• 한국진공학회:학술대회논문집
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• 한국진공학회 2011년도 제40회 동계학술대회 초록집
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• pp.345-345
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• 2011

MgO는 암염구조를 가진 전형적인 이온 결합성 화합물로서 7.8eV의 띠틈을 갖고 흡습성이 강하다. 면 방전 구조 PDP에서 MgO 보호막은 면 방전으로 인한 유전층의 식각을 보호하고 2차 전자 방출을 통해 방전 전압을 낮추는 역할을 한다. 하지만 MgO 보호막은 증착시 흡수된 수분이 제거되어야 하고, 방전 특성 개선 및 방전 효율 향상을 위해 가공 처리에 관한 연구가 진행 되어야 한다. 본 연구는 MgO 보호막의 전자적 특성의 변화를 알아보기 위해 $O_2$ 분위기에서 전자빔 증착법을 이용해 MgO Powder를 사용하여 시료를 제작하였다. 표면에 흡착된 수분제거로 인한 특성 변화를 알아보기 위해 진공 챔버내에서 시료를 $500^{\circ}C{\sim}550^{\circ}C$의 열처리를 실시한 후 XPS(X-ray Photoelectron Spectroscopy), REELS(Reflection Electron Energy Loss Spectroscopy), UPS(Ultraviolet photoelectron Spectroscopy)를 이용하여 전자적 특성을 연구하였다. XPS 측정결과 시료의 열처리를 통해 C1s spectrum의 O-C=O(289eV) binding energy가 없어져 박막에 흡착된 불순물이 제거 되었으며 O1s spectrum에서 Hydroxides가 감소하고 530.0eV의 MgO 결합에너지쪽으로 커짐으로써 박막의 구조를 확인할 수 있었다. 그리고 $O^2$ 분위기에서 성장시킨 MgO 박막 기판을 열처리 후 REELS를 이용해 띠틈을 얻어보면 Ep=500eV에서 띠틈이 6.77eV, Ep=1500eV에서 띠틈이 7.33eV로 각각 측정되었다. Ep=500eV의 REELS 스펙트럼으로부터 산소 결함에 의한 표면 F Center는 4.22eV로 확인되었다.

• Macromolecular Research
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• 제12권4호
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• pp.399-406
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• 2004

Glass-like carbon precursors shrink significantly during curing and carbonization, which leads to crack formation and bending. Cured furan resin powder and ethanol were added to furan resin to diminish the weight loss, to suppress the shrinkage and bending, and to readily release the gases evolved during polymerization and curing. Curing and carbonization were controlled by pressure and slow heating to avoid damage to the samples. The effect of the filler and ethanol on the fabrication process was examined by measuring the properties of the glass-like carbon, such as the specific gravity, bending strength, electrical resistivity, and microstructural change. The specific gravities of the filler-added glass-like carbons were higher than those of the ethanol-added samples because of the formation of macropores from the vaporization of ethanol during the curing and polymerization processes. Although the ethanol-added glass-like carbons exhibited lower bending strengths after carbonization than did the filler-added samples, the opposite result was observed after aging at 2,600$^{\circ}C$. We found that the macropores created from ethanol were contracted and removed upon heat treatment. The electrical resistivity of the glass-like carbon aged at 2,600$^{\circ}C$ was lower than those of the samples carbonized at 1,000$^{\circ}C$. We attribute this phenomenon to the fact that aging at high temperature led to well-developed microstructures, the removal of macropores, and the reduction of the surface area.

• 동아시아식생활학회지
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• 제24권6호
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• pp.883-895
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• 2014

This study investigated quality characteristics of pan breads prepared with 0, 10, 20, 30 and 40% purple rice flour and naturally fermented blueberry-rice starters. RVA (Rapid Visco Analyzer) analysis showed that wheat flour retrogradation was not retarded by addition of purple rice flour. Using amylography, gelatinization tem. perature of purple rice flour samples was higher than that of the control, whereas maximum viscosity temperature. and maximum viscosity of purple rice flour samples were lower than those of the control. Weights of pan breads containing purple rice flour were lower than that of the control, whereas volume, specific volume and baking loss rate were higher than those of the control. The anthocyanin contents and antioxidative activites as measured by DPPH radical scavenging activity of breads increased as the concentration of purple rice flour increased. The moisture content of pan breads containing purple rice flour decreased as storage time increased. The pH of breads containing purple rice flour was higher than that of the control. Color L value decreased, whereas a and b values increased significantly, as storage time increased. In texture analyzer measurement, hardness of breads containing purple rice flour significantly increased as storage time increased. Breads containing 10~20% purple rice flour showed acceptable sensory properties, such as mouth feel, appearance, flavor, texture, taste and overall acceptability.

• 한국재료학회지
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• 제25권6호
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• pp.274-278
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• 2015

The possibility of using the chemical precipitation method of up-cycled ammonium paratungstate (APT) was studied and compared with the thermal decomposition method. $WO_3$ particles were synthesized by chemical precipitation method using a 1:2 weight ratio of APT: Di-water. For thermal decomposition, APT powder was heated for 4h at $600^{\circ}C$ in air atmosphere. The reaction products were characterized by X-ray diffraction (XRD), X-ray fluorescence spectrometer (XRF), particle size analyzer (PSA), and field emission-scanning electron microscopy (FE-SEM). Thermogravimetric analysis (TGA) of the up-cycled APT allowed for the identification of the sequence of decomposition and reduction reactions that occurred during the heat treatment. TGA data indicated a total weight loss of 10.78% with the reactions completed in $658^{\circ}C$. The XRD results showed that APT completely decomposed to $WO_3$ by thermal decomposition and chemical precipitation. The particle size of the synthesized $WO_3$ powders by thermal decomposition with 2 h of planetary milling was around $2{\mu}m$ During the chemical precipitation process, the particle size of the synthesized $WO_3$ powders showed a round-shape with ${\sim}0.6{\mu}m$ size.

• Journal of Welding and Joining
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• 제26권4호
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• pp.50-54
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• 2008

In this research, anode for SOFC has been manufactured from two different kinds of feedstock materials through thermal spraying process and the properties of the coatings were characterized and compared. One kind of feedstock was manufactured from spray drying method which includes nano-components of NiO, YSZ (300 nm) and graphite. And the other is manufactured by blending the micron size NiO coated graphite, YSZ and graphite powders as feedstock materials. Microstructure, mechanical properties and electrical conductivity of the coatings as-sprayed, after oxidation and after hydrogen reduction containing nano composite which is prepared from spray-dried powders were evaluated and compared with the same properties of the coatings prepared from blended powder feedstock. The coatings prepared from the spray dried powders has better properties as they provide larger triple phase boundaries for hydrogen oxidation reaction and is expected to have lower polarization loss for SOFC anode applications than that of the coatings prepared from blended feedstock. A maximum electrical conductivity of 651 S/cm at $800^{\circ}C$ was achieved for the coatings from spray dried powders which much more than that of the average value.

• 콘크리트학회논문집
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• 제14권3호
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• pp.275-282
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• 2002

고유동 콘크리트를 제조할 경우는 유동성 향상을 위한 다량의 고성능 감수제와 재료분리를 방지하기 위한 다량의 분체 혹은 증점제로 말미암아 제조비용이 고가이고, 또한 품질관리에도 많은 어려움이 있다. 그러므로, 본 연구에서는 유동성 및 재료분리 저항성이 우수한 고유동 콘크리트를 경제적으로 제조하기 위하여 분리저감형 유동화제의 최적배합비를 결정한 다음, 유동화 공법으로 접근하는 것을 검토하였다. 실험결과로 유동화제 첨가량이 증가할수록 유동성 및 블리딩량은 증가하였고, 공기량 및 재료분리저항성은 저하하는 것으로 나타났다. 따라서, 여기에 증점제를 첨가함에 따라 양호한 유동성에서 블리딩량이 저하하였고, 재료분리저항성도 증대되었는데, 마지막으로 AE제량 증가에 따라 저하된 공기량이 회복되므로써 양질의 분리저감형 유동화제로 최적배합비를 결정할 수 있었다. 경화 콘크리트 특성으로 유동화 공법으로 제조된 고유동 콘크리트의 압축강도는 베이스 콘크리트보다 증가하는 것으로 나타났고, 무다짐 공시체의 압축강도는 표준다짐 공시체의 압축강도와 유사한 것으로 나타나 다짐 방법간의 차이는 없는 것으로 나타났다.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2008년도 춘계 학술발표회 제20권1호
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• pp.365-368
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• 2008

본 연구에서는 극히 낮은 물-결합재비를 갖는 240MPa 초고강도 콘크리트를 개발하고자 분말도가 높아 반응속도가 빠르며, 조기강도가 우수하나 극히 낮은 물-시멘트비에서 더욱 우수한 유동성을 확보할 수 있는 고강도용 '하이플로 시멘트'를 주원료로 하고, 기타 초고강도용 혼합재로 실리카흄, 슬래그 미분말 및 특수 혼합재 등을 사용한 다성분계 시멘트 결합재의 최적조합을 도출하였으며, 시멘트 결합재의 분산성과 균질성을 확보하기 위하여 고효율 초고속전단 옴니믹서를 사용하여 프리믹스 타입의 시멘트를 제조하였다. 또한 고속믹싱방법을 통해 초고강도 콘크리트의 유동성을 확보하였으며, 초고강도용 특수골재를 선정하여 실험을 실시한 결과, 수중양생을 실시한 경우 180MPa이상의 강도를 확보하였으며, 증기양생을 실시한 경우 200MPa이상의 강도를 얻을 수 있었고, 최종적으로 특화된 양생방법을 통해 240MPa이상의 안정된 초고강도 콘크리트 품질을 확보하였다.

• Transactions on Electrical and Electronic Materials
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• 제10권6호
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• pp.217-221
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• 2009

The use of the carbon nanotube (CNT) is superior to the general powder state materials in their thermal and chemical properties. Because its ratio of diameter to length (aspect ratio) is very large, it is known to be a type of ideal nano-reinforcement material. Based on this advantage, the existing carbon black of the semiconductive shield materials used in power cables can acquire excellent properties by the use of a small amount of CNTs. Therefore, we fabricated specimens using a solution mixing method. We investigated the thermal properties of the CNT, such as its storage modulus, loss modulus, and its tan delta using a dynamic mechanical analysis 2980. We found that a high thermal resistance level is demonstrated by using a small amount of CNTs. We also investigated the chemical properties of the CNT, such as the oxidation reaction by using Fourier transform infrared spectroscopy (FT-IR) made by Travel IR. In the case of the FT-IR tests, we searched for some degree of oxidation by detecting the carboxyl group (C=O). The results confirm a tendency for a high cross-linking density in a new network in which the CNTs situated between the carbon black constituent molecules show a bond using similar constructive properties.

• 청정기술
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• 제22권4호
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• pp.250-257
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• 2016

As an attempt to replacing petroleum-based chemicals with bio-based ones, synthesis of furfural from biomass-derived xylose attracts much attention in recent days. Conventionally, furfural from xylose has been produced via the utilization of highly corrosive, toxic, and environmentally unfriendly mineral acids such as sulfuric acid or hydrochloric acid. In this study, microwave-assisted biphasic reaction process in the presence of novel bio-based heterogeneous acid catalysts was developed for the eco-benign and effective synthesis of furfural from xylose. The microwave was irradiated for reaction acceleration and a biphasic system consisting of $H_2O$ : MIBK (1 : 2) was designed for continuous extraction of furfural into the organic phase in order to reduce the undesired side products formed by decomposition/condensation/oligomerization in the acidic aqueous phase. Moreover, sulfonated amorphous carbonaceous materials were prepared from wood powder, the most abundant lignocellulosic biomass. The prepared catalysts were characterized by FT-IR, XPS, BET, elemental analysis and they were used as bio-based heterogeneous acid catalysts for the dehydration of xylose into furfural more effectively. For further optimization, the effect of temperature, reaction time, water/organic solvent ratio, and substrate/catalyst ratio on the xylose conversion and furfural yield were investigated and 100% conversion of xylose and 74% yield of furfural was achieved within 5 h at $180^{\circ}C$. The bio-based heterogeneous acid catalysts could be used three times without any significant loss of activity. This greener protocol provides highly selective conversion of xylose to furfural as well as facile isolation of product and bio-based heterogeneous acid catalysts can alternate the environmentally-burdened mineral acids.

• 한국가스학회지
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• 제13권5호
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• pp.7-14
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• 2009

본 연구는 석탄화력발전소 노의 연소효율 향상을 위하여 미분탄 수송배관의 공기-입자 유동장의 압력손실 특성을 분석하여 미분탄 수송장치 내에 설치되어 유량을 제어하는 오리피스의 설계에 적용하고자 하는 것이다. 통상의 미분탄 수송배관장치는 관의 형태에 따라 직선관, 곡선관 및 엘보우로 구성된다. 본 연구에서는 공기유동과 입자운동의 상호작용 해석을 통하여 직선관과 곡선관을 갖는 미분탄 수송배관장치 내의 압력손실을 분석하였다. 총 압력손실은 공기-미분탄 입자의 마찰 손실 증가와 배관의 길이, 곡선관 각도의 증가에 따라 증가하는 것으로 확인되었다. 연구결과로 압력손실과 유량제어를 위한 최적화된 오리피스 설계 프로그램이 개발되었으며 그 계산 결과를 기존의 실험결과와 비교, 분석하였다.