• Title/Summary/Keyword: Pressure-temperature diagram

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Pressure-Temperature Phase Diagram of $(TMTSF)_2BF_4$ ($(TMTSF)_2BF_4$의 압력-온도 상태도 연구)

  • Jo, Y.J.
    • Progress in Superconductivity
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    • v.14 no.1
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    • pp.24-29
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    • 2012
  • $(TMTSF)_2BF_4$ containing non-centrosymmetric anions is well known to exhibit a metal insulator transition around 37 K by ordering of the anions with a $q_2$=(1/2, 1/2, 1/2) wave vector. We established pressure-temperature phase diagram of the $(TMTSF)_2BF_4$ compound and showed that it can belong to the general phase diagram of the $(TMTSF)_2X$ family. Application of hydrostatic pressure decreases the anion ordering transition temperature and the superconducting state is finally stabilized below 3.77 K under 7.7 kbar. Magnetoresistance measurement on the $(TMTSF)_2BF_4$ under 7.8 kbar is performed but neither the field-induced spin-density-wave state nor the rapid oscillation is observed up to 9 T.

Estimation of the Lubricating Oil Rheology at High Pressure Based on Phase Diagram

  • Rahman, Md.Z.;Ohno, N.
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 2002.10b
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    • pp.85-86
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    • 2002
  • For rheology investigation of lubricating oils, first phase diagrams were made from determined free volume based on density measurements and the temperature-pressure relation was estimated using the expansion coefficient of free volume and the temperature-pressure relation of the viscoelastic transition point. Next, the authors proposed the density-pressure-temperature relation and the viscosity-pressure-temperature relation of the tested oils based on the free volume and the phase diagrams. Moreover, it was shown that the Ehrenfest equation or the gradient of the phase diagram is closely related to the expansion coefficient of free volume.

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Program Development for Drawing of 26 Properties and System Analysis on T-s Diagram of Water or Vapor (물의 T-s 선도 상에서 26 종류의 물성치 작도 및 시스템 해석 프로그램 개발)

  • Kim, Deok-Jin
    • Proceedings of the SAREK Conference
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    • 2008.11a
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    • pp.157-164
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    • 2008
  • The temperature-entropy diagram of water or vapor displays graphically the thermophysical properties, so it is very conveniently used in various thermal systems. On general T-s chart of water, there are temperature, pressure, quality, specific volume, specific enthalpy, specific entropy. However, various state and process values besides above properties can be plotted on T-s diagram. In this study, we developed the software drawing twenty six kinds of properties, that is temperature, pressure, quality, specific volume, specific internal energy, specific enthalpy, specific entropy, specific exergy, exergy ratio, density, isobaric specific heat, isochoric specific heat, ratio of specific heat, coefficient of viscosity, kinematic coefficient of viscosity, thermal conductivity, prandtl number, ion product, static dielectric constant, isentropic exponent, velocity of sound, joule-thomson coefficient, pressure coefficient, volumetric coefficient of expansion, isentropic compressibility, and isothermal compressibility. Also, this software can analyze and print the system values of mass flow rate, volume flow rate, internal energy flow rate, enthalpy flow rate, entropy flow rate, exergy flow rate, heat flow rate, power output, power efficiency, and reversible work. Additionally, this software support the functions such as MS-Power Point.

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Pressure-Temperature Diagram of Critical Condition for Disproportionation of Nd-Fe-B Alloy in Hydrogen

  • Kwon, H.W.;Kim, D.H.;Yu, J.H.
    • Journal of Magnetics
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    • v.15 no.4
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    • pp.155-158
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    • 2010
  • The HDDR (hydrogenation, disproportionation, desorption, and recombination) process can be used as an effective way of converting a no coercivity Nd-Fe-B ingot material, with a coarse $Nd_2Fe_{14}B$ grain structure, to a highly coercive one with a fine grain structure. Careful control of the HDDR process can lead to an anisotropic powder with good $Nd_2Fe_{14}B$ grain texture; the most critical step for inducing texture is disproportionation. The critical conditions (hydrogen pressure and temperature) for the disproportionation reaction of fully hydrogenated $Nd_{12.5}Fe_{81.1-(x+y)}B_{6.4}Ga_xNb_y$ (x = 0 or 0.3, y = 0 or 0.2) alloys, in different atmospheres of pure hydrogen and a mixed gas of hydrogen and argon, was investigated with TPA (thermopiezic analyser). From this, the hydrogen pressure-temperature diagram showing the critical conditions was established. The critical disproportionation temperature of the fully hydrogenated $Nd_{12.5}Fe_{81.1-(x+y)}B_{6.4}Ga_xNb_y$ alloys was slightly increased as the hydrogen pressure decreased in both pure hydrogen and mixed gas. The critical disproportionation temperature of the hydrogenated alloys was higher in the mixed gas than in pure hydrogen. Addition of Ga and Nb increased the critical disproportionation temperature of the fully hydrogenated Nd-Fe-B alloys.

Spent Fuel Voloxidation Process Analysis (사용후핵연료 Voloxidation 공정 분석)

  • Kang, Jo Hong;Park, Byung Heung
    • Journal of Institute of Convergence Technology
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    • v.4 no.2
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    • pp.47-50
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    • 2014
  • Voloxidation is a process for converting $UO_2$ into $U_3O_8$ while removing some volatile products in spent fuels (SF). Various oxidative gas conditions including air and mixture of Ar and $O_2$ could be adopted for the process. The gas flows into a reactor under high temperature ($>500^{\circ}C$) and components of SF are reacted with the gas. SF is composed of various components such as actinides, lanthanides, and alkali metals. Therefore, it is of significance to understand their behavior during the reactions for process development. However, due to the limit of available experiments, phase diagram analysis should be preceded. TPP diagram is constructed with respect to temperature-pressure-pressure. It shows a stable phase depending on partial pressures of gas components as well as temperature. In this work, we investigated TPP diagrams for actinides, lanthanides and other oxides to determine stable oxide forms under different gas conditions. The results would be used to set up a material balance under a pyroprocessing scheme of SF and compare the gas conditions for the optimization of fission products removal.

Power and Efficiency Optimization through Exergy Analysis of Power Plant (발전 플랜트의 엑서지 해석으로부터 발전량 및 발전효율 최적화)

  • Kim, Deok-Jin;Lee, Jae-Byoung;Kang, Su-Hwan
    • Plant Journal
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    • v.9 no.3
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    • pp.43-47
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    • 2013
  • Even if an expert who has majored energy engineering, it is a difficult concept to understand power output optimization and power efficiency optimization. In this study a diagram applying thermodynamic state value as specific exergy and exergy ratio was developed. Although general peoples who did not major energy engineering can be easily understand the concept of power output optimization and power efficiency through the developed diagram. A represented property that can identify the performance of power plant is the main steam temperature and pressure. At the developed diagram the maximum power output line and maximum power efficiency line are shown according to the temperature and pressure of main steam. Therefore we can identify how much a power plant approach to maximum power output and maximum power efficiency.

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A Parametric Analysis of Performance of Gas Turbine Combined, Split Cylinder, Constant Volume, Pressure, Temperature, Mixed Cycle Engine (가스터빈 결합, 분리실린더, 등적.등압.등온 혼합사이클 엔진성능의 변수 분석)

  • Kim Dong-Ho;Bae Jong-Uk
    • Journal of Advanced Marine Engineering and Technology
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    • v.28 no.7
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    • pp.1082-1091
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    • 2004
  • Analyzed Parametrically was an internal combustion engine combined with gas turbine the cycle of which is splitted into compression side cylinder and expansion side one, and heat adding of which is during constant volume pressure, temperature process. The advantages of each measures were analyzed by means of thermal cycle diagram. The thermal efficiency of partial load cutting off firstly isothermal heat adding and secondly isobaric heat adding also was analyzed The authors suggested some potentials about the performance as for thermal efficiency, mean effective pressure and reducing emissions and noise supposed were the operating parameter of the engine set to some values and were some problems solved.

A comparing on the use of Centrifugal Turbine and Tesla Turbine in an application of Organic Rankine Cycle

  • Thawichsri, Kosart;nilnont, Wanich
    • International Journal of Advanced Culture Technology
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    • v.3 no.2
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    • pp.58-66
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    • 2015
  • This paper aims to compare the use of Centrifugal Turbine and Tesla Turbine in an application of Organic Rankine Cycle (ORC) Machine using Isopentane as working fluid expanding. The working fluid has boiling point below boiling water and works in low-temperature sources between $80-120^{\circ}C$ which can be produced from waste heat, solar-thermal energy and geothermal energy etc. The experiment on ORC machine reveals that the suitability of high pressure pump for working fluid has result on the efficiency of work. In addition, Thermodynamics theory on P-h diagram also presented the effect of heat sources' temperature and flow rate on any work. Thus, the study and design on ORC machine has to concern mainly on pressure pump, flow rate and optimized temperature. Result experiment and calculate ORC Machine using centrifugal Turbine efficiency better than Tesla turbine 30% but Tesla Turbine is cheaper and easily structure. Further study on the machine can be developed throughout the county due to its low cost and efficiency.

Coal pyrolysis behaviors at supercritical CO2 conditions

  • Hakduck Kim;Jeongmin Choi;Heechang Lim;Juhun Song
    • Advances in Energy Research
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    • v.8 no.4
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    • pp.265-273
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    • 2022
  • In this study, a product gas yield and carbon conversion were measured during the coal pyrolysis. The pyrolysis process occurred under two different atmospheres such as subcritical (45 bar, 10℃) and supercritical CO2 condition (80 bar, 35℃). Under the same pressure (80 bar), the atmosphere temperature increased from 35℃ to 45℃ to further examine temperature effect on the pyrolysis at supercritical CO2 condition. For all three cases, a power input supplied to heating wire placed below coal bed was controlled to make coal bed temperature constant. The phase change of CO2 atmosphere and subsequent pyrolysis behaviors of coal bed were observed using high-resolution camcorder. The pressure and temperature in the reactor were controlled by a CO2 pump and heater. Then, the coal bed was heated by wire heater to proceed the pyrolysis under supercritical CO2 condition.