30 mM phosphate buffer (pH 7) containing 15 wt. % acetonitrile as a running buffer. By virtue of the high ionic mobilities of the negatively charged cyano complexes of Pd(II) and Pt(II), they were separated using a cathodic injection and anodic detection scheme. The metal complexes eluted through the capillary were detected by direct UV absorption at 214 nm. A linear relationship between peak area and concentration was obtained for both ions and the detection limit was lower than $10^{-14}$ mole. The proposed method was applied to real sample, e.g., anode slime obtained from an electrolytic copper refinary, as a method for the simultaneous determination of palladium and platinum.

코카인으로 유도된 행동과다, 역내성 및 Dopamine 수용체 초과민성에 미치는 인삼 Saponin의 효과 (Effects of Ginseng Saponins on Cocaine-Induced Hyperactivity, Reverse Tolerance and Dopamine Receptor Super-sensitivity in Mice)

  • 김학성;정주연
    • Journal of Ginseng Research
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    • 제19권2호
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    • pp.101-107
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    • 1995
  • The present study was undertaken to examine the effects of ginseng saponins [ginseng total saponin (GTS), protopanaxadiol saponin (PD) and protopanaxatriol saponin (PT)] on the hyperactivity, reverse tolerance and dopamine receptor super-sensitivity induced by cocaine. A single treatment with cocaine produced hyperactivity. Repeated administration of cocaine developed reverse tolerance and dopamine receptor super-sensitivity was also developed in reverse tolerant mice which had received the same cocaine. The hyperactivity and the developments of reverse tolerance and dopamine receptor super-sensitivity by cocaine were inhibited by ginseng saponins. From these results, it is proposed that ginseng saponins may be useful for the prevention and therapy of the adverse actions of cocaine. In addition, the rank order of inhibitory potential was observed as PT>GTS>PD. Key words Cocaine, hyperactivity, reverse tolerance, dopamine receptor super-sensitivity, ginseng saponins.

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재배조건 및 채굴시기가 연포장재 필름으로 개별포장한 수삼의 저장성에 미치는 영향 (Influence of Cultivation Condition and Harvest Time on the Storage Stability of Fresh Ginseng Individually Packaged in a Soft Film)

  • 손현주;김은희;성현순
    • Journal of Ginseng Research
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    • 제25권2호
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    • pp.94-100
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    • 2001
  • The influence of cultivation condition and harvest time on the storage stability of the fresh ginseng (50g) individually packaged in a soft film bag (ONY/LDPE/L-LDPE; 200$\times$300 mm, 90㎛) was investigated. When the fresh ginsengs were divided into four groups of direct-planted ginseng on the paddy soil(PD), transplanted ginseng on the upland(UT) and each group was stored at 25$\^{C}$ for 40 days, the quality deterioration rate was the highest in PD group while PT, UD and UT groups exhibited similar quality patterns from each other. When each group was stored at 10$\^{C}$, the quality deterioration rate was also the highest in PD group and the other three groups exhibited similar quality patterns from each other till 90 days passed after storage. However, the quality deterioration rate of UT group was 54% which was higher than UD group or PT group 180 days after storage. When the fresh ginseng harvested between September of 1997 and October of 1998 was individually packaged with the soft film and stored at 25$\^{C}$ for 12 days, the quality deterioration rate was the lowest in the group harvested in October while relatively high in the groups harvested between July and September.

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THE PARTIAL COMBUSTION OF METHANE TO SYNGAS OVER PRECIOUS METALS AND NICKEL CATALYSTS SUPPORTED ON -γAL2O3 AND CEO2

  • Seo, Ho-Joon
    • Environmental Engineering Research
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    • 제10권3호
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    • pp.131-137
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    • 2005
  • The catalytic activity of precious metals(Rh, Pd, Pt) and nickel catalysts supported on ${\gamma}-Al_2O_3\;and\;CeO_2$ in the partial combustion of methane(PCM) to syngas was investigated based on the product distribution in a fixed bed now reactor under atmospheric condition and also on analysis results by SEM, XPS, TPD, BET, and XRD. The activity of the catalysts based on the syngas yield increased in the sequence $Rh(5)/CeO_2{\geq}Ni(5)/CeO_2>>Rh(5)/Al_2O_3>Pd(5)/Al_2O_3>Ni(5)/Al_2O_3$. Compared to the precious catalysts, the syngas yield and stability of the $Ni(5)/CeO_2$ catalyst were almost similar to $(5)/CeO_2$ catalyst, and superior to these of any other catalysts. The syngas yield of $Ni(5)/CeO_2$ catalyst was 90.66% at 1023 K. It could be suggested to be the redox cycle of the successive reaction and formation of active site, $Ni^{2-}$ and the lattice oxygen, $O^{2-}$ produced due to reduction of $Ce^{4-}$ to $Ce^{3-}$.

Automated detection of panic disorder based on multimodal physiological signals using machine learning

  • Eun Hye Jang;Kwan Woo Choi;Ah Young Kim;Han Young Yu;Hong Jin Jeon;Sangwon Byun
    • ETRI Journal
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    • 제45권1호
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    • pp.105-118
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    • 2023
  • We tested the feasibility of automated discrimination of patients with panic disorder (PD) from healthy controls (HCs) based on multimodal physiological responses using machine learning. Electrocardiogram (ECG), electrodermal activity (EDA), respiration (RESP), and peripheral temperature (PT) of the participants were measured during three experimental phases: rest, stress, and recovery. Eleven physiological features were extracted from each phase and used as input data. Logistic regression (LoR), k-nearest neighbor (KNN), support vector machine (SVM), random forest (RF), and multilayer perceptron (MLP) algorithms were implemented with nested cross-validation. Linear regression analysis showed that ECG and PT features obtained in the stress and recovery phases were significant predictors of PD. We achieved the highest accuracy (75.61%) with MLP using all 33 features. With the exception of MLP, applying the significant predictors led to a higher accuracy than using 24 ECG features. These results suggest that combining multimodal physiological signals measured during various states of autonomic arousal has the potential to differentiate patients with PD from HCs.

수지말단(手指末端) 체온(體溫)과 인성검사(人性檢査)와의 상관성(相關性)에 관(關)한 연구(硏究) (A Study on the Correlation between the Fingertip's Temperature and MMPI)

  • 윤상희;류희영
    • 동의신경정신과학회지
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    • 제3권1호
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    • pp.46-55
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    • 1992
  • This clinical study aims to find out the effect of the fingertip's temperature and beverage-taking on the personality test by MMPI (Minnesota Multiphasic Personality Inventory). This is based on the sample survey on the 5 groups ; two or more-veined-handed group (15 persons), one-veined-handed group (22 persons), non-veined-hanede group(13 persons), beverage-taking group (41 persons) and beverage-non-taking group (14 persons). The result was obtained as follows ; 1. In the comparative examination on the two or mire-veined-haned group and the non-veined-handed group, there was significant difference of the temperature between the scale D and the scales of Mf, Pa, Pt, and Sc. 2. For the scales of Hs, D, Hy and the scales of Pd, Pa, Pt, Sc, the one-veined-handed group showed higher T-scores and lower fingertip's temperature than the non-veined-handed group without singnificant difference between them. 3. For the scales of D, Hy and the scales of Pd, Pa, Pt, Sc, the beverage-taking group showed higher T-scores and lower fingertip's temperature than the beverage-non-taking group without significant difference between them. As a result, I could find that low temperature on the fingertip, protruded vein on three knuckles(三關) of the finger and beverage-taking would cause the blood-extravasation(血瘀) and the lack of the transports in the spleen(脾不運化) and have an influence on Neurosis and Psychosis.

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