• Title/Summary/Keyword: Precursor type

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Effects of Precursor and Thidiazuron on Triterpene Saponin Biosynthesis in Centella asiatica (L.) Urban

  • Kim, Ok-Tae;Kim, Min-Young;Ahn, Jun-Cheul;Li, Mei-Yang;Hwang, Baik
    • Korean Journal of Medicinal Crop Science
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    • v.13 no.2
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    • pp.91-94
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    • 2005
  • Plants have been known to accumulate a very diverse range of triterpene saponins. We have investigated the regulation of saponin biosynthesis in higher plants using Centella asiatica (L.) Urban as a model plant. Effects of a feeding precursor on asiaticoside production from leaves and on the level of two-type OSCs mRNA were investigated. As a feeding precursor, squalene negatively affected the levels of CYS and bAS mRNA, but it also decreased the production of asiaticoside from whole plants. Plant hormones regulate secondary metabolism, and in plant tissue cultures they could affect both culture growth and secondary metabolite production. Although enhancement of asiaticoside production from whole plant cultures by addition of TDZ (thidiazuron) has been reported, the positive effect of TDZ on the levels of OSCs transcripts was not observed.

Controlling Size, Shape and Polymorph of TiO2 Nanoparticles by Temperature-Controlled Hydrothermal Treatment

  • Kwon, Do Hun;Jung, Young Hee;Kim, Yeong Il
    • Journal of the Korean Chemical Society
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    • v.59 no.3
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    • pp.238-245
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    • 2015
  • The crystallization and morphology change of amorphous titanias by hydrothermal treatment have been investigated. The amorphous titanias were prepared by pure water hydrolysis of two different precursors, titanium tetraisopropoxide (TTIP) and TTIP modified with acetic acid (HOAc) and characterized prior to hydrothermal treatment. In order to avoid complicate situation, the hydrothermal treatment was performed in a single solvent water with and without strong acids at various temperatures. The effects of strong acid, temperature and time were systematically investigated on the transformation of amorphous titania to crystalline TiO2 under simple hydrothermal condition. Without strong acid the titanias were transformed into only anatase phase nanoparticle regardless of precursor type, temperature and time herein used (up to 250 ℃ and 48 hours). The treatment temperature and time effected only on the crystalline size, not on the crystal phase et al. However, it was clearly revealed that the strong acids such as HNO3 and HCl catalyzed the formation of rutile phase depending on temperature. HCl was slightly better than HNO3 in this catalytic activity. The morphology of rutile TiO2 formed was also a little affected by the type of acid. The precursor modifier, HOAc slightly reduced the catalytic activity of the strong acids in rutile phase formation.

Friction-wear Characterization and Fabrication of Carbon/Carbon Composite via Mesophase Pitch (메조페이스 핏치계 탄소/탄소 복합재료의 제조 및 마찰 마모특성)

  • 박종규;이진용;하헌승;임연수;이승구
    • Journal of the Korean Ceramic Society
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    • v.35 no.9
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    • pp.974-980
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    • 1998
  • This study is concerned with the production of carbon fiber reinforced carbon(C/C) with polyaromatic mesophase pitch as matrix precursor and with the investigation of friction-wear characteristics in ambient air using a constant speed type of friction tester. The main problem in using the polyaromatic mesophase as the matrix precursor is the high viscosity which may limit the complete impregnation of the fiber preform in the vacuum. To solve these problems two dimensional carbon fiber fabrics were infiltrated with meso-phase pitch in the pitch impregnator. After the impregnation and the heat treatment process. C/C com-posites were characterized by density porosity to monitor the influence of high pressure and temperature. It showed that the bulk density was increased and the apparent porosity and the density increasing rate was reduced as repeating the impregnation the carbonization and the heat treatment. The friction-wear charac-teristics of C/C composites were investigated by measuring the average friction coefficient and the specific wear rate as functions friction speed and friction pressure using a constant speed type of friction tester. C/C composite4s showed the average friction coefficient to be reduced as increasing the friction speed and the friction pressure.

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Synthesis of (${Ba_{1.3}}{Al_{12}}{O_{19}}$:$Mn^{2+}$) by Ultrasonic Spray Pyrolysis and Effect of Precursor Type on Morphology and Photoluminescence (초음파 분무 열분해법에 의한 바륨 헥사알루미네이트(${Ba_{1.3}}{Al_{12}}{O_{19}}$:$Mn^{2+}$) 제조 및 전구체 종류에 따른 형성과 발광 특성)

  • 김경화;강윤찬;김창해;박희동;최세영
    • Journal of the Korean Ceramic Society
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    • v.38 no.2
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    • pp.173-178
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    • 2001
  • 본 연구에서는 PDP용 녹색 형광체의 대안인 $Ba_{1.3}$A $l_{12}$ $O_{19}$:$Mn^{2+}$ 분말을 초음파 분무 열분해법으로 합성하였으며 활성제인 $Mn^{2+}$의 첨가량과 모체를 구성하는 바륨 및 알루미늄의 전구체 물질들의 조합을 변화시킴으로써 형광체 분말의 형태 및 발광특성을 조절하였다. 최적의 발광 휘도를 나타내는 $Mn^{2+}$의 농도는 0.25몰을 첨가하였을 때이며 녹색 발광 영역인 517nm에서 최대 발광 효율을 나타내었다. 바륨의 전구체 물질로는 초산염, 질산염, 염화물 및 수산화물을 사용하였으며 알루미늄 전구체 물질로는 질산염 및 염화물을 사용하였다. 전구체는 합성된 분말의 형상에 영향을 미치는데 구형을 유지하거나 혹은 뭉치거나 구형이 깨지는 등 전구체 조합에 따라 얻어지는 분말의 형태가 달라졌다. 합성된 형광체 분말들은 일반적인 고상 반응의 온도보다 낮은 열처리 온도인 140$0^{\circ}C$, 5시간 유지에서는 좋은 VUV 발광 특성을 가졌다. 또한 전구체의 조합은 형광체 발광 효율에도 영향을 미치는데 바륨과 알루미늄은 염화물을, 망간은 질산염을 사용하였을 때 가장 좋은 발광 휘도를 나타내었다.다.다.다.

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Characterization of ZnO Nanorods and SnO2-CuO Thin Film for CO Gas Sensing

  • Lim, Jae-Hwan;Ryu, Jee-Youl;Moon, Hyung-Sin;Kim, Sung-Eun;Choi, Woo-Chang
    • Transactions on Electrical and Electronic Materials
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    • v.13 no.6
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    • pp.305-309
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    • 2012
  • In this study, ZnO nanorods and $SnO_2$-CuO heterogeneous oxide were grown on membrane-type gas sensor platforms and the sensing characteristics for carbon monoxide (CO) were studied. Diaphragm-type gas sensor platforms with built-in Pt micro-heaters were made using a conventional bulk micromachining method. ZnO nanorods were grown from ZnO seed layers using the hydrothermal method, and the average diameter and length of the nanorods were adjusted by changing the concentration of the precursor. Thereafter, $SnO_2$-CuO heterogeneous oxide thin films were grown from evaporated Sn and Cu thin films. The average diameters of the ZnO nanorods obtained by changing the concentration of the precursor were between 30 and 200 nm and the ZnO nanorods showed a sensitivity value of 21% at a working temperature of $350^{\circ}C$ and a carbon monoxide concentration of 100 ppm. The $SnO_2$-CuO heterogeneous oxide thin films showed a sensitivity value of 18% at a working temperature of $200^{\circ}C$ and a carbon monoxide concentration of 100 ppm.

Overproduction and Purification of Ribose-Binding Proteins from the Wild-Type Mutant and Revertant Strains in Escherichia coli (리보스 결합단백질의 대량생산을 위한 야생형 수송결합변이, 복귀변이 유전자의 클로닝과 이들 단백질의 순수정제)

  • ;Randall Linda L.
    • Korean Journal of Microbiology
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    • v.26 no.4
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    • pp.291-297
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    • 1988
  • Three alleles of rbsB gene, rbsB, rbsB103, and rbsB106 from the wild type, the mutant and the revertant strain, respectively, were cloned for overproduction of proteins under the control of lambda $P_{L}$ promoter. Five different species of precursor and mature ribose-binding proteins were purified to homogeneity using DEAE-Sephadex column chromatography, osmotic shock pocedure, CM-Sephadex column chromatography, and Chromatofocusing column chromaography. pI of the precursor proteins and mature proteins were determined and found to be pH 8.0 and 7.5, respectively. The purified proteins were subjected to amino acid sequencing. The results confirmed the amino acid changes deduced from the DNA sequencing.

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Preparation of Anodic Iron Oxide Composite Incorporated with WO3 on the Stainless Steel Type-304 Substrate Through a Single-step Anodization (단일공정 양극산화를 이용한 WO3가 복합된 304 스테인레스 강 산화 피막 제조)

  • Kim, Moonsu;Lee, Jaewon;Lee, Kiyoung;Kim, Yong-Tae;Choi, Jinsub
    • Journal of the Korean institute of surface engineering
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    • v.53 no.5
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    • pp.257-264
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    • 2020
  • Anodization of Fe and Fe alloys is one of the most promising techniques to obtain iron oxide films applying to the various electrochemical devices due to their electrochemical catalytic properties. In this study, we investigate on the preparation of anodic iron oxide composite incorporated with WO3 through a single-step anodization of stainless steel type-304 (STS304) as a substrate. The effects of applied voltage and tungsten precursor on the structural characteristics of iron oxide composite with different amount of incorporated WO3 were observed. It is demonstrated that when the voltage of 60 V applied with 20 mM of Na2WO4 as a precursor, anodic iron oxide composite with a large pore diameter and a thick oxide length in which WO3 is uniformly incorporated is obtained.

Solvothermal Synthesis of α-Al2O3 from Boehmite with Seeding Technique

  • Jo, Hye Youn;Park, Min-Gyeong;Lee, Seung-Ho;Kim, Dae Sung;Lee, Young Kwan;Lim, Hyung Mi
    • Journal of the Korean Ceramic Society
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    • v.52 no.4
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    • pp.273-278
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    • 2015
  • ${\alpha}-Al_2O_3$ was synthesized by solvothermal synthesis using ${\alpha}-Al_2O_3$ seed, precursor of fine boehmite (Al(OOH)) or gibbsite ($Al(OH)_3$), and 1, 4-butanediol solvent. The seed content and precursor type were selected as variables in order to synthesize ${\alpha}-Al_2O_3$. The formation time of ${\alpha}-Al_2O_3$ was reduced and the size of the particles was decreased with addition of the seed. When the seed content was increased, the size of the synthesized ${\alpha}-Al_2O_3$ was reduced. Morphologies of the as-synthesized ${\alpha}-Al_2O_3$ with ${\alpha}-Al_2O_3$ seed were polyhedron-shaped, while the shape was plate-like or polyhedral without the seed, depending on the additives or the average particle size of the boehmite precursor. The aggregation of as-synthesized ${\alpha}-Al_2O_3$ from boehmite was smaller than that from gibbsite. As-synthesized ${\alpha}-Al_2O_3$, with 140 nm size, was obtained by using the seed and boehmite precursor.

Spectroscopic Evidence of Jet-Cooled p-Chloro-α-Methylbenzyl Radical in Corona Excitation

  • Huh, Chang-Soon;Yoon, Young-Wook;Lee, Sang-Kuk
    • Bulletin of the Korean Chemical Society
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    • v.33 no.9
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    • pp.2943-2948
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    • 2012
  • We report the first spectroscopic evidence of the jet-cooled p-chloro-${\alpha}$-methylbenzyl radical. The visible vibronic emission spectrum was recorded from the corona discharge of precursor p-chloro-ethylbenzene seeded in a large amount of inert carrier gas helium using a pinhole-type glass nozzle coupled with a technique of corona excited supersonic expansion. From the comparison with the vibronic spectrum of the p-chlorobenzyl radical, we identified the evidence of formation of the jet-cooled p-chloro-${\alpha}$-methylbenzyl radical in the corona discharge of precursor p-chloro-ethylbenzene.