• 한국자기학회지
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• 제4권3호
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• pp.282-284
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• 1994

물의 양성자완화에 의하여 기생 강자성 ${\alpha}-Fe_{2}O_{3}$의 유효 자기능률 결정을 위한 이론식을 유도하였다. 그 이론식을 유도함에 있어서 그 결정입자의 대응전자스핀과 물분자의 양성자 스핀사이의 거리가 상대적 거리보다 오히려 동경벡터로 고려되어야 한다는 사실을 제외하고서 자유 상자성 이론들을 함유함고 있는 수용액에 적용된 수학적 과정과 정확히 동일하다는 것을 알았다. 또한 유도된 이론식에 의하여 계산된 결정입자의 유효자기능률이 Hiral에 의하여 결정된 실험치 잘 일치함을 알았다.

• 한국의학물리학회지:의학물리
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• 제12권1호
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• pp.31-39
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• 2001

핵자기공명분광학(NMR Spectroscopy)을 이용해서 우리는 생물체의 조직안에 있는 각종 대사물질들을 측정할 수 있게 되었으며, 이것은 또 지금까지 알려진 여러 방법 중에서 생물체내의 신진대사 물질이나 생화학적인 변화를 비침습적(noninvasive)으로 알아낼 수 있는 유일한 방법에 속한다. 양성자 핵자기공명분광학은 최근들어 사람이나 흑은 동물뇌의 생화학적인 특성을 연구하는데 많이 사용되어오고 있다. 핵자기공명영상은 주로 물분자에 있는 양성자의 밀도와 그들의 이완현상(relaxation phenomena)을 측정하여 영상화하지만 핵자기공명분광학은 생체조직내의 신진대사에 관한 생화학적인 정보를 제공한다. 많은 경우에 있어서 핵자기공명분광학은 CT나 MRI 영상에서는 발견할 수 없는 정보를 제공함으로써 특정질병의 진단에 사용될 수 있으며, 따라서 환자들의 질병상태를 효과적으로 진단하는데 쓰여질 수 있다. 따라서 본 연구에서는 사람의 뇌에서 수소 핵자기공명분광학을 이용하여 대사물질들의 농도를 정량화하는 방법을 시도하였다. 이를 위해 펀텀을 이용하여 대사물질들 각각의 스팩트럼을 구했고, 성인 남녀 16명을 대상으로 insula gray matter 부위의 대사물질들의 농도를 측정하였다. 그리고 이 값들은 다른 연구자들에 의해 밝혀진 값들과 매우 근사한 값을 제공하였다.

• 한국자기공명학회논문지
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• 제20권1호
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• pp.1-6
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• 2016

The proton NMR line widths and spin-lattice relaxation rates, $T_1^{-1}$, of ferroelectric $LiH_3(SeO_3)_2$, $Li_2SO_4{\cdot}H_2O$, and $LiN_2H_5SO_4$ single crystals were measured as a function of temperature. The line width measurements reveal rigid lattice behavior of all the crystals at low temperatures and line narrowing due to molecular motion at higher temperatures. The temperature dependences of the proton $T_1^{-1}$ for these crystals exhibit maxima, which are attributed to the effects of molecular motion by the Bloembergen - Purcell - Pound theory. The activation energies for the molecular motions of $^1H$ in these crystals were obtained. From these analysis, $^1H$ in $LiH_3(SeO_3)_2$ undergoes molecular motion more easily than $^1H$ in $LiN_2H_5SO_4$ and $Li_2SO_4{\cdot}H_2O$ crystals.

• 한국자기학회지
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• 제8권2호
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• pp.57-61
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• 1998

비정질 Fe81B13.5C2에서 싸이클로드론을 이용하여 양성자를 조사시키고, 자기 감수율의 주파수 특성을 측정하였다. 초기 감수율 스펙트럼은 전형적인 Debye 형이며, 이완 주파수는 3MHz 정도로 측정되었다. 자구회전에 의한 저주파 감수율은 양성자 조사에 따라 감소하였으나 고주파 감수율은 증가하였다. 조사량에 따른 감수율 이완 주파수 증가는 조사에 의해 국소결합에서 자구회전에 대한 pinning력 증가에 의한 것으로 설명되었다.

• Bulletin of the Korean Chemical Society
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• 제14권3호
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• pp.392-398
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• 1993

• Bulletin of the Korean Chemical Society
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• 제35권3호
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• pp.881-885
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• 2014

Photophysics of 10-hydroxybenzo[h]quinoline (HBQ) has been in controversy, in particular, on the nature of the electronic states before and after the excited state intramolecular proton transfer (ESIPT), even though the dynamics and mechanism of the ESIPT have been well established. We report highly time resolved fluorescence spectra over the full emission frequency regions of the enol and keto isomers and the anisotropy in time domain to determine the accurate rates of the population decay, spectral relaxation and anisotropy decay of the keto isomer. We have shown that the ~300 fs component observed frequently in ESIPT dynamics arises from the $S_2{\rightarrow}S_1$ internal conversion in the reaction product keto isomer and that the ESIPT occurs from the enol isomer in $S_1$ state to the keto isomer in $S_2$ state.

• Bulletin of the Korean Chemical Society
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• 제27권2호
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• pp.197-202
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• 2006

In the reaction A + B $^\rightarrow_\leftarrow$ C, where A and B are ionic reactants having opposite charges, a B molecule approaching an A will experience a switching of the interaction potential when the A molecule is captured by one of the other B molecules in the medium. In the reversible case, the former B molecule still has a chance to react with the A, so that one needs to take into account the switched interaction between the reactant B and the product C as well as that between the reactants to treat the kinetics accurately. It is shown that this kind of interaction potential switching affects the relaxation kinetics in an intriguing way as observed in a recent experiment on an excited-state proton transfer reaction.

• Macromolecular Research
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• 제12권6호
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• pp.559-563
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• 2004

Both the ultrasonic velocity at 3 MHz and the absorption coefficient in the frequency range from 0.2 to 2 MHz were measured for aqueous solutions of poly(sodium 4-styrenesulfonate) over the concentration range from 5 to $25\%$ (by weight). The pulse echo overlap method was employed to measure the ultrasonic velocity over the temperature range from 10 to $90^{\circ}C;$ the high-Q ultrasonic resonator method was used for the measurement of the absorption coefficient at $20^{\circ}C.$ The velocities exhibited their maximum values at ca. 55, 59, 63, 67, and $71^{\circ}C.$ for the 25, 20, 15, 10, and $5\%$ solutions, respectively. The velocity increased with respect to the poly(sodium 4-styrene-sulfonate) concentration at a given temperature. A study of the concentration dependence of the both the relaxation frequency and amplitude indicated that the relaxation at ca. 200 kHz is related to structural fluctuations of the polymer molecules, such as the segmental motions of the polymer chains and that the relaxation at ca. 1 MHz resulted from the proton transfer reactions of the oxygen sites of $SO_3.$ Both the absorption and the shear viscosity increase upon increasing the polymer concentration, but they decrease upon increasing the temperature.

• Journal of Biosystems Engineering
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• 제28권3호
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• pp.253-260
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• 2003

In this study, the feasibility of magnetic resonance techniques for nondestructive internal quality evaluation of Korean red ginseng was examined. Relaxation time constants were measured using various grades of red ginsengs. Solid state magnetic resonance imaging technique was applied to image dried red ginsengs which have low moisture contents (about 13%). A 7 tesla magnetic resonance imaging system operating at a proton resonant frequency of 300 ㎒ was used for acquiring MR images of dried Korean red ginseng. The comparison test of cross cut digital images and magnetic resonance images of heaven grade, good grade with cavity inside, and good grade with white part inside red ginseng suggested the feasibility of the internal quality evaluation of Korean red ginsengs using MRI techniques. A good grade red ginseng included abnormal tissues such as cavities or white parts inside was observed by the signal intensity of MR image based on magnetic resonance properties of proton nucleus. Analysis on an one dimensional profile of acquired MR image of Korean red ginseng showed easy discrimination of normal and abnormal tissues. MR techniques suggested ways to detect internal defects of red ginsengs effectively.

• Food Science and Biotechnology
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• 제16권4호
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• pp.646-649
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• 2007

The effect of the addition of 2 kinds of chemically modified starches (the anti-caking agents; tapioca starch and com starch) on caking of ramen soup was observed using a low-resolution proton-pulsed nuclear magnetic resonance (NMR) technique. After storing ramen soup samples with diverse compositions of modified starch at 20-40% relative humidity for 4 weeks, changes in the spin-spin relaxation time constant ($T_2$) were measured as a function of temperature. $T_2-Temperature$ curves for ramen soup containing modified starches showed that the caking initiation temperature (glass transition temperature) was increased by $5^{\circ}C$ following the addition of only 0.5% modified cornstarch. The results indicate that the modified com starch used in this study would be an effective anti-caking agent for ramen soup, thus prolonging the shelf life of the product.