• 제목/요약/키워드: Pretreatment temperature

검색결과 459건 처리시간 0.023초

고농도 페놀 폐수의 습식산화와 호기성 생물학적 통합처리 (Integrated Wet Oxidation and Aerobic Biological Treatment of the Wastewater Containing High Concentration of Phenol)

  • 최호준;이승호;유용호;윤왕래;서일순
    • KSBB Journal
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    • 제22권4호
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    • pp.244-248
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    • 2007
  • 고농도 페놀폐수 전처리 습식산화공정의 반응온도, 초기 pH 및 균일촉매 ($CuSO_4$) 등이 후처리 호기성 생물학적 공정에 미치는 영향을 조사하였다. 습식산화에서의 높은 반응온도와 산성 초기조건이 후처리 생물학적 산화공정에서 높은 산화속도와 최종 COD 제거율을 유발하였다. 습식산화에서 균일촉매를 사용하면 전처리 습식산화반응은 낮은 반응온도에서도 높은 COD 제거속도를 보였으나, 후처리 생물학적 산화공정에서는 낮은 최종 COD 제거율을 나타내었다.

Flip Chip 접속을 위한 무전해 니켈 범프의 형성 및 특성 연구 (Fabrication and Characteristics of Electroless Ni Bump for Flip Chip Interconnection)

  • 전영두;임영진;백경옥
    • 한국재료학회지
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    • 제9권11호
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    • pp.1095-1101
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    • 1999
  • 무전해 니켈 도금을 이용하여 플립칩 공정에 응용하기 위한 범프와 UBM층을 형성하고 특성을 조사하였다. 도금전 zincate 처리를 해석하고 도금 변수인 온도, pH 등에 따른 도금층의 특성 변화, 공정 후의 열처리 효과들을 관찰하였다. 이를 통해 각 변수들이 도금층의 특성에 미치는 영향과 전자패키지 응용시 요구되는 무전해 니켈 도금 조건을 제시하였다. 도금직후의 니켈은 P가 10wt% 포함되며, $60\mu\Omega$-cm의 비저항, 500HV의 경도의 비정질 결정구조를 갖으며 열처리후 결정질 변태와 동시에 경도가 증가한다. 무전해 범프를 실제 테스트 칩에 형성한 후, ACF 플립칩 접속하여 무전해 니켈 범프의 장점과 미세 전자 패키징응용의 가능성을 확인하였다.

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Cancer Chemopreventive Properties of Processed Ginseng

  • Surh, Young-Joon
    • 고려인삼학회:학술대회논문집
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    • 고려인삼학회 1998년도 Advances in Ginseng Research - Proceedings of the 7th International Symposium on Ginseng -
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    • pp.270-280
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    • 1998
  • Ginseng is one of the most widely used medicinal plants, particularly in East Asian countries. Certain fractions or purified ingredients of ginseng have been shown to exert inhibitory effects on growth of cancer cells in culture or on tumorigenesis in experimental animals. Moreover, a recent epidemiologic study reveals that ginseng intake is associated with a reduced risk for environmentally related cancers such as esophageal, gastric, colorectal, and pulmonary tumors. Heat treatment of Panax ginseng C. A. Meyer at the temperature higher than that applied to the conventional preparation of red ginseng yielded a mixture of saponins with potent antioxidative properties. Thus, the methanol extract of heat-processed ginseng (designated as'NGMe') attenuated lipid peroxidation in rat brain homogenates induced by ferric ion or ferric ion plus ascorbic acid. Furthermore, the extract protected against strand scission in f Xl 74 supercoiled DNA Induced by UV photolysis of H2O2 and was also capable of scavenging superoxide generated in vitro by xanthine/xanthine oxidate or in differentiated human promyelocytic leukemia (HL-60) cells by the tumor promoter,12-0-tetvade- canoylphorbol-13-acetate (TPA). Since tumor promotion is closely linked to oxidative stress, we have determined possible anti-tumor promotional effects of NGMe on two-stage mouse skin tumorigenesis. Topical application of NGMe onto shaven backs of female ICR mice 10 min prior to TPA significantly ameliorated skin papillomagenesi s initiated by 7,12-dimethylbenz (a) anthracene (DMBA).'Likewise, TPA-induced epidermal ornithine decarboxylase activity and elevation of tumor necrosis factor-a were suppressed signifies%fly by NGMe pretreatment. NGMe topically applied onto surface of hamster buccal pouch 10 min before each topical application of DMBA inhibited oral carcinogenesis by 76olo in terms of multiplicity. Taken together, these results suggest that processed Panax ginseng C. A. Meyer has potential cancer chemopreventive activities.

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The a-Si:H/poly-Si Heterojunction Solar Cells

  • Kim, Sang-Su;Kim, do-Young;Lim, Dong-Gun;Junsin Yi;Lee, Jae-Choon;Lim, Koeng-Su
    • Journal of Electrical Engineering and information Science
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    • 제2권5호
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    • pp.65-71
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    • 1997
  • We present heterojunction solar cells with a structure of metal/a-Si:H(n-i-p)/poly-Si(n-p)/metal for the terrestrial applications. This cell consists fo two component cells: a top n-i-p junction a-Si:Hi cell with wide-bandgap 1.8eV and a bottom n-p junction poly-Si cell with narrow-bandgap 1.1eV. The efficiency influencing factors of the solar cell were investigated in terms of simulation an experiment. Three main topics of the investigated study were the bottom cell with n-p junction poly-Si, the top a-Si:H cell with n-i-p junction, and the interface layer effects of heterojunction cell. The efficiency of bottom cell was improved with a pretreatment temperature of 900$^{\circ}C$, surface polishing, emitter thickness of 0.43$\mu\textrm{m}$, top Yb metal, and grid finger shading of 7% coverage. The process optimized cell showed a conversion efficiency about 16%. Top cell was grown by suing a photo-CVD system which gave an ion damage free and good p/i-a-Si:H layer interface. The heterojunction interface effect was examined with three different surface states; a chemical passivation, thermal oxide passivation, and Yb metal. the oxide passivated cell exhibited the higher photocurrent generation and better spectral response.

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Quality and characteristics of ginseng seed oil treated using different extraction methods

  • Lee, Myung-Hee;Kim, Sung-Soo;Cho, Chang-Won;Choi, Sang-Yoon;In, Gyo;Kim, Kyung-Tack
    • Journal of Ginseng Research
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    • 제37권4호
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    • pp.468-474
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    • 2013
  • Ginseng seed oil was prepared using compressed, solvent, and supercritical fluid extraction methods of ginseng seeds, and the extraction yield, color, phenolic compounds, fatty acid contents, and phytosterol contents of the ginseng seed oil were analyzed. Yields were different depending on the roasting pretreatment and extraction method. Among the extraction methods, the yield of ginseng seed oil from supercritical fluid extraction under the conditions of 500 bar and $65^{\circ}C$ was the highest, at 17.48%. Color was not different based on the extraction method, but the b-value increased as the roasting time for compression extraction was increased. The b-values of ginseng seed oil following supercritical fluid extraction were 3.54 to 15.6 and those following compression extraction after roasting treatment at $200^{\circ}C$ for 30 min, were 20.49, which was the highest value. The result of the phenolic compounds composition showed the presence of gentisic acid, vanillic acid, ferulic acid, and cinnamic acid in the ginseng seed oil. No differences were detected in phenolic acid levels in ginseng seed oil extracted by compression extraction or solvent extraction, but vanillic acid tended to decrease as extraction pressure and temperature were increased for seed oil extracted by a supercritical fluid extraction method. The fatty acid composition of ginseng seed oil was not different based on the extraction method, and unsaturated fatty acids were >90% of all fatty acids, among which, oleic acid was the highest at 80%. Phytosterol analysis showed that ${\beta}$-sitosterol and stigmasterol were detected. The phytosterol content of ginseng seed oil following supercritical fluid extraction was 100.4 to 135.5 mg/100 g, and the phytosterol content following compression extraction and solvent extraction was 71.8 to 80.9 mg/100 g.

Zymomonas mobilis를 이용한 목질계 에탄올 생산을 위한 균주 개선에 관한 연구 동향 (Recent Progress in Strain Development of Zymomonas mobilis for Lignocellulosic Ethanol Production)

  • 전용재
    • 생명과학회지
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    • 제29권1호
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    • pp.135-145
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    • 2019
  • 자이모모나스 모빌리스(Zymomonas mobilis)는 수십 년 동안 생화학적 발효 기술을 통한 수송용 에탄올을 생산하기에 적합한 산업용 미생물로 각광을 받아왔다. 최근 이 균주의 포스트 게놈 시대 도래 및 미국 듀폰사(DuPont, USA)의 세계 최대 산업용 목질계 에탄올 생산 시설 완료 등은, 이 미생물을 이용한 산업적 에탄올 생산 공정 가시화를 위한 다양한 연구들을 파생시키고 있다. 특히, 산업용 셀룰로오스 에탄올 발효공정에 이용되는 미생물은 다양한 독성 발효 저해물질 및 물리적 스트레스에 보다 쉽게 노출 될 수 있다. 따라서 본 논문은 이 미생물이 보유한 최신 생리학적 이해와 관련 된 정보와 다양한 환경적 스트레스에 견딜 수 있는 산업적 강건성 및 산업용 균주 개발 방법에 대한 사례 및 이 균주를 이용한 가격 경쟁적인 목질계 에탄올 생산 공정 개발에 필요한 균주 개발에 대한 미래 지향적 연구 방향에 대하여 기술하였다.

Soda Pulping of Torch Ginger Stem: Promising Source of Nonwood-Based Cellulose

  • ZENDRATO, Herman Marius;DEVI, Yunita Shinta;MASRUCHIN, Nanang;WISTARA, Nyoman J.
    • Journal of the Korean Wood Science and Technology
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    • 제49권4호
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    • pp.287-298
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    • 2021
  • Torch ginger (Etlingera elatior Jack) is a potential source of lignocellulose material for various derivative products. This study aims to determine the chemical components, ratio of syringyl to guaiacyl units (S/G) in lignin, and crystallinity of the biomass of torch ginger. The effects of soda pulping on the chemical characteristics of torch ginger pulp were also studied. Pulping of the chips was conducted with active alkali of 15%, 20%, and 25% and a Liquor-to-Wood (L/W) ratio of 4:1, 5:1, and 6:1. The impregnation and pulping times at maximum temperature (170℃) were 120 and 90 min, respectively. To assess the effect of treatments on the properties of pulping, a two-factorial experimental design was applied. Results showed that the content of α-cellulose and hemicellulose in the torch ginger was 48.48% and 31.50%, respectively, with an S/G ratio of 0.70 in lignin. Soda pulping changed the crystalline structure of the biomass from triclinic to monoclinic. Active alkali, L/W ratio, and interactions considerably influenced the observed responses. The degree of delignification increased with an increase in the loading of active alkali, which lead to a decrease in the kappa number of the pulp. An active alkali content of 25% and an L/W ratio of 6:1 resulted in the highest delignification selectivity with a kappa number of 2.78 and a yield of 24%. Given its cellulose content and ease of pulping, torch ginger can be a potential raw material for derivative products that require delignification as pretreatment. However, the increase in cellulose crystallinity should be considered when converting torch ginger to bioethanol.

폐기물 자원회수 향상을 위한 친환경 폐페인트 처리프로세스 개발 (Development of a Sustainable Waste Paint Treatment Process for Waste Resource Recovery Improvement)

  • 문종욱;황석호;김대영
    • 한국건설관리학회논문집
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    • 제23권1호
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    • pp.73-82
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    • 2022
  • 국내 지정폐기물 중 하나인 폐페인트는 현재 전량 소각 방법으로 처리되고 있으며, 다른 폐기물에 비해 재활용도 거의 이루어지지 않고 있어, 자원이 부족한 우리나라에 엄청난 자원의 손실뿐 아니라 소각으로 인한 에너지원의 낭비, 그리고 소각 시 발생하는 대기오염 등의 환경문제도 유발하고 있다. 이를 위해 본 연구에서는 기존의 폐페인트의 소각처리법을 탈피하여, 온도 조절에 의한 증발·응축, 열분해를 통해 전처리 조작하는 방법으로 전환하고, 이때 발생하는 잔재물을 활용하여 일정한 형상(과립형 및 분말형)으로 성형한 후 이를 대체에너지 열원으로 재활용할 수 있는 친환경(지속가능한) 폐페인트 처리프로세스를 제시하고자 한다. 폐페인트를 처리하는 새로운 방법과 재활용하는 기술개발이 이루어지고 보급된다면 환경적·경제적 면에서 그 효과가 클 것으로 기대한다.

Optimized pretreatment conditions for the environmental DNA (eDNA) analysis of Apostichopus japonicus

  • Kang, Yu-An;Lee, Soo Rin;Kim, Eun-Bi;Park, Sang Un;Lim, Sang Min;Andriyono, Sapto;Kim, Hyun-Woo
    • Fisheries and Aquatic Sciences
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    • 제25권5호
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    • pp.264-275
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    • 2022
  • A non-destructive environmental DNA protocol for the genetic analysis of sea cucumber (Apostichopus japonicus) resources DNA was established. Among the several commercial DNA extraction kits, the DNeasy® Plant Mini Kit was selected as the best choice to obtain the high-quality genomic DNAs from the mucous sea cucumber. As the temperature and incubation time increased, the amount of extracted environmental DNA was also large, but it was judged that the increased amount did not affect as much as 2-3 times. Therefore, these conditions were not considered to be the main factors to consider in actual environmental DNA extraction. However, the amount of seawater relative to the size of the sample was judged as a major consideration, and a sufficient amount of environmental DNA for analysis was secured when stored within 1 min while stirring the volume of seawater corresponding to the total sea cucumber weight (g). In securing the environmental DNA of sea cucumbers, the mortality rate of sea cucumbers in all experiments was 0, and it was judged that the effects of sea cucumbers were not significant through this treatment. Through the results of this study, sea cucumber DNA research, which has been conducted in a destructive method, can be conducted non-destructively through environmental DNA analysis. Through this study, we have secured a standard protocol that can successfully extract the sea cucumber DNA through environmental DNA. It is not only excellent in terms of time and cost of traditional DNA analysis method currently used, but it is completely non-destructive in the ecosystem of the survey area. It is believed that the system can be transformed in a way that does not affect it. However, it is thought that various standard protocols should be established considering the characteristics of each type.

인공관절 라이너용 가교된 초고분자량폴리에틸렌(UHMWPE)의 열처리 조건에 따른 기계적 특성 변화 (Effect of Heat Treatment on Mechanical Properties of Cross-Linked Ultra-High Molecular Weight Polyethylene Used for Artificial Joint Liner)

  • 김현묵;김동훈;구자욱;최낙삼;김성곤
    • Composites Research
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    • 제22권2호
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    • pp.1-6
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    • 2009
  • 감마선 조사된 초고분자량폴리에틸렌(UHMWPE)을 다양한 온도조건으로 열처리하여 기계적 물성변화를 구하였다. 열처리 조건은 어닐링(annealing)과 재용융(remelting) 온도범위를 선정하여 열처리하였다. $130^{\circ}C$ 이하의 어닐링 처리에 의해 강도와 파단시 연신율, 경도의 변화는 별로 없었지만, $140^{\circ}C$ 이상의 재용융처리에서는 기계적 물성의 급격한 저하가 발생하였다. FTIR해석 결과, 감마선 전처리에 따라 형성된 프리래디컬이 산화되었음을 알았다. 이와 같은 기계적 성질의 변화거동으로 나타나는 정량적인 데이터는 다양한 인공관절 부품의 설계와 해석에 필요한 기초적인 자료로 이용될 수 있다.