• Title/Summary/Keyword: Problem of synthesis

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A Study on DMT Synthesis Using Crude TPA Sludge Generated from PET Alkaline Waste Water as Raw Materials (PET 감량폐약으로부터 발생되는 crude TPA sludge를 원료로 한 DMT 합성에 관한 연구)

  • Cho, Hwan;Kim, Jong Bo;Jeong, Hee Cheon;Jeon, Byung Dae
    • Textile Coloration and Finishing
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    • v.7 no.2
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    • pp.9-16
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    • 1995
  • When alkaline waste water of PET fabric is treated with sulfuric acid, undegradable material, crude TPA sludge is generated, so that treatment has a serious problem. The result of DMT synthesis using crude TPA sludge generated from PET alkaline waste water were as follows: 1. When crude TPA generated from alkaline waste water is reactioned with methanol under catalyst of sulfuric acid, pure DMT can be obtained. 2. In DMT synthesis from crude TPA, addition of copper sulfate can increase yield, and increasing the amount of sulfuric acid can shorten reaction time.

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Performance Comparison and Duration Model Improvement of Speaker Adaptation Methods in HMM-based Korean Speech Synthesis (HMM 기반 한국어 음성합성에서의 화자적응 방식 성능비교 및 지속시간 모델 개선)

  • Lee, Hea-Min;Kim, Hyung-Soon
    • Phonetics and Speech Sciences
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    • v.4 no.3
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    • pp.111-117
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    • 2012
  • In this paper, we compare the performance of several speaker adaptation methods for a HMM-based Korean speech synthesis system with small amounts of adaptation data. According to objective and subjective evaluations, a hybrid method of constrained structural maximum a posteriori linear regression (CSMAPLR) and maximum a posteriori (MAP) adaptation shows better performance than other methods, when only five minutes of adaptation data are available for the target speaker. During the objective evaluation, we find that the duration models are insufficiently adapted to the target speaker as the spectral envelope and pitch models. To alleviate the problem, we propose the duration rectification method and the duration interpolation method. Both the objective and subjective evaluations reveal that the incorporation of the proposed two methods into the conventional speaker adaptation method is effective in improving the performance of the duration model adaptation.

Analysis of a Flexible Multi-body System with Over-constraints (여유구속을 갖는 유연체 기계시스템의 동역학 해석)

  • Seo, Jong-Hwi;Park, Tae-Won;Chae, Jang-Soo;Seo, Hyun-Seok
    • Proceedings of the KSME Conference
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    • 2003.04a
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    • pp.874-880
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    • 2003
  • Many mechanical systems are over-constrained if only rigid bodies are used to model the system. One example of such system is a satellite system with solar panels. To avoid this over-constrained problem, solar panels can be modeled as flexible bodies. The CMS(Component Mode Synthesis) method is widely used to analyze the flexible multi-body system because it can considerably approximate the deformation of the flexible bodies using small number of well-selected mode. However, it is very difficult to decide the boundary condition and the selection of modes. In this paper, the methods for mode synthesis and setting the boundary condition are presented to analyze the flexible multi-body system with over-constraints. Finally, the reliability of proposed method is verified by solar panel's deployment test.

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A State Space Modeling and Evolutionary Programming Approach to Automatic Synthesis of Chemical Processes

  • Choi, Soo-Hyoung;Lee, Bom-Sock;Chung, Chang-Bock
    • 제어로봇시스템학회:학술대회논문집
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    • 2004.08a
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    • pp.1870-1873
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    • 2004
  • The objective of this study is to investigate the possibility of chemical process synthesis purely based on mathematical programming when given an objective, feed conditions, product specifications, and model equations for available process units. A method based on a state space approach is proposed, and applied to an example problem with a reactor, a heat exchanger, and a separator. The results indicate that a computer can automatically synthesize an optimal process without any heuristics or expertise in process design provided that global optimization techniques are improved to be suitable for large problems.

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Automatic Synthesis of Chemical Processes by a State Space Approach (상태공간 접근법에 의한 화학공정의 자동합성)

  • 최수형
    • Journal of Institute of Control, Robotics and Systems
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    • v.9 no.10
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    • pp.832-835
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    • 2003
  • The objective of this study is to investigate the possibility of chemical process synthesis purely based on mathematical programming when given an objective, feed conditions, product specifications, and model equations for available process units. A method based on a state space approach is proposed, and applied to an example problem with a reactor, a heat exchanger, and a separator. The results indicate that a computer can automatically synthesize an optimal process without any heuristics or expertise in process design provided that global optimization techniques are improved to be suitable for large problems.

Synthesis and Photovoltaic Properties of Organo Dendritic Photosensitizers based on Carbazole for Dye-sensitized Solar Cells (신규 Carbazole 유도체의 합성과 이를 적용한 DSSC의 광전 변환 특성)

  • Jung, Daeyoung;Kim, Myeongseok;Yang, Hyunsik;Kim, Jaehong
    • 한국신재생에너지학회:학술대회논문집
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    • 2011.05a
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    • pp.119.1-119.1
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    • 2011
  • Since Gratzel et al. reported the first efficient dye-sensitized solar cells(DSSCs) in 1991, they have attracted much attention due to their relatively high power conversion efficiency and potentially low cost production. To date, high performance and good stability of DSSC based on Ru-dyes as a photosensitizer had been widely addressed in the literatures. However, the Ru-dyes are facing the problem of manufacturing costs and environmental issues. In order to obtain even cheaper photosensitizers for DSSC, the metal-free organic photosensitizers are strongly desired. The metal-free organic dyes offer superior molar extinction coefficients, low cost, and diverse molecular structures as compared to the conventional Ru-dyes, In this work, we have studied on the synthesis and characterization of the organo dendritic dyes containing different number of electron acceptor moieties in a molecule.

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Design of GBSB Neural Networks Using LMI (LMI를 이용한 GBSB 신경망 설계)

  • Cho, Hyuk;Park, Joo-Young;Park, Dai-Hee
    • Proceedings of the Korean Institute of Intelligent Systems Conference
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    • 1997.10a
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    • pp.409-412
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    • 1997
  • In this paper, we propose a novel synthesis method of GBSB(Generalized BSB)-based neural autoassociative memories in which we analyze qualitative properties of GBSB model, recast a design problem of an associative memory to LMIP(Linear Matrix Inequality Problem), and optimize the LMIP using LMI techniques. The obtained memory satisfies many of the required properties of associative memories and has some peculiar properties. Comparing experimental results with those of others, we show its correctness and effectiveness.

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Transient testing from LV / SC coupled analysis by new shock synthesis

  • Girard, Alain;Cavro, Etienne;Dupuis, Paul-Eric
    • Advances in aircraft and spacecraft science
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    • v.5 no.2
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    • pp.177-186
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    • 2018
  • This paper deals with the idea to replace the usual high-level sine sweep test on shaker at system level, very severe, by a low level one completed by a transient test in the same configuration, in order to be more representative of the real environment, thus limiting over testing and improving the payload comfort. The problem of the transient test specification is first discussed. The proposed solution is to derive from LV/SC coupled analyses a shock response spectrum corresponding to two damping ratios. Then, the question of adequate shock synthesis is tackled. A new method with a given spectrum is considered for better potential and accuracy than the usual wavelets. A campaign on the Intespace bi-shaker devoted to system level showed its capability to perform the resulting test with one spectrum. First investigations to extend this approach to two spectra are in progress.

Partitioned structural eigenvalue analysis (부분 구조물 합성으로 이루어진 고유치 문제 해석)

  • Jung, Eui-Il;Na, Hye-Joong;No, Suk-Hong;Chun, Du-Hwan
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2005.05a
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    • pp.117-119
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    • 2005
  • For large structural eigen-analysis, the whole structure is divided into some partitioned structures and through synthesis of partitioned structural model the eigen-data of structure can be obtained. In that case, eigenvalue problem consists of semidefinite mass matrix form because of displacement constraint condition. In this work the eigenvalue problem is considered by means of several method, determinant search and null space reduction method.

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Enhancement of Glucose-Fueled Cell-Free Protein Synthesis by the Addition of Lipids (지질의 첨가를 통한 포도당 기반 무세포 단백질 합성 시스템의 단백질 발현 효율 향상)

  • Lee, So Jeong;Kim, Ho-Cheol;Kim, Dong-Myung
    • Korean Chemical Engineering Research
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    • v.57 no.1
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    • pp.85-89
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    • 2019
  • Cell-free protein synthesis utilizes the translational machinery in a cell extract. Unlike the conventional cell-based expression methods, not being affected by the conditions for cell growth, cell-free protein synthesis enables flexible manipulation of individual factors affecting the efficiency protein biosynthesis. However, the high cost and low stability of the energy sources to regenerate ATP have limited the use of cell-free synthesis for large-scale production of recombinant proteins. One of the approaches to address this problem is to use glucose as an alternative energy source to regenerate ATP through the glucose-metabolizing pathways in a cell extract. In this study, in an attempt to improve the efficiency of ATP regeneration by reinforcing oxidative phosphorylation process, we supplemented with cellular lipids to a glucose-fueled reaction mixture for cell-free protein synthesis. As a result of the lipid supplementation, the productivity of chloramphenicol acetyltransferase in a cell-free synthesis system using glucose increased more than 6 fold compared to when the lipid was not supplemented.