• 제목/요약/키워드: Property Variation

검색결과 821건 처리시간 0.028초

UAFM(초음파원자현미경) 팁의 진동-접촉 해석과 나노 표면에의 응용 (Vibro-Contact Analysis of Ultrasonic Atomic Force Microscopy Tip and It's Application to Nano Surface)

  • 박태성;곽동열;박익근;김정석
    • 비파괴검사학회지
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    • 제30권2호
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    • pp.132-138
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    • 2010
  • 본 연구에서는 접촉역학 특성에 의한 캔틸레버 탑의 접촉-진동을 연구하고 나노스케일의 표면에서 탄성특성을 이미지화 하였다. 스프링-질량 모텔과 Herzian 이론을 이용하여 접촉공진주파수를 이론적으로 계산하고 초음파원자현미경을 이용하여 캔틸레버의 자유공진주파수와 접촉공진주파수의 변화를 분석하였다. 또한, 프로토타입의 초음파원자현미경을 이용하여 구상화 열처리된 시험편의 탄성 이미지를 위상과 진폭 신호를 이용하여 성공적으로 얻을 수 었었다.

폴리이미드에 스퍼터 증착한 Cu-Cr, Cu-Ti 합금박막의 열처리 전후의 접착력과 미세구조 (Microsstructure of Sputter-Deposited and Annealed Cu-Cr, Cu-Ti Alloy Films on Polyimide Substrate and Their Adhesion Property)

  • 서환석;김기범
    • 한국표면공학회지
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    • 제27권5호
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    • pp.261-272
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    • 1994
  • Both Cu-Cr and Cu-Ti alloy films with different composition were prepared by dc magnetron sputtering onto polyimide substrate and their adhesion and microstructure were observed. In addition, the effect of heat treatment at $400^{\circ}C$ for 2 hours on the variation of adhesion properties and on the changess of microstructure were investigated. Cu-Cr alloy films have crystalline structure of either for or bcc phase depending on the composition of the film. However, the Cu-Ti alloy film forms fcc phase at low Ti concentration while it forms an amorphous phase as the Ti concentration in the films is increased to more than 25at.%. TEM analysis reveal that the microstructure of Cu-Cr and Cu-Ti films forms an open structure with vacant spaces. The adhesion between Cu-Cr, Cu-Ti alloy films and polyimide substrate is relatively good before the heat treatment, but is noticeably reduced after the heat treatment. In particular, the adhesion strength is significantly reduced in the Cu-Ti alloy films after the heat treatment. The reduction of adhesion strength after the heat treatment is identified to relate with the formation of oxide phases at the metal/polyimide interface by AES(Auger Electron Spectroscopy).

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Regulatory Mechanism of L-Alanine Dehydrogenase from Bacillus subtilis

  • 김수자;김유진;서미란;전봉숙
    • Bulletin of the Korean Chemical Society
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    • 제21권12호
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    • pp.1217-1221
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    • 2000
  • L-alanine dehydrogenase from Bacillus subtilis exhibits allosteric kinetic properties in the presence of $ZN^{2+}$. $ZN^{2+}$ induces the binding of substrate (L-alanine) to be cooperative at pH 8.0. The effect of pH variation between pH 7.0 and pH 10.0 on the inhibition by $ZN^{2+}$ correlates with the pH effect on the $K_m$ values for L-alanine within these pH range indicating that $ZN^{2+}$ and substrate compete for the same site. No such cooperativity is induced by $ZN^{2+}$ when the reaction is carried out at pH 10. At this higher pH, $ZN^{2+}$ binds with the enzyme with lower affinity and noncompetitive with respect to L-alanine. Inhibition of L-alanine dehydrogenase by $ZN^{2+}$ depends on the ionic strength. Increase in KCI concentration reduced the inhibition, but allosteric property in $ZN^{2+}$ binding is conserved. A model for the regulatory mechanism of L-alanine dehydrogenase as a noncooperative substrate-cooperative cofactor allosteric enzyme, which is compatible in both concerted and the sequential allosteric mechanism, is proposed.

Experimental investigation on the variation of thermal conductivity of soils with effective stress, porosity, and water saturation

  • Lee, So-Jung;Kim, Kyoung-Yul;Choi, Jung-Chan;Kwon, Tae-Hyuk
    • Geomechanics and Engineering
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    • 제11권6호
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    • pp.771-785
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    • 2016
  • The thermal conductivity of soils is an important property in energy-related geotechnical structures, such as underground heat pumps and underground electric power cable tunnels. This study explores the effects of geotechnical engineering properties on the thermal conductivity of soils. The thermal conductivities of quartz sands and Korean weathered silty sands were documented via a series of laboratory experiments, and its variations with effective stress, porosity, and water saturation were examined. While thermal conductivity was found to increase with an increase in the effective stress and water saturation and with a decrease in porosity, replacing air by water in pores the most predominantly enhanced the thermal conductivity by almost one order of magnitude. In addition, we have suggested an improved model for thermal conductivity prediction, based on water saturation, dry thermal conductivity, saturated thermal conductivity, and a fitting parameter that represents the curvature of the thermal conductivity-water saturation relation.

PECVD를 이용한 DLC 박막의 표면 마모 특성 향상을 위한 플루오린 첨가의 영향 (Effect of fluorine gas addition for improvement of surface wear property of DLC thin film deposited by using PECVD)

  • 박현준;김준형;문경일
    • 한국표면공학회지
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    • 제54권6호
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    • pp.357-364
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    • 2021
  • In this study, DLC films deposited by PECVD were evaluated to the properties of super-hydrophobic by CF4 treatment. The structure of DLC films were confirmed by Raman Spectra whether or not mixed sp3 (like diamond) peak and sp2 (like graphite) peak. And the hydrogen contents in the DLC films (F-DLC) were measured by RBS analysis. In addition, DLC films were analyzed by scratch test for adhesion, nano-indentation for hardness and tribo-meter of Ball-on-disc type for friction coefficient. In the result of analysis, DLC films had traditional structure regardless of variation of hardness at constant conditions. Also adhesion of DLC film was increased as higher material hardness. Otherwise, friction coefficient was increased as lower material hardness. The DLC films were treated by CF4 plasma treatment to enhance the properties of super-hydrophobic. And the DLC films were measured by ESEM(Enviromental Scanning Electron Microscope) for water condensation.

Effect of Hydrogen Charging Time and Tensile Loading Speed on Tensile Properties of 304L Stainless Steels

  • Hwang, SeungKuk;Lee, Sangpill;Lee, Jinkyung;Bae, Dongsu;Lee, Moonhee;Nam, Seunghoon
    • 한국산업융합학회 논문집
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    • 제22권1호
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    • pp.11-20
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    • 2019
  • This study dealt with the tensile strength characteristics of stainless steel 304L steel by hydrogen charging. Especially, the effect of hydrogen charging time on the tensile strength and ductility of 304L stainless steels was evaluated, in conjunction with the observation of their fracture surfaces. The tensile properties of hydrogen-charged 304L stainless steels were also investigated with the variation of tensile loading speeds. The hydrogen amount of 304L stainless steels obviously increased with the increase of hydrogen charging time. The tensile properties of 304L stainless steels were clearly affected by the short term charging of hydrogen. In particular, the elongation of 304L stainless steels decreased with increasing hydrogen charging time, due to the hydrogen embrittlement. It was also found that the tensile properties of hydrogen-charged 304L stainless steels were very sensitive to the crosshead speed for tensile loading.

EFFECT OF PLASTICIZERS ON THE PROPERTIES OF COSMETIC MASK USING POLYVINYL ALCOHOL (PVA) AS A FILM FORMER

  • Park, J.H.;K.Y.Kyong;Kwak, T.J.;Yoon, M.S.;Kang, S.H.
    • 대한화장품학회:학술대회논문집
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    • 대한화장품학회 1999년도 IFSCC . ASCS 학술대회 발표 논문
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    • pp.51-55
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    • 1999
  • Cosmetic mask is one of the traditional cosmetic product and is used to keep skin healthy and beautiful through moisturizing effect, cleansing effect and acceleration effect on microcirculation. There are several types of cosmetic mask such as peel-off type, tissue-off type, wash-off type and cotton sheet type immersed in cosmetic water. It is important for cosmetic formulators to develop an adequate type of cosmetic mask that meets the needs of the target consumers because each type of cosmetic mask has benefits and problems in its usage and efficacy. Polyvinyl alcohol (PVA) is widely used as an active ingredient of peel-off type cosmetic mask and the physical property of the PVA film changes with the usage of other ingredients. We studied the change of physical properties of the film containing PVA by formulating peel-off type cosmetic mask with the variation of humectants. Methylguceth-20 and glycereth-26 reduce the interaction between skin surface and PVA film without serious weakening of tensile strength and they can alleviate irritation. Glycerin, urea and betaine help PVA film soften and they also have excellent efficacy as humectants.

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Experimental investigation of the effect of the addition of Aerosil 200 nanoparticles on the water absorption of polymer concrete

  • A.M. Fattahi;Babak Safaei;Elham Moaddab;Zahra Pezeshki
    • Advances in nano research
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    • 제14권1호
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    • pp.81-92
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    • 2023
  • In this work, the effect of the addition of Aerosil 200, an insulating resin applied in many industries, on the water absorption of cement plast mixture has been experimentally evaluated. First, the preparation stages of cement plast mixture was evaluated based on corresponding standards and then, the effect of the addition of Aerosil 200 nanoparticles (NPs) to cement plast mixtures with sand weight percentage range of 0-0.1% on the variation of water absorption properties was evaluated based on National Standard Institution of Iran 20185 for Concrete Flooring Blocks - Requirements and Test Procedures. Based on the obtained results, it could be found that excessive addition of NPs did not affect the physical properties of the final product. Water absorption percentage was increased in the weight percentage of cement. By the increase of the amount of Aerosil 200 NPs in the prepared cement plast mixture, the percentage of water absorption in weight percentage of sand was decreased. Cement plast with NPs presented significantly lower water absorption than that without NPs.

Effects of neutron irradiation on densities and elastic properties of aggregate-forming minerals in concrete

  • Weiping Zhang;Hui Liu;Yong Zhou;Kaixing Liao;Ying Huang
    • Nuclear Engineering and Technology
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    • 제55권6호
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    • pp.2147-2157
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    • 2023
  • The aggregate-forming minerals in concrete undergo volume swelling and microstructure change under neutron irradiation, leading to degradation of physical and mechanical properties of the aggregates and concrete. A comprehensive investigation of volume change and elastic property variation of major aggregate-forming minerals is still lacking, so molecular dynamics simulations have been employed in this paper to improve the understanding of the degradation mechanisms. The results demonstrated that the densities of the selected aggregate-forming minerals of similar atomic structure and chemical composition vary in a similar trend with deposited energy due to the similar amorphization mechanism. The elastic tensors of all silicate minerals are almost isotropic after saturated irradiation, while those of irradiated carbonate minerals remain anisotropic. Moreover, the elastic modulus ratio versus density ratio of irradiated minerals is roughly following the density-modulus scaling relationship. These findings could further provide basis for predicting the volume and elastic properties of irradiated concrete aggregates in nuclear facilities.

Study on Stiffened-Plate Structure Response in Marine Nuclear Reactor Operation Environment

  • Han Koo Jeong;Soo Hyoung Kim;Seon Pyoung Hwang
    • 한국해양공학회지
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    • 제37권5호
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    • pp.205-214
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    • 2023
  • As the regulations on greenhouse gas emissions at sea become strict, efforts are being made to minimize environmental pollutants emitted from fossil fuels used by ships. Considering the large sizes of ships in conjunction with securing stable supplies of environment-friendly energy, interest in nuclear energy to power ships has been increasing. In this study, the neutron irradiation that occurs during the nuclear reactor operation and its effect on the structural responses of the stiffened-plate structures are investigated. This is done by changing the material properties of DH36 steel according to the research findings on the neutron-irradiated steels and then performing the structural response analyses of the structures using analytical and finite-element numerical solutions. Results reveal the influence of neutron irradiation on the structural responses of the structures. It is shown that both the strength and stiffness of the structures are affected by the neutron-irradiation phenomenon as their maximum flexural stress and deflection are increased with the increase in the amount of neutron irradiation. This implies that strength and stiffness need to be considered in the design of ships equipped with marine nuclear reactors.