• Title/Summary/Keyword: Properties of substances

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Microstructure and Textural Properties of Cell Mass from Cooked Kidney bean and Soybean (강남콩 고물과 대두 고물의 미세구조와 조직감에 대한 연구)

  • Kim, Jeong-Kyo;Watanabe, Tokuji;Lee, Cherl-Ho
    • Korean Journal of Food Science and Technology
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    • v.19 no.2
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    • pp.164-170
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    • 1987
  • The microstructure, contents of pectic substances and textural properties of cell masses separated from cooked kindey bean and soybean were investigated. Cooked kidney bean could be easily separated to the individual cells, while soybean yielded mixture of individual cells and cell clusters. The break down of the middle lamella was observed, but cell wall was not injured . Separated cells from kidney bean were spherical, while those from soybean were long sack shape as observed in both optical microscope and SEM. Cooked soybean cell mass, which had higher content of pectic substances, showed higher cohesiveness and adhesiveness compared to kidney bean cell mass.

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A Study on Biosorption of Calcium Ion Using Aerobic Granular Sludge (호기성 그래뉼 슬러지를 이용한 칼슘이온의 생물흡착에 관한 연구)

  • Kim, Hyun-Gu;Ahn, Dae-Hee
    • Journal of Environmental Science International
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    • v.28 no.8
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    • pp.677-687
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    • 2019
  • This study evaluated the biosorption properties of calcium ion using Aerobic Granular Sludge (AGS). A sequencing batch reactor was used to induce the production of Extracellular Polymeric Substances (EPS) through salinity injection, and the calcium ion adsorption efficiency was analyzed by a batch test. The EPS contents showed significant changes (104-136 mg/g MLVSS) at different salinity concentrations. The calcium ion adsorption efficiency was highest for AGS collected at 5.0% salinity, and it was confirmed that the biosorption efficiency of AGS was increased owing to the increase in EPS content. The results of the Freundlich isotherms showed that the ion binding strength (1/n) was 0.3941-0.7242 and the adsorption capacity ($K_f$) was 2.4082-3.3312. The specific surface area and the pore size of the AGS were $586.1m^2/g$ and 0.7547 nm, respectively, which were not significantly different from each other. It was confirmed that the influence of biological properties, such as EPS content, was relatively large among the factors affecting calcium ion adsorption.

Antimicrobial and cytotoxic properties of calcium-enriched mixture cement, Iranian propolis, and propolis with herbal extracts in primary dental pulp stem cells

  • Mohammad Esmaeilzadeh;Shirin Moradkhani;Fahimeh Daneshyar;Mohammad Reza Arabestani;Sara Soleimani Asl;Soudeh Tayebi;Maryam Farhadian
    • Restorative Dentistry and Endodontics
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    • v.48 no.1
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    • pp.2.1-2.12
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    • 2023
  • Objectives: In this study, natural substances were introduced as primary dental pulp caps for use in pulp therapy, and the antimicrobial and cytotoxic properties of these substances were investigated. Materials and Methods: In this in vitro study, the antimicrobial properties of calcium-enriched mixture (CEM) cement, propolis, and propolis individually combined with the extracts of several medicinal plants were investigated against Enterococcus faecalis, Escherichia coli, Pseudomonas aeruginosa, and Staphylococcus aureus. Then, the cytotoxicity of each substance or mixture against pulp stem cells extracted from 30 primary healthy teeth was evaluated at 4 concentrations. Data were gathered via observation, and optical density values were obtained using the 3-(4,5-dimethylthiazol-2-yl)-2,5-diphenyl-2H-tetrazolium bromide (MTT) test and recorded. SPSS software version 23 was used to analyze the data. Data were evaluated using 2-way analysis of variance and the Tukey test. Results: Regarding antimicrobial properties, thyme alone and thyme + propolis had the lowest minimum inhibitory concentrations (MICs) against the growth of S. aureus, E. coli, and P. aeruginosa bacteria. For E. faecalis, thyme + propolis had the lowest MIC, followed by thyme alone. At 24 and 72 hours, thyme + propolis, CEM cement, and propolis had the greatest bioviability in the primary dental pulp stem cells, and lavender + propolis had the lowest bioviability. Conclusions: Of the studied materials, thyme + propolis showed the best results in the measures of practical performance as a dental pulp cap.

Estimation for Retention Factor of Isoflavones in Physico-Chemical Properties

  • Lee, Seung-Ki;Row, Kyung-Ho
    • Bulletin of the Korean Chemical Society
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    • v.24 no.9
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    • pp.1265-1268
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    • 2003
  • The estimation of retention factors by correlation equations with physico-chmical properties maybe helpful in chromatographic work. The physico-chemical properties were water solubility (S), hydrophobicity (P), total energy ($E_t$), connectivity index 1 ($^1{\chi}$), hydrophilic-lipophlic balance (x) and hydrophilic surface area (h) of isoflavones. The retention factors were experimentally measured by RP-HPLC. Especially, the empirical regulations of water solubility and hydrophobicity were expressed in a linear form. The equation between retention factors and various physico-chemical properties of isoflavones was suggested as $k = a_0 + a_1\;log S + a_2log\;P^Q + a_3(E_t) + a_4(^1{\chi}) + a_5(x) + a_6(h)$, and the correlation coefficients estimated were relatively higher than 0.95. The empirical equations might be successfully used for a prediction of the various chromatographic characteristics of substances, with a similar chemical structure.

A Study of the Evaluation of Combustion Properties of Tetralin (테트랄린의 연소특성치 평가에 관한 연구)

  • Ha, Dong-Myeong
    • Journal of the Korean Society of Safety
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    • v.33 no.4
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    • pp.8-14
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    • 2018
  • In the industrial chemical process involving combustible materials, reliable safety data are required for design prevention, protection and mitigation measures. The accurate combustion properties are necessary to safely treatment, transportation and handling of flammable substances. The combustion parameters necessary for process safety are lower flash point, upper flash point, fire point, lower explosion limit(LEL), upper explosion limit(UEL)and autoignition temperature(AIT) etc.. However, the combustion properties suggested in the Material Safety Data Sheet (MSDS) are presented differently according to the literatures. In the chemical industries, tetralin which is widely used as a raw material of intermediate products, coating substances and rubber chemicals was selected. For safe handling of tetralin, the lower and flash point, the fire point, and the AIT were measured. The LEL and UEL of tetralin were calculated using the lower and upper flash point obtained in the experiment. The flash points of tetralin by using the Setaflash and Pensky-Martens closed-cup testers measured $70^{\circ}C$ and $76^{\circ}C$, respectively. The flash points of tetralin using the Tag and Cleveland open cup testers are measured $78^{\circ}C$ and $81^{\circ}C$, respectively. The AIT of the measured tetralin by the ASTM E659 apparatus was measured at $380^{\circ}C$. The LEL and UEL of tetralin measured by Setaflash closed-cup tester at $70^{\circ}C$ and $109^{\circ}C$ were calculated to be 1.02 vol% and 5.03 vol%, respectively. In this study, it was possible to predict the LEL and the UEL by using the lower and upper flash point of tetralin measured by Setasflash closed-cup tester. A new prediction method for the ignition delay time by the ignition temperature has been developed. It is possible to predict the ignition delay time at different ignition temperatures by the proposed model.

Restoration Report on the Chosun Dynasty Lacquered Wares Inlaid with Mother-of-Pearl (조선시대 나전칠기 수리)

  • Yi, Young Hee
    • Journal of Conservation Science
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    • v.5 no.2 s.6
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    • pp.25-34
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    • 1996
  • The essential point to be considered when restoring lacquered ware is to know its materials and properties, and prior studios from the conservational and scientific examination is the way to achieve it. Recently, to get a close examination of its materials and methods involved in lacquered ware making, cross section microscope studies are being applied. Cross section microscope studies shows that lacquering process has been simplified and that bone and earth substances have been added to the materials, a method also traced from the lacquered wooden coffin excavated from the 'Nak Rang Tomb' and by the lacquered wares of the 'Kyongjoo An Ap' areas. The significance of this Chosun Dynasty lacquered wares's inlaid with mother-of pearl restoration can be found in that we have been able to harmonize the very traditional and the very modern scientific method of our time and that we were able to launch a step forward from using only the synthetics to open up a new range of natural materials such as lacquers, bone and earth substances, oxhide-glue and nacres and of referring to the traditional methods.

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Manufacture and Properties of Inorganic Chemical Treated Wood by Introducing of Fluorides

  • Kim, Soung-Joon;Lee, Jong-Shin
    • Journal of the Korean Wood Science and Technology
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    • v.36 no.2
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    • pp.73-78
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    • 2008
  • Inorganic chemical treated wood was prepared by impregnation of calcium or magnesium chloride ($CaCl_2$ or $MgCl_2$) solution and immersion in saturated solution of ammonium fluoride ($NH_4F$) as a reactant in order to make an introduction of a refractory fluorides with fungicidal and insecticidal effects in wood. The weight percent gains (WPGs) were increased with increase in concentration of calcium chloride or magnesium chloride solution, and were higher in treatment with calcium chloride than with magnesium chloride. Inorganic substances were produced mainly in the lumina of tracheides. These substances were proved to be the calcium fluoride or magnesium fluoride by the energy dispersive X-ray analyzer in conjunction with a scanning electron microscope (SEM-EDX). The treated wood showed good decay resistance because the weight losses were hardly occurred by the test fungi such as Tyromyces palustris and Trametes versicolor. The fire resistance effect was superior to the treated wood compared with that of the untreated wood.

Spectroscopic Investigations of Soil Humic and Fulvic Acids from Okch'ǒn Basin

  • Hyun Sang Shin;Hichung Moon;Han Beom Yang;Seok Sung Yun
    • Bulletin of the Korean Chemical Society
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    • v.15 no.9
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    • pp.777-781
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    • 1994
  • Three humic acids (HA) and one fulvic acid (FA) are extracted from soils of the Okch'on Basin (Koyesan, Yongkwang and Taejon), and are purified and characterized using $^1H,\;^{13}C$ NMR, and IR spectroscopic methods. The results are compared with one another and with commerical humic acid (Aldrich Co) and aquatic humic acid from Gorleben underground aquifer in Germany. The IR and $^1H\;and\;^{13}C$ NMR spectral features are found to be nearly identical, suggesting that humic substances formed in the Okch'on Basin have quite similar chemical properties. These humic substances from Okch'on Basin soils have undergone low degree of aromatic condensation and have high contents of aliphatic functionalities including carbohydrates.

Prediction of Upper Explosion Limits(UEL) by Measurement of Upper Flash Point Using Setaflash Apparatus for n-Alcohols (Setaflash 장치를 이용한 노말 알코올류의 상부인화점 측정에 의한 폭발상한계의 예측)

  • Ha, Dong-Myeong
    • Journal of the Korean Society of Safety
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    • v.25 no.2
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    • pp.35-40
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    • 2010
  • Explosion limit and flash point are the major combustion properties used to determine the fire and explosion hazards of the flammable substances. In this study, in order to predict upper explosion limits(UEL), the upper flash point of n-alcohols were measured under the VLE(vapor-liquid equilibrium) state by using Setaflash closed cup tester(ASTM D3278). The UELs calculated by Antoine equation using the experimental upper flash point are usually lower than the several reported UELs. From the given results, using the proposed experimental and predicted method, it is possible to research the upper explosion limits of the other flammable substances.

Prediction of Upper Explosion Limits(UEL) by Measurement of Upper Flash Points for n-Alkanes and Aromatic Compounds (노말알칸류와 방향족탄화수소류의 상부인화점 측정에 의한 폭발상한계의 예측)

  • Ha, Dong-Myeong
    • Journal of the Korean Society of Safety
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    • v.26 no.4
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    • pp.59-64
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    • 2011
  • Explosion limit and flash point are the major combustion properties used to determine the fire and explosion hazards of the flammable substances. In this study, in order to predict upper explosion limits(UELs), the upper flash point of n-alkanes and aromatic compounds were measured under the VLE(vapor-liquid equilibrium) state by using Setaflash closed cup tester(ASTM D3278). The UELs calculated by Antoine equation and chemical stoichiometric coefficient tusing the experimental upper flash point were compared with the several reported UELs. From the given results, using the proposed experimental and predicted method, it is possible to research the upper explosion limits of the other flammable substances.