• 한국방사성폐기물학회:학술대회논문집
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• 한국방사성폐기물학회 2005년도 춘계 학술대회
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• pp.248-254
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• 2005

본 연구에서는 음이온 교환수지와 Sr-Spec 수지를 사용하여 $^{90}Sr,\;^{241}Am$ 및 Pu 동위원소들에 대하여 축차적으로 분리하는 정량법을 제시하였다. Pu 동위원소는 음이온 교환수지를 이용하여 분리하였다. 아메리슘 및 스트론튬은 옥살산 공침법을 사용하여 토양 메트릭스 성분으로부터 분리하였다. 아메리슘은 철공침법을 사용하여 스트론튬으로부터 분리한후 음이온 교환수지를 사용하여 란탄나이드 성분으로부터 순수분리하였다. 스트론튬은 Sr-Spec 수지를 사용하여 순수분리하였다. Pu 및 Am 동위원소는 알파스펙트로메타로 정량하였고 Sr-90은 액체섬광계수기를 사용하여 베타선을 측정하였다. 본 연구에서 고찰된 $^{90}Sr,\;^{241}Am$ 및 Pu 동위원소 분석법을 IAEA 기준시료에 적용하여 분석법의 타당성을 검증하였다.

• 한국기후변화학회지
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• 제9권1호
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• pp.47-58
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• 2018

In this study, we evaluated the uncertainty in the process of selecting GCM and downscaling method for assessing the impact of climate change, and influence of user-centered climate change information on reproducibility of Chungju Dam inflow was analyzed. First, we selected the top 16 GCMs through the evaluation of spatio-temporal reproducibility of 29 raw GCMs using 30-year average of 10-day precipitation without any bias-correction. The climate extreme indices including annual total precipitation and annual maximum 1-day precipitation were selected as the relevant indices to the dam inflow. The Simple Quantile Mapping (SQM) downscaling method was selected through the evaluation of reproducibility of selected indices and spatial correlation among weather stations. SWAT simulation results for the past 30 years period by considering limitations in weather input showed the satisfactory results with monthly model efficiency of 0.92. The error in average dam inflow according to selection of GCMs and downscaling method showed the bests result when 16 GCMs selected raw GCM analysi were used. It was found that selection of downscaling method rather than selection of GCM is more is important in overall uncertainties. The average inflow for the future period increased in all RCP scenarios as time goes on from near-future to far-future periods. Also, it was predicted that the inflow volume will be higher in the RCP 8.5 scenario than in the RCP 4.5 scenario in all future periods. Maximum daily inflow, which is important for flood control, showed a high changing rate more than twice as much as the average inflow amount. It is also important to understand the seasonal fluctuation of the inflow for the dam management purpose. Both average inflow and maximum inflow showed a tendency to increase mainly in July and August during near-future period while average and maximum inflows increased through the whole period of months in both mid-future and far-future periods.

• 한국수자원학회논문집
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• 제52권3호
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• pp.195-206
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• 2019

본 연구에서는 주 단위 지하수자원 관리 취약시기 평가 방법을 개발하였다. 강수의 지하수위에 대한 영향을 고려하기 위하여 한계 침투량을 고려한 강우이동평균 방법을 통해 지하수위와의 상관계수를 산정하였다. 취약 시기 평가 기준을 개발하고 평가 기준에 대한 가중치를 엔트로피 방법을 이용하여 산정하였다. 강수와의 상관계수와 산정된 가중치를 이용한 주 단위 지하수자원 관리 취약시기 평가 방법을 개발하였으며, 개발한 방법을 통하여 소규모 행정구역을 대상으로 취약시기를 평가하였다. 본 연구에서 개발된 방법은 지역적일뿐만 아니라 계절적인 지하수자원의 효율적 관리 대책 수립의 근거가 될 수 있을 것이다.

• 한국수자원학회논문집
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• 제49권2호
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• pp.107-119
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• 2016

미래 기후변화 시나리오에 따르면 극한강우사상이 현재보다 더 강화될 것으로 전망되기 때문에, 기후변화의 영향이 추정절차에 반영되지 않는다면 가능최대강수량(PMPs)을 과소 추정하게 될 가능성이 매우 높다. 본 연구에서는 미래의 강우 변동이 반영된 PMPs가 추정된다. PMPs 계산을 위하여 수문기상학적 방법이 이용되며, 기존에 사용되어오던 지형영향비를 대신하여 산악전이비가 가능최대강수량의 산정에 적용된다. 미래 주요호우사상들로부터의 DAD는 기상청 RCM (HEDGEM3-RA) RCP 8.5 기후변화 시나리오의 일 강수자료를 기반으로 편의보정 및 이동평균 된 변화인자를 이용하여 간접적으로 산출된다. 미래 PMPs 산출결과, 현재보다 증가하는 것으로 나타났으며 증가율은 2045년 기준으로 평균적으로 연간 3 mm 정도 증가하는 것으로 예측되었으며, 먼 미래로 갈수록 PMPs의 증가율은 커졌으나 미래강우자료로부터 유발되는 PMPs 추정의 불확실성 또한 증가되고 있는 것으로 파악된다.

• 한국광물학회:학술대회논문집
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• 한국광물학회.한국암석학회 2001년도 공동학술발표회 논문집
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• pp.45-47
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• 2001

Jeju island is composed mainly of volcanic rocks such as basalts, trachytic andesites, tracytes, and sedimentary rocks. About 80% of Jeju soils are classified as Andisols. The amount of annual precipitation in Jeju island is about 1872mm, which is 1.5 times the annual precipitation of south Korea. There is a significant difference In amount of precipitation with regions even within Jeju island. In study area, the annual amount of rainfall is about 1280mm, the lowest in Jeju island while south part of the island has the annual precipitation of 2056mm, though they are only tens of kilometers apart. The parent materials of soils in study area are pyroclastic rocks and tuffs. The soils of non-andic properties have developed in this area since pedogenic process of pyroclastic materials is strongly influenced by climatic factor, especially precipitation. In order to investigate the mineralogical characteristics of soils, X-ray analysis for <0.2 and 2-0.2$\mu\textrm{m}$ size fractions was performed with ethylene glycol solvation, K-, Mg-saturation, heat treatment(110, 330, 550$^{\circ}C$). Acid-oxalate and DCB(sodium hydrosulfite, sodium citrate, sodium bicarbonate) dissolution method was used to assess tile total amounts or Al, si, and hydroxy interlayer or 2:1 layer silicates. XRD was also applied for samples treated with DCB only and DCB-oxalate sequentially. XRD patterns showed that 2:1 and 1:1 layer silicates were found, which are different from soils of Andisols. Vermiculite, chlorite, hydroxy interlayered minreals, and interstratified minerals(vermiculite/chlorite) were observed in 2-0.2$\mu\textrm{m}$ size fractions. After DCB treatments, ethylene glycolated samples with Mg-saturation showed expanded d-spacing, suggesting the possibility of hydroxy interlayered minerals. The amounts of hydroxy interlayered minerals increased in surface soil. Unlike Andisols, short range ordered minerals such as allophane, imogolite and gibbsite were hardly found. Mica and kaolinte existed in small amounts. Results are summarized in Fig 1 and Fig. 2.

• 한국결정성장학회지
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• 제22권2호
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• pp.99-104
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• 2012

BCP(biphasic calcium phosphate) 분말을 제조하기 위하여 $Ca(NO_3)_2{\cdot}4H_2O$, $(NH_4)_2HPO_4$를 출발 물질로 공침법(co-precipitation process)을 이용하여 합성하였다. 합성된 분말의 열처리 전 후의 HAp(Hydroxyapatite)/${\beta}$-TCP(${\beta}$-Tricalcium phosphate) 결정상 비율 및 분광학적 특성을 XRD 및 FT-IR를 이용하여 분석하였다. BCP 분말의 생체활성 거동을 평가하기 위하여 Hanks' Balanced Salt Solution(HBSS)에 침적시켜 시간에 따라 형상, 이온농도의 변화 및 결정상을 분석한 결과 낮은 결정화도의 HAp가 생성됨을 확인하였다. BCP분말의 세포독성 평가에서도 대조군에 비하여 세포성장률이 우수함을 관찰하였다.

• 한국지구과학회지
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• 제35권5호
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• pp.342-353
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• 2014

Data for model analysis derived from the finite volume (fv) GCM (Goddard Earth Observing System Ver. 4, GEOS-4) and the Land Data Assimilation System (LDAS) have been utilized in a mesoscale model. These data are tested to provide initial conditions and lateral boundary forcings to the Purdue Mesoscale Model (PMM) for a case study of the Midwestern flood that took place from 21-23 May 1998. The simulated results with fvGCM and LDAS soil moisture and temperature data are compared with that of ECMWF reanalysis. The initial conditions of the land surface provided by fvGCM/LDAS show significant differences in both soil moisture and ground temperature when compared to ECMWF control run, which results in a much different atmospheric state in the Planetary Boundary Layer (PBL). The simulation result shows that significant changes to the forecasted weather system occur due to the surface initial conditions, especially for the precipitation and temperature over the land. In comparing precipitation, moisture budgets, and surface energy, not only do the intensity and the location of precipitation over the Midwestern U.S. coincide better when running fvGCM/LDAS, but also the temperature forecast agrees better when compared to ECMWF reanalysis data. However, the precipitation over the Rocky Mountains is too large due to the cumulus parameterization scheme used in the PMM. The RMS errors and biases of fvGCM/LDAS are smaller than the control run and show statistical significance supporting the conclusion that the use of LDAS improves the precipitation and temperature forecast in the case of the Midwestern flood. The same method can be applied to Korea and simulations will be carried out as more LDAS data becomes available.

• 자원리싸이클링
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• 제30권6호
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• pp.36-42
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• 2021

폐리튬이온배터리에 함유된 유가금속을 회수하기 위해 고온에서 용융환원처리한다. 용융환원된 금속상을 염산용액으로 침출한 다음 용매추출과 침전으로 유가금속을 분리한 여과액에는 니켈(II)과 미량의 규소(IV)가 함유되어 있다. 여액으로부터 고순도 니켈화합물을 회수하기 위해 흡착법에 의한 규소(IV)의 분리와 니켈(II)의 선택적 침전에 대해 조사했다. Polyacrylamide는 규소(IV)를 선택적으로 흡착했으나 용액의 점도 역시 증가하여 여과가 어렵다. 침전제로 탄산나트륨을 첨가하면 니켈(II)과 미량의 규소(IV)가 공침되었다. 반면 옥살산나트륨은 상온에서 니켈(II)만을 선택적으로 침전시켜 순도 99.99% 이상의 니켈옥살산염 결정상을 회수할 수 있었다.

• Metals and materials international
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• 제24권6호
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• pp.1193-1201
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• 2018

Dilatometry is a useful technique to obtain experimental data concerning transformation. In this paper, a dilation conversional model was established to calculate carbides fraction in AISI H13 hot-work tool steel based on the measured length changes. After carbides precipitation, the alloy contents in the matrix changed. In the usual models, the content of carbon atoms after precipitation is considered as the only element that affects the lattice constant and the content of the alloy elements such as Cr, Mo, Mn, V are often ignored. In the model introduced in this paper, the alloying elements (Cr, Mo, Mn, V) changes caused by carbides precipitation are incorporated. The carbides were identified using scanning electron microscope and transmission electron microscope. The relationship between lattice constant of carbides and temperature are measured by high-temperature X-ray diffraction. The results indicate that the carbides observed in all specimens cooled at different rates are V-rich MC and Cr-rich $M_{23}C_6$, and most of them are V-rich MC, only very few are Cr-rich $M_{23}C_6$. The model including the effects of substitutional alloying elements shows a good improvement on carbides fraction predictions. In addition, lower cooling rate advances the carbides precipitation for AISI H13 specimens. The results between experiments and mathematical model agree well.

• 대기
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• 제28권4호
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• pp.443-455
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• 2018

Nowcasting algorithms using weather radar data are mostly based on extrapolating the radar echoes. We estimate the echo motion vectors that are used to extrapolate the echo properly. Therefore, understanding the general characteristics of these motion vectors is important to improve the performance of nowcasting. General characteristics of radar-based motions are analyzed for warm season precipitation over Jeju region. Three-year summer season data (June~August, 2011~2013) from two radars (GSN, SSP) in Jeju are used to obtain echo motion vectors that are retrieved by Variational Echo Tracking (VET) method which is widely used in nowcasting. The highest frequency occurs in precipitation motion toward east-northeast with the speed of $15{\sim}16m\;s^{-1}$ during the warm season. Precipitation system moves faster and eastward in June-July while it moves slower and northeastward in August. The maximum frequency of speed appears in $10{\sim}20m\;s^{-1}$ and $5{\sim}10m\;s^{-1}$ in June~July and August respectively while average speed is about $14{\sim}15m\;s^{-1}$ in June~July and $8m\;s^{-1}$ in August. In addition, the direction of precipitation motion is highly variable in time in August. The speed of motion in Lee side of the island is smaller than that of the windward side.