• Carbon letters
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• 제13권3호
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• pp.182-186
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• 2012

A new model and resultant equation for the coagulation of acrylonitrile monomers in precipitation polymerization are suggested in consideration of the surface tension (${\gamma}$) and cohesive energy density ($E_{CED}$). The equation was proven to be quite favorable by considering figure fittings from known surface tensions and cohesive energy densities of certain organic solvents. The relationship between scale value of surface tension (${\gamma}$/M) and cohesive energy density of monomers can be obtained by changing the coagulation bath component for effective precipitation polymerization of acrylonitrile in wet spinning.

• 한국전기전자재료학회논문지
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• 제11권9호
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• pp.705-710
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• 1998

Intrinsic gettering is usually to improve wafer quality, which is an important factor for reliable ULSI devices. In order to generate oxygen precipitation in lightly and heavily boron doped silicon wafers with or without high $^75 As^+$ ion implantation, the 2-step annealing method was adopted. After annealing, the were cleaved and etched with th Wright etchant. The morphology of cross section on samples was inspected by FESEM(field emission scanning electron microscopy). The morphology of unimplanted samples was rater rough than that of the implanted. Oxygen precipitation density observed by an optical microscope in lightly boron doped samples was about 3$\times10^6/cm^3$. However, in heavily boron doped samples, the density of oxygen precipitation was largest at $600^{\circ}C$ in 1st annealing, and decreased abruptly until $800^{\circ}C$, But it increased slightly at $1000^{\circ}C$ and was independent with the implantation.

• 대기
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• 제19권2호
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• pp.199-211
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• 2009

In this paper, we examine the multiple change-point and change pattern in the 54 years (1954-2007) time series of the annual and the heavy precipitation characteristics (amount, days and intensity) averaged over South Korea. A Bayesian approach is used for detecting of mean and/or variance changes in a sequence of independent univariate normal observations. Using non-informative priors for the parameters, the Bayesian model selection is performed by the posterior probability through the intrinsic Bayes factor of Berger and Pericchi (1996). To investigate the significance of the changes in the precipitation characteristics between before and after the change-point, the posterior probability and 90% highest posterior density credible intervals are examined. The results showed that no significant changes have occurred in the annual precipitation characteristics (amount, days and intensity) and the heavy precipitation intensity. On the other hand, a statistically significant single change has occurred around 1996 or 1997 in the heavy precipitation days and amount. The heavy precipitation amount and days have increased after the change-point but no changes in the variances.

• 한국수자원학회논문집
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• 제41권3호
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• pp.265-276
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• 2008

수공구조물의 설계를 위해서는 충분한 기간의 관측자료가 필요하지만, 우리나라의 수문자료는 대부분 충분한 수의 관측자료를 보유하고 있지 못하는 실정이다. 따라서 본 연구에서는 핵밀도함수를 이용한 비동질성 Markov 모형을 통해 시간강수량 자료를 모의하였다. 첫 번째로 시간강수량 자료에 변동핵밀도함수를 이용하여 천이확률을 산정하였으며, 두 번째로 난수와 천이확률을 통해 강수가 발생하는 시간을 결정하였다. 세 번째로 강수가 발생한 시간의 강수량의 크기를 핵밀도함수를 통해 추정하였다. 분석결과에서 모의된 시간강수량은 관측시간강수량과 비슷한 통계적 특성을 보이고 있는 것으로 나타났다. 또한, 시간강수량의 모의발생을 위하여 산정한 천이확률을 이용해 강수의 무차원시간분포곡선을 유도하였다.

• 한국세라믹학회지
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• 제34권12호
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• pp.1247-1253
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• 1997

Sinter-active yttria powders were prepared by a solution precipitation with using a self-decomposing precipitation agent NH2CONH2(urea). The cold-pressed powders can be sintered to full density and the microstructure of grains less than 200 nm at a temperature as low as 120$0^{\circ}C$. The activity of the yttria powder has been controlled by varying nucleation conditions during precipitation and by minimizing formation of aggregates. The type of precursor is decisive in preparation of a sinter-active oxide powder, and urea is desirable as a precipitation agent for an active yttrium oxide powder.

• 한국물환경학회지
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• 제24권3호
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• pp.345-353
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• 2008

In order to design storage-based non-point source management facilities, the aspect of statistical features of the entire precipitation time series should be considered since non-point source pollutions are delivered by continuous rainfall runoffs. The 3-parameter mixed exponential probability density function instead of traditional single-parameter exponential probability density function is applied to represent the probabilistic features of long-term precipitation time series and model urban stormwater runoff. Finally, probability density functions of water quality control basin overflow are derived under two extreme intial conditions. The 31-year continuous precipitation time series recorded in Busan are analyzed to show that the 3-parameter mixed exponential probability density function gives better resolution.

• 대기
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• 제18권2호
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• pp.111-120
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• 2008

This study presents a change-point in the 30 years (1976-2005) time series of the annual and the heavy precipitation characteristics (amount, days and intensity) averaged over South Korea using Bayesian approach. The criterion for the heavy precipitation used in this study is 80 mm/day. Using non-informative priors, the exact Bayes estimators of parameters and unknown change-point are obtained. Also, the posterior probability and 90% highest posterior density credible intervals for the mean differences between before and after the change-point are examined. The results show that a single change-point in the precipitation intensity and the heavy precipitation characteristics has occurred around 1996. As the results, the precipitation intensity and heavy precipitation characteristics have clearly increased after the change-point. However, the annual precipitation amount and days show a statistically insignificant single change-point model. These results are consistent with earlier works based on a simple linear regression model.

• 한국분말재료학회지
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• 제23권4호
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• pp.287-296
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• 2016

$Ni_{1/3}Co_{1/3}Mn_{1/3}(OH)_2$ powders have been synthesized in a continuously stirred tank reactor via a co-precipitation reaction between aqueous metal sulfates and NaOH using $NH_4OH$ as a chelating agent. The co-precipitation temperature is varied in the range of $30-80^{\circ}C$. Calcination of the prepared precursors with $Li_2CO_3$ for 8 h at $1000^{\circ}C$ in air results in Li $Ni_{1/3}Co_{1/3}Mn_{1/3}O_2$ powders. Two kinds of obtained powders have been characterized by X-ray diffraction (XRD), scanning electron microscopy, particle size analyzer, and tap density measurements. The co-precipitation temperature does not differentiate the XRD patterns of precursors as well as their final powders. Precursor powders are spherical and dense, consisting of numerous acicular or flaky primary particles. The precursors obtained at 70 and $80^{\circ}C$ possess bigger primary particles having more irregular shapes than those at lower temperatures. This is related to the lower tap density measured for the former. The final powders show a similar tendency in terms of primary particle shape and tap density. Electrochemical characterization shows that the initial charge/discharge capacities and cycle life of final powders from the precursors obtained at 70 and $80^{\circ}C$ are inferior to those at $50^{\circ}C$. It is concluded that the optimum co-precipitation temperature is around $50^{\circ}C$.

• 대기
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• 제29권2호
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• pp.183-196
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• 2019

High-quality and high-resolution meteorological information is essential to reduce damages due to disastrous weather phenomena such as flash flood, strong wind, and heat/cold waves. There are many meteorological observation stations operated by Korea Meteorological Administration (KMA) in Seoul Metropolitan Area (SMA). Nonetheless, they are still not enough to represent small-scale weather phenomena like convective storm cells due to its poor resolution, especially over urban areas with high-rise buildings and complex land use. In this study, feasibilities to use additional pre-existing networks (e.g., operated by local government and private company) are tested by investigating the effects of network density on the gridded horizontal distribution of two meteorological variables (temperature and precipitation). Two heat wave event days and two precipitation events are chosen, respectively. And the automatic weather station (AWS) networks operated by KMA, local-government, and SKTechX in Incheon area are used. It is found that as network density increases, correlation coefficients between the interpolated values with a horizontal resolution of 350 m and observed data also become large. The range of correlation coefficients with respect to the network density shows large in nighttime rather than in daytime for temperature. While, the range does not depend on the time of day, but on the precipitation type and horizontal distribution of convection cells. This study suggests that temperature and precipitation sensors should be added at points with large horizontal inhomogeneity of land use or topography to represent the horizontal features with a resolution higher than 350 m.

• 응용통계연구
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• 제21권3호
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• pp.547-560
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• 2008

스펙트럼 밀도함수(spectral density function)는 시계열 자료가 정상성(stationarity)을 만족하는 경우에 주파수 영역(frrqllrnFr domain)에서 시계열 자료의 자기공분산함수(auto-covariance function)을 결정짓는 함수이고, 평활된 주기도(smoothed periodogram)는 스펙트럼 밀도함수의 일치 추정량(consistent estimator)이 됨이 잘 알려져 있다. 본 연구에서는 시계열 자료를 평활된 주기도를 이용하여 군집화하는 방법을 소개한다. 최근 김희영과 박만식 (2007)의 연구에 의하면 이 거리는 정상시계열들을 효율적으로 분류하고 있음을 알 수 있다. 본 연구는 시계열 자료를 분류하는데 사용된 기존의 거리들을 간략히 소개하고, 우리나라 22개 지역에서 1987년 1월부터 2007년 12월까지 측정한 월별 강수량 자료를 대상으로 평활된 주기도 거리를 이용하여 지역을 군집화한다.