• Title/Summary/Keyword: Powder Compacts

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The Preparation of Seeded Alumina from Alkoxide: (II) Sintering (알콕사이드로부터 Seed가 첨가된 알루미나의 제조: (II) 소결특성)

  • 김창은;임광일;이해욱
    • Journal of the Korean Ceramic Society
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    • v.29 no.6
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    • pp.480-488
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    • 1992
  • The sintering behaviors of seeded alumina from alkoxide were studied. Room temp. desiccated powder exhibited better sintering behavior due to its packing ability and powder activity. $\alpha$-Al2O3 2wt% seeded compacts sintered with 97.5%TD, 1~3${\mu}{\textrm}{m}$ diameters at 140$0^{\circ}C$, 2hrs. Fe-nitrate doped compacts resulted in enhanced initial sintering behavior due to ionic effects of Fe3+ but failed to refined microstructure.

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Preparation of Proton-Conducting Gd-Doped Barium Cerate by Oxalate Coprecipitation Method

  • Yong Sung Choi;Soo Man Sim
    • The Korean Journal of Ceramics
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    • v.4 no.3
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    • pp.213-221
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    • 1998
  • $BaCe_{0.9}Gd_{0.1_O_{2.95}$ powder was synthesized by oxalate coprecipitation method. Precipitate with a stoichimetric ratio of the cations was prepared by adding a mixture of Ba, Ce and Gd nitrate solution to an oxalic acid solution at pH 4. Reaction between the constituent oxides to form a perovskite phase was initiated at $800^{\circ}C$ and a single phase $BaCe_{0.9}Gd_{0.1_O_{2.95}$ powder having good sinterability was obtained after calcination at $1000^{\circ}C$. Sintering green compacts of this powder for 6 h showed a considerable densification to start at $1100^{\circ}C$ and resulted in 93% and 97% relative densities at $1300^{\circ}$ and at $1450^{\circ}C$, respectively. Whereas the power compacts prepared by solid state reaction had lower relative densities, 78% at $1300^{\circ}$and 90% at $1450^{\circ}C$. Fine particles of $CeO_2$ second phase were observed in the surface of the sintered compacts. This was attributed to the evaporation of BaO from the surface that had been exposed during thermal etching.

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Sinter-bonding of Iron Based Compacts Containing P and Cu

  • Pieczonka, Tadeusz;Kazior, Jan
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09a
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    • pp.306-307
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    • 2006
  • The sinter-bonding behavior of iron based powder mixtures was investigated. To produce the green compacts to be joined the following powders based on $H{\ddot{o}}gan{\ddot{a}}s$ AB grade NC 100.24 plain iron powder were used: NC 100.24 as delivered, PNC 30, PNC 60 and NC 100.24 + 4%Cu powder mixtures. Dimensional behaviour of all those materials during the sintering cycle was monitored by dilatometry. Simple ring shaped specimens as the outer parts and cylindrical as the inner parts were pressed. The influence of parts' composition on joining strength was established. Diffusion of alloying elements: copper and phosphorous, across the bonding surface was controlled by metallography, SEM and microanalysis.

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Microwave Heating and Pre-sintering of Copper Powder Metal Compacts in Separated Electric and Magnetic Fields

  • Zimmerman, Darin T.;Johnson, Earnie J.;Ma, JunKun;Miskovsky, Nicholas M.;Weisel, Gary J.;Weiss, Brock L.
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09a
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    • pp.266-267
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    • 2006
  • We present a systematic study of the heating and pre-sintering behavior of porous copper powder metal compacts. We employ a TE102 single mode microwave system to position the samples in the separated electric field (E) or magnetic field (H) anti-node of the cavity. We observe significant differences in the heating, pre-sintering, and microstructure evolution of the samples due to the individual fields. We note that sample history (whether heated first in the E-field or H-field) greatly effects a difference in heating trends and subsequent heating behavior and does not appear to be solely a thermal process.

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Softening-hardening Mechanisms in the Direct Hot-extrusion of Aluminium Compacts

  • Zubizarreta, C.;Arribas, I.;Gimenez, S.;Iturriza, I.
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09b
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    • pp.718-719
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    • 2006
  • Two different commercial aluminium powder grades have been densified by direct hot extrusion. The extrusion temperature was $425^{\circ}C$, with an extrusion ratio of 1:16. Prior to extrusion, some green compacts were pre-sintered ($500^{\circ}C$). The evolution of the extrusion load during the process and the hardness of the final products have been investigated. Additionally, microstructural characterization by X-ray diffraction (XRD), Scanning Electron Microscopy (SEM) and Electron Backscattered Diffraction (EBSD) was carried out. The obtained results evidence grain refinement. Additionally, inter-metallic precipitation, dynamic recovery and geometric dynamic recrystallization take place depending on some process variables, powder composition, heat treatment, strain $\ldots$

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