• 제목/요약/키워드: Properties of substances

검색결과 722건 처리시간 0.026초

SnAgCu계 무연솔더의 전기화학적 반응에 따른 타펠 특성 (Tafel Characteristics by Electrochemical Reaction of SnAgCu Pb-Free Solder)

  • 홍원식;김광배
    • 한국재료학회지
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    • 제15권8호
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    • pp.536-542
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    • 2005
  • Recently European Council(EU) published the RoHS(restriction of the use of certain hazardous substances in electrical and electronic equipment) which is prohibit the use of Pb, Hg, Cd, $Cr^{+6}$, PBB or PBDE in the electrical and electronic equipments. So EU member States shall ensure that, from 1 July 2006, new electrical and electronic equipment put on the market does not contain 6 hazardous substances. The one of the most important in electronics manufacturing process is soldering. Soldering process use the chemical substances which are applied in fluxing and cleaning processes and it can generate the malfunction of electronics caused by corrosion in the fields conditions. Therefore this study researched on the polarization and Tafel properties of Sn40Pb and Sn3.0Ag0.5Cu(SAC) solder based on the electrochemical theory. We prepared SnPb specimens which was aged in $150^{\circ}C,\;180^{\circ}C$ for 15 minutes ana Sn3.0Ag0.5Cu specimens that was aged in $180^{\circ}C,\;220^{\circ}C$ for 10 minutes. Experimental polarization curves were measured in distilled ionized water and $3.5 wt\%$, 1 mole NaCl electrolyte of $40^{\circ}C$, pH 7.5. Ag/AgCl and graphite were utilized by reference and counter electrode, respectively. To observe the electrochemical reaction, polarization test was conducted from -250 mV to +250 mV. From the polarization curves that were composed of anodic and cathodic curves, we obtained Tafel slop, reversible electrode potential(Ecorr) and exchange current density(Icorr). In these results, corrosion rate for two specimen were compared Sn3.0Ag0.5Cu with SnPb solders

볏짚에서 분리한 Bacillus 균주들이 분비하는 항균물질들의 특성들 (Properties of Antimicrobial Substances Produced by Bacillus species Isolated from Rice Straw)

  • 류샤오밍;야오좡;심재민;이강욱;김현진;김정환
    • 한국미생물·생명공학회지
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    • 제45권2호
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    • pp.133-142
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    • 2017
  • 볏짚으로부터 200 bacilli 균주들이 분리되었고 이중 3 균주는 Bacillus cereus ATCC1457를 강력히 저해하였다. 분자생물학적 방법들을 사용하여 이들을 동정한 결과 RSC15는 B. licheniforms로 RSC26과 RSC42는 B. amyloliquefaciens들로 확인되었다. 항균물질들은 내열성을 지녀서 $100^{\circ}C$ 20분 처리 후에도 활성의 절반이 유지되었다. 배양상등액의 SDS-PAGE 분석결과 2종의 다른 항세균물질들이 확인 되었고 이들은 3.5 kDa 이하였다. 컬럼크로마토그래피 방법들을 사용하여 B. licheniformis RSC15가 만드는 항세균물질들을 부분정제한 결과 비활성은 955.0 AU/mg에서 6,400 AU/mg으로 증가하였다.

CLUSTER P-V CONTAINING SYSTEMS FOR THE DECREASING OF POLYMERIC MATERIAL COMBUSTION

  • Kodolov, V.I.;Bystrov, S.G.;Mikhailov, V.I.;Lipanov, A.M.
    • 한국화재소방학회:학술대회논문집
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    • 한국화재소방학회 1997년도 International Symposium on Fire Science and Technology
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    • pp.104-111
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    • 1997
  • Cluster systems are microcrystals of vanadiumoxided compounds such as Barium, Calcium or Sodium Metavanadates or Sodium Vanadium Bronze which are distributed into dimethyl- or diethylphosphites or microcrystals of vanadium oxides, for instance, vanadium oxide (+3), distributed into the methylphosphonic acid melted. During the interaction of vanadium compounds with the correspondent phosphororganic substances biue viscous liquids are formed. These liquids have paramagnetic properties. According to the UV and IR spectroscopic investigations as well as the results of EPR spectra the substances obtained consist of the nucleus containing 6 to 12 of vanadium atoms and the shell including ligands which are molecules of phosphites or methylphosphonic acid. Here every atom of vanadium interacts with four of phosphorus containing molecules. Sizes of the particles in these systems donot exceed 200 nm. Introduction of cluster systems (0,1 -0,3 % vanadium) into epoxy compositions before the introduction of curing agent - polyethylenepolyamine 6 -8 % leads to the acceleration of composition crosslinking and to the combustion decreasing: 1) Oxygen Index grows to 35: 2)mass losses during combustion decrease to 1-2%, 3) combustion time does not exceed 1 s; 4) the intumescence of material sample is being observed during the burner action as well as the foam coke formation.

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A Vapor Sensor Based on a Porous Silicon Microcavity for the Determination of Solvent Solutions

  • Bui, Huy;Nguyen, Thuy Van;Nguyen, The Anh;Pham, Thanh Binh;Dang, Quoc Trung;Do, Thuy Chi;Ngo, Quang Minh;Coisson, Roberto;Pham, Van Hoi
    • Journal of the Optical Society of Korea
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    • 제18권4호
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    • pp.301-306
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    • 2014
  • A porous silicon microcavity (PSMC) sensor has been made for vapors of solvent solutions, and a method has been developed in order to obtain simultaneous determination of two volatile substances with different concentrations. In our work, the temperature of the solution and the velocity of the air stream flowing through the solution have been used to control the response of the sensor for ethanol and acetone solutions. We study the dependence of the cavity-resonant wavelength shift on solvent concentration, velocity of the airflow and solution temperature. The wavelength shift depends linearly on concentration and increases with solution temperature and velocity of the airflow. The dependence of the wavelength shift on the solution temperature in the measurement contains properties of the temperature dependence of the solvent vapor pressure, which characterizes each solvent. As a result, the dependence of the wavelength shift on the solution temperature discriminates between solutions of ethanol and acetone with different concentrations. This suggests a possibility for the simultaneous determination of the volatile substances and their concentrations.

Enhanced silkworm antioxidant activity by feeding functional substances

  • Park, Jong Woo;Lee, Chang Hoon;Jeong, Chan Young;Kang, Sang Kuk;Kim, Seong-Wan;Kim, Nam-Suk;Kim, Kee Young
    • International Journal of Industrial Entomology and Biomaterials
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    • 제44권2호
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    • pp.37-43
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    • 2022
  • Silkworm food has been found to be effective for dementia, liver function, lowering blood sugar, and possesses antioxidant properties, which has been attracting attention as a health functional food. In this study, methods for enhancing the functionality of silkworms were explored and the production potential of high-functional silkworms was analyzed. For enhancing antioxidant activity, ascorbic acid, caffeic acid, laminarin, and glutathione were injected or fed to 5th instar silkworms, and the antioxidant activity of silkworm extract was comparatively analyzed. There was no significant change in polyphenol and flavonoid content, but it was confirmed that 2,2-diphenyl-1-picrylhydrazyl radical scavenging ability, superoxide dismutase-like activity, and reducing power were slightly increased after injection of ascorbic acid, caffeic acid, and glutathione. To confirm the increase in antioxidant efficacy through feeding, an inducer was mixed with sucrose and sprayed on mulberry leaves. As a result, the growth rate of silkworms improved and all indicators of antioxidant activity were improved in silkworms fed with ascorbic acid and glutathione. Considering these results, producing high-functional silkworms was deemed possible.

Analysis of microstructural characteristics and components of red and yellow ink pigments used in permanent makeup

  • Hyun Sook Jin;Byung Soo Chang
    • Applied Microscopy
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    • 제52권
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    • pp.3.1-3.8
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    • 2022
  • Our purpose in this study is to analyze the microstructural characteristics and constituent elements of inorganic substances added to the yellow ink and red ink pigments used in permanent makeup. We observed the microstructural properties of inorganic pigments added to the ink using a scanning electron microscopy (SEM) and analyzed the constituent elements of the inorganic pigment particles using an energy dispersive X-ray spectroscopy (EDX). In red wine-colored ink, cubic titanium dioxide with a diameter of 110 to 200 nm was the major component, and rod-shaped iron oxide was rarely observed. Most of the ingredients of taupe yellow ink were rod-shaped yellow iron oxide, and a small amount of cubic titanium dioxide was observed. Red wine-colored ink and taupe yellow ink contained lumps composed of titanium dioxide particles. In red wine-colored ink, lumps were formed by agglomeration. However, we observed that the surface of the lump composed of titanium dioxide in the taupe yellow ink had a smooth surface caused by external physical compression. The titanium dioxide particle mass which found in taupe yellow ink in this study is an artificial product. When this mass accumulates in the dermis, it may cause a color mismatch. Therefore, permanent makeup using fine pigments should be free of foreign substances that may cause trouble in the skin. In addition, there is a need to improve the quality of the ink so that the required color can be safe and long lasting in the dermis.

지질막에 대한 Dammarane-Type Triterpenoidal Glycosides와 그 Aglycones의 작용 (Action of Dammarane-Type Triterpenoidal Glycosides and Their Aglycones on Lipid Membranes)

  • Kim, Yu.A.;Park, Kyeong-Mee;Hyun, Hack-Chul;Song, Yong-Bum;Shin, Han-Jae;Park, Hwa-Jin
    • Journal of Ginseng Research
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    • 제20권3호
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    • pp.269-273
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    • 1996
  • We investigated the effects of ginseng glycosides and their aglycones on processes of single ion channel formation and channel properties. The glycosides, Rg, and Rb, , and their aglycones, 20-(S)-protopanaxatriol (PT) and 20-(S)-protopanaxadiol (PD) increased the membrane permeability for ions. PT, PD, Rg1, and Rb1; at concentrations of 0.5, 3.0, 10.0 and 30.0 $\mu\textrm{g}$/ml respectively; Induced single ion channel fluctuations with the life times in the range of 0.1~1005 in open states and conductances from 5 to 30 pS in 1 M KCI. At high concentrations of these substances, rapid fluctuations of transmembrane ion current with amplitude from hundred pS to dozen nS were observed. Against other substances, ginsenoside Rbl began to increase the membrane conductance at concentration of about 60 $\mu\textrm{g}$/ml without fluctuation of single ion channel. Membranes treated with PT, PD, Rg1 and Rb1 are more permeable to K+, than to Cl while zero current membrane potentials with 10 gradients of KCI were 12, 16, 8, 25 mV respectively. Key words : Membrane conductance, single ion channel, ginsenosides.

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Biological Characterization of the Chemical Structures of Naturally Occurring Substances with Cytotoxicity

  • Park, Hee-Juhn;Jung, Hyun-Ju;Lee, Kyung-Tae;Choi, Jong-Won
    • Natural Product Sciences
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    • 제12권4호
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    • pp.175-192
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    • 2006
  • Screening for the cytotoxicity from plant origin is the first stage for anti-cancer drug development. A variety of terpenoids with exomethylene, epoxide, allyl, $\alpha,\beta-unsaturated$ carbonyl, acetylenes, and $\alpha-methylene-\gamma-lactone$ induces apoptosis and/or differentiation as well as cytotoxicity through the ROS signal transduction pathways. These are found among monoterpenes, sesquiterpenes, triterpenes, flavonoids, coumarins, diarylheptanoids, and even organosulfuric compounds. The most essential characteristics of natural cytotoxic substances is to possess the strong electrophilicity that is susceptible to nucleophilic biomolecules in the cell. Thiol-reductants and superoxide dismutase can block or delay apoptosis. Thus, ROS and the resulting cellular redox-potential changes can be parts of the signal transduction pathway during apoptosis. Disturbance of the balance of oxireduction by the pigment of natural quinones also caused the induction of the differentiation and apoptosis. Saponins with the cytotoxicity are restricted to their monodesmosides, rather than to bisdesmosides. Those saponins exhibited calcium ion-mediated apoptosis in addition to cytotoxicity whereas they showed also differentiation without extracellular calcium ion. The properties on cytotoxicity, apoptosis, and differentiation were assumed to depend on resultant oxidative stress to the cells. In this review, we describe a spectrum of cytotoxic compounds with various action mechanisms.

서양의 식이보충제와 기능성 식품에 대한 인식 (A Understanding of Dietary Supplements and Functional Foods in the Occident)

  • 서민준;박진한
    • 동국한의학연구소논문집
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    • 제11권
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    • pp.41-51
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    • 2008
  • Dietary supplements are used by more than one-half of the adult US population. By contrast, herbal products in Germany are carefully regulated by the same standards as drugs, and efforts are under way to standardize their regulation in the entire European Union. Most herbal users do not inform their physicians that they are taking these supplements, and most physicians do not inquire. Although some herbal products have clinically proven benefits, it is increasingly apparent that many contain potentially toxic substances, particularly in relation to interactions with drugs. Hence, it is essential that practicing physicians develop a working knowledge of herbals-specifically, about claims for their usage and potential or proven efficacies and toxicities-and that they incorporate such knowledge into the evaluation and management of their patients. By contrast, functional foods-integral components of the diet that are understood to contribute added health benefits-are the subject of intense and widespread research in food and nutritional science. Examples include many polyphenolic substances, carotenoids, soy isoflavones, fish oils, and components of nuts that possess antioxidant and other properties that decrease the risk of vascular diseases and cancer. Practicing physicians are advised to stay abreast of these emerging findings in order to best advise their patients on the value of health-promoting diets in disease prevention.

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세피올라이트를 활용한 시멘트 경화체의 미세먼지 흡착 특성 (Fine Dust Adsorption of Cement Matrix Using Sepiolite )

  • 전은영;이상수
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2023년도 가을학술발표대회논문집
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    • pp.71-72
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    • 2023
  • As industrialization and urbanization accelerate, environmental issues have moved from local concerns to global issues. Among them, air pollution is the most important issue. Modern people spend more than 88% of their day indoors, but the concentration of fine dust and pollutants flowing indoors is increasing. The indoor environment has its own complexity, and various substances used indoors, such as building materials, furniture, electronics, and cleaning agents, emit chemical substances and cause various diseases. Therefore, when selecting building materials and interior finishing materials, the pollutant emission and adsorption capacity must be greatly considered. These considerations will ensure the construction of a sustainable future environment and a healthy life within that environment. Therefore, in order to reduce the generation of indoor air pollutants, this study aims to examine the fine dust adsorption properties of cement hardening materials using sepiolite, which has a porous structure and high absorption power among clay minerals. As a result of the experiment, it was found that the concentration of fine dust decreased as the addition rate of sepiolite increased. It is believed that the fine dust concentration was reduced due to the high porosity due to the microfibrous structure and large specific surface area of sepiolite, which has a porous structure among clay minerals. It is believed that these experimental results can be used as basic research for future use of sepiolite as a construction material.

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