• Title/Summary/Keyword: Pseudo Point

Search Result 171, Processing Time 0.023 seconds

Cr(VI) removal using Fe2O3-chitosan-cherry kernel shell pyrolytic charcoal composite beads

  • Altun, Turkan;Ecevit, Huseyin
    • Environmental Engineering Research
    • /
    • v.25 no.3
    • /
    • pp.426-438
    • /
    • 2020
  • In this study, cherry kernel shell pyrolytic charcoal was synthesized (CKSC) and composite beads were obtained by blending this pyrolytic charcoal with chitosan and Fe2O3 nanoparticles (Fe-C-CKSC). Cr(VI) adsorption from aqueous solutions by Fe-C-CKSC composite beads and CKSC adsorbents was studied comparatively. The effects of Cr(VI) initial concentration, adsorbent dosage, contact time, pH and temperature parameters on Cr(VI) adsorption were investigated. Adsorption reached an equilibrium point within 120 min for CKSC and Fe-C-CKSC adsorbents. The maximum Cr(VI) removal was obtained at the initial pH value of 1.56 for CKSC and 2.00 for Fe-C-CKSC. The optimum adsorbent dosage was found to be 5 g/L for CKSC and 3 g/L for Fe-C-CKSC. Based on the Langmuir model, the maximum adsorption capacities were calculated as 14.455 mg/g and 47.576 mg/g for CKSC and Fe-C-CKSC, respectively. Thermodynamic and kinetic studies were performed. As a result of adsorption kinetics calculations, adsorption was found to be consistent with the pseudo second order kinetic model. Characterization of the synthesized adsorbents was performed by SEM, BET, FTIR and elemental analysis. This study has shown that low cost adsorbents CKSC and Fe-C-CKSC can be used in Cr(VI) removal from aqueous solutions.

A Self-Consistent Semi-Analytical Model for AlGaAs/InGaAs PMHEMTs

  • Abdel Aziz, M.;El-Banna, M.;El-Sayed, M.
    • JSTS:Journal of Semiconductor Technology and Science
    • /
    • v.2 no.1
    • /
    • pp.59-69
    • /
    • 2002
  • A semi-analytical model based on exact numerical analysis of the 2DEG channel in pseudo-morphic HEMT (PMHEMT) is presented. The exactness of the model stems from solving both Schrodinger's wave equation and Poisson's equation simultaneously and self-consistently. The analytical modeling of the device terminal characteristics in relation to the charge control model has allowed a best fit with the geometrical and structural parameters of the device. The numerically obtained data for the charge control of the channel are best fitted to analytical expressions which render the problem analytical. The obtained good agreement between experimental and modeled current/voltage characteristics and small signal parameters has confirmed the validity of the model over a wide range of biasing voltages. The model has been used to compare both the performance and characteristics of a PMHEMT with a competetive HEMT. The comparison between the two devices has been made in terms of 2DEG density, transfer characteristics, transconductance, gate capacitance and unity current gain cut-off frequency. The results show that PMHEMT outperforms the conventional HEMT in all considered parameters.

Direct Numerical Simulation of Turbulent Heat Transfer to Fluids at Supercritical Pressure Flowing in Vertical Tubes (직접수치모사를 이용한 수직원형관내 초임계압 유체의 난류 열전달 특성 연구)

  • Bae, Joong-Hun;Yoo, Jung-Yul;Choi, Hae-Cheon
    • Transactions of the Korean Society of Mechanical Engineers B
    • /
    • v.28 no.11
    • /
    • pp.1302-1314
    • /
    • 2004
  • Turbulent heat transfer to $CO_2$ at supercritical pressure flowing in vertical tubes is investigated using direct numerical simulation (DNS). A conservative space-time discretization scheme for variable-density flows at low Mach numbers is adopted in the present study to treat steep variations of fluid properties at supercritical pressure just above the thermodynamic critical point. The fluid properties at these conditions are obtained using PROPATH and used in the form of tables in the simulations. The buoyancy influence induced by strong variation of density across the pseudo-critical temperature proved to play a major role in turbulent heat transfer at supercritical state. Depending on the degree of buoyancy influence, turbulent heat transfer may be enhanced or significantly deteriorated, resulting in local hot spots along the heated surface. Based on the results of the present DNS combined with theoretical considerations, the physical mechanism of this local heat transfer deterioration is elucidated.

Property Evaluation of Reaction Sintered SiC/SiC Composites Fabricated by Melt Infiltration Process (용융함침법에 의한 반응소결 SiC/SiC 복합재료의 특성 평가)

  • Lee, Sang-Pill;Shin, Yun-Seok;Kohyama, Akira
    • Transactions of the Korean Society of Mechanical Engineers A
    • /
    • v.31 no.2 s.257
    • /
    • pp.205-210
    • /
    • 2007
  • SiC/SiC composites and monolithic SiC materials have been fabricated by the melt infiltration process, through the creation of crystallized SiC phase by the chemical reaction of C and Si. The reinforcing material used in this system was a braided Hi-Nicalon SiC fiber with double interphases of BN and SiC. The microstructures and the mechanical properties of RS-SiC based materials were investigated through means of SEM, TEM, EDS and three point bending test. The matrix morphology of RS-SiS/SiC composites was greatly composed of the SiC phases that the chemical composition of Si and C is different. The TEM analysis showed that the crystallized SiC phases were finely distributed in the matrix region of RS-SiC/SiC composites. RS-SiC/SiC composites also represented a good flexural strength and a high density, accompanying a pseudo failure behavior.

Removal of Pb(II) and Cd(II) From Aqueous solution Using Oxidized Activated Carbons Developed From Pecan Shells.

  • Youssef, A.M.;EL-Khouly, Sahar M.;El-Nabarawy, Th.
    • Carbon letters
    • /
    • v.9 no.1
    • /
    • pp.8-16
    • /
    • 2008
  • Oxidized activated carbons were prepared by reacting steam-activated carbon developed from pecan shells with nitric acid of varying strength (15, 30, 45 and 60%). The textural properties and the chemistry of the surface of the non-oxidized and of the oxidized carbons were determined from nitrogen adsorption and base neutralization capacities. The uptake of Pb(II) and Cd(II) from aqueous solution by these carbons was determined by kinetic and equilibrium experiments as well as by the column method. Treatment with nitric acid brought about drastic decrease in surface area and remarkable increase in the pore size of the carbon with these changes depending on the strength of nitric acid. Nitric acid increased the surface acidity by developing new surface oxygen functional groups of acidic nature. $HNO_3$-oxidized carbons exhibited high adsorption capacities for Pb(II) and Cd(II). The adsorption of these ions increased with the decrease of the surface pH of the carbon and with the increase of the solution pH from 2.5 to 6 and 7. The amount adsorbed from lead and cadmium was also related to the amount of surface acidity, the pH of the point of zero charge and on some metal ion parameters. Cadmium and lead uptake by the investigated carbons followed pseudo-second order model and the equilibrium sorption data fitted Langmuir adsorption model.

A Study on the Somatic Cells in Half Milk Samples of Dairy Goats (젖염소 분방유즙에서 체세포에 대한 연구)

  • Kim, Hye-Ra;Lee, Jeong-Chi;Jeong, Ji-Young;Lee, Youn-Kyung;Shin, Sung-Shik;Lee, Chai-Yong
    • Journal of Veterinary Clinics
    • /
    • v.24 no.2
    • /
    • pp.177-181
    • /
    • 2007
  • In the present study, a total of 547 half milk samples were collected from 274 dairy goats to perform somatic cell counts (SCC) and California mastitis test (CMT). Milk smear was stained with Pyronin Y-Methyl Green stain were classified into either epithelial or blood cells, etc. Of the 547 halves the percentage of CMT negative milk samples were 86%. Among these, 58.2% were CMT negative with SCC<500,000/ml, while 27.8% were CMT negative with SCC>500,000 ml. As expected, CMT score increased with the increase of SCC. The number of epithelial cells decreased with the increasing number of somatic cells, while the opposite was observed with the number of blood cells. These results indicate that the critical point in milk quality & CMT should be considered on the false (pseudo-SC) SCC in dairy goat.

Capacity spectrum method based on inelastic spectra for high viscous damped buildings

  • Bantilas, Kosmas E.;Kavvadias, Ioannis E.;Vasiliadis, Lazaros K.
    • Earthquakes and Structures
    • /
    • v.13 no.4
    • /
    • pp.337-351
    • /
    • 2017
  • In the present study a capacity spectrum method based on constant ductility inelastic spectra to estimate the seismic performance of structures equipped with elastic viscous dampers is presented. As the definition of the structures' effective damping, due to the damping system, is necessary, an alternative method to specify the effective damping ratio ${\xi}eff$ is presented. Moreover, damping reduction factors (B) are introduced to generate high damping elastic demand spectra. Given the elastic spectra for damping ratio ${\xi}eff$, the performance point of the structure can be obtained by relationships that relate the strength demand reduction factor (R) with the ductility demand factor (${\mu}$). As such expressions that link the above quantities, known as R - ${\mu}$ - Τ relationships, for different damping levels are presented. Moreover, corrective factors (Bv) for the pseudo-velocity spectra calculation are reported for different levels of damping and ductility in order to calculate with accuracy the values of the viscous dampers velocities. Finally, to evaluate the results of the proposed method, the whole process is applied to a four-storey reinforced concrete frame structure and to a six-storey steel structure, both equipped with elastic viscous dampers.

Syntheses and Properties of the High-Tc Superconductive Bi_{2-x}Mo_xSr_2Ca_2Cu_3O_y$ System

  • Keu Hong Kim;Jong Tae Lim;Seung Koo Cho;Byoung Chan Kwak;Don Kim;Jae Shi Choi
    • Bulletin of the Korean Chemical Society
    • /
    • v.11 no.1
    • /
    • pp.25-28
    • /
    • 1990
  • The superconducting properties have been studied for high-Tc superconductors of the $Bi_{2-x}Mo_xSr_2Ca_2Cu_3O_y$ system (x = 0.03-0.30). The crystal structure is pseudo tetragonal with the average lattice parameters a = 5.38 ${\AA}$, b = 5.44 ${\AA}$ and c = 30.6 ${\AA}$. All samples exhibit superconductivity with Tc offset at 79 K and Tc onset at 90-115 K. The Tc onset point decreases with increasing x, but the Tc offset points are nearly the same for all samples. Scanning electron micrographs show a special growth behavior of the grains with a plate shape. It is suggested that the decrease in Tc onset points with substitution of Mo for Bi is due to the decrease in lattice parameters and to the p-orbital of Mo. It is concluded that Mo does not play a crucial role in the superconducting transition of the $Bi_2Sr_2Ca_2Cu_3O_y$ system.

A Study on implementing Android library for streaming multimedia contents to multiple devices in Wi-Fi Direct networks (Wi-Fi Direct 망에서 다수의 단말에게 동영상 스트리밍을 위한 안드로이드 라이브러리 개발)

  • Park, Chan-Je;Kim, Dong-Woo;Kim, Sung-Wook;Lee, Dong-Gun;Yoo, Hong-Suk;Goyal, Ankita;Kim, Dong-Kyun;Yang, Eun-Joo
    • Proceedings of the Korea Information Processing Society Conference
    • /
    • 2013.11a
    • /
    • pp.253-256
    • /
    • 2013
  • Device-to-device (D2D) 통신 기술은 기지국 및 Access Point (AP)와 같은 인프라의 경유 없이 트래픽 교환이 단말기간에 직접적으로 이루어지도록 하는 기술이다. 오늘날 D2D 통신 기술은 셀룰러 망 과부하 문제의 해결책으로써 많은 관심을 받고 있다. 본 논문에서는 대표적인 D2D 통신 기술인 Wi-Fi Direct에 기반하여 형성된 네트워크에 존재하는 다수의 단말에게 동영상을 스트리밍하기 위한 안드로이드 라이브러리 개발 사례를 소개한다. 본 논문에서 소개하는 라이브러리는 의사 브로드캐스트(Pseudo-broadcast) 방식을 사용하여 다수의 단말에게 동영상을 스트리밍한다. 의사 브로드캐스트 방식은 빠른 전송 속도로 동영상을 스트리밍할 뿐만 아니라 한 번의 전송을 다수의 단말에게 동일한 데이터를 전송할 수 있는 장점이 있다.

Efficient Adsorption of Methylene Blue from Aqueous Solution by Sulfuric Acid Activated Watermelone Rind (Citrullus lanatus)

  • Lee, Seo-Yun;Choi, Hee-Jeong
    • Applied Chemistry for Engineering
    • /
    • v.32 no.3
    • /
    • pp.348-356
    • /
    • 2021
  • The lignocellulose-based dried watermelon rind (WR) was modified with sulfuric acid, namely SWR for enhancement of methylene blue (MB) adsorption from the aqueous solution. According to FT-IR analysis, after the modification of WR with sulfuric acid, the functional groups of R-SO3H, COOH and -OH groups was formated or enhanced on the surface of the WR. Moreover, the point of zero charge (pHpzc) was changed from 6.3 to 4.1 after modification, which widened the range for adsorbing of cationic dye MB. The adsorption process of MB onto the SWR was suitable for pseudo-2nd-order and Langmuir model and the maximum adsorption capacity of Langmuir was found to be 334.45 mg/g at pH 7. In adition, the adsorption process occurs through the electrostatic interaction, hydrogen bridge formation, electron donor-acceptor relationship, and 𝜋-𝜋 electron dispersing force between functional groups on the carbon surface with MB molecules. Depending on functional groups available on the SWR surface, the MB adsorption mechanism can occur in combination with various interactions.