• 제목/요약/키워드: Pozzolanic Reaction

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Effect of curing on alkalinity and strength of cement-mortar incorporating palm oil fuel ash

  • Payam Shafigh;Sumra Yousuf;Belal Alsubari;Zainah Ibrahim
    • Advances in concrete construction
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    • 제15권3호
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    • pp.191-202
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    • 2023
  • Palm oil fuel ash (POFA) is a newly emerging pozzolanic material having high amount of silica content. Various forms of POFA were used in cement-based materials (CBMs) in replacement of cement in different dosages of low and high volume. Although, there are many researches on POFA to be used in concrete and mortar, however, this material was not practically used in the construction industry. Engineers and designers need to be confident to use any new developed materials by knowing all engineering properties at short and long terms. As durability concern, concrete pH value is one of the most important properties. Portland cement produces are alkaline initially, however, it may be reduced due to aging and its components. It is believed that by incorporation of supplementary cementitious materials in CBMs the pH value reduces due to utilization of Ca(OH)2 in pozzolanic reaction. This study is the first attempts to understand the pH value of mortars containing up to 30% POFA under different curing conditions and its changes with time. The results were also compared with the pH of ground granulated ballast furnace slag (GGBFS) and fly ash (FA) content mortars. In addition, the compressive strength of different mortars under different curing conditions were also studied. The results showed that the pH value of control mix (without cementitious materials) was more than all the blended cement mortars indifferent curing conditions at the same ages. However, there was a reducing trend in the pH value of all mortar mixes containing POFA.

PMM for Surface Treatment of Concrete with the Utilization of By-Products

  • Drochytka, Rostislav;Zizkova, Nikol
    • International Journal of Concrete Structures and Materials
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    • 제2권1호
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    • pp.49-55
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    • 2008
  • The disadvantage of PMM's (polymer-modified mortars) that are currently on the market is the utilization of expensive polymer additives and also the cost of the other components. One of the possibilities how to decrease this price is the effective utilization of waste materials which are very inexpensive in spite of their good properties. The combinations of different degree in polymer adhesiveness and waste secondary raw materials - fly ash - are experimentally verified in the paper. The use of fly ash in adhesive materials for ceramic tiles is limited by unsatisfactory initial adhesiveness to sintered ceramic sherd as a result of a running pozzolanic reaction that lowers the efficiency of polymer additives. On the other hand, the use of adhesive and backfill coating materials for gluing ETICS board insulation materials has brought very good results.

납슬러지 고형화 및 용출 특성 (The Characteristics of Solidification and Leachability of Lead Sludge)

  • 연익준;주소영;김광렬
    • 환경위생공학
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    • 제14권3호
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    • pp.22-30
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    • 1999
  • This study was carried out to examine the compressive strength characteristics of solids solidified with the lead sludge with mixture of cement and fly ashes as additive. And the additives are commercial fly ash and ESP(Electrostatic precipitator) fly ash. The compressive strength of solidified lead sludge solid was increased by adding fly ash up to 46~62%, which was the results of pozzolanic reaction. When replaced the cement with 10%of commercial fly ash, the solid showed the highest value $210{\;}kg/cm^2$, and the solidification conditions were 0.55 of the water/cement ratio and curing for 14 days. Also, the results of leaching test by EPT(Environmental Protection Agency-Toxicity Test) were showed that the solidified lead has leached out under 10%, which was less than 0.173 mg/L of EPA standard. As leaching solutions, the demineralized water, 0.1N acetic acid solution, and synthetic brine were used. and the observations by SEM of the solidified lead-laden solid after EPT leaching test were indicated the severe erosion on solid surface.

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제지 슬러지 소각회의 시멘트 혼화 재료로서의 이용 가능성에 관한 연구 (A Study on the Capability to Use with Admixture Material of Paper Sludge Ash)

  • 김재진;문경주;노병남;문성필;소양섭
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 1999년도 학회창립 10주년 기념 1999년도 가을 학술발표회 논문집
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    • pp.89-92
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    • 1999
  • The purpose of this study is to evaluate the capability to use with cement admixture materials because Paper Sludge Ash consists of Si, Ca and Al which are chief content in Pozzolan. For the derivation of Pozzolanic reaction in Paper Sludge Ash, it is measured compressive strength on cement mortar which is replaced mixing of Paper Sludge Ash and inorganic admixture ; ie, gypsum, lime and slaked lime, regularly. In the result of test, the strength decrease remarkably when cement is only replaced with Paper Sludge Ash, but the strength is almost equal when cement is replaced with Paper Sludge Ash is mixed with inorganic admixture material in proportions of 5~15%. Consequently, It is possible to use Paper Sluge Ash with admixture materials of cement.

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플라이애시 및 실리카흄을 사용한 고강도유동화콘크리트의 공학적 특성에 관한 실험적 연구 (제1보, 아직 굳지않은 콘크리트의 시공성 검토) (An Experimental Study on the Engineering Properties of High Strength Flowing Concrete Using Flyash and Silicafume (Part I. Workability of Fresh Concrete))

  • 김진만;이상수;김규용;김무한
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 1994년도 가을 학술발표회 논문집
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    • pp.161-166
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    • 1994
  • Production of high strength concrete requires a low water-cement ratio and this leads to the high cement content. Mineral admixture like fly ash(FA) is often cheaper than ordinary portland cement(OPC) and this factor in combination with possible improvement in workability and moderation of the heat evolution of the cement-rich mixes tends to encourage its use. The other mineral admixture that its use has been widly advocated is silica fume that increases compressive strength due to its pozzolanic reaction. The objective of this study is to assess the contribution of mineral admixtures(FA, SF) to the workability and the strength of concrete with low water-binder ratios. In this experimental study that investigates and analyzes the properties of fresh concrete, it is presented that using admixtures like flysh and silica fume as binding material increases properties of high strength flowing concrete having very low water cementitious ratios of 0.25 and 0.30.

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플라이애시 및 실리카흄을 사용한 고강도유동화 콘크리트의 공학적 특성에 관한 실 험적 연구 (제 2보. 경화콘크리트의 공학적 특성 검토) (An Experimental Study on the Engineering Properties of High Strength Flowing Concrete Using Flyash and Silicafume (Part 2. Engineering Properties of Hardened concrete))

  • 김진만;이상수;김규용;김무한
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 1995년도 봄 학술발표회 논문집
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    • pp.84-87
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    • 1995
  • Production of high strength concrete requires a low water-cement ratio and this leads to the high cement content. Mineral admixture like fly ash(FA) is often cheaper than ordinary portland cement(OPC) and this factor in combination with possible improvement in workability and moderation of the heat evolution of the cement-rich mixes tends to encourage its use. The other mineral admisture that its use has been widly advocated is silica fume that increases compressive strength due to its pozzolanic reaction. The objective of this study is to assess the contribution of mineral admixtures(FA, SF) to the workability and the strength of concrete with low water-binder ratios. In this experimental study that investigates and analyzes the properties of fresh concrete. it is presented that using admixtures like flyash and silica fume as binding material increases properties of high strength flowing concrete having very low water cementitious ratios of 0.25 and 0.30.

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플라이애쉬를 혼입한 콘크리트의 염화물 확산특성 (The properties of chloride ion diffusion in concrete with Fly-ash)

  • 박정준;고경택;김도겸;김성욱;하진규
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2002년도 봄 학술발표회 논문집
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    • pp.207-212
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    • 2002
  • Reportedly, the use of mineral admixtures make concrete more durable and tighten against water. But, it is needed to study more about the relationship between the admixtures and the chloride ion diffusion. When concrete is mixed with fly-ash, pozzolanic reaction occur to time. So we should consider the factors that can evaluate inner structure of concrete in order to evaluate the chloride diffusion of the concrete more accurately. Therefore, in this study, we analyzed the correlation between chloride ion diffusion and physical properties such as compressive strength, void ratio, air permeability of the concrete, and tried to use them as fundamental data for analyzing chloride ion diffusion mechanism of the concrete mixed with fly-ash.

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Strength Characteristics of Stabilized Dredged soil and Correlation with Index Properties

  • 김윤태;도탕하이;강효섭
    • 한국지반공학회:학술대회논문집
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    • 한국지반공학회 2010년도 춘계 학술발표회
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    • pp.489-494
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    • 2010
  • A geo-composite soil (GCS) is a stabilized mixture of bottom ash, cement and dredged soil. Various samples with different mass ratios of mixtures were tested under curing time of 7 and 28 days to investigate physical properties and compressive strength. This paper focused on the effect of bottom ash on the strength characteristics of Busan marine dredged soil. Cement has been added as an additive constituent to enhance self-hardening of the blended mixture. The unconfined compressive strength of GCS increases with an increase in curing time due to pozzolanic reaction of the bottom ash. The strength after 28 days of curing is found to be approximately 1.3 to 2.0 times the strength after 7 days of curing, regardless of mixture conditions. The secant modulus of GCS is in the range of 55 to 134 times the unconfined compressive strength. The correlation of unconfined compressive strength with bottom ash content and initial void ratio are suggested.

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혼합재를 사용한 시멘트경화체의 동결융해 저항성 (Freezing and Thawing Resistance of Hardened Cement Paste Containing Blending Materials)

  • 이양수;김정환;최상흘;한기성
    • 한국세라믹학회지
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    • 제27권3호
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    • pp.437-443
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    • 1990
  • The resistivity of cement paste and mortar for freezing and thawing was investigated for densifying the structure of cement paste and mortor, slag, diatomaceous earth and fly ash as blending materials and superplasticizer were used, and air entraining agent was added to absorb the volume expansion by freezing and thawing reaction. And then the specimens were subjected to freeze-thaw in water. When both of air entraining agent and superplasticizer as additives were mixed to specimens, their freeze-thaw resistance was enhanced by the air entraining effect and the water reduction effect. When 4% of slag were added to cement, freeze-thaw resistance was especially excellent. In addition, it was found that the specimens with blending materials were more influenced by curing periods than those without admixture. It is assumed that the curing periods contribute to exibit the potential hydraulicity and pozzolanic reactivity of blending materials and to densify their texture.

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고로슬래그 미분말이 초고강도 SFRCC의 압축강도에 미치는 영향 (Influence of Ground Granulated Blast-Furnce Slag on Compressive Strength of Ultra-High Strength SFRCC)

  • 박정준;고경택;류금성;강수태;김성욱
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2005년도 추계 학술발표회 제17권2호
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    • pp.399-402
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    • 2005
  • In ultra-high strength SFRCC(Steel Fiber Reinforced Cementious Composites), much silica fume are used to improve strength, flowability and durability. Silica fume have merits of filling the voids, enhancement of reheological chracteristics, production of secondary hydrates by pozzolanic reaction in reactive powder concretes. However silica fume has been imported in high-cost in domestic industry, we need to investigate replaceable material in stead of silica fume in a view of economy Therefore, in this paper, in order to investigate replacement of silica fume in ultra-high strength SFRCC we used the granulate blast-furnce slag with finess 4000, 6000, 8000. As a results, we have evaluated that the bigger the finess the more increase compressive strength of ultra-high strength SFRCC using the blast-furnce slag and there was no problem from the viewpoint of flowability and compressive strength when we use blast-furnce $50\%$ with replacement ratio of silica fume

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