• 제목/요약/키워드: Potassium Hydroxide

검색결과 211건 처리시간 0.028초

한국잔디종자의 발아촉진을 위한 Sodium Hypochlorite와 Potassium Hydroxide 처리효과의 비교 (Comparison of Sodium Hypochiorite and Potassium Hydroxide as Seed Treatment for Stimulating Germination of Korean Lawngrass (Zoysia japonica Steud.) Seed)

  • 구자형;원동찬;김태일
    • 아시안잔디학회지
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    • 제2권1호
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    • pp.41-48
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    • 1988
  • Research was conducted to obtain easy and secure methods for promoting germination of Korean lawngrass (Zoysia japonic a Steud.) seed. The effect of sodium hypochiorite (NaOCl) treatment on germination of seeds was compared with that of potassium hydroxide (KOH) treatment under conditions of duration of seed storage after harvest and temperature of treatment. Emergence of seedlings from soil and micro-flora infection rate among seed treatments were investigated. 1. The promotion of germination was much more evident in seeds treated with 4% NaOCl for 8 and 10 hours than in seeds treated with 25% or 30% KOH for 30 and 40 minutes. Longer durations of storage before seed treatment in KOH than in NaOCl were required to initiate enough germination. 2. Differences in temperature of treatment with NaOCT did not have much influence on germination of seeds and treatment temperature of 15˚C was better than that of 200˚C and 300˚C for promoting germination. But seed treatment with KOH significantly promoted germination with increasing temperature of treatment from I 5˚C to 20˚C and 30˚C. 3. GA$_3$ treatment enhanced germination in NaOCl-pretreated seeds at early stage of imbibition and in-creased about 10% germination after 10 days of imbibition in KOH-pretreated seeds. 4. NaOC1 treatments significantly decreased the rate of the infection of microflora in seed samples and enhaced emergence of seedlings from soil compared with KOH treatment. 5. NaOC1 treatment had advantage over KOH treatment with respect to ease of preparing, securing and handling in stimulating germinating of Korean lawngrass seeds.

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물유리의 농도와 첨가제 종류에 따른 방염제의 성능 (Flame Retardancy of Plywood Treated with Various Water Glass Concentration and Additives)

  • PARK, Sohyun;HAN, Yeonjung;SON, Dong Won
    • Journal of the Korean Wood Science and Technology
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    • 제49권1호
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    • pp.44-56
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    • 2021
  • 소방청의 방염성능기준에 제시된 45°멕켈 버어너법을 이용하여 물유리 농도와 첨가제 종류에 따른 합판의 탄화길이 및 면적 등의 방염성능을 측정하였다. 합판에 농도 20-50%의 물유리를 처리한 결과, 방염성능은 물유리의 농도와 비례하는 경향을 나타냈다. 그러나 30%를 넘는 고농도의 물유리로 처리된 합판의 표면에서 백화현상과 끈적임이 발생하여 농도 30%를 최적 조건으로 결정하였다. 농도 30%의 물유리에 서로 다른 비율의 첨가제를 추가하여 실험을 수행한 결과, 수산화칼륨 15% 조건과 수산화알루미늄 1-10%의 조건에서 방염성능 기준을 만족하였다. 반면에 황산마그네슘은 방염성능에 크게 영향을 미치지 않았다. 물유리와 첨가제에 따른 방염성능의 결과는 방염제를 활용한 불연재에 대한 기초자료로 활용될 것으로 기대된다.

Isothiocyanate 유도체의 Prodrug를 위한 합성 연구 (Studies on the Synthesis of Bis-dithiocarbamates as Prodrugs of Isothiocyanates)

  • 심영섭;정오영;김완주;이문희
    • 약학회지
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    • 제26권2호
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    • pp.91-96
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    • 1982
  • In an attempt to design prodrugs for the Derivatives of the Isothiocyanates R-N=C=S were synthesized eleven novel bis-dithiocarbamates. The best way of preparing the dithiocarbamates was the formation of the dithiocarbonates followed by the reaction of the dithiocarbonates with amines. Thus, the treatment of the diols with carbon disulfide in the presense of potassium hydroxide afforded the potassium salts of the ditniocarbonic acids. The potassium salts were then reacted with alkyl halides to give the dithiocarbonates, which upon treatment with amines produces the dithiocarbamates. In case of vicinal diol (n=o in the above formula), only one of the hydroxy groups was reacted to give the mono-dithiocarbonate. The dithiocarbonates failed to react with amides and aromatic amines. Dithiocarbonates of the different types were obtained when the active double bonds, such as $CH_{2}=CH-Z$ , (Z are electron withdrawing groups), were allowed to react with the free dithiocarbonic acids produced in situ by carefully neutralizing the Potassium salts of the corresponding acids. These compounds are considered to be of some value as prodrugs for the active double bonds.

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원자력산업에서 지르코늄 스크랩 재활용을 위한 세정기술에 관한 연구 (A Study of Cleaning Technology for Zirconium Scrap Recycling in the Nuclear Industry)

  • 이지은;조남찬;안창모;노재수;문종한
    • 청정기술
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    • 제19권3호
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    • pp.264-271
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    • 2013
  • 본 연구에서는 지르코늄 피복관 제조공정에서 발생되는 스크랩을 원전급(nuclear grade)으로 재활용하기 위해 스크랩 표면에 부착되어 있는 오염물 제거조건을 최적화하였다. 주 오염물은 피복관 제조시 필거링 공정에서 사용하고 있는 수용성 냉각윤활제 잔류물로서 튜브 표면에 압착 및 탄화된 것으로 가정된다. 스크랩 발생 빈도가 높은 ${\phi}9.50mm$, zirlo 합금 튜브를 피 세정 대상물로 선정하여 세정 후 피 세정물 표면에 잔존하고 있는 오염물의 특성분석과 피 세정물의 표면 성분분석으로 세정성을 평가하였다. 세정제별 세정능력을 평가하기 위하여 수산화나트륨(sodium hydroxide) 계열 2종과 수산화칼륨(potassium hydroxide) 계열 3종을 선정하여 비교하였다. 또한 온도 및 초음파 강도에 따른 세정 효과 분석을 위해 상온, $40^{\circ}C$, $60^{\circ}C$에서 각각 세정한 결과, 세정온도 및 초음파 강도가 높을수록 세정효과도 높은 것으로 나타났다. 육안검사 결과 수산화나트륨 계열은 초음파 강도와 무관하게 모두 양호한 것으로 나타났으나 수산화칼륨 계열은 초음파 강도 120 W 이상에서 피 세정물의 표면상태가 양호한 것으로 나타났다. 중량측정법에 의한 세정효과 분석결과 수산화나트륨 계열은 세정효율이 97.6% ($60^{\circ}C$, 120 W)까지 나타났으나 수산화칼륨 계열은 피 세정물의 표면상태 불량으로 중량측정 방법을 적용하는 것이 부적합한 것으로 나타났다. 피 세정물의 표면 오염물 분석 결과 C, O, Ca, Zr 성분이 검출되었으며 그 중 C, O의 성분이 대부분을 차지하였음을 알 수 있었다. 피 세정물의 세정 정도에 따라 C, O 구성 비율의 변화가 큰 것으로 나타났으며 세정이 잘될수록 C의 구성비율이 감소되며 상대적으로 O의 구성 비율이 증가되었다. 본 연구 결과를 바탕으로 산업현장에 적용하기 위하여 세정공정을 알카리세정, 수세, 건조의 3단계로 구분하고 각 단계별로 세정변수를 조정함으로써 세정효과의 극대화를 기대할 수 있다.

과산화조제에 의한 면직물의 저온표백에 관한 연구 (A Study on the Low Temperature Bleaching of Cotton with Peroxygen Boosters)

  • Choi, Chul Ho;Lee, Chan Min
    • 한국염색가공학회지
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    • 제8권2호
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    • pp.35-42
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    • 1996
  • Peroxodisulfates are being developed as low temperature bleaching agents for cotton fabrics to save the thermal energy. In this research we used the colar difference meter to determine the whiteness which peroxide booster will possibly make an effect on cotton fabric at the low temperature process using consist of temperature with different conditions agents, such as sodium hydroxide, sodium peroxodisulfate and potassium peroxodisulfate. The peroxide bleaching follows a laboratory experiments, using a statistical plan for three variables: the concentrations of hydrogen peroxide and sodium hydroxide and the temperature of bathing. The purpose of this research was to use the response surface analysis method to evaluate the relative importance of factors providing optimum whiteness. A ridge analysis of the data on whiteness response results in 3-D response surface diagrams for optimizing the concentrations of hydrogen peroxide and sodium hydroxide at about 42~52$^{\circ}C$.

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실리콘 웨이퍼 습식 식각장치 설계 및 공정개발 (Design of Single-wafer Wet Etching Bath for Silicon Wafer Etching)

  • 김재환;이용일;홍상진
    • 반도체디스플레이기술학회지
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    • 제19권2호
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    • pp.77-81
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    • 2020
  • Silicon wafer etching in micro electro mechanical systems (MEMS) fabrication is challenging to form 3-D structures. Well known Si-wet etch of silicon employs potassium hydroxide (KOH), tetramethylammonium hydroxide (TMAH) and sodium hydroxide (NaOH). However, the existing silicon wet etching process has a fatal disadvantage that etching of the back side of the wafer is hard to avoid. In this study, a wet etching bath for 150 mm wafers was designed to prevent back-side etching of silicon wafer, and we demonstrated the optimized process recipe to have anisotropic wet etching of silicon wafer without any damage on the backside. We also presented the design of wet bath for 300 mm wafer processing as a promising process development.

알루미늄 자연발색에 관한 연구 (Integral coloring of aluminum)

  • 이구종;박광자
    • 한국표면공학회지
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    • 제17권4호
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    • pp.99-105
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    • 1984
  • Integral coloring of aluminum and its alloy with the elecrolytic solution of sulfosallicylic acid and sodium hydroxide was investigated in this study. Addition of hydrogen peroxide and potassium permanganate accelerated the anodizing speed and deepened the color of anodized film. Electron microscopic study was also performed on the surface and cross section.

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조기강도 개선형 시멘트 및 초기수화 촉진 혼화제를 사용한 콘크리트의 조기압축강도 발현특성 평가 (Evaluation of Early Compressive Strength of Concrete Using Early Strength Improvement Type Cement and Early Strength Activator)

  • 박규연;김규용;최경철
    • 한국건축시공학회지
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    • 제14권4호
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    • pp.322-328
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    • 2014
  • 본 연구에서는 콘크리트의 조기강도 확보를 통해 골조공기를 단축하는 것을 목표로 하여 시멘트 종류, 고성능감수제의 감수율, 초기수화 촉진 혼화제의 혼입에 따른 콘크리트의 조기강도 발현성능을 검토하였다. 조기강도 개선형 시멘트와 Sodium persulfate, Potassium hydroxide의 초기수화 촉진물질에 의해 12시간에 5MPa, 18시간에 14MPa의 조기강도를 확보할 수 있는 것으로 나타났다. 이를 통해 건설현장에서 거푸집의 골조공기를 단축시켜 원가절감이 가능할 것으로 기대된다.

지중 환경하에서의 철근콘크리트 구조물의 열화인자별 한계수명 평가 (Service-life Prediction of Reinforced Concrete Structures in Subsurface Environment)

  • 권기정;정해룡;박주완
    • 방사성폐기물학회지
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    • 제14권1호
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    • pp.11-19
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    • 2016
  • This paper focuses on the estimation of durability and service-life of reinforced concrete structures in Wolsong Low- and intermediate-level wastes Disposal Center (WLDC) in Korea. There are six disposal silos located in the saturated environment. The silo concrete is degraded due to reactions with groundwater and chemical attacks, and finally it will lose its properties as a transport barrier. The infiltration of sulfate and magnesium, leaching of potassium hydroxide, and chlorine induced corrosion are the most significant factors for degradation of reinforced concrete structure in underground environment. From the result of evaluation of the degradation time for each factor, the degradation rate of the reinforced concrete due to sulfate and magnesium is $1.308{\times}10^{-3}cm/yr$, and it is estimated to take 48,000 years for full degradation while potassium hydroxide is leached in depth of less than 1.5 cm at 1,000 years after the initiation of degradation. In case of chlorine induced corrosion, it takes 1,648 years to initiate corrosion in the main reinforced bar and 2,288 years to reach the lifetime limit of the structural integrity, and thus it is evaluated as the most significant factor.