• Proceedings of the Korean Radioactive Waste Society Conference
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• 2005.06a
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• pp.248-254
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• 2005

This paper presents a quantitative method of sequential separation of $^{90}Sr,\;^{241}Am$ and Pu nuclides with an anion exchange resin and a Sr-Spec resin. The Pu isotopes were purified with an anion exchange resin. The americium and strontium fractions were separated from the matrix elements with an oxalate co-precipitation method. Americium fraction was separated from the strontium fraction with iron co-precipitation method and purified from lanthanides with anion exchange resin. Strontium-90 was purified from other hindrance elements with the Sr-Spec resin after oxalate co-precipitation. The measurement of Pu and Am isotopes was carried out by an ${\alpha}$-spectrometer. Strontium-90 was measured by a liquid scintillation counter. The radiochemical procedure of $^{90}Sr,\;^{241}Am$ and Pu nuclides investigated in this study has been validated by application to IAEA-Reference soils.

• Journal of Climate Change Research
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• v.9 no.1
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• pp.47-58
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• 2018

In this study, we evaluated the uncertainty in the process of selecting GCM and downscaling method for assessing the impact of climate change, and influence of user-centered climate change information on reproducibility of Chungju Dam inflow was analyzed. First, we selected the top 16 GCMs through the evaluation of spatio-temporal reproducibility of 29 raw GCMs using 30-year average of 10-day precipitation without any bias-correction. The climate extreme indices including annual total precipitation and annual maximum 1-day precipitation were selected as the relevant indices to the dam inflow. The Simple Quantile Mapping (SQM) downscaling method was selected through the evaluation of reproducibility of selected indices and spatial correlation among weather stations. SWAT simulation results for the past 30 years period by considering limitations in weather input showed the satisfactory results with monthly model efficiency of 0.92. The error in average dam inflow according to selection of GCMs and downscaling method showed the bests result when 16 GCMs selected raw GCM analysi were used. It was found that selection of downscaling method rather than selection of GCM is more is important in overall uncertainties. The average inflow for the future period increased in all RCP scenarios as time goes on from near-future to far-future periods. Also, it was predicted that the inflow volume will be higher in the RCP 8.5 scenario than in the RCP 4.5 scenario in all future periods. Maximum daily inflow, which is important for flood control, showed a high changing rate more than twice as much as the average inflow amount. It is also important to understand the seasonal fluctuation of the inflow for the dam management purpose. Both average inflow and maximum inflow showed a tendency to increase mainly in July and August during near-future period while average and maximum inflows increased through the whole period of months in both mid-future and far-future periods.

• Journal of Korea Water Resources Association
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• v.52 no.3
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• pp.195-206
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• 2019

In this study, the vulnerable period assessment method for weekly groundwater resources management was developed considering correlation between data of groundwater level, river level, precipitation applying critical infiltration concept. The vulnerable periods of 3 case study were assessed using data of groundwater, precipitation, river level, and results were compared. The weights for between observation stations were calculated using correlation of groundwater, precipitation, river level data, and weights that could be considered recently trend of data for each observation station. The vulnerable period was assessed using final calculated weights and multi criteria decision method, compared result for each case study. The developed method can be a quantitative basis for the establishment of efficient groundwater resources management and the decision of specific countermeasure applyment.

• Journal of Korea Water Resources Association
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• v.49 no.2
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• pp.107-119
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• 2016

Since future climate scenarios indicate that extreme precipitation events will intensity, probable maximum precipitations (PMPs) without being taken climate change into account are very likely to be underestimated. In this study future PMPs in accordance with the variation of future rainfall are estimated. The hydro-meteorologic method is used to calculate PMPs. The orographic transposition factor is applied in place of the conventional terrain impact factor which has been used in previous PMPs estimation reports. Future DADs are indirectly obtained by using bias-correction and moving-averaged changing factor method based on daily precipitation projection under KMA RCM (HEDGEM3-RA) RCP 8.5 climate change scenario. As a result, future PMPs were found to increase and the spatially-averaged annual PMPs increase rate in 4-hour and $25km^2$ was projected to be 3 mm by 2045. In addition, the increased rate of future PMPs is growing increasingly in the future, but it is thought that the uncertainty of estimating PMPs caused by future precipitation projections is also increased in the distant future.

• Proceedings of the Mineralogical Society of Korea Conference
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• 2001.06a
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• pp.45-47
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• 2001

Jeju island is composed mainly of volcanic rocks such as basalts, trachytic andesites, tracytes, and sedimentary rocks. About 80% of Jeju soils are classified as Andisols. The amount of annual precipitation in Jeju island is about 1872mm, which is 1.5 times the annual precipitation of south Korea. There is a significant difference In amount of precipitation with regions even within Jeju island. In study area, the annual amount of rainfall is about 1280mm, the lowest in Jeju island while south part of the island has the annual precipitation of 2056mm, though they are only tens of kilometers apart. The parent materials of soils in study area are pyroclastic rocks and tuffs. The soils of non-andic properties have developed in this area since pedogenic process of pyroclastic materials is strongly influenced by climatic factor, especially precipitation. In order to investigate the mineralogical characteristics of soils, X-ray analysis for <0.2 and 2-0.2$\mu\textrm{m}$ size fractions was performed with ethylene glycol solvation, K-, Mg-saturation, heat treatment(110, 330, 550$^{\circ}C$). Acid-oxalate and DCB(sodium hydrosulfite, sodium citrate, sodium bicarbonate) dissolution method was used to assess tile total amounts or Al, si, and hydroxy interlayer or 2:1 layer silicates. XRD was also applied for samples treated with DCB only and DCB-oxalate sequentially. XRD patterns showed that 2:1 and 1:1 layer silicates were found, which are different from soils of Andisols. Vermiculite, chlorite, hydroxy interlayered minreals, and interstratified minerals(vermiculite/chlorite) were observed in 2-0.2$\mu\textrm{m}$ size fractions. After DCB treatments, ethylene glycolated samples with Mg-saturation showed expanded d-spacing, suggesting the possibility of hydroxy interlayered minerals. The amounts of hydroxy interlayered minerals increased in surface soil. Unlike Andisols, short range ordered minerals such as allophane, imogolite and gibbsite were hardly found. Mica and kaolinte existed in small amounts. Results are summarized in Fig 1 and Fig. 2.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.22 no.2
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• pp.99-104
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• 2012

The co-precipitation technique has been applied to synthesize biphasic calcium phosphate (BCP). $Ca(NO_3)_2{\cdot}4H_2O$ and $(NH_4)_2HPO_4$ as the starting materials was used. X-ray diffraction (XRD) and Fourier transformed infrared (FT-IR) spectroscopy were used to characterize the structure of as-synthesized and calcined BCP powders. After immersion in Hanks' Balanced Salt Solution (HBSS), for 1 week a precipitation started to be formed with individual small granules on the specimen surface. An MTT assay indicated that BCP powders have no cytotoxic effects on MG-63 cells, and that they have good biocompatibility.

• Journal of the Korean earth science society
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• v.35 no.5
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• pp.342-353
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• 2014

Data for model analysis derived from the finite volume (fv) GCM (Goddard Earth Observing System Ver. 4, GEOS-4) and the Land Data Assimilation System (LDAS) have been utilized in a mesoscale model. These data are tested to provide initial conditions and lateral boundary forcings to the Purdue Mesoscale Model (PMM) for a case study of the Midwestern flood that took place from 21-23 May 1998. The simulated results with fvGCM and LDAS soil moisture and temperature data are compared with that of ECMWF reanalysis. The initial conditions of the land surface provided by fvGCM/LDAS show significant differences in both soil moisture and ground temperature when compared to ECMWF control run, which results in a much different atmospheric state in the Planetary Boundary Layer (PBL). The simulation result shows that significant changes to the forecasted weather system occur due to the surface initial conditions, especially for the precipitation and temperature over the land. In comparing precipitation, moisture budgets, and surface energy, not only do the intensity and the location of precipitation over the Midwestern U.S. coincide better when running fvGCM/LDAS, but also the temperature forecast agrees better when compared to ECMWF reanalysis data. However, the precipitation over the Rocky Mountains is too large due to the cumulus parameterization scheme used in the PMM. The RMS errors and biases of fvGCM/LDAS are smaller than the control run and show statistical significance supporting the conclusion that the use of LDAS improves the precipitation and temperature forecast in the case of the Midwestern flood. The same method can be applied to Korea and simulations will be carried out as more LDAS data becomes available.

• Resources Recycling
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• v.30 no.6
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• pp.36-42
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• 2021

Spent lithium-ion batteries are treated by reduction-smelting at high temperatures to recover valuable metals. Solvent extraction and precipitation of the HCl leaching solution of reduction-smelted metallic alloys resulted in a filtrate containing Ni(II) and a small amount of Si(IV). Adsorption and precipitation experiments were conducted to recover pure Ni(II) compounds from the filtrate. Si(IV) was selectively loaded onto polyacrylamide, but this method did not efficiently filter the solution due to an increase in viscosity. The addition of Na₂CO₃ as a precipitant to the filtrate led to the simultaneous precipitation of Ni(II) and Si(IV). However, it was possible to recover nickel oxalate with a purity higher than 99.99% by selectively precipitating Ni(II) with the addition of Na₂C₂O₄ as a precipitant.

• Metals and materials international
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• v.24 no.6
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• pp.1193-1201
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• 2018

Dilatometry is a useful technique to obtain experimental data concerning transformation. In this paper, a dilation conversional model was established to calculate carbides fraction in AISI H13 hot-work tool steel based on the measured length changes. After carbides precipitation, the alloy contents in the matrix changed. In the usual models, the content of carbon atoms after precipitation is considered as the only element that affects the lattice constant and the content of the alloy elements such as Cr, Mo, Mn, V are often ignored. In the model introduced in this paper, the alloying elements (Cr, Mo, Mn, V) changes caused by carbides precipitation are incorporated. The carbides were identified using scanning electron microscope and transmission electron microscope. The relationship between lattice constant of carbides and temperature are measured by high-temperature X-ray diffraction. The results indicate that the carbides observed in all specimens cooled at different rates are V-rich MC and Cr-rich $M_{23}C_6$, and most of them are V-rich MC, only very few are Cr-rich $M_{23}C_6$. The model including the effects of substitutional alloying elements shows a good improvement on carbides fraction predictions. In addition, lower cooling rate advances the carbides precipitation for AISI H13 specimens. The results between experiments and mathematical model agree well.

• Atmosphere
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• v.28 no.4
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• pp.443-455
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• 2018

Nowcasting algorithms using weather radar data are mostly based on extrapolating the radar echoes. We estimate the echo motion vectors that are used to extrapolate the echo properly. Therefore, understanding the general characteristics of these motion vectors is important to improve the performance of nowcasting. General characteristics of radar-based motions are analyzed for warm season precipitation over Jeju region. Three-year summer season data (June~August, 2011~2013) from two radars (GSN, SSP) in Jeju are used to obtain echo motion vectors that are retrieved by Variational Echo Tracking (VET) method which is widely used in nowcasting. The highest frequency occurs in precipitation motion toward east-northeast with the speed of $15{\sim}16m\;s^{-1}$ during the warm season. Precipitation system moves faster and eastward in June-July while it moves slower and northeastward in August. The maximum frequency of speed appears in $10{\sim}20m\;s^{-1}$ and $5{\sim}10m\;s^{-1}$ in June~July and August respectively while average speed is about $14{\sim}15m\;s^{-1}$ in June~July and $8m\;s^{-1}$ in August. In addition, the direction of precipitation motion is highly variable in time in August. The speed of motion in Lee side of the island is smaller than that of the windward side.