• The Korean Journal of Pesticide Science
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• v.9 no.4
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• pp.422-428
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• 2005

In vivo antifungal activity of 44 fungicides consisting of 3 clubroot fungicides, 7 Oomycetes fungicides, 7 botriticides, 7 blasticides, 9 sterol biosynthesis inhibitors, and 11 broad spectrum fungicides were investigated against Plamodiophora brassicae, the causal agent of clubroot disease in Chinese cabbage. When fluazinam, flusulfamide and cyazofamid, commercial fungicide to control clubroot of Chinese cabbage in Korea, were applied to infested soil, club formations by P. brassicae were strongly inhibited at pot (35 $cm^2$) per 0.63 mg. Ethaboxam and cymoxanil, Oomycetes fungicides, completely controlled Chinese cabbage clubroot at 5 mg/pot, but cymoxanil represented sever phytotoxicity. Besides, dichlofluanid and procymidone of botriticides effectively controlled the development of Chinese cabbage clubroot at 2.5 mg/pot. Chlorothalonil, quintozene and trichlamide, broad spectrum fungicides, showed disease-control efficacy of 85%, 100% and 100% at 2.5 mg/pot, respectively. Most of sterol biosynthesis inhibitors displayed the strong antifungal activity against P. brassicae on cabbage seedlings and plant growth -retarding activity. From these results, 7 fungicides were selected and further tested in vivo antifungal activity against P. brassicae in glasshouse. Among them, ethaboxam showed the most antifungal activity against P. brassicae on cabbage seedlings, followed by fenarimol, procymidone, nuarimol and chlorothalonil.

• Asian Journal of Turfgrass Science
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• v.24 no.2
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• pp.170-175
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• 2010

A total of 24 isolates of S. homoeocarpa were isolated from 16 golf courses in Korea. Chemical resistance of 24 isolates was determined by in vitro fungal growth on fungicide-amended media with thiophanatemethyl (Benzimidazole fungicide family), tebuconazole (demethylation inhibitor fungicide family: DMI), and iprodione (dicarboximide fungicide family). Results indicated that 83.3% of 24 isolates were resistant to iprodione, 62.5% resistant to thiophanate-methyl and 0% resistant to tebuconazale. The dual resistance of iprodione and thiophanate-methyl was 58.3.%. Occurrence rate of fungicide resistance of thiophanate-methyl and iprodione had no relation to turfgrass varieties and isolated locations of pathogen. In the filed test, procymidone, boscalid, and fluquinconazole+pyrimethanil effectively controlled the dollar spot of creeping bentgrass.

• The Plant Pathology Journal
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• v.17 no.3
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• pp.149-153
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• 2001

A total of 2109 isolates of Botrytis cinerea were collected from infected plants fo strawberry, tomato, and cucumber in Korea from 1994 to 1996. Based on in virtotests for mycelial growth on potato-dextrose agar containing fungicides, the esolates were classified into six phenotypic groups : SSR, SRR, RSS, RRS, RSR, and RRR, representing sensitivity (S) or resistance (R) to carbendazim, procymidone, and diethofencarb. In that order the isolation frequencies of the SSR, SRR, RSS, RRS, RSR, and RRR phenotypes were 28.7, 1.1, 28.8, 39.4, 1.0, and 0.9%, respectively. Three isolates from each SSR, SRR, RSS, RRS, and RSR and an isolate of RRR phenotype were selected and evaluated for their fitness-related characteristics such as pathogenic aggressiveness, mycelial growth rate, sporulation, and sclerotial formation. Competitive abilities of the SSR, SRR, RSS, RRS, and RSR phenotypes were also compared by inculating mixtures of conidial suspensions of two phenotypes to cucumber plant, and then determining re-isolation frequencies from lesions. In general, significant differences in fitness-related characteristics, except pathogenic aggressiveness, were found not only between but also within phenotype groups. In the competitiveness tests, carbendazim-sinsitive phenotypes (SSR and SRR) were found to be more competitive than the resistant ones (RSS and RSR), whereas, the procymidone-resistant phenotypes (SRR and RRS) appeared to be more competitive than the sensitive ones (SSR, RSS, and RSR). There was no consistent dominance in competitiveness between the diethofencarb-resistant and sensitive phenotypes. The RSR phenotype was the least competitive among the five phenotypes.

• Journal of Food Hygiene and Safety
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• v.24 no.4
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• pp.338-347
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• 2009

The content of residual pesticides in commercial agricultural products in Gyeongsangbuk-Do area was investigated for 5 years extending the year 2004 through 2008. The detection rates of residual pesticides in agricultural products by year were similar in range of 11.6~16.4%. But the violation rates showed lower values in the last years from 4.5% of the year 2004 to 0% of the year 2007. The highest residual concentration of each pesticide detected in commercial agricultural products was investigated by year. That is, in the year 2004 and 2005, chlorpyrifos, chlorothalonil, diazinon, endosulfan, ethoprophos, fenarimol and procymidone were detected over the tolerance in kale, parsley, celery, chard and lettuce, and in the year 2006, permethrin in the soybean and peanut. The detection rate and violation rate of pesticides were highly increased in the order of the endosulfan, chlorpyrifos, procymidone, chlorfenapyr, fenitrothion, imazalil, isoprothiolane, methidathion and permethrin. The detection rate and violation rate of pesticides were increased after August every year.

• Journal of Food Hygiene and Safety
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• v.24 no.4
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• pp.357-367
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• 2009

This study was carried out to investigate the current status of pesticide residues in 3,735 agricultural products in the northern area of Seoul from January to December in 2008. 3,735 samples, comprising 119 types of agricultrural products were assessed via a multiresidue method to detect 260 pesticides. Pesticide residues were detected in 19.7% (737 of 3,735 samples), and the rate at which the detected residues violated the maximum residue levels(MRLs) of the Korean Food Code was 3.2% (121 of 3,735 samples). Pesticide residues were detected in 72 spin-aches, 64 peppers, 45 sweet peppers, 40 perilla leaves, 38 korean cabbages and 37 dried agricultural products. The samples that violated the MRLs included 14 perilla leaves, 13 spinaches, 12 leek, 6 lettuces(leaf), 6 chards and 6 gyeojchaes. Procymidone, endosulfan, chlorfenapyr, cypermethrin, bifenthrin, tebuconazole and fenvalerate were all frequently observed. Procymidone, endosulfan, dimethomorph and diniconazole were the pesticides most frequently detected at levels that violated the Korean Food Code MRLs.

• Horticultural Science & Technology
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• v.31 no.5
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• pp.633-639
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• 2013

Fungicide applications are required to prevent the strawberry from Botrytis fruit rot and powdery mildew that infect open strawberry flowers, however, their effects of fungicides on pollen germination of strawberry have been rarely documented, particularly those from recently developed active fungicidal ingredients. In this study we have evaluated the effects of 24 commercial fungicidal formulations and 6 organic materials on pollen germination in 3 strawberry cultivars using in vitro assays. Pollens from strawberry had higher germination rates on agar with sucrose of 18% and $25^{\circ}C$ than other tested conditions. Pollen germination rates of cvs. Seolhyang, Maehyang, and Kumhyang at 18% sucrose and $25^{\circ}C$ were 15.3, 18.4 and 30.7%, respectively. Pyraclostrobin, azoxystrobin, kresoxim-methyl, dichlofluanid, iminoctadine tris, and sulfur showed the strongest inhibitory efficacy with the germination rates of more than 93.8% compared to the no-fungicide control. Germination was not significantly affected by simeconazole and procymidone. This in vitro germination study may provide information useful for selecting fungicides in flowering stage to strawberry farmers.

• The Korean Journal of Pesticide Science
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• v.17 no.4
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• pp.283-292
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• 2013

A series of monitoring studies were carried out to evaluate the residue level of pesticides in different native soils from 1999 to 2006. The nation-wide collection of soil samples from paddy, greenhouse, upland and orchard, were analyzed by GLC (ECD or NPD) and GC/MS. The results obtained are summarized as follows; out of 14 pesticides detected from paddy soils in 1999, the highest residue level was 0.25 mg $kg^{-1}$, and the frequency was 21.7% as butachlor, 20.0% as isoprothiolane, and 16.7% as iprobenfos. In 2003, 7 pesticides were detected and their frequencies were 0~36.0%; the frequency was 36.0% as isoprothiolane and 33.3% as oxadiazon. In the year 2000, 57 pesticides in the greenhouse soil samples were detected with the highest frequency of 65.3%. Of the pesticides detected, endosulfan and procymidone showed the frequency of 65.3 and 50.0%, respectively. In 2004, 19 pesticides were detected from greenhouse soils, and their frequencies and residue levels were decreased. Endosulfan and procymidone showed high detection frequencies and concentrations of 21.3 and 9.3% and 0.76 and 0.31 mg $kg^{-1}$, respectively. In 2001, a total of 25 pesticides were detected through monitoring in 170 upland soils and the highest residue level was 2.24 mg $kg^{-1}$. The detection frequencies showed the range of 0~53.5%. Especially, endosulfan showed the highest frequency of 53.5%. Residue levels and frequencies of pesticide in the year 2005 were almost the same compared with that of the year 2001. As a result of monitoring in 150 orchard soils in 2002, 26 pesticides were detected and the highest residue level was 1.43 mg $kg^{-1}$. Of them, the frequency of endosulfan showed the highest as 45.3%. In 2006, 20 pesticides were detected in orchard soils. The frequency of total endosulfan was the highest as 5.3% but was lower than that of the year 2002.

• The Korean Journal of Pesticide Science
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• v.15 no.2
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• pp.114-124
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• 2011

The characteristics of pesticide residues by multiresidue analysis method using GC, HPLC and GC-MSD were examined for 18,069 numbers of 91 kinds of vegetables in Seoul from 2007 to 2009. Detection rates of pesticide residues were 11.2% in 2007, 8.5% in 2008 and 12.0% in 2009, respectively, and the excess rates of Maximum Residue Limits (MRLs) showed a declining tendency as 4.6% in 2007, 2.8% in 2008 and 2.1% in 2009, respectively. The pesticides exceeding MRLs were 43 ingredients in 2007, 30 ingredients in 2008 and 36 ingredients in 2009, respectively. The frequencies of pesticides exceeding MRLs were 71 of azoxystrobin in 2007, 29 of procymidone in 2008, 24 of endosulfan in 2009, respectively. The excess rate of mustard green for MRLs in comparison with sample numbers was the highest among vegetables analyzed more than 10 cases each year. As a result of comparing annually pesticide residues about pesticide ingredients showed high frequency rates for pesticide detection, there was a statistical significance for the detection quantities of diazinon, endosulfan, paclobutrazol and procymidone.

• Korean Journal of Environmental Agriculture
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• v.25 no.2
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• pp.180-189
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• 2006

This survey was done to investigate the pesticide residues on agricultural products on the markets in Incheon area from 2003 to 2005. A total of 10,431 samples was analyzed the residues by GC. The violation rates of the samples over maximum residue limits (MRLs) of pesticide residues established by Korean Food and Drug Administration (KFDA) in the survey of 2003, 2004 and 2005 were 1.3%, 0.9%, and 1.2%, respectively. The rate from the samples of 2005 surveyed in general wholesale markets was 3.1%, whereas that from agricultural wholesale market was 0.93%. Of the total violated samples, more than 70% of the rates were recorded from the samples of Gyeonggi-do and Incheon area in 2003 and 2004. However, the rates from Gyeonggi-do and Incheon in 2005 were remarkably reduced to 25.6% and 23.3%, respectively. Most commonly encountered agricultural commodity over MRLs was crown daisy. Positively detected pesticides were 12, 17 and 32 in the survey of 2003, 2004 and 2005, respectively. The pesticides detected yearly over MRLs during three years were chlorothalonil, chlorpyrifos, diazinon, endosulfan, procymidone. Decreasing tendency in detected and violated rates of the residues was observed in chlorpyrifos and diazinon, while increasing tendency in detected rates was recorded in chlorothalonil, endosulfan, procymidone.

• Proceedings of the Korean Society of Food Hygiene and Safety Conference
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• 2001.10a
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• pp.120-122
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• 2001

This study was carried out to monitor suspected endocrine disrupting pesticides and industrial organic chemicals among circulated agricultural products in the north area of Seoul in 2001. Procymidone, vinclozolin, endosulfan, chlorothalonil, chloropyrifos and pendimetaline (pesticides) and butylated hydroxytoluene(industrial organic chemicals) were certified by GC-MS. Detected 6 pesticides were remained mostly in the green vegetables, spices and wild plants with $3\%$ detected. Butylated hydroxytoluene(industrial organic chemicals) used for green house cover stuffs was contained mostly in the green vegetables, spices and wild plants not in the fruits and cereals with $43\%$ detected. In the same agricultural products containing butylated hydroxy toluene showed same detection tendency with remaining endocrine disrupting pesticides.