• Carbon letters
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• v.13 no.3
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• pp.182-186
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• 2012

A new model and resultant equation for the coagulation of acrylonitrile monomers in precipitation polymerization are suggested in consideration of the surface tension (${\gamma}$) and cohesive energy density ($E_{CED}$). The equation was proven to be quite favorable by considering figure fittings from known surface tensions and cohesive energy densities of certain organic solvents. The relationship between scale value of surface tension (${\gamma}$/M) and cohesive energy density of monomers can be obtained by changing the coagulation bath component for effective precipitation polymerization of acrylonitrile in wet spinning.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.11 no.9
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• pp.705-710
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• 1998

Intrinsic gettering is usually to improve wafer quality, which is an important factor for reliable ULSI devices. In order to generate oxygen precipitation in lightly and heavily boron doped silicon wafers with or without high $^75 As^+$ ion implantation, the 2-step annealing method was adopted. After annealing, the were cleaved and etched with th Wright etchant. The morphology of cross section on samples was inspected by FESEM(field emission scanning electron microscopy). The morphology of unimplanted samples was rater rough than that of the implanted. Oxygen precipitation density observed by an optical microscope in lightly boron doped samples was about 3$\times10^6/cm^3$. However, in heavily boron doped samples, the density of oxygen precipitation was largest at $600^{\circ}C$ in 1st annealing, and decreased abruptly until $800^{\circ}C$, But it increased slightly at $1000^{\circ}C$ and was independent with the implantation.

• Atmosphere
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• v.19 no.2
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• pp.199-211
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• 2009

In this paper, we examine the multiple change-point and change pattern in the 54 years (1954-2007) time series of the annual and the heavy precipitation characteristics (amount, days and intensity) averaged over South Korea. A Bayesian approach is used for detecting of mean and/or variance changes in a sequence of independent univariate normal observations. Using non-informative priors for the parameters, the Bayesian model selection is performed by the posterior probability through the intrinsic Bayes factor of Berger and Pericchi (1996). To investigate the significance of the changes in the precipitation characteristics between before and after the change-point, the posterior probability and 90% highest posterior density credible intervals are examined. The results showed that no significant changes have occurred in the annual precipitation characteristics (amount, days and intensity) and the heavy precipitation intensity. On the other hand, a statistically significant single change has occurred around 1996 or 1997 in the heavy precipitation days and amount. The heavy precipitation amount and days have increased after the change-point but no changes in the variances.

• Journal of Korea Water Resources Association
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• v.41 no.3
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• pp.265-276
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• 2008

The observed data of enough period need for design of hydrological works. But, most hydrological data aren't enough. Therefore in this paper, hourly precipitation generated by nonhomogeneous Markov chain model using variable Kernel density function. First, the Kernel estimator is used to estimate the transition probabilities. Second, wet hours are decided by transition probabilities and random numbers. Third, the amount of precipitation of each hours is calculated by the Kernel density function that estimated from observed data. At the results, observed precipitation data and generated precipitation data have similar statistic. Also, rainfall mass curve is derived by calculated transition probabilities for generation of hourly precipitation.

• Journal of the Korean Ceramic Society
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• v.34 no.12
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• pp.1247-1253
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• 1997

Sinter-active yttria powders were prepared by a solution precipitation with using a self-decomposing precipitation agent NH2CONH2(urea). The cold-pressed powders can be sintered to full density and the microstructure of grains less than 200 nm at a temperature as low as 120$0^{\circ}C$. The activity of the yttria powder has been controlled by varying nucleation conditions during precipitation and by minimizing formation of aggregates. The type of precursor is decisive in preparation of a sinter-active oxide powder, and urea is desirable as a precipitation agent for an active yttrium oxide powder.

• Journal of Korean Society on Water Environment
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• v.24 no.3
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• pp.345-353
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• 2008

In order to design storage-based non-point source management facilities, the aspect of statistical features of the entire precipitation time series should be considered since non-point source pollutions are delivered by continuous rainfall runoffs. The 3-parameter mixed exponential probability density function instead of traditional single-parameter exponential probability density function is applied to represent the probabilistic features of long-term precipitation time series and model urban stormwater runoff. Finally, probability density functions of water quality control basin overflow are derived under two extreme intial conditions. The 31-year continuous precipitation time series recorded in Busan are analyzed to show that the 3-parameter mixed exponential probability density function gives better resolution.

• Atmosphere
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• v.18 no.2
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• pp.111-120
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• 2008

This study presents a change-point in the 30 years (1976-2005) time series of the annual and the heavy precipitation characteristics (amount, days and intensity) averaged over South Korea using Bayesian approach. The criterion for the heavy precipitation used in this study is 80 mm/day. Using non-informative priors, the exact Bayes estimators of parameters and unknown change-point are obtained. Also, the posterior probability and 90% highest posterior density credible intervals for the mean differences between before and after the change-point are examined. The results show that a single change-point in the precipitation intensity and the heavy precipitation characteristics has occurred around 1996. As the results, the precipitation intensity and heavy precipitation characteristics have clearly increased after the change-point. However, the annual precipitation amount and days show a statistically insignificant single change-point model. These results are consistent with earlier works based on a simple linear regression model.

• Journal of Powder Materials
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• v.23 no.4
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• pp.287-296
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• 2016

$Ni_{1/3}Co_{1/3}Mn_{1/3}(OH)_2$ powders have been synthesized in a continuously stirred tank reactor via a co-precipitation reaction between aqueous metal sulfates and NaOH using $NH_4OH$ as a chelating agent. The co-precipitation temperature is varied in the range of $30-80^{\circ}C$. Calcination of the prepared precursors with $Li_2CO_3$ for 8 h at $1000^{\circ}C$ in air results in Li $Ni_{1/3}Co_{1/3}Mn_{1/3}O_2$ powders. Two kinds of obtained powders have been characterized by X-ray diffraction (XRD), scanning electron microscopy, particle size analyzer, and tap density measurements. The co-precipitation temperature does not differentiate the XRD patterns of precursors as well as their final powders. Precursor powders are spherical and dense, consisting of numerous acicular or flaky primary particles. The precursors obtained at 70 and $80^{\circ}C$ possess bigger primary particles having more irregular shapes than those at lower temperatures. This is related to the lower tap density measured for the former. The final powders show a similar tendency in terms of primary particle shape and tap density. Electrochemical characterization shows that the initial charge/discharge capacities and cycle life of final powders from the precursors obtained at 70 and $80^{\circ}C$ are inferior to those at $50^{\circ}C$. It is concluded that the optimum co-precipitation temperature is around $50^{\circ}C$.

• Atmosphere
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• v.29 no.2
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• pp.183-196
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• 2019

High-quality and high-resolution meteorological information is essential to reduce damages due to disastrous weather phenomena such as flash flood, strong wind, and heat/cold waves. There are many meteorological observation stations operated by Korea Meteorological Administration (KMA) in Seoul Metropolitan Area (SMA). Nonetheless, they are still not enough to represent small-scale weather phenomena like convective storm cells due to its poor resolution, especially over urban areas with high-rise buildings and complex land use. In this study, feasibilities to use additional pre-existing networks (e.g., operated by local government and private company) are tested by investigating the effects of network density on the gridded horizontal distribution of two meteorological variables (temperature and precipitation). Two heat wave event days and two precipitation events are chosen, respectively. And the automatic weather station (AWS) networks operated by KMA, local-government, and SKTechX in Incheon area are used. It is found that as network density increases, correlation coefficients between the interpolated values with a horizontal resolution of 350 m and observed data also become large. The range of correlation coefficients with respect to the network density shows large in nighttime rather than in daytime for temperature. While, the range does not depend on the time of day, but on the precipitation type and horizontal distribution of convection cells. This study suggests that temperature and precipitation sensors should be added at points with large horizontal inhomogeneity of land use or topography to represent the horizontal features with a resolution higher than 350 m.

• The Korean Journal of Applied Statistics
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• v.21 no.3
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• pp.547-560
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• 2008

It is well known that spectral density function determines auto-covariance function of stationary time-series data and smoothed periodogram is a consistent estimator of spectral density function. Recently, Kim and Park (2007) showed that smoothed- periodogram based distances performs very well for the classification. In this paper, we introduce classification methods with smoothed periodogram and apply the approaches to the monthly precipitation measurements obtained from January, 1987 through December, 2007 at 22 locations in South Korea.