• Title/Summary/Keyword: Pr$^{3+}$

Search Result 1,590, Processing Time 0.028 seconds

Do Clinical Features and Survival of Single Hormone Receptor Positive Breast Cancers Differ from Double Hormone Receptor Positive Breast Cancers?

  • Ng, Char-Hong;Pathy, Nirmala Bhoo;Taib, Nur Aishah;Ho, Gwo-Fuang;Mun, Kein-Seong;Rhodes, Anthony;Looi, Lai-Meng;Yip, Cheng-Har
    • Asian Pacific Journal of Cancer Prevention
    • /
    • v.15 no.18
    • /
    • pp.7959-7964
    • /
    • 2014
  • The significance of the single hormone receptor positive phenotype of breast cancer is still poorly understood. The use of hormone therapy has been found to be less effective for this type, which has a survival outcome midway between double positive and double negative phenotypes. The aim of this study was to investigate differences in patient and tumor characteristics and survival between double-receptor positive (ER+PR+), double receptor negative (ER-PR-) and single receptor positive (ER+PR- and ER-PR+) breast cancer in an Asian setting. A total of 1,992 patients with newly diagnosed stage I to IV breast cancer between 2003 and 2008, and where information on ER and PR were available, were included in this study. The majority of patients had ER+PR+ tumors (n=903: 45.3%), followed by 741 (37.2%) ER-PR-, 247 (12.4%) ER+PR-, and 101 (5.1%) ER-PR+ tumors. Using multivariate analysis, ER+PR- tumors were 2.4 times more likely to be grade 3 compared to ER+PR+ tumors. ER+PR- and ER-PR+ tumors were 82% and 86% respectively less likely to be grade 3 compared with ER-PR- tumors. ER-PR+ tumours were associated with younger age. There were no survival differences between patients with ER+PR+ and ER-PR+ tumors. However, ER+PR- tumors have poorer survival compared with ER+PR+ tumours. ER-PR- tumours had the worst survival. Adjuvant hormonal therapy with tamoxifen was found to have identical survival advantage in patients with ER+PR+ and ER-PR+ tumors whereas impact was slightly lower in patients with ER+PR- tumors. In conclusion, we found ER+PR- tumors to be more aggressive and have poorer survival when compared to ER+PR+ tumors, while patients with ER-PR+ tumours were younger, but had a similar survival to their counterparts with ER+PR+ tumours.

Influence of $Pr_6O_{11}/CoO$ Composition Ratio on I-V Characteristics of $ZnO-Pr_6O_{11}-CoO-Dy_2O_3$ Based varistors ($ZnO-Pr_6O_{11}-CoO-Dy_2O_3$계 바리스터의 I-V 특성에 $Pr_6O_{11}/CoO$ 조성비 영향)

  • Nahm, Choon-Woo;Ryu, Jung-Sun;Yoon, Han-Soo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 2000.05b
    • /
    • pp.179-184
    • /
    • 2000
  • The I-V characteristics of $ZnO-Pr_6O_{11}-CoO-Dy_2O_3$ based varistors were investigated in the $Pr_6O_{11}/CoO$ composition ratio range of 0.5/0.5 to 1.0/1.0 and sintering temperature range of 1300 to $1350^{\circ}C$ as the basic study to develop the advanced $Pr_6O_{11}$-based ZnO varistors. All varistors except for $Pr_6O_{11}$/CoO = 0.5/1.0 exhibited the best I-V characteristics at $1350^{\circ}C$. However, the varistors with $Pr_6O_{11}$/CoO= 0.5/1.0 exhibited the best I-V characteristics at $1350^{\circ}C$. The varistors with $Pr_6O_{11}$/CoO= 0.5/1.0 of all varistors exhibited the best I-V characteristics, which the nonlinear exponent is 36.9 and the leakage current is 7.6 ${\mu}A$ Therefore, it was estimated that ZnO-$Pr_6O_{11}-CoO-Dy_2O_3$ ceramics with $Pr_6O_{11}$/CoO= 0.5/1.0 will be usefully used as varistor materials in the future.

  • PDF

Structural and Magnetic Studies on Electrochemically Lithiated $PrBa_2Cu_3O_y$

  • Choy, Jin-Ho;Chun, Sung-Ho;Kang, Seong-Gu
    • Bulletin of the Korean Chemical Society
    • /
    • v.11 no.6
    • /
    • pp.564-567
    • /
    • 1990
  • A lithiated compound $Li_{0.1}Pr^{3+}Ba_2Cu_3O_y$ has been successfully prepared by electrochemical method, which is achieved with a two electrode cell of the type: Metal(Li)/($Li^+\;,\;ClO_4^-$) + propylene carbonate/$PrBa_2Cu_3O_y$. All Pr ions in the lithiated compound are stabilized with a trivalent state as the other rare earths (Ⅲ) substituted in the 90K superconductor lattice ($Y_{1-x}Ln_x^-Ba_2Cu_3O_{7-{\delta}}$). Powder X-ray diffraction analysis shows that both compounds, $PrBa_2Cu_3O_y$ and $Li_{0.1}PrBa_2Cu_3O_y$ are isostructural with the 90 K superconductor, ($YBa_2Cu_3O_{7-{\delta}}$), nevertheless both of them are non-metallic and also non-superconducting down to 10 K. Magnetic susceptibility ${\chi}$ vs. temperature data indicate that Curie contribution from the magnetic ions (Pr and Cu) is weakened on the one hand, but on the other hand temperature-independent part of susceptibility ${\chi}_o$ increases depending upon the rate of lithium intercalation in $PrBa_2Cu_3O_y$ lattice.

Emitting Level Change and Enhancement of Red Emission from $SrTiO_3:Pr^{3+}$ by $Y^{3+}$ Addition

  • An, Hee-Kyung;Suh, Kyung-Soo;Lee, Jin-Ho;Cho, Kyoung-Ik;Kang, Shin-Hoo
    • 한국정보디스플레이학회:학술대회논문집
    • /
    • 2000.01a
    • /
    • pp.33-34
    • /
    • 2000
  • The effect of $Y^{3+}$ addition to $SrTiO_3:Pr^{3+}$ on the photoluminescence and cathodoluminescence was studied. We discovered that light emitting levels of $Pr^{3+}$ vary by addition of $Y^{3+}$. In $(Sr_{1-x}Y_x)TiO_3:Pr^{3+}$, both the green and red emission are discovered while the red emission prevails in $Sr(Ti_{1-x}Y_x)O_3:Pr^{3+}$ . $Sr(Ti_{1-x}Y_x)O_3:Pr^{3+}$ shows enhancement of red emission by two kinds of enhancement process.

  • PDF

The Effect of Pr Additive on Magnetostriction of Amorphous Fe-B Alloy (Pr 첨가가 Fe-B 비정질합금의 자왜에 미치는 영향)

  • 조용수;김윤배;김창석;김택기
    • Journal of the Korean Magnetics Society
    • /
    • v.4 no.2
    • /
    • pp.126-129
    • /
    • 1994
  • In order to invetigate the effect of Pr additive on the magnetostriction of amorphous Fe-B alloys, amorphous $Fe_{86-x}B_{14}Pr_{x}(2{\leq}x{\leq}8\;at.%)$ alloys were prepared by a rapid solidification process. As the Pr content increased in the as-prepared amorphous $Fe_{84}B_{14}Pr_{2}$ alloy annealed at $300^{\circ}C$ for 2 hr increased to 70 ppm. Ac power loss and permeability$(f=50\;kHz,\;B_{m}=0.1\;T)$ of the annealed amorphous $Fe_{84}B_{14}Pr_{2}$ alloy were 15 W/kg and $5.5{\times}10^{3}$, respectively.

  • PDF

Synthesis and characterization of CaZrO3:Pr3+ phosphor by skull melting method (스컬용융법에 의한 CaZrO3:Pr3+ 형광체 합성 및 특성분석)

  • Choi, Hyunmin;Kim, Youngchool;Seok, Jeongwon
    • Journal of the Korean Crystal Growth and Crystal Technology
    • /
    • v.31 no.5
    • /
    • pp.228-232
    • /
    • 2021
  • Ca1-xZrO3:xPr phosphor with perovskite structure was successfully synthesized by using skull melting method. The crystal structure, morphology and optical properties of synthesized phosphor were characterized using X-ray diffraction (XRD), scanning electron microscopy (SEM), ultraviolet fluorescence reaction and photoluminescence. The XRD results indicated that single crystals of CaZrO3:Pr3+ belongs to orthorhombic perovskite system. The synthesized phosphor could be excited by UV light (254 nm) and the emission spectra results indicated that green luminescence of CaZrO3:Pr3+ due to charge transfer transition 3P03H4, 3P13H5 and 3P03H5 at 506, 536 and 548 nm was dominant.

A Semi-graphical Analysis on the Sublattice Anisotropy of a Two Sublattice System with Uniaxial Anisotropy: Application to Pr2Fe14B

  • Kim, Y.B.;Jin-Han-Min
    • Journal of Magnetics
    • /
    • v.3 no.3
    • /
    • pp.74-77
    • /
    • 1998
  • A method to analyze the anisotropy constants of a two sublattice system with uniaxial anisotropy has been investigated by extending the Sucksmith and Thompson's method to higher order anisotropy terms. Using the method, a set of anisotropy constants for Pr-sublattice of $Pr_2Fe_{14}B at 4.2K has been obtained as K_{1Pr}=5210 J/kg, K_{2Pr}=-7200 J/kg, K_{3Pr}=-770 J/kg, K_{4Pr}=4940 J/kg and K_{SPr}=700 J/kg for N_{PrFe}=2.2 T/Am^2kg^{-1}.$ The magnetization calculated by an energy minimum method by using the sublattice anisotropy constants well reproduced the experimental results and satisfied the simulation assumptions.

  • PDF

$Pr^{3+}-and$ $Pr^{3+}/Er^{3+}$-Doped Selenide Glasses for Potential $1.6{\mu}m$ Optical Amplifier Materials

  • Choi, Yong-Gyu;Park, Bong-Je;Kim, Kyong-Hon;Heo, Jong
    • ETRI Journal
    • /
    • v.23 no.3
    • /
    • pp.97-105
    • /
    • 2001
  • $1.6\;{\mu}m$ emission originated from $Pr^{3+}:\;(^3F_3,\;^3F_4)\;{\longrightarrow}\;^3H_4$ transition in $Pr^{3+}-\;and\;Pr^{3+}/Er^{3+}$-doped selenide glasses was investigated under an optical pump of a conventional 1480 nm laser diode. The measured peak wavelength and fullwidth at half-maximum of the fluorescent emission are ~1650nm and 120nm, respectively. A moderate lifetime of the thermally coupled upper manifolds of ${\sim}212{\pm}10{\mu}s$ together with a high stimulated emission cross-section of ${\sim}(3{\pm}1){\times}10^{-20}\;cm^2$ promises to be useful for $1.6{\mu}m$ band fiber-optic amplifiers that can be pumped with an existing high-power 1480 nm laser diode. Codoping $Er^{3+}$ enhances the emission intensity by way of a nonradiative $Er^{3+}:\;^4I_{13/2}\;{\longrightarrow}\;Pr^{3+}:\;(^3F_3,\;^3F_4)$ energy transfer. The Dexter model based on the spectral overlap between donor emission and acceptor absorption describes well the energy transfer from $Er^{3+}$ to $Pr^{3+}$ in these glasses. Also discussed in this paper are major transmission loss mechanisms of a selenide glass optical fiber.

  • PDF

A Study on the PR Method of Cadastral Re-survey Project Using Hutton's PR Model (허튼(Hutton)의 PR모델을 이용한 지적재조사 홍보 방법)

  • Park, Kwang-Soon;Hong, Sung-Eon
    • Journal of the Korea Academia-Industrial cooperation Society
    • /
    • v.10 no.3
    • /
    • pp.684-694
    • /
    • 2009
  • This study is aimed at looking into the PR method of cadastral re-survey, and at looking for the reason of the delay of cadastral re-survey project. We thought that the reason why the cadastral re-survey project was delayed was a lack of a national agreement on it owing to an insufficient PR. So, to solve this question, we proposed an alternative plan for the PR method of cadastral re-survey, using Hutton's PR model. As a result of a study, a total of 31 PR methods was made which were apt for every practical PR on the basis of 6 three-dimensional models of PR practice. But, some of Hutton's PR models proved to be unfit for the cadastral re-survey project. Therefore, we formed and proposed a new model to apt for the cadastral re-survey project. The result of this study is expected to be of help in getting a foundation to form a national agreement on the quick operation of a upcoming cadastral re-survey project.

Chloro- and Hydrido Complexes of (Pentamethylcyclopentadienyl) bis(phosphine)ruthenium ((펜타메틸시클로펜타디에닐) 비스(포스핀)루테늄의 염화물과 수소화물 유도체)

  • Dong-Hwan Lee
    • Journal of the Korean Chemical Society
    • /
    • v.36 no.2
    • /
    • pp.248-254
    • /
    • 1992
  • Bis(phosphine)ruthenium derivatives $({\eta}^5-C_5Me_5)RuCl(PR_3)_2(PR_3=PMe_3,\; PMe_2Ph,\;PEt_3,\;PMePh_2$, 1/2DPPE, 1/2DPPB) (2a${\sim}$2f) have been synthesized by the reaction of $[({\eta}^5-C_5Me_5)RuCl_2]_2$ (1) with excessive phosphine in ethanol. The reaction of complexes $({\eta}^5-C_5Me_5)Ru(PR_3)_2Cl\;with\;NaBH_4$ in ethanol gave the corresponding hydride complexes $({\eta}^5-C_5Me_5)Ru(PR_3)_2H (PR_3=PMe_3, PEt_3, PMePh_2$, 1/2 DPPE, 1/2DPPB) (3a${\sim}$3e). Chloride complexes (2a${\sim}$2f) and hydride complexes (3a${\sim}$3e) were isolated as crystals, which were characterized by IR, $^1H-NMR$ , and elemental analysis.

  • PDF