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Factors of Trichloroethylene Degradation by Methanotrophic Consortium Biofilm Reactor(MCBR) (혼합 메탄자화균 생물막 반응기에 의한 Trichloroethylene 분해의 영향 인자)

  • Lee, Moo-Yeal;Cho, Hyun-Jeong;Yang, Ji-Won
    • Journal of Korean Society of Environmental Engineers
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    • v.22 no.6
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    • pp.991-1000
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    • 2000
  • Methanotrophic consortium utilizing methane as the primary carbon source and secreting soluble methane monooxygenase (sMMO) was immobilized on celite R-635 to continuously treat a wastewater containing trichloroethylene (TCE). With influent 2 ppm of TCE. 80.4 and 84.5% of TCE was degraded in 6 and 20 hour of hydraulic retention time (HRT). respectively. and the removal efficiency of TCE was increased with an increase in HRT in methanotrophic consortium biofilm reactor (MCBR). With influent 5 ppm of TCE and 10 hour of HRT. average efficiency of TCE removal was decreased in initial stage. but gradually increased to 81%. TCE was degraded to 88.5 and 96.5% with 10 and 15 hour of HRT. respectively. when methane was supplied alternately with continuous oxygen supply at influent 5 ppm of TCE. The efficiency of TCE degradation was decreased probably because oxidation reaction of methane was proceeded slowly on MMO. when high concentration of methane was supplied with depletion of oxygen. As results of the pilot-scale study. biodegradation of TCE by MCBR system might be feasible at full-scale operation.

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A Study on Greenhouse Gas Inventories for Regional Governments (A Case Study of Jeonbuk Province) (지자체 온실가스 인벤토리 구축연구 - 전라북도 사례)

  • Jang, Nam-Jung
    • Journal of Korean Society of Environmental Engineers
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    • v.31 no.7
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    • pp.565-572
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    • 2009
  • Greenhouse gas(GHG) inventories and basic strategies for Jeonbuk regional government were established to reduce greenhouse gas emissions. The method to construct GHG inventories of Jeonbuk followed the 'Revised IPCC 1996 Guidelines'which was used for the 'Third National Communication of the Republic of Korea under UNFCCC'. Korean government could use primary energy consumption for the energy industries section in the national GHG inventories. However, regional governments should use secondary energy consumption (included electricity consumption) for the energy industries section for their GHG inventories because they could not control the emission of energy transformation section. In the result of Jeonbuk GHG inventories in 2006, carbon dioxide($CO_2$) emissions from fuel combustion covered 87.1% of total emissions. Methane($CH_4$), carbon dioxide($CO_2$) from other sections, nitrous oxide($N_2O$) and F-gas(HFCs, PFCs, $SF_6$) accounted for 8.1, 2.2, 1.6 and 1.0% of total emissions, respectively. The sectional emission decreased in the order of the energy(88.0%), agriculture(7.6%), waste(2.3%) and industrial processes(2.1%) section. The energy industries section that contained electricity consumption was the most dominant emission source in the energy section. F-gas consumption, rice cultivation and waste incineration were main emission sources in the industrial processes, agriculture and waste section, respectively. In this study, basic directions of each section were established by the results of Jeonbuk GHG inventories in 2006.

Chemical weathering in King George Island, Antarctica

  • Jeong, Gi-Young
    • Proceedings of the Mineralogical Society of Korea Conference
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    • 2003.05a
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    • pp.66-66
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    • 2003
  • King George island, Antarctica, is mostly covered by ice sheet and glaciers, but the land area is focally exposed for several thousand years after deglaciation. For a mineralogical study of chemical weathering in the polar environment, glacial debris was sampled at the well-developed patterned ground which was formed by long periglaclal process. As fresh equivalents, recently exposed tills were sampled at the base of ice cliff of outlet glaciers and at the melting margin of ice cap together with fresh bedrock samples. Fresh tills are mostly composed of quartz, plagioclase, chlorite, and illite, but those derived from hydrothermal alteration zone contain smectite and illite-smectite. In bedrocks, chlorite was the major clay minerals in most samples with minor illite near hydrothermal alteration zone and interstratified chlorite-smectite in some samples. Smectite closely associated with eolian volcanic glass was assigned to alteration in their source region. Blocks with rough surface due to chemical disintegration showed weathering rinds of several millimeter thick. Comparision between inner fresh and outer altered zones did not show notable change in clay mineralogy except dissolution of calcite and some plagioclase. Most significant weathering was observed in the biotite flakes, eolian volcanic glass, sulfides, and carbonates in the debris. Biotite flakes derived from granodiorite were altered to hydrobiotite and vermiculite of yellow brown color. Minor epitactic kaolinite and gibbsite were formed in the cleaved flakes of weathered biotite. Pyrite was replaced by iron oxides. Calcite was congruently dissolved. Volcanic glass of basaltic andesite composition showed alteration rim of several micrometer thick or completely dissolved leaving mesh of plagioclase laths. In the alteration rim, Si, Na, Mg, and Ca were depleted, whereas Al, Ti, and Fe were relatively enriched. Mineralization of lichen and moss debris is of much interest. They are rich of A3 and Si roughly in the ratio of 2:1 to 3:1 typical of allophane. In some case, Fe and Ti are enriched in addition to Al and Si. Transmission electron microscopy of the samples rich of volcanic glass showed abundant amorphous aluminosilicates, which are interpreted as allophane. Chemical weathering in the King George Island is dominated by the leaching of primary phyllosilicates, carbonates, eolian volcanic glass, and minor sulfides. Authigenesls of clay minerals is less active. Absence of a positive evidence of significant authigenic smectite formation suggests that its contribution to the clay mineralogy of marine sediments are doubtful even near the maritime Antarctica undergoing a more rapid and intenser chemical weathering under more humid and milder climate.

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Daily Variation of Particulate Organic Carbon in Wonmun Bay on the South Coast of Korea in Late Summer (늦여름 원문만 굴양식장 입자유기탄소의 일변동)

  • KANG Chang-Keun;LEE Pil-Yong;KIM Pyoung-Joong;CHOI Hee-Gu
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.26 no.3
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    • pp.279-287
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    • 1993
  • Daily variation of particulate organic carbon(POC) and some factors controlling its level were examined for a semi-enclosed bay(Wonmun Bay, south coast of Korea), in which a lot of suspended oyster culture farms existed, in September, 1992. Observations were made at hourly interval. In spite of the relatively short survey period, strong short-term variation of POC concentration could be observed. Concentrations of POC were the range of $58{\sim}582{\mu}g/l(average 272{\mu}g/l)$ and their variation pattern was similar to those of chlorophyll a with the range of $0.90{\sim}7.25{\mu}g/l(average 3.35{\mu}g/l)$. The low C/N ratios also suggested that marine microalgae was a major component of POC for Wonmun Bay. Primary production, average $1.97\;gC/m^2/day$, was the main source of POC beacuse the supply of POC via freshwater input and exchange with the outer part of the bay was little. Oyster population also excreted a small amount of POC. About $40\%$ of produced POC was decomposed heterotrophically. Another important cause for the fluctuation of observed POC was tidal cycle. Considerable POC, which amounted $37\%$ of produced POC, was lost from the bay due to flushing by tidal cycle. It was also calculated that about $16\%$ was transported onto the sediment. It seemed that a part of POC was consumed by oyster and other heterotrophs.

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New discoveries, skarn zonation, and skarn textures at the Geodo Mine in the Taebaeksan Basin, South Korea

  • Kim, Eui-Jun;Yang, Seok-Jun;Shin, Seungwook;Nam, Hyeong-Tae;Shin, Dongbok;Im, Heon-Kyoung;Oh, Il-Hwan;No, Sang-Gun;Cho, Sung-Jun;Park, Maeng-Eon
    • Geosciences Journal
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    • v.22 no.6
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    • pp.881-889
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    • 2018
  • The Geodo skarn deposit is located in the Taebaeksan Basin, central eastern Korean Peninsula. The geology of the deposit consists of Cambrian to Ordovician calcareous sedimentary rocks and the Cretaceous Eopyeong granitoids. The skarns at Geodo occur around the Eopyeong granitoids, which consist, from early to late, of magnetite-bearing equigranular quartz monzodiorite, granodiorite, and dykes. These dykes emanated randomly from equigranular granodiorite and some of dykes spatially accompany skarns. Skarn Fe mineralization, referred as Prospect I and II in this study, is newly discovered beyond previously known skarns adjacent to the quartz monzodiorite. These discoveries show a vertical and lateral variation of skarn facies, grading from massive reddish-brown garnet-quartz in a lower and proximal zone to banded in an upper and distal zone, reflecting changes in lithofacies of the host rocks. Skarn veins in distal locations are parallel to sedimentary laminae, suggesting that lithologic control is important although proximal skarn has totally obliterated primary structures, due to intense retrograde alteration. Skarns at Geodo are systematically zoned relative to the causative dykes. Skarn zonation comprises proximal garnet, distal pyroxene, and vesuvianite (only in Prospect I) at the contact between skarn and marble. Retrograde alteration is intensely developed adjacent to the contact with dykes and occurs as modification of the pre-existing assemblages and progressive destruction such as brecciation of the prograde assemblages. The retrograde alteration assemblages consist predominantly of epidote, K-feldspar, amphibole, chlorite, and calcite. Most of the magnetite (the main ore mineral), replaces calc-silicate minerals such as garnet in the lower proximal exoskarn, whereas it occurs massive in distal pyroxene and amphibole in the upper and distal exoskarn. The emanation of dykes from the equigranular granodiorite has provided channelways for ascent of skarn-forming fluids from a deep source, whereas the style and nature of skarns suggest that originally structurally-controlled skarn-forming fluids may migrate long distances laterally to produce skarn in calcareous sedimentary rocks.

Current Status of Hyperspectral Remote Sensing: Principle, Data Processing Techniques, and Applications (초분광 원격탐사의 특성, 처리기법 및 활용 현용)

  • Kim Sun-Hwa;Ma Jung-Rim;Kook Min-Jung;Lee Kyu-Sung
    • Korean Journal of Remote Sensing
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    • v.21 no.4
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    • pp.341-369
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    • 2005
  • Hyperspectral images have emerged as a new and promising remote sensing data that can overcome the limitations of existing optical image data. This study was designed to provide a comprehensive review on definition, data processing methods, and applications of hyperspectral data. Various types of airborne, spaceborne, and field hyperspectral image sensors were surveyed from the available literatures and internet search. To understand the current status of hyperspectral remote sensing technology and research development, we collected several hundreds research papers from international journals (IEEE Transactions on Geoscience and Remote Sensing, International Journal of Remote Sensing, Remote Sensing of Environment and AVIRIS Workshop Proceedings), and categorized them by sensor types, data processing techniques, and applications. Although several hyperspectral sensors have been developing, AVIRIS has been a primary data source that the most hyperspectral remote sensing researches were relied on. Since hyperspectral data have very large data volume with many spectral bands, several data processing techniques that are particularly oriented to hyperspectral data have been developed. Although atmospheric correction, spectral mixture analysis, and spectral feature extraction are among those processing techniques, they are still in experimental stage and need further refinement until the fully operational adaptation. Geology and mineral exploration were major application in early stage of hyperspectral sensing because of the distinct spectral features of rock and minerals that could be easily observed with hyperspectral data. The applications of hyperspectral sensing have been expanding to vegetation, water resources, and military areas where the multispectral sensing was not very effective to extract necessary information.

Life Cycle Assessment on Process of Wet Tissue Production (물티슈 제조공정의 전과정 평가)

  • Ahn, Joong Woo
    • Clean Technology
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    • v.24 no.4
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    • pp.269-274
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    • 2018
  • In this study, Life Cycle Assessment (LCA) of wet tissue manufacturing process was performed. The wet tissue manufacturing process consists of preparation of wetting agent (chemical liquid), impregnation of nonwoven fabric into wetting agent and primary and secondary packaging. Data and information were collected on the input and output of the actual process from a certain company and the database of the Korea Ministry of Environment and some foreign countries (when Korean unavailable) were employed to connect the upper and the lower process flow. Based on the above and the potential environmental impacts of the wet tissue manufacturing process were calculated. As a result of the characterization, Ozone Layer Depletion (OD) is 3.46.E-06 kg $CFC_{11}$, Acidification (AD) is 5.11.E-01 kg $SO_2$, Abiotic Resource Depletion (ARD) is $3.52.E+00\;1yr^{-1}$, Global Warming (GW) is 1.04.E+02 kg $CO_2$, Eutrophication (EUT) is 2.31.E-02 kg ${PO_4}^{3-}$, Photochemical Oxide Creation (POC) was 2.22.E-02 kg $C_2H_4$, Human Toxicity (HT) was 1.55.E+00 kg 1,4 DCB and Terrestrial Ecotoxicity (ET) was 5.82.E-04 kg 1,4 DCB. In order to reduce the environmental impact of the manufacturing process, it is necessary to improve the overall process as other general cases and change the raw materials including packaging materials with less environmental impact. Conclusively, the energy consumed in the manufacturing process has emerged as a major issue, and this needs to be reconsidered other options such as alternative energy. Therefore, it is recommended that a process system should be redesigned to improve energy efficiency and to change to an energy source with lower environmental impact. Due to the nature of LCA, the final results of this study can be varied to some extent depending on the type of LCI DB employed and may not represent of all wet tissue manufacturing processes in the current industry.

The Power Converter Circuit Characteristics for 3 kW Wireless Power Transmission (3 kW 무선 전력전송을 위한 전력 변환기 회로 특성)

  • Hwang, Lark-Hoon;Na, Seung-kwon;Kim, Jin Sun;Kang, Jin-hee
    • Journal of Advanced Navigation Technology
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    • v.24 no.6
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    • pp.566-572
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    • 2020
  • In a wireless power transmitter, the characteristics and effects of wireless power transmission between two induction coils are investigated, and a power converter circuit and a battery charger/discharger circuit using wireless power transmission technology are proposed. The advantage of wireless power transmitters and wireless chargers is that, instead of the existing plug-in-mounted wired charger (OBC; on-board charger), the user can wirelessly charge the battery without connecting the power source when charging power to the battery. There is. In addition, the advantage of wireless charging can bring about an energy efficiency improvement effect by using the secondary side rectifier circuit and the receiving coil, but the large-capacity long-distance wireless charging method has a limitation on the transmission distance, so many studies are currently being conducted. The purpose of the study is to study the transmitter circuit and receiver circuit of a wireless power transmission device using a primary coil, a secondary coil, and a half bridge series resonance converter, which can transmit power of a non-contact type power transmitter. As a result, a new topology was applied to improve the power transmission distance of the wireless charging system, and through an experiment according to each distance, the maximum efficiency (95.8%) was confirmed at an output of 3 kW at an 8 cm transmission distance.

Analysis of Components to Determine Illegal Premium Gasoline (가짜 고급휘발유 판정을 위한 성분 분석)

  • Lim, Young-Kwan;Kang, Byung-Seok;Lee, Bo-O-Mi;Park, So-Hwi;Park, Jang-Min;Go, Young-Hoon;Kim, Seung-Tae;Kang, Dea-Hyuk
    • Tribology and Lubricants
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    • v.37 no.6
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    • pp.232-239
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    • 2021
  • Petroleum is the most consumed energy source in Korea with a usage rate of 38.7% among the available primary energy sources. The price of liquid petroleum products in Korea includes taxes such as transportation·environment·energy tax. Thus, illegal production and distribution of liquid petroleum is widespread because of its huge price difference from that of the normal product and its tax-free nature. Generally, the illegal petroleum product is produced by mixing liquid petroleum with other similar petroleum alternatives. The two kinds of gasoline, common gasoline and premium gasoline, are being distributed in Korea. The premium gasoline is often adulterated with cheaper common gasoline that lowers the octane number of gasoline. It is possible to distinguish them with their color difference, green and yellow for different grade gasoline. However, when small volume of common gasoline is added to premium gasoline, it is difficult to determine whether premium gasoline contained common grade or not. In this study, we inspect gasoline, which is illegally produced by mixing common gasoline to premium gasoline. When the ratio of mixing common gasoline is increased, premium gasoline shows decreasing absorbance at 600 nm and 650 nm under UV-Vis spectrometer. Moreover, the detected intensity (mV·s) of green dye in high performance liquid chromatography (HPLC) was decreased by common gasoline under 0.99 correlation value. The more the common gasoline is mixed, the more olefin and naphthene are detected by gas chromatography. In addition, trimethyl pentane as octane improver, paraffin and toluene are decreased by common gasoline mixing. The findings of this study suggests that illegal petroleum can be identified by analysis of components and simulated samples.

Water Quality Assessment and Turbidity Prediction Using Multivariate Statistical Techniques: A Case Study of the Cheurfa Dam in Northwestern Algeria

  • ADDOUCHE, Amina;RIGHI, Ali;HAMRI, Mehdi Mohamed;BENGHAREZ, Zohra;ZIZI, Zahia
    • Applied Chemistry for Engineering
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    • v.33 no.6
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    • pp.563-573
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    • 2022
  • This work aimed to develop a new equation for turbidity (Turb) simulation and prediction using statistical methods based on principal component analysis (PCA) and multiple linear regression (MLR). For this purpose, water samples were collected monthly over a five year period from Cheurfa dam, an important reservoir in Northwestern Algeria, and analyzed for 12 parameters, including temperature (T°), pH, electrical conductivity (EC), turbidity (Turb), dissolved oxygen (DO), ammonium (NH4+), nitrate (NO3-), nitrite (NO2-), phosphate (PO43-), total suspended solids (TSS), biochemical oxygen demand (BOD5) and chemical oxygen demand (COD). The results revealed a strong mineralization of the water and low dissolved oxygen (DO) content during the summer period. High levels of TSS and Turb were recorded during rainy periods. In addition, water was charged with phosphate (PO43-) in the whole period of study. The PCA results revealed ten factors, three of which were significant (eigenvalues >1) and explained 75.5% of the total variance. The F1 and F2 factors explained 36.5% and 26.7% of the total variance, respectively and indicated anthropogenic pollution of domestic agricultural and industrial origin. The MLR turbidity simulation model exhibited a high coefficient of determination (R2 = 92.20%), indicating that 92.20% of the data variability can be explained by the model. TSS, DO, EC, NO3-, NO2-, and COD were the most significant contributing parameters (p values << 0.05) in turbidity prediction. The present study can help with decision-making on the management and monitoring of the water quality of the dam, which is the primary source of drinking water in this region.