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http://dx.doi.org/10.5012/bkcs.2006.27.2.197

Reversible Excited-State Proton Transfer: Effect of the Switching of Interaction Potential by Reaction  

Lee, Jin-uk (Department of Chemistry, Seoul National University)
Uhm, Je-sik (Department of Chemistry, Seoul National University)
Lee, Woo-Jin (Department of Chemistry, Seoul National University)
Lee, Sang-youb (Department of Chemistry, Seoul National University)
Sung, Jae-young (Department of Chemistry, Chung-Ang University)
Publication Information
Bulletin of the Korean Chemical Society / v.27, no.2, 2006 , pp. 197-202 More about this Journal
Abstract
In the reaction A + B $^\rightarrow_\leftarrow$ C, where A and B are ionic reactants having opposite charges, a B molecule approaching an A will experience a switching of the interaction potential when the A molecule is captured by one of the other B molecules in the medium. In the reversible case, the former B molecule still has a chance to react with the A, so that one needs to take into account the switched interaction between the reactant B and the product C as well as that between the reactants to treat the kinetics accurately. It is shown that this kind of interaction potential switching affects the relaxation kinetics in an intriguing way as observed in a recent experiment on an excited-state proton transfer reaction.
Keywords
Excited-state proton transfer; Reversible diffusion-influenced reaction; Effects of reactant force field;
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1 Szabo, A. J. Chem. Phys. 1991, 95, 2481   DOI
2 Agmon, N.; Edelstein, A. L. J. Chem. Phys. 1994, 100, 4181   DOI   ScienceOn
3 Pines, E.; Huppert, D. J. Chem. Phys. 1986, 84, 3576   DOI
4 Rice, S. A.; Butler, P. R.; Pilling, M. J.; Baird, J. K. J. Chem. Phys. 1979, 70, 4001   DOI
5 Gopich, I. V.; Agmon, N. Phys. Rev. Lett. 2000, 84, 2730; Agmon, N.; Gopich, I. V. J. Chem. Phys. 2000, 112, 2863   DOI   ScienceOn
6 Zel'dovich, Y. B.; Ovchinnikov, A. A. JETP Lett. 1977, 26, 440
7 Erratum, J. Chem. Phys. 1992, 96, 1663   DOI
8 Agmon, N.; Szabo, A. J. Chem. Phys. 1990, 92, 5270   DOI
9 Szabo, A.; Zwanzig, R. J. Stat. Phys. 1991, 65, 1057   DOI
10 Burlatsky, S. F.; Oshanin, G. S.; Ovchinnikov, A. A. Chem. Phys. 1991, 152, 13   DOI   ScienceOn
11 Martinho, J. M. G.; Farinha, J. P.; Berberan-Santos, M. N.; Duhamel, J.; Winnik, M. A. J. Chem. Phys. 1992, 96, 8143   DOI
12 Agmon, N. Phys. Rev. E 1993, 47, 2415   DOI
13 Kim, H.; Yang, M.; Shin, K. J. J. Chem. Phys. 1999, 111, 1068   DOI
14 Hong, K. M.; Noolandi, J. J. Chem. Phys. 1978, 68, 5163, 5172   DOI
15 Naumann, W.; Molski, A. J. Chem. Phys. 1994, 100, 1511   DOI   ScienceOn
16 Molski, A.; Naumann, W. J. Chem. Phys. 1994, 100, 1520   DOI   ScienceOn
17 Huppert, D.; Goldberg, S. Y.; Masad, A.; Agmon, N. Phys. Rev. Lett. 1992, 68, 3932   DOI   ScienceOn
18 Solntsev, K. M.; Huppert, D.; Agmon, N. J. Phys. Chem. A 2001, 105, 5868   DOI   ScienceOn
19 Lee, S.; Karplus, M. J. Chem. Phys. 1987, 86, 1883   DOI
20 Yang, M.; Lee, S.; Shin, K. J. J. Chem. Phys. 1998, 108, 9069   DOI   ScienceOn
21 Naumann, W. J. Chem. Phys. 1994, 101, 10953   DOI   ScienceOn
22 Yang, M.; Lee, S.; Shin, K. J. Phys. Rev. Lett. 1997, 79, 3783   DOI   ScienceOn
23 Edelstein, A. L.; Agmon, N. J. Phys. Chem. 1995, 99, 5389   DOI   ScienceOn
24 Agmon, N.; Schnörer, H.; Blumen, A. J. Phys. Chem. 1991, 95, 7326   DOI
25 Pines, E.; Huppert, D.; Agmon, N. J. Chem. Phys.1988, 88, 5620   DOI
26 Agmon, N.; Pines, E.; Huppert, D. J. Chem. Phys. 1988, 88, 5631   DOI
27 Agmon, N.; Huppert, D.; Masad, A.; Pines, E. J. Phys. Chem. 1991, 95, 10407   DOI
28 Agmon, N.; Huppert, D.; Masad, A.; Pines, E. J. Phys. Chem. 1992, 96, 2020   DOI
29 Solntsev, K. M.; Agmon, N. Chem. Phys. Lett. 2000, 262, 320
30 Edelstein, A. L.; Agmon, N. J. Chem. Phys. 1993, 99, 5396   DOI   ScienceOn
31 Edelstein, A. L.; Agmon, N. J. Mol. Liq. 1995, 64, 241   DOI   ScienceOn
32 Gopich, I. V.; Doktorov, A. B. J. Chem. Phys. 1996, 105, 2320   DOI   ScienceOn
33 Sung, J.; Lee, S. J. Chem. Phys. 1999, 111, 796   DOI
34 Sung, J.; Lee, S. J. Chem. Phys. 1999, 111, 10159   DOI   ScienceOn
35 Sung, J.; Lee, S. J. Chem. Phys. 2000, 112, 2128   DOI   ScienceOn
36 Eigen, M.; Kruse, W.; Maass, G.; de Maeyer, L. Prog. React. Kinet. 1964, 2, 287
37 Bernasconi, C. F. Relaxation Kinetics; Academic: New York, 1976
38 Sung, J.; Shin, K. J.; Lee, S. J. Chem. Phys. 1997, 107, 9418   DOI   ScienceOn
39 Sung, J.; Shin, K. J.; Lee, S. J. Chem. Phys. 1998, 109, 9101   DOI
40 Naumann, W.; Shokhirev, N. V.; Szabo, A. Phys. Rev. Lett. 1997, 79, 3074   DOI   ScienceOn