• 제목/요약/키워드: Pseudo Component

검색결과 84건 처리시간 0.027초

Dependence of an Interfacial Diels-Alder Reaction Kinetics on the Density of the Immobilized Dienophile: An Example of Phase-Separation

  • Min, Kyoung-Mi;Jung, Deok-Ho;Chae, Su-In;Kwon, Young-Eun
    • Bulletin of the Korean Chemical Society
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    • 제32권5호
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    • pp.1679-1684
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    • 2011
  • Interfacial reactions kinetics often differ from kinetics of bulk reactions. Here, we describe how the density change of an immobilized reactant influences the kinetics of interfacial reactions. Self-assembled monolayers (SAMs) of alkanethiolates on gold were used as a model interface and the Diels-Alder reaction between immobilized quinones and soluble cyclopentadiene was used as a model reaction. The kinetic behavior was studied using varying concentrations of quinones. An unusual threshold density of quinones (${\Gamma}_c$ = 5.2-7.2%), at which the pseudo-first order rate constant started to vary as the reaction progressed, was observed. This unexpected kinetic behavior was attributed to the phase-separation phenomena of multi-component SAMs. Additional experiments using more phase-separated two-component SAMs supported this explanation by revealing a significant decrease in ${\Gamma}_c$ values. When the background hydroxyl group was replaced with carboxylic or phosphoric acid groups, ${\Gamma}_c$ was observed at below 1%. Also, more phase-separated thermodynamically controlled SAMs produced a lower critical density (3% < ${\Gamma}_c$ < 4.9%) than that of the less phaseseparated kinetically controlled SAMs (6.5% < ${\Gamma}_c$ < 8.9%).

Pulsed Power전원장치용 Gas Puffing INPIStron의 개발 (Development of Gas Puffing INPIStron for Pulsed Power Supply)

  • 서길수;김영배;조국희;이형호
    • 대한전기학회논문지:전기물성ㆍ응용부문C
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    • 제49권12호
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    • pp.679-684
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    • 2000
  • Closing switch, key component of pulsed power system, is constructed simply and used frequently due to the easy control and manufacture of one. The kind of one are spark-gap, triggered vacuum switch, pseudo-spark switch and INPIStron. But the electrode of spark gap switch is damaged with the hot spot by Z-pinch and then the life of one become short. INPIStron with inverse pinch effect has long life but it is difficult trigger system to provide uniform discharge between cathode and anode. In this paper, the design and manufacturing of INPIStron with gas puffing trigger method in order to supply uniform discharge inter-electrode and the performance of the developed INPIStron applied to 500[kA]-2[MJ] pulsed power system is presented.

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Smart Particles Containing Multiple Rugate-structured Photonic Crystal

  • Jang, Seunghyun
    • 통합자연과학논문집
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    • 제5권4호
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    • pp.253-256
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    • 2012
  • The rugate porous silicons containing multiple photonic band gaps have been generated by applying a composite waveform summed three computer-generated pseudo-sinusoidal current waveforms and exhibit three sharp photonic band gaps in the optical reflectivity spectrum. Generated multiple rugate porous silicons display three rugate peaks corresponding to the each of the sine components varied from 0.42, 0.36, and 0.30 Hz, with a spacing of 0.06 Hz between each sine component. The resulting rugate PSi films have been removed from the silicon substrate by applying an lift-off current and are then made into particles by ultrasono-method in a organic solution. The sensing experiments using these particles for organic solvents such as toluene, hexane, acetone, and methanol have been achieved. Condensing of organic vapors in the pores increases the refractive indices of entire particle which results a red shift in the photonic peaks.

Wind tunnel study of wind loading on rectangular louvered panels

  • Zuo, D.;Letchford, C.W.;Wayne, S.
    • Wind and Structures
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    • 제14권5호
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    • pp.449-463
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    • 2011
  • Drag forces on a rectangular louvered panel, both as a free-standing structure and as a component in a generic low-rise building model, were obtained in a wind tunnel study. When tested in a building model, the porosity ratio of the wall opposite the louvered panel was varied to investigate its effect on the loading of the louvered panel. Both mean and pseudo-steady drag coefficients were obtained. Comparisons with the provisions for porous walls in contemporary loading standards indicate that for some opposite wall porosity ratios, the standards specify significantly different wind loads (larger and smaller) than obtained from this wind tunnel study.

A novel hybrid testing approach for piping systems of industrial plants

  • Bursi, Oreste S.;Abbiati, Giuseppe;Reza, Md S.
    • Smart Structures and Systems
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    • 제14권6호
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    • pp.1005-1030
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    • 2014
  • The need for assessing dynamic response of typical industrial piping systems subjected to seismic loading motivated the authors to apply model reduction techniques to experimental dynamic substructuring. Initially, a better insight into the dynamic response of the emulated system was provided by means of the principal component analysis. The clear understanding of reduction basis requirements paved the way for the implementation of a number of model reduction techniques aimed at extending the applicability range of the hybrid testing technique beyond its traditional scope. Therefore, several hybrid simulations were performed on a typical full-scale industrial piping system endowed with a number of critical components, like elbows, Tee joints and bolted flange joints, ranging from operational to collapse limit states. Then, the favourable performance of the L-Stable Real-Time compatible time integrator and an effective delay compensation method were also checked throughout the testing campaign. Finally, several aspects of the piping performance were commented and conclusions drawn.

EUCLIDEAN SUBMANIFOLDS WITH CONFORMAL CANONICAL VECTOR FIELD

  • Chen, Bang-Yen;Deshmukh, Sharief
    • 대한수학회보
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    • 제55권6호
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    • pp.1823-1834
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    • 2018
  • The position vector field x is the most elementary and natural geometric object on a Euclidean submanifold M. The position vector field plays very important roles in mathematics as well as in physics. Similarly, the tangential component $x^T$ of the position vector field is the most natural vector field tangent to the Euclidean submanifold M. We simply call the vector field $x^T$ the canonical vector field of the Euclidean submanifold M. In earlier articles [4,5,9,11,12], we investigated Euclidean submanifolds whose canonical vector fields are concurrent, concircular, torse-forming, conservative or incompressible. In this article we study Euclidean submanifolds with conformal canonical vector field. In particular, we characterize such submanifolds. Several applications are also given. In the last section we present three global results on complete Euclidean submanifolds with conformal canonical vector field.

자이로 컴파스 얼라인먼트 오차특성을 고려한 스트랩다운 관성항법장치의 상호분산해석 (Covariance analysis of strapdown INS considering characteristics of gyrocompass alignment errors)

  • 박흥원;박찬국;이장규
    • 제어로봇시스템학회:학술대회논문집
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    • 제어로봇시스템학회 1993년도 한국자동제어학술회의논문집(국내학술편); Seoul National University, Seoul; 20-22 Oct. 1993
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    • pp.34-39
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    • 1993
  • Presented in this paper is a complete error covariance analysis for strapdown inertial navigation system(SDINS). We have found that in SDINS the cross-coupling terms in gyrocompass alignment errors can significantly influence the SDINS error propagation. Initial heading error has a close correlation with the east component of gyro bias erro, while initial level tilt errors are closely related to accelerometer bias errors. In addition, pseudo-state variables are introduced in covariance analysis for SDINS utilizing the characteristics of gyrocompass alignment errors. This approach simplifies the covariance analysis because it makes the initial error covariance matrix to a diagonal form. Thus a real implementation becomes easier. The approach is conformed by comparing the results for a simplified case with the covariance analysis obtained from the conventional SDINS error model.

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얼굴인증 방법들의 조명변화에 대한 견인성 연구 (Study On the Robustness Of Four Different Face Authentication Methods Under Illumination Changes)

  • 고대영;천영하;김진영;이주헌
    • 대한전자공학회:학술대회논문집
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    • 대한전자공학회 2003년도 하계종합학술대회 논문집 Ⅳ
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    • pp.2036-2039
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    • 2003
  • This paper focuses on the study of the robustness of face authentication methods under illumination changes. Four different face authentication methods are tried. These methods are as follows; Principal Component Analysis, Gaussian Mixture Models, 1-Dimensional Hidden Markov Models, 2-Dimensional Hidden Markov Models. Experiment results involving an artificial illumination change to face images are compared with each others. Face feature vector extraction method based on the 2-Dimensional Discrete Cosine Transform is used. Experiments to evaluate the above four different face authentication methods are carried out on the Olivetti Research Laboratory(ORL) face database. For the pseudo 2D HMM, the best EER (Equal Error Rate) performance is observed.

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전자기 가진 원 저감에 의한 BLDC Fan Motor의 공진 소음 저감에 관한 연구 (Study on the Noise Reduction of BLDC Fan Motor by the Diminution of the Electro-Magnetic Exciting Source)

  • 신현정;이동일
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2006년도 제37회 하계학술대회 논문집 B
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    • pp.857-860
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    • 2006
  • It is important to diminish noise source of an electric motor used in appliances. We studied on the noise reduction of BLDC motor to drive a fan. Especially, this study was focused on detent torque caused by interaction between a permanent magnet of rotor and groove in stator. This source and rotating system brought about a resonance. This paper showed that the higher harmonic component of this torque had a main factor to lessen noise. So, we had designed new magnets with shape like a peanut and pseudo-sinusoidal flux density for low-noise BLDC motor in refrigerator.

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웨이브렛 변환과 다중 가중치를 이용한 강인한 패턴 워터마킹 (Robust pattern watermarking using wavelet transform and multi-weights)

  • 김현환;김용민;김두영
    • 한국통신학회논문지
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    • 제25권3B호
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    • pp.557-564
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    • 2000
  • This paper presents a watermarking algorithm for embedding visually recognizable pattern (Mark, Logo, Symbol, stamping or signature) into the image. first, the color image(RGB model)is transformed in YCbCr model and then the Y component is transformed into 3-level wavelet transform. Next, the values are assembled with pattern watermark. PN(pseudo noise) code at spread spectrum communication method and mutilevel watermark weights. This values are inserted into discrete wavelet domain. In our scheme, new calculating method is designed to calculate wavelet transform with integer value in considering the quantization error. and we used the color conversion with fixed-point arithmetic to be easy to make the hardware hereafter. Also, we made the new solution using mutilevel threshold to robust to common signal distortions and malicious attack, and to enhance quality of image in considering the human visual system. the experimental results showed that the proposed watermarking algorithm was superior to other similar water marking algorithm. We showed what it was robust to common signal processing and geometric transform such as brightness. contrast, filtering. scaling. JPEG lossy compression and geometric deformation.

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