• 제목/요약/키워드: Properties of substances

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기능성 지표물질 확인을 위한 동양란 심비디움(Cymbidium) 향기 성분 비교 분석 (A Comparison of Functional Fragrant Components of Cymbidium (Oriental Orchid) Species)

  • 김성민;장유진;홍종원;송성호;박천호
    • 원예과학기술지
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    • 제34권2호
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    • pp.331-341
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    • 2016
  • 본 연구는 기능성 지표물질 확인을 위한 동양란 심비디움(Cymbidium) 향기 성분 비교 분석을 목적으로 하며, GC/MS 방법을 사용하여 한국춘란(Cymbidium goerigii L.), 중국춘란(C. forrestii R.)과 일경구화(C. faberi R.)의 향기성분을 비교 분석하였다. 분석은 한국춘란으로 '민춘란', '주금화', 중국춘란으로 '취개', '송매', '용자', 일경구화로 '최매', '남양매', '화자'등을 사용하였다. GC/MS 방법을 통해 검출된 성분들을 peak area(%)값 분석을 사용하여 3%이상의 주요 향기성분으로 분류하였다. 향기 성분 분석 결과 한국춘란에서는 유방암, 자궁경부암, 교모세포종암에 세포독성 기능성을 가진 ${\alpha}$-bergamotene과, 인체 간암 세포(HepG2)의 사멸과 성장 억제, 항진균제 및 바베스열원충, 충치균에 대한 억제 기능성을 가진 nerolidol이 가장 많았다. 중국 춘란에서는 nerolidol과 악성 흑색종 세포(B16-F10), 인체 간암 세포와 백혈병 세포(HL-60, K562)의 사멸과 억제 등의 기능성을 가진 ${\beta}$-bisabolene이 가장 많았다. 일경구화에서는 교모세포종(SF-767)의 억제와 간암세포주(BEL-7402)에 소염작용 억제 효과를 가진 ${\alpha}$-pinene, 위장 보호 효과 기능을 가진 1,8-cineole과 페로몬의 기능을 가진 1,3,7-octatriene이 가장 많았다. 이상에서 동양란의 주요 향기 성분으로 밝혀진 물질들은 인간에게 유익한 다양한 기능성을 갖고 있는 것으로 확인되었다.

골판지 원지 제조용 압축고지 내의 이물질 종류 및 재생섬유의 특성 (Type of Foreign Materials in Waste Paper Used for the Manufacture of Linerboard and Physical Properties of Recycled Fibers)

  • 윤승락;황종열
    • 펄프종이기술
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    • 제39권3호
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    • pp.1-11
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    • 2007
  • To evaluate the quality of waste paper used for the manufacture of linerboard, the types of papers and foreign materials in compressed waste paper currently used were investigated. The recycled fibers were obtained from printing paper, newspaper, wrapping paper, white coated paperboard and corrugated container. Their fibers were observed by using a microscope, and the mechanical properties of the recycled papers manufactured from the recycled fibers were investigated. The compressed wastepaper was composed of 54% paperboard, 20% printing paper, and 20% newsprint. The content of foreign materials was about 4%, showing higher contents compared to 1% of foreign substances provided by Korea paper manufacturers' association. The types of foreign materials were various, which include vinyls, plastics, metals, woods, styrofoams, and cloths. Sound fibers were generally observed in the recycled fibers of printing papers and wrapping paper. The recycled fibers of white coated board, corrugated container and newsprint showed to be generally damaged. The whiteness of each recycled fiber were highly affected by pulp bleaching and ink-particle mixing conditions. The values of breaking length and burst index were lower than those for corrugating medium and liner board specified in KS. Although the anatomical characteristics of recycled fibers varied, their strengths appeared to be similar. This result may be explained by the use of non-deinked fiber.

Cyanoethyl화에 의한 제지용 섬유의 화학적 개질효과에 관한 연구 (A Study on Chemical Modification Effect of Papermaking Fiber by Cyanoethylation)

  • 윤세영;조병묵;오정수
    • Journal of the Korean Wood Science and Technology
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    • 제25권1호
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    • pp.56-64
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    • 1997
  • Since there are three hydroxyl groups on each anhydroglucose ring of the cellulose, the renewable resources, we can get various functional papers by the chemical modification of cellulose. The reaction involving the introduction of the ${\beta}$-cyanoethyl ($-CH_2-CH_2$-CN) group into organic substances containing reactive hydrogen atoms is known as cyanoethylation. Cellulose reacts with acrylonitrile in the presence of strong alkalis in a typical manner of primary and secondary alcohols to form cyanoethyl ethers. In cyanoethylation, important factors of reaction are temperature, concentration of the NaOH, and addition rate of acrylronitrile. FT-IR spectra of cyanoethyl group was confirmed at $2250cm^{-1}$, which corresponds the introduction of aliphatic nitrile group. Effect of cyanoethyl DS(degree of substitution) on strength properties was resulted that cyanoethylated BKP of DS 0.04 appeared to be the best choice for overall strength properties. Also, excellent thermal stability in aging characteristics was obtained.

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Evaluation of Cudrania tricuspidata Leaves on Antioxidant Activities and Physicochemical Properties of Pork Patties

  • Cuong, Tran Van;Chin, Koo Bok
    • 한국축산식품학회지
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    • 제38권5호
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    • pp.889-900
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    • 2018
  • Characterization and utilization of the bioactive compounds from natural resources is one of the most concerns to maintain quality properties of foods, especially to prevent the oxidation of lipids in meat products. Phytochemical components and antioxidant activities of Cudrania tricuspidata (CT) leaves extracted using various solvents and their effects on physicochemical properties of pork patties during refrigerated storage were measured. The combined solvents of 80% ethanol, 80% methanol and pure double-distilled (dd)-water obtained the higher total phenolic compounds, flavonoids content, and antioxidant activities as compared to the pure solvent alone. Among the individual antioxidant components, catechin was the predominant polyphenol in CT leaves in all extracts. The addition of CT leaves extracts into pork patties showed high antioxidant activities since thiobarbituric acid-reactive substances (TBARS) values of added CT extracts were lower than those of the control (p<0.05). In conclusion, CT leaf phytochemical components displayed antioxidant activity that varied with the extract solvent used. CT extracts were superior to control in retarding lipid oxidation of pork patties, which was evident as reduced TBARS and peroxide values (POV).

Effects of Dietary Fiber and Stevioside Mixture on Quality Attributes of Sausage and the Blood Properties of Rats

  • Kang, Jong-Ok;Hong, Sung-Moon
    • 한국축산식품학회지
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    • 제32권2호
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    • pp.142-148
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    • 2012
  • This study was conducted to examine the physiochemical characteristics (PC) of a sausage with added dietary fiber and stevioside mixture, as well as the blood properties (BP) of rats with feeding of the sausage. There were no significant differences between the control and the treatments in the PC; in case of treatments, as additive contents of dietary fiber (1-3%) and stevioside (0.05-1.5%), redness ($a^*$) gradually increased, but yellowness ($b^*$) rapidly decreased (p<0.05). The pH level and water holding capacity (WHC) also tended to decrease. Thiobarbituric acid reactive substances (TBARS) were of little change. However, the texture of sensory evaluation and the adhesiveness of texture analysis had significantly low values (p<0.05). BP, such as blood sugar, high density lipoprotein (HDL) cholesterol, low density lipoprotein (LDL) cholesterol and triglyceride (TG), did not increase and total cholesterol (TC) actually decreased (p>0.05). However, body weights of rats increased with treatments. Overall, it is suggested that adding dietary fiber and stevioside mixture to sausages can moderately improve the redness, and also reduce the levels of sugar, cholesterol and neutral lipids in the blood without noticeably affecting the WHC, oxidant stability, appearance, and taste.

피혁 폐기물을 재활용한 재생가죽의 내노화특성 연구 (A Study on Anti-Aging Properties of Recycled Leather Using Shaving Scrap by Applying Antioxidant)

  • 서은호;임성욱;이윤섭;김원주;박은영
    • 한국염색가공학회지
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    • 제35권3호
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    • pp.151-158
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    • 2023
  • In this study, we investigated the durability properties of the recycled leather using shaving scrap with antioxidant. Recycled leather sheets were manufactured by mixing shaving scrap and NB latex as a binder. HALS(Hindered Amine Light Stabilizer) and UVA(UV absorbers) were used as antioxidant. Mechanical properties such as hardness, tensile strength, elongation, tear strength and abrasion resistance were measured. Light aging resistance was evaluated using UV lamp and the degree of discoloration of the recycled leather sheets using a gray scale. In addition, to evaluate heat aging and UV aging, the degree of discoloration of the recycled leather sheets over time was measured using colorimeter. Washing fastness was evaluated on the degree of dyeing of recycled leather sheets for six type of multi-fiber woven fabrics (Acetate, Cotton, Nylon-66, Polyester, Acryl, Wool). To determine whether hazardous substances were detected in recycled leather sheets, the contents of arylamine and Cr 6+ were evaluated. As a result, when used in combination with antioxidant, the heat aging and light aging of recycled leather were improved and hazardous substance were not detected.

Identification of Carotenoids from Green Alga Haematococcus pluvialis by HPLC and LC-MS (APCI) and Their Antioxidant Properties

  • Ranga, Rao;Sarada, A.R.;Baskaran, V.;Ravishankar, G.A.
    • Journal of Microbiology and Biotechnology
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    • 제19권11호
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    • pp.1333-1341
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    • 2009
  • Haematococcus pluvial is, a green alga, accumulates astaxanthin (3,3'-dihydroxy-$\beta$,$\beta$'-carotene-4,4'-dione) upto 2-3% on a dry weight basis. In the present study, identification of carotenoids from Haematococcus cyst cell extract by HPLC and LC-MS (APCI) and their antioxidant properties were evaluated in in vitro model systems. The extract exhibited 89% and 78% antioxidant activities in the $\beta$-carotene linoleate model and the hydroxyl radical scavenging model, at 9 ppm of total carotenoid, respectively. The extract also showed 80%, 85%, and 79% antioxidant activities against lipid peroxidation in the kidney, brain, and liver of rats. Low-density lipoprotein oxidation induced by $Cu^{2+}$ ions was also protected (45%, 64%, and 75%) by the extract in a dose-dependent manner with different carotenoid levels. Thiobarbituric acid reactive substances concentration in the blood, liver, and kidney of rats were also significantly (p<0.005) decreased in H. pluvialis-treated rats. The potent antioxidant activity is attributable to various carotenoids present in the extract.

Physicochemical properties of reduced-salt cured pork loin as affected by different freezing temperature and storage periods

  • Kim, Haeun;Chin, Koo Bok
    • Animal Bioscience
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    • 제35권3호
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    • pp.494-502
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    • 2022
  • Objective: The objective of this study was to evaluate functional properties of reduced-salt pork meat products made of pre-rigor pork loin treated by different freezing temperatures (-30℃ and -70℃) during storage. Methods: Pre-rigor cured pork loin with 1.0% added salt was compared to post-rigor muscle added with 1.5% salt for pH, color (L*, a*, b*), cooking loss (CL), expressible moisture, warner-Bratzler shear value, thiobarbituric acid reactive substances (TBARS), and volatile basic nitrogen (VBN). Results: Pre-rigor cured pork loins had higher pH and temperature than post-rigor ones as raw meat (p<0.05). pH values were higher for pre-rigor pork loins than those of post-rigor pork loins (p<0.05). Color values did not different among treatments (p>0.05). No color differences were observed during storage period after cooking (p>0.05). The CL (%) of pre-rigor cured pork loins was the lowest when frozen at -70℃. The TBARS and VBN increased from 8 weeks of storage (p<0.05), but no further changed thereafter (p>0.05). Pre-rigor cured pork loins added with 1.0% salt showed similar characteristics to post-rigor pork loins added with 1.5% salt. Conclusion: Cured pork loins could be produced using pre-rigor muscle added with 1/3 of the original salt level (1.5%) and could be stored for up to 4 wks of frozen storage, regardless of a frozen temperature of -30℃ or -70℃ without detrimental effects.

QSPR Models for Chromatographic Retention of Some Azoles with Physicochemical Properties

  • Polyakova, Yulia;Jin, Long Mei;Row, Kyung-Ho
    • Bulletin of the Korean Chemical Society
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    • 제27권2호
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    • pp.211-218
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    • 2006
  • This work deals with 24 substances composed of nitrogen-containing heterocycles. The relationships between the chromatographic retention factor (k) and those physicochemical properties which are relevant in quantitative structure-properties relationship (QSPR) studies, such as the polarizability $(\alpha)$, molar refractivity (MR), lipophilicity (logP), dipole moment $(\mu)$, total energy $(E_{tot})$, heat of formation $(\Delta H_f)$, molecular surface area $(S_M)$, and binding energy $(E_b)$, were investigated. The accuracy of the simple linear regressions between the chromatographic retention and the descriptors for all of the compounds was satisfactory (correlation coefficient, $0.8 \leq r \leq 1.0$). The QSPR models of these nitrogen-containing heterocyclic compounds could be predicted with a multiple linear regression equation having the statistical index, r = 1.000. This work demonstrated the successful application of the multiple linear approaches through the development of accurate predictive equations for retention factors in liquid chromatography.

Synthesis of Nanoporous Metal Oxide Films Using Anodic Oxidation and Their Gas Sensing Properties

  • Suh, Jun Min;Kim, Do Hong;Jang, Ho Won
    • 센서학회지
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    • 제27권1호
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    • pp.13-20
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    • 2018
  • Gas sensors based on metal oxide semiconductors are used in numerous applications including monitoring indoor air quality and detecting harmful substances like volatile organic compounds. Nanostructures, for example, nanoparticles, nanotubes, nanodomes, and nanofibers have been widely utilized to improve gas sensing properties of metal oxide semiconductors, and this increases the effective surface area, resulting in participation of more target gas molecules in the surface reaction. In the recent times, 1-dimensional (1D) metal oxide nanostructures fabricated using anodic oxidation have attracted great attention due to their high surface-to-volume ratio with large-area uniformity, reproducibility, and capability of synthesis under ambient air and pressure, leading to cost-effectiveness. Here, we provide a brief overview of 1D metal oxide nanostructures fabricated by anodic oxidation and their gas sensing properties. In addition, recent progress on thin film-based anodic oxidation for application in gas sensors is introduced.