• Title/Summary/Keyword: Pressure-Composition

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Effects of Indium and Tin on Interfacial Property of Porcelain Fused to Low Gold Alloys (도재소부용 금합금에서 인듐, 주석 첨가가 금속-도재계면 특성에 미치는 영향)

  • Nam, Sang-Yong;Kwak, Dong-Ju;Chung, Suk-Min
    • Journal of Technologic Dentistry
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    • v.23 no.1
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    • pp.31-43
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    • 2001
  • This study was performed to observe the micro-structure change of surface, behavior of oxide change of element, the component transformation of the alloy and the bonding strength between the porcelain interface in order to investigate effects of indium, tin on interfacial properties of porcelain fused to low gold alloy. Hardness of castings was measured with a micro-Vicker's hardness tester. The compositional change of the surface of heat-treated specimen was analyzed with an EDS and an EPMA. The interfacial shear bonding strength between alloy specimen and fused porcelain was measured with a mechanical testing system(MTS 858.20). The results were as follows: 1) The hardness value of alloy increased as increasing amount of indium addition. 2) The formation of oxidation increased as increasing indium and tin contents after heat treatment. 3) Diffusion of indium and tin elements increased as increasing indium and tin contents in metal-porcelain surface after porcelain fused to metal firing. 4) The most interfacial shear bonding strength was increased as increasing a composition of adding elements, and a heat-treatment time, and an oxygen partial pressure. From the results of this study it was found that the addition of alloying elements such as indium and tin increase hardness of as-cast alloy, produce surface oxide layer of adding elements by heat-treatment which may improve interfacial bonding strength between alloy and porcelain.

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Variation in the Kind of Formed Superconducting Oxide and Microstructure with Heat-Treatment Temperature in Yb-Ba-Cu-Ag Ribbons (Yb-Ba-Cu-Ag 리본의 열처리 온도에 따라 형성된 초전도 산화물의 종류와 미세구조의 변화)

  • 송명엽
    • Journal of the Korean Ceramic Society
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    • v.35 no.1
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    • pp.79-87
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    • 1998
  • Melt spun YbBa2Cu3Agx(x=0, 5, 12, 16 and 53) precursor alloy ribbons were oxidized at 263-330$^{\circ}C$ and treated at 820$^{\circ}C$, 855$^{\circ}C$ and 885$^{\circ}C$ under 1.0 atm oxygen pressure. In the ribbons treated at 820$^{\circ}C$, 855$^{\circ}C$and 885$^{\circ}C$ 1-2-4 phase (YbBa2Cu4O8) and 1-2-3 phase (YbBa2Cu3O{{{{ OMICRON _7-$\delta$ }})were formed respectively. The shape of 1-2-4 phase was distorted or ellipsoid. The 2-4-7 and 1-2-3 phases tooked the shape of bar. All the ribbons showed zero critical current density Jc at 77K in zero magnetic field. By considering the shape and the highest critical temperature (among the three phases) of the 1-2-3 phase we tried to increase the critical current density of the ribbons treated at 885$^{\circ}C$ by press deformation. About tenribbons were stacked and coupled by press deformation and then treated at 885$^{\circ}C$ These 1-2-3 phase did not show any texture in any of the ribbons. However they exhibited weak texture in the multilayered specimens. Among the multilayered specimens YbBa2Cu3Ag16 exhibited a Jc of 180 A/cm2 Among the above ribbons YbBa2Cu3Ag16 ribbon has the optimum composition to produce textured superconducting oxide with improved Jc by press deformation. Onset critical temperatures Ton of the multilayered YbBa2Cu3Agx(x=5, 12, 16 and 53) were measured as 88-90 K.

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Effect of Working Pressure and Substrate Bias on Phase Formation and Microstructure of Cr-Al-N Coatings

  • Choi, Seon-A;Kim, Seong-Won;Lee, Sung-Min;Kim, Hyung-Tae;Oh, Yoon-Suk
    • Journal of the Korean Ceramic Society
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    • v.54 no.6
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    • pp.511-517
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    • 2017
  • With different working pressures and substrate biases, Cr-Al-N coatings were deposited by hybrid physical vapor deposition (PVD) method, consisting of unbalanced magnetron (UBM) sputtering and arc ion plating (AIP) processes. Cr and Al targets were used for the arc ion plating and the sputtering process, respectively. Phase analysis, and composition, binding energy, and microstructural analyses were performed using X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), and field emission scanning electron microscopy (FESEM), respectively. Surface droplet size of Cr-Al-N coatings was found to decrease with increasing substrate bias. A decrease of the deposition rate of Cr-Al-N films was expected due to the increase of substrate bias. The coatings were grown with textured CrN phase and (111), (200), and (220) planes. X-ray diffraction data show that all Cr-Al-N coatings shifted to lower diffraction angles due to the addition of Al. The XPS results were used to determine the $Cr_2N$, CrN, and (Cr,Al)N binding energies. The compositions of the Cr-Al-N films were measured by XPS to be Cr 23.2~36.9 at%, Al 30.1~40.3 at%, and N 31.3~38.6 at%.

The Design of the Container Logistics Information System Reflects the Port Logistics Environment (항만물류 특성을 반영한 컨테이너 정보시스템 설계)

  • Park, Young-Jae
    • Journal of Digital Convergence
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    • v.13 no.5
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    • pp.159-167
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    • 2015
  • The nature of port logistics requires global visibility and traceability. However, the traditional RFID technology still applied cannot meet these demands. IP-USN and M2M in port logistics have faced challenges of the prerequisite of network composition and immense communications at the base where a grand number of containers are installed. To resolve the issue, this study suggests an IP-RFID-based smart port logistics service platform. The IP-RFID-based port logistics service system resolved the communication problem by separating the RFID tag and AP, which allows internet connection, from the tag. The tags connected with thermo-sensors, humidity sensors, pressure sensors, GPS, etc. are attached to the containers insuring global visibility and traceability, key factors in logistics, by obtaining desired real-time information regardless of time and location.

The structure and the surface composition of semiconductor CdZnTe films by EBE (EBE로 증착된 반도체 CdZnTe 박막의 결정구조와 표면조성)

  • 박국상;김선옥;이기암
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.5 no.1
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    • pp.25-36
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    • 1995
  • We have investigated the structure and the conductivity of the $Cd_{1-y}Zn_{y}$ Te films evaporated on the glass substrates (Corning 7059) by Electron Beam Evaporator (EBE) in pressure of approximately $1 {\times} 10^{-6}$ torr.The structure temperatures were held at both room temperature and $300^{\circ}C$, and the samples have annealed for an hour at $300^{\circ}C$ The survace com-position of the as-prepared films were slightly different from those of CdZn Te source material.Cd losses on the CdZnTe surface was measured about 4% of atomic ratio at room temperature substrate, whereas Zn atomic ratio was nearly constant, relatively. The strure is observed to be polycrystalline whose phase is mainly cubic phase. Thermal expansion coefficient was $6.30 {\times} 10^{-5}/^{\circ}C$ which was calculated from the variation of lattice parameter by X-ray powder pat-terns measured at $400^{\circ}C$.Diffraction peaks were slightly increased by annealing for an hour at $300^{\circ}C $, but they werey highly affected by substrate temperature during evaporation.

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Preparation and Characterization of Solid Dispersions of Eprosartan with Hydrophilic Polymers (친수성 고분자를 이용한 에프로살탄 고체분산체의 제조 및 특성 분석)

  • Hwang, Jun-Seok;Ko, Ji-Eun;Kim, So-Hee;Huh, Kang-Moo
    • Polymer(Korea)
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    • v.36 no.4
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    • pp.500-506
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    • 2012
  • In this study, we developed and optimized hydrophilic polymer based solid dispersion formulations (SDs) for enhancing the aqueous solubility of eprosartan, one of poorly soluble drugs, that has been broadly used for the treatment of high blood pressure. Poly(ethylene glycol) (PEG) and poly(vinyl pyrrolidone) (PVP) based SDs were prepared by hot melting and solvent evaporation methods and the drug/polymer composition varied in the range of 1:1~1:5 with or without poloxamer 407 (P407) as a polymeric surfactant. The SDs prepared by solvent evaporation showed more reduced crystallinity than ones by hot melting, and PVP based SDs showed more enhanced solubility and lower crystallinity than PEG based SDs. Furthermore, it was observed from DSC and PXRD analysis that the SDs with P407 (drug:polymer: P407 = 1:5:1) demonstrated no crystallinity and the most enhanced solubility (more than 3~4 times).

A Comparative Study on the Precursors for the Atomic Layer Deposition of Silicon Nitride Thin Films (원료물질에 따른 실리콘 질화막의 원자층 증착 특성 비교)

  • Lee Won-Jun;Lee Joo-Hyeon;Lee Yeon-Seong;Rha Sa-Kyun;Park Chong-Ook
    • Korean Journal of Materials Research
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    • v.14 no.2
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    • pp.141-145
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    • 2004
  • Silicon nitride thin films were deposited by atomic layer deposition (ALD) technique in a batch-type reactor by alternating exposures of precursors. XJAKO200414714156408$_4$ or$ SiH_2$$Cl_2$ was used as the Si precursor, $NH_3$ was used as the N precursor, and the deposited films were characterized comparatively. The thickness of the film linearly increased with the number of deposition cycles, so that the thickness of the film can be precisely controlled by adjusting the number of cycles. As compared with the deposition using$ SiCl_4$, the deposition using $SiH_2$$Cl_2$ exhibited larger deposition rate at lower precursor exposures, and the deposited films using $SiH_2$$Cl_2$ had lower wet etch rate in a diluted HF solution. Silicon nitride films with the Si:N ratio of approximately 1:1 were obtained using either Si precursors at $500^{\circ}C$, however, the films deposited using $SiH_2$$Cl_2$ exhibited higher concentration of H as compared with those of the $SiC_4$ case. Silicon nitride thin films deposited by ALD showed similar physical properties, such as composition or integrity, with the silicon nitride films deposited by low-pressure chemical vapor deposition, lowering deposition temperature by more than $200^{\circ}C$.

Characteristics of Plasma Carburizing Process in Surface Hardening of SCM415 Steel (플라즈마 침탄 공정을 이용한 SCM415강의 표면 경화 특성)

  • Kim, Dae-Wook;Kim, Dong-Won;Lim, Byeong-Soo;Kim, Seuk-Buom
    • Korean Journal of Materials Research
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    • v.8 no.8
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    • pp.707-713
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    • 1998
  • The influence of plasma carburizing process on the surface hardness of SCM415 low-alloy steel (0.15% C) was investigated under the various process conditions of gas composition. gas pressure, plasma current density. temperature and time. The effective case depth was found to depend on the amount of methan gas containing carbon. thus the deepest case depth and the uniform hardeness were obtained with the 100% methan gas. The case depth increased with the plasma current density. The effective plasma carburizing temperature of SCM415 steel was found to be higher than 85$0^{\circ}C$, and the case depth was proportional to the square root of carburizing time under the same current density. The bending fatigue strength of the plasma carburized specimen is' higher than those of as- received specimen or reheat-quenched specimen.

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Geography of Microstate Migration Caused by Environmental Problems: The Case of Tuvalu (환경문제로 인한 미소국가 이주의 지리학: 투발루의 사례)

  • Shen, Shawn
    • Journal of the Korean Geographical Society
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    • v.51 no.2
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    • pp.185-200
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    • 2016
  • The discipline of Geography is broadly concerned with the interconnections between people and the environment. Particularly, this unique human-environment relationship often can be typically reflected from, and well illustrated by, the dynamics of microstates' island environment. While Tuvaluans living on vulnerable, low-lying atolls in the Pacific are not primarily responsible for contributing to climate change, yet they are experiencing its dreadful effects. Population pressure, caused by the differences in population size, distribution, and composition, has been constantly affected by resource unavailability and environmental instability on the islands. It also represents one of our challenges in understanding the complex influence of population dynamics on the living environment. What can be learned from Tuvalu in the context of population geography and environmental geography as well as its relationship with other Pacific island microstates? What are Tuvaluans' migration responses to their atolls' environmental crisis as well as the carrying capacity scenarios related to overpopulation? What are the current living experiences and settlement situations of Tuvaluan internal and external migrants both at home and abroad? This research examines the contemporary migration literature in the context of Tuvalu's population geography, while analyzing Tuvaluan migration patterns, discourses and perspectives in relation to environmental change.

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A Effect of Reaction Conditions on Syngas Yield for the Preparation of Syngas from Landfill Gas (매립지가스(LFG)로부터 합성가스 제조시 반응조건에 따른 수율에 미치는 연구)

  • CHO, WOOKSANG;CHOI, KEONGDON;BAEK, YOUNGSOON
    • Transactions of the Korean hydrogen and new energy society
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    • v.26 no.5
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    • pp.477-483
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    • 2015
  • LFG (Land-Fill Gas) includes components of $CH_4$, $CO_2$, $O_2$, $N_2$, and water. The preparation of synthesis gas from LFG as a DME (Dimethyl Ether) feedstock was studied by methane reforming of $CO_2$, $O_2$ and steam over $NiO-MgO-CeO_2/Al_2O_3$ catalyst. Our experiments were performed to investigate the effects of methane conversion and syngas yield on the amount of LFG components over $NiO-MgO-CeO_2/Al_2O_3$ catalyst. Results were obtained through the methan reforming experiments at the temperature of $900^{\circ}C$ and GHSV of 8,800. The results were as following; it has generally shown that syngas yield increase with the increase of oxygen and steam amounts and then decrease. Highly methane conversion of above 98% and syngas yield of approximately 60% were obtained in the feed of gas composition flow-rate of 243ml/min of $CH_4$, 241ml/min of $CO_2$, 195ml/min of $O_2$, 48ml/min of $N_2$, and 450ml/min of steam, respectively, under reactor pressure of 1 bar for 200 hrs of reaction time. Also, it was shown that catalyst deactivation by coke formation was reduced by excessively adding oxygen and steam as an oxidizer of the methane reforming.