• Title/Summary/Keyword: Pseudo-R2

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Effects of Activated Carbon Particle Sizes on Caffeine Adsorptions (활성탄 입자 크기가 카페인 흡착에 미치는 영향)

  • Kim, Tae-Yang;Do, Si-Hyun;Hong, Seong-Ho
    • Journal of Korean Society of Water and Wastewater
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    • v.29 no.3
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    • pp.407-414
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    • 2015
  • The effect of activated carbon particle diameter (i.e. US sieve No. $8{\times}10$ ($d_p{\approx}2.19mm$), $18{\times}20$ ($d_p{\approx}0.92mm$), $50{\times}60$ ($d_p{\approx}0.27mm$) and $170{\times}200$ ($d_p{\approx}0.081mm$) on caffeine adsorption is investigated. BET surface area was increased with decreasing particle diameter ($d_p$), and caffeine adsorption rates increased with decreasing $d_p$. Moreover, pseudo-second order model is predicted the experimental data more accurately than pseudo-first order model, and the fastest rate constant ($k_2$) was $1.7g\;mg^{-1}min^{-1}$ when $d_p$ was 0.081 mm. Surface diffusion coefficient (Ds) was decreased with decreasing $d_p$ based on the minimum sum of square error (SSE). Practically, certain ranges of Ds are acceptable with high reliability ($R^2$) and it is determined that the effect of $d_p$ on Ds is unclear. The effect of pH on caffeine adsorption indicated the dependency of m/L ratio (mass liquid ratio) and $pH_{pzc}$. The $pH_{pzc}$ (i.e. $7.9{\pm}0.2$) was not affected by $d_p$. The higher caffeine adsorption at pH 4 and pH 7 than at pH 10 is due to $pH_{pzc}$, not $pk_a$ of caffeine.

Design and Analysis of Linear Span of A New Family of Non-linear Binary Sequences with 5-Valued Cross-Correlation Functions (5-값 상호상관관계를 갖는 새로운 비선형 이진수열군의 설계와 선형스팬 분석)

  • Choi, Un-Sook;Cho, Sung-Jin;Kim, Han-Doo
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.17 no.3
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    • pp.619-626
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    • 2013
  • The design of PN(Pseudo Noise) sequences with good cross-correlation properties is important for many research areas in communication systems. In this paper we propose new family of binary sequences $S^r=\{Tr_1^m\{[Tr_m^n(a{\alpha}^t+{\alpha}^{dt})]^r\}{\mid}a{\in}GF(2^n),\;0{\leq}t<2^n-1\}$ composed of Gold-like sequences and find the value of cross-correlation function when $d=2^{n-1}(3{\cdot}2^m-1)$, where n=2k, gcd(r, $2^m-1$)=1. Also we analyze the linear span of $S^r$ for some special r. Proposed sequences are extension of Gold-like sequences and GMW-sequences.

Adsorption of methylene blue from an aqueous dyeing solution by use of santa barbara amorphous-15 nanostructure: Kinetic and isotherm studies

  • Alizadeh, Reza;Zeidi, Amir
    • Advances in environmental research
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    • v.6 no.2
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    • pp.113-125
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    • 2017
  • Santa Barbara Amorphous-15(SBA-15) nanoparticles were utilized as the inexpensive and effective adsorbents to remove methylene blue dye from the aqueous solution.SBA-15 was created by Zhao et al method. Infrared spectroscopy, X-ray diffraction and scanning electron microscopy (SEM) were used for the evaluated physical properties of SBA-15. The results of diffraction X-ray indicated that was the crystalline structure for it. Also IR spectroscopy indicated was a silica the whole structure of the groups and SEM image verify the structure of relatively identical particles size of SBA-15. Factors affecting adsorption including the amounts of adsorbent, pH and contact time were investigated by a SBA-15 nanomaterial design. The extent of dye removal enhanced with increasing initial dye concentration and pH from 4 to 10. The higher percentage adsorption were obtained under optimum conditions of variables (sorbent dose of 200 mg/liter, initial MB concentration 10 mg/liter, initial pH of 10 and temperature of $25^{\circ}C$). Maximum adsorption happened after the 2 hour and the kinetic processes of the dyes adsorption were described by applying the pseudo-first-order and the pseudo-second-order and the relatively High correlation with the kinetic Ellovich models. It was found that the pseudo-second-order models kinetic equation described the data of dye adsorption with a good correlation (R2>0.999) which indicated chemisorption mechanism. Freundlich and Langmuir adsorption models were investigated in conditions of variables (adsorbent dose 0.01 gr/liter, MB concentration 10, 20, 30 mg/liter, pH of 4, 7, 10, contact time 90 min and temperature of $27^{\circ}C$). The adsorption data were represented by Langmuir isotherm model. These values are higher than the adsorption capacities of some other adsorbents that have recently been published in the literature.

RELATING GALOIS POINTS TO WEAK GALOIS WEIERSTRASS POINTS THROUGH DOUBLE COVERINGS OF CURVES

  • Komeda, Jiryo;Takahashi, Takeshi
    • Journal of the Korean Mathematical Society
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    • v.54 no.1
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    • pp.69-86
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    • 2017
  • The point $P{\in}{\mathbb{P}}^2$ is referred to as a Galois point for a nonsingular plane algebraic curve C if the projection ${\pi}_P:C{\rightarrow}{\mathbb{P}}^1$ from P is a Galois covering. In contrast, the point $P^{\prime}{\in}C^{\prime}$ is referred to as a weak Galois Weierstrass point of a nonsingular algebraic curve C' if P' is a Weierstrass point of C' and a total ramification point of some Galois covering $f:C^{\prime}{\rightarrow}{\mathbb{P}}^1$. In this paper, we discuss the following phenomena. For a nonsingular plane curve C with a Galois point P and a double covering ${\varphi}:C{\rightarrow}C^{\prime}$, if there exists a common ramification point of ${\pi}_P$ and ${\varphi}$, then there exists a weak Galois Weierstrass point $P^{\prime}{\in}C^{\prime}$ with its Weierstrass semigroup such that H(P') = or , which is a semigroup generated by two positive integers r and 2r + 1 or 2r - 1, such that P' is a branch point of ${\varphi}$. Conversely, for a weak Galois Weierstrass point $P^{\prime}{\in}C^{\prime}$ with H(P') = or , there exists a nonsingular plane curve C with a Galois point P and a double covering ${\varphi}:C{\rightarrow}C^{\prime}$ such that P' is a branch point of ${\varphi}$.

Synecological Characteristics and Vitality Analysis of the Berchemia berchemiaefolia Habitat (망개나무자생지의 식생특성과 활력도 분석)

  • Park, In-Hwan;Cho, Kwang-Jin
    • Journal of the Korean Society of Environmental Restoration Technology
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    • v.14 no.2
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    • pp.97-105
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    • 2011
  • This study was carried out to investigate vegetation and tree vitality of Berchemia berchemiaefolia habitat to recommend basic information for synecological characteristics. Totally 9 vegetation data were collected and analyzed. And one plant community (Quercus serrata-Berchemia berchemiaefolia community) including 43 families 66genera 72 species 8 varieties and 3 forma was differentiated. Quercus serrata-Berchemia berchemiaefolia community was subdivided into Typical subunit and Quercus mongolica subunit. Species showing the higer r-NCD value in the plant community were Berchemia berchemiaefolia, Quercus serrata, Lindera obtusiloba, Fraxinus rhynchophylla, Acer pseudo-sieboldianum, Corylus heterophylla var. thunbergii. In tree vitality result, Berchemia berchemiaefolia population containing 35 individual was estimated 3 monitoring categories; 1) General 2) Principal 3) Absolute. These categories frequencies arranged by the order General Monitoring (85.7%; 30 individual), Principal Monitoring (11.4%; 4 individual) and Absolute Monitoring (2.9%; 1 individual).

Using nonlinear static procedures for seismic assessment of the 3D irregular SPEAR building

  • Bento, R.;Bhatt, C.;Pinho, R.
    • Earthquakes and Structures
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    • v.1 no.2
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    • pp.177-195
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    • 2010
  • This paper presents an appraisal of four nonlinear static procedures (CSM, N2, MPA and ACSM) employed in seismic assessment of plan-irregular buildings. It uses a three storey reinforced concrete plan-irregular frame building exemplifying typical older constructions of the Mediterranean region in the early 1970s that was tested in full-scale under bi-directional pseudo-dynamic loading condition at JRC, Ispra. The adequacy and efficiency of the simplified analytical modelling assumptions adopted were verified. In addition, the appropriate variants of code-prescribed NSPs (CSM and N2) to be considered for subsequent evaluation were established. Subsequent parametric studies revealed that all such NSPs predicted reasonably well both global and local responses, having the benchmark values been determined through nonlinear dynamic analyses using a suit of seven ground motions applied with four different orientations. The ACSM, however, predicted responses that matched slightly better the median dynamic results.

Automated Analysis for PDC-R Technique by Multiple Filtering (다중필터링에 의한 PDC-R 기법의 자동화 해석)

  • Joh, Sung-Ho;Rahman, Norinah Abd;Hassanul, Raja
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.30 no.3C
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    • pp.141-148
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    • 2010
  • Electrical noises like self potential, burst noises and 60-Hz electrical noises are one of the causes to reduce reliability of electrical resistivity survey. Even the PDC-R (Pseudo DC resisitivity) technique, recently developed, is suffering from the problem of low reliability due to electrical noises. That is, both DC-based and AC-based resistivity technique is subject to reliability problem due to electrical noises embedded in urban geotechnical sites. In this research, a new technique to enhance reliability of the PDC-R technique by minimizing influence of electrical noises was proposed. In addition, an automated procedure was also proposed to facilitate data analysis and interpretation of PDC-R measurements. The proposed technique is composed of two steps: 1. to extract information only related with the input current by means of multiple-filter technique, and 2. to undertake a task to sort out signal information only to show stable and reliable characteristics. This automated procedure was verified by a synthetic harmonic wave including DC shift, burst random noises and 60-Hz electrical noises. Also the procedure was applied to site investigation at urban areas for proving its feasibility and accuracy.

The Evaluation Of Creditability Of Interest Spread On Business Cycle (금리 스프레드의 경기예측력 평가)

  • Chi, Ho-Joon;Park, Sang-Kyu
    • The Korean Journal of Financial Management
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    • v.19 no.2
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    • pp.233-251
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    • 2002
  • 본 연구는 우리나라를 대상으로 장단기 스프레드와 신용스프레드가 경기변동에 대해 어떠한 예측력을 갖고 있는가를 살펴보았다. 이를 위해 1991년부터 2001년까지를 분석기간으로 하여 Probit 분석을 통해 금리스프레드와 경기변동과의 시차 및 불황확률을 추정하여 평가해 보았으며, 인과관계 검정을 시도해 보았다. 우선 금리스프레드와 경기변동에 대한 불황확률을 알아보기 위해서 Probit 모형을 이용하여 불황확률을 추정하였다. 그 결과 장단기 금리스프레드 중에서는 5년 만기 1종 국민주택채권수익률-콜금리(HCS)는 3개월, 5년 만기 1종 국민주택채권수익률-1년 만기 금융채수익률(HGS)은 7개월, 5년 만기 1종 국민주택채권수익률-1년 만기 통안증권수익률(HMS)은 9개월의 시차를 보이는 경우가 Pseudo $R^2$ 값이 가장 높게 나타났지만 불황확률을 토대로 경기 호황과 불황 국면을 비교해 본 결과 HMS는 Pseudo $R^2$의 값도 상대적으로 높았을 뿐만 아니라 매우 높은 경기변동 예측력을 보여주었다. HCS와 HGS의 경우에는 IMF 체제 전후의 불황기와 그 이후에 도래한 호황기는 예측력이 높게 나타났으나 1990년대 초반에는 제대로 불황확률을 예측하지 못하는 것으로 나타났다. 또한 3년 만기 회사채수익률-5년 만기 국민주택채권수익률(CHS)와 3년 만기회사채수익률 -3년 만기 금융채수익률(CGS)로 나타낸 신용 스프레드에서는 유의적인 결과를 도출하지는 못하였다. 한편 인과관계에서도 HCS, HGS, HMS 등의 장단기 스프레드는 경기변동에 대하여 일방적 원인변수로 작용하는 것으로 나타나 선행결합관계를 보여주었으나 CHS, CGS 등의 신용스프레드는 경기변동과 어떠한 유의적인 결합관계도 보여주지 못하였다. 따라서 장단기 스프레드는 경기변동을 예측하는데 유용한 정보를 제공하지만 신용스프레드는 경기변동을 예측하는데 도움을 주지 못하는 것으로 나타났다.

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Construction of bivariate asymmetric copulas

  • Mukherjee, Saikat;Lee, Youngsaeng;Kim, Jong-Min;Jang, Jun;Park, Jeong-Soo
    • Communications for Statistical Applications and Methods
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    • v.25 no.2
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    • pp.217-234
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    • 2018
  • Copulas are a tool for constructing multivariate distributions and formalizing the dependence structure between random variables. From copula literature review, there are a few asymmetric copulas available so far while data collected from the real world often exhibit asymmetric nature. This necessitates developing asymmetric copulas. In this study, we discuss a method to construct a new class of bivariate asymmetric copulas based on products of symmetric (sometimes asymmetric) copulas with powered arguments in order to determine if the proposed construction can offer an added value for modeling asymmetric bivariate data. With these newly constructed copulas, we investigate dependence properties and measure of association between random variables. In addition, the test of symmetry of data and the estimation of hyper-parameters by the maximum likelihood method are discussed. With two real example such as car rental data and economic indicators data, we perform the goodness-of-fit test of our proposed asymmetric copulas. For these data, some of the proposed models turned out to be successful whereas the existing copulas were mostly unsuccessful. The method of presented here can be useful in fields such as finance, climate and social science.

Isothermal and Kinetic Studies of the Adsorption Removal of Pb(II), Cu(II), and Ni(II) Ions from Aqueous Solutions using Modified Chara Sp. Algae

  • Kalash, Khairi R.;Alalwan, Hayder A.;Al-Furaiji, Mustafa H.;Alminshid, Alaa. H.;Waisi, Basma I.
    • Korean Chemical Engineering Research
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    • v.58 no.2
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    • pp.301-306
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    • 2020
  • We investigated the individual biosorption removal of lead, copper, and nickel ions from aqueous solutions using Chara sp. algae powder in a batch mode. The impact of several parameters, such as initial concentration of the metal ions, contacting time, sorbent dose, and pH on the removal efficiency, was investigated. The maximum removal efficiency at optimum conditions was found to be 98% for Pb(II) at pH = 4, 90% for Cu(II) at pH = 5, and 80% for Ni(II) at pH = 5. The isotherm study was done under the optimum conditions for each metal by applying the experimental results onto the well-known Freundlich and Langmuir models. The results show that the Langmuir is better in describing the isotherm adsorption of Pb(II) and Ni(II), while the Freundlich is a better fit in the case of Cu(II). Similarly, a kinetic study was performed by using the pseudo-first and second-order equations. Our results show that the pseudo-second-order is better in representing the kinetic adsorption of the three metal ions.