• Title/Summary/Keyword: Proton Exchange Membrane

검색결과 528건 처리시간 0.03초

연료전지 시스템을 위한 풀-브리지 소프트 위상 천이 PWM DC-DC 컨버터 (Full-bridge Soft-Switching PS-PWM DC-DC Converter for Fuel Cell Generation System)

  • 문상필;서기영;이현우;;신휘범
    • 한국조명전기설비학회:학술대회논문집
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    • 한국조명전기설비학회 2005년도 학술대회 논문집
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    • pp.371-376
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    • 2005
  • In this paper, a new a new full-bridge soft-switching phase shift PWM DC-DC Converter has been proposed, which is suitable for fuel cell based power generation system. The proposed converter has outstanding advantage over the conventional DC-DC converter with respect to high efficiency, high power density, and hish component utilization. In special. the proposed converter has predominant high boosting output voltage and high efficiency characteristics under the inherently severs low output voltage of the fuel cell through the overall load conditions. Moreover, the developed converter has been experimentally tested with the help of a fuel cell simulator, and can generate the V-I characteristics of proton exchange membrane(PEM) fuel cell, so that the performance of the proposed converter could be effectively examined and the validity of the converter could be verified.

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PEMFC 발전시스템용 고효율 PCS 개발에 관한 연구 (A Study on Development of High Efficiency PCS using in PEMFC Generation System)

  • 곽동걸;정원석;정도영;김춘삼;심재선
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2009년도 춘계학술대회 논문집 에너지변화시스템부문
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    • pp.266-268
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    • 2009
  • In this paper, authors deal with a power conditioning system (PCS) of high efficiency for a proton exchange membrane fuel cell (PEMFC) generation system. Fuel cells are a direct current (DC) power generators. They generate electricity through an electrochemical process that converts the energy stored in a fuel directly into electricity. Fuel cells have many benefits, which produce no particulate matter, nitrogen or sulfur oxides. And they have few moving parts and produce little or no noise. When fueled by hydrogen, they yield only heat and water as byproducts. Their wide application can reduce our dependence on fossil fuels and foreign sources of petroleum. This paper studies on a novel PCS circuit topology of high efficiency using in PEMFC generation system The controlling switches in the PCS is operated to soft switching. Some digital simulation results and experimental results for the proposed PCS is confirmed to the validity of the analytical results.

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Organic-inorganic Nano Composite Membranes of Sulfonated Poly(Ether Sulfone-ketone) Copolymer and $SiO_2$ for Fuel Cell Application

  • Lee, Dong-Hoon;Park, Hye-Suk;Seo, Dong-Wan;Kim, Whan-Gi
    • 한국분말야금학회:학술대회논문집
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    • 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part 1
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    • pp.487-488
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    • 2006
  • Novel bisphenol-based wholly aromatic poly(ether sulfone-ketone) copolymer containing pendant sulfonate groups were prepared by direct aromatic nucleophilic substitution polycondensation of 4,4-difluorobenzophenone, 2,2'-disodiumsulfonyl-4,4'-fluorophenylsulfone (40mole% of bisphenol A) and bisphenol A. Polymerization proceeded quantitatively to high molecular weight in N-methyl-2-pyrrolidinone at $180^{\circ}C$. Organic-inorganic composite membranes were obtained by mixing organic polymers with hydrophilic $SiO_2$ (ca. 20nm) obtained by sol-gel process. The polymer and a series of composite membranes were studied by FT-IR, $^1HNMR$, differential scanning calorimetry (DSC) and thermal stability. The proton conductivity as a function of temperature decreased as $SiO_2$ content increased, but methanol permeability decreased. The nano composite membranes were found to posse all requisite properties; Ion exchange capacity (1.2meq./g), glass transition temperatures $(164-183\;^{\circ}C)$, and low affinity towards methanol $(4.63-1.08{\times}10^{-7}\;cm^2/S)$.

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Intermodulation 방법에 의한 자동차용 연료전지 스택의 실시간 진단방법 개발 (Development of Real-time Diagnosis Method for PEMFC Stack via Intermodulation Method)

  • 이용현;유승열;김종현
    • 한국자동차공학회논문집
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    • 제22권7호
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    • pp.76-83
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    • 2014
  • During PEMFC(Proton Exchange Membrane Fuel Cell) operation monitoring and diagnosis are important issues for reliability and durability. Stack defect can be followed by a critical cell voltage drop in the stack. One method for monitoring the cell voltage is CVM(Cell Voltage Monitoring), where all cells in the stack are electrically connected to a voltage measuring system and monitored these voltages. The other methods are based on the EIS(Electrochemical Impedance Spectroscopy) and on nonlinear frequency response. In this paper, intermodulation(IM) method for diagnosis PEMFC stack is introduced. To detect one or more critical PEMFC cell voltage PEMFC stack is excited by two or more test sinusoid current, and the frequency response of the stack voltage is analyzed. If one or more critical cell voltage exists, higher harmonics on the voltage frequency spectrum will appear. For the proposed IM method, stack simulation and experiments are conducted.

Soft-switching resonant technique을 적용한 고효율 PEMFC inverter (High-efficiency fuel-cell power inverter with soft-switching resonant technique)

  • 한경희;조영래;백수현
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2005년도 추계학술대회 논문집 전기기기 및 에너지변환시스템부문
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    • pp.326-328
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    • 2005
  • In order to reduce the capital and overall operating cost of a fuel-cell system, a high-efficiency fuel-cell power inverter with a simple framework is required. The high-order two-inductance two-capacitance (LLCC) resonant technique is adopted in this study to implement a low-frequency 60-Hz sine wave voltage inverter utilized in the proton exchange membrane fuel-cell (PEMFC) system. The methodology for inverting dc voltage into low-frequency ac boltage is usually generated by the pulse-width-modulation (PWM) technique. However, the PWM-type inverter output has high-frequency harmonic components. Although an adequately designed filter could be utilized to overcome this problem, there are still some undesirable effects introduced by the high-frequency switching loss, electromagnetic-interference, harmonic current, and load variation. A novel power inverter via the LLCC resonant technique is designed for inverting dc voltage into 60-Hz ac sine wave voltage in the PEMFC system. This circuit scheme has the merits of low harmonic components, soft switching, high efficiency, and simplified implementation. The effectiveness of the proposed resonant inverter used for the PEMFC system is verified by numerical simulations and experimental results.

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고분자전해질형 단위 연료전지의 주요 작동 조건이 공기극 플러딩 현상에 미치는 영향 (Effect of Main Operating Conditions on Cathode Flooding Characteristics in a PEM Unit Fuel Cell)

  • 민경덕;김한상
    • 대한기계학회논문집B
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    • 제30권5호
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    • pp.489-495
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    • 2006
  • Proton exchange membrane (PEM) should be sufficiently hydrated with a careful consideration of heat and water management. Water management has been a critical operation issue for better understanding the operation and optimizing the performance of a PEM fuel cell. The flooding on cathode side resulting from excess water can limit the fuel cell performance. In this study, the visual cell was designed and fabricated fur the visualization of liquid water droplet dynamics related to cathode flooding in flow channels. The experiment was carried out to observe the formation, growth and removal of water droplets using CCD imaging system. Effects of operating conditions such as cell temperature, air flow rate and air relative humidity on cathode flooding characteristics were mainly investigated. Based on this study, we can get the basic insight into flooding phenomena and its two-phase flow nature. It is expected that data obtained can be effectively used fur the setup and validation of two-phase PEM fuel cell models considering cathode flooding.

80kW급 고분자 전해질 연료전지의 공기공급계(터보 블로워) 개발 (Development of air supply system(Turbo blower) for 80kW PEM fuel cell)

  • 이희섭;김창호;이용복
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2006년도 춘계학술대회
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    • pp.67-72
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    • 2006
  • Blower as an air supply system is one of the most important BOP (Balance of Plant) system fur FCV(Fuel Cell Vehicle). For generating and blowing compressed air, the motor of air blower consumes maximum 25% of net power and fuel cell demands a clean air. Considering the efficiency of whole FCV, low friction lubrication of high speed rotor is needed. For the purpose of reducing electrical power and supplying clean air to Fuel cell, oil-free air foil bearings are applied at the each side of brushless motor (BLDC) as journal bearings which diameter is 50mm. The normal power of driving motor has 1.7kW with the 30,000rpm operating range and the flow rate of air has maximum 160 SCFM. The impeller of blower was adopted a mixed type of centrifugal and axial which has several advantages for variable operating condition. The performance of turbo-blower and parameters of air foil bearings was investigated analytically and experimentally. From this study, the performance of the blower was confirmed to be suitable far 80kw PEM FC.

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침탄된 316L 스테인리스 강의 접촉저항 및 내식 특성 (The Contact Resistance and Corrosion Properties of Carburized 316L Stainless Steel)

  • 홍원혁;고석진;장동수;이정중
    • 한국표면공학회지
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    • 제46권5호
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    • pp.192-196
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    • 2013
  • Stainless steels (AISI 316L) are carburized by Inductively coupled plasma using $CH_4$ and Ar gas. The ${\gamma}_c$ phase(S-phase) is formed on the surface of stainless steel after carburizing process. The XRD peak of carburized samples is shifted to lower diffracting angle due to lattice expansion. Overall, the thickness of ${\gamma}_c$ phase showed a linear dependence with respect to increasing temperature due to the faster rate of diffusion of carbon. However, at temperatures above 500, the thickness data deviated from the linear trend. It is expected that the deviation was caused from atomic diffusion as well as other reactions that occurred at high temperatures. The interfacial contact resistance (ICR) and corrosion resistance are measured in a simulated proton exchange membrane fuel cell (PEMFC) environment. The ICR value of the carburized samples decreased from 130 $m{\Omega}cm^2$ (AISI 316L) to about 20 $m{\Omega}cm^2$. The sample carburized at 200 showed the best corrosion current density (6 ${\mu}Acm^{-2}$).

상용차용 고분자 전해질 연료전지 냉각시스템 배열에 따른 성능 특성 (Performance of Fuel Cell System for Medium Duty Truck by Cooling System Configuration)

  • 우종빈;김영현;유상석
    • 한국수소및신에너지학회논문집
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    • 제32권4호
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    • pp.236-244
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    • 2021
  • Fuel cell systems for medium duty truck require high power demands under driving. Since high power demands results in significant heat generation, thermal management is crucial for the performance and durability of medium duty truck. Therefore, various configurations of dual stacks with cooling systems are investigated to understand appropriate thermal management conditions. The simulation model consists of a dynamic fuel cell stack model, a cooling system model equipped with a controller, and the mounted controller applies a feedback controller to control the operating temperature. Also, In order to minimize parasitic power, the comparison of the cooling systems involved in the arrangement was divided into three case. As a result, this study compares the reaction of fuel cells to the placement of the cooling system under a variety of load conditions to find the best placement method.

캘빈방전 효과를 이용한 초순수 및 전해이온수의 정전기 방전 연구 (A Study on Electrostatic Discharging in Ultrapure and Electrolyzed Waters Using Kelvin's Thunderstorm Effect)

  • 김형원;정윤원;최인식;최병선;최동현;유근걸
    • 반도체디스플레이기술학회지
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    • 제21권1호
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    • pp.5-11
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    • 2022
  • Despite the increasing importance of manufacturing and application R&D for ultrapure deionized water and electrolyzed ion water, various and systematic studies have not been conducted until now. In this study, the electrostatic discharge (ESD) behavior of electrolyzed ion water using a proton exchange membrane(PEM) was evaluated according to the type, flow rate, and bubble of electrolyzed ion water. In addition, by observing that Oxidation Reduction Potential (ORP) value returns to the unique value of electrolyzed ion water after electrostatic discharge, the possibility of two types of ions participating in electrostatic discharge ((H2O)n+ (assumed)) and ions for maintaining the characteristics of electrolyzed water could be inferred. In order to confirm the chemical structure and characteristics of the cations, in-depth research related to water molecular orbital energy or band gap should be followed.