• Title/Summary/Keyword: Potassium Hydroxide

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Effect of surface modification of carbon felts on capacitive deionization for desalination

  • Lee, Jong-Ho;Ahn, Hong-Joo;Cho, Donghwan;Youn, Jeong-Il;Kim, Young-Jig;Oh, Han-Jun
    • Carbon letters
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    • v.16 no.2
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    • pp.93-100
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    • 2015
  • Surface modified carbon felts were utilized as an electrode for the removal of inorganic ions from seawater. The surfaces of the carbon felts were chemically modified by alkaline and acidic solutions, respectively. The potassium hydroxide (KOH) modified carbon felt exhibited high Brunauer-Emmett-Teller (BET) surface areas and large pore volume, and oxygen-containing functional groups were increased during KOH chemical modification. However, the BET surface area significantly decreased by nitric acid ($HNO_3$) chemical modification due to severe chemical dissolution of the pore structure. The capability of electrosorption by an electrical double-layer and the efficiency of capacitive deionization (CDI) thus showed the greatest enhancement by chemical KOH modification due to the appropriate increase of carboxyl and hydroxyl functional groups and the enlargement of the specific surface area.

CO2 adsorption characteristics of slit-pore shaped activated carbon prepared from cokes with high crystallinity

  • Park, Mi-Seon;Lee, Si-Eun;Kim, Min Il;Lee, Young-Seak
    • Carbon letters
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    • v.16 no.1
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    • pp.45-50
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    • 2015
  • High crystallinity coke-based activated carbon (hc-AC) is prepared using a potassium hydroxide solution to adsorb carbon dioxide ($CO_2$). The $CO_2$ adsorption characteristics of the prepared hc-AC are investigated at different temperatures. The X-ray diffraction patterns indicate that pitch-based cokes prepared under high temperature and pressure have a high crystal structure. The textural properties of hc-AC indicate that it consists mainly of slit-like pores. Compared to other textural forms of AC that have higher pore volumes, this slit-pore-shaped hc-AC exhibits higher $CO_2$ adsorption due to the similar shape between its pores and $CO_2$ molecules. Additionally, in these high-crystallinity cokes, the main factor affecting $CO_2$ adsorption at lower temperature is the pore structure, whereas the presence of oxygen functional groups on the surface has a greater impact on $CO_2$ adsorption at higher temperature.

Synthesis and Anti Bacterial and Anti-ulcer Evaluation of New S-mannich Bases of 4,6-diaryl-3,4-dihydropyrimidin-2(1H)-thiones

  • Kodhati, Venkateshwarlu;Vanga, Malla Reddy;Yellu, Narsimha Reddy
    • Journal of the Korean Chemical Society
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    • v.57 no.2
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    • pp.234-240
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    • 2013
  • The synthesis of title compounds were accomplished by synthetic sequence shown in Scheme 1. Chalcones on cyclocondensation with thiourea in ethanol and potassium hydroxide under reflux yielded the respective dihydropyramidin-2(1H)-thiones. Each of the dihydropyrimidin thiones was, then subjected to the Mannich condensation in alkaline medium using three different secondary amines, viz., dimethylamine, diethylamine and morpholine to obtain a new series of S-Mannich bases. All the synthesised compounds ($C_1-C_{15}$) were evaluated for their antiulcer and antibacterial activities. Compounds $C_4$, $C_5$, $C_6$, $C_{14}$ and $C_{15}$ exhibited relatively more potent antiulcer activity but not comparable to the standard; Omeprazole, while $C_1$, $C_2$, $C_3$ and $C_{13}$ were moderate in activity at 100 mg/kg p.o. All the compounds ($C_1-C_{15}$) showed mild to moderate activity against both Gram-positive (S.aureus, L.delbrueckii) and Gram-negative (P.vulgaris, E.coli) bacteria. Amongst the compounds tested, only $C_6$, $C_9$, $C_{12}$ and $C_{15}$ were found to be potent.

Production of Biodiesel from Yellow Oleander (Thevetia peruvian) Oil and its Biodegradability

  • Yarkasuwa, Chindo Istifanus;Wilson, Danbature;Michael, Emmanuel
    • Journal of the Korean Chemical Society
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    • v.57 no.3
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    • pp.377-381
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    • 2013
  • Thevetia peruviana (Yellow Oleander) seed oil was extracted with n-hexane in a soxhlet extractor. The ethanolysis and methanolysis of the oil were carried out with 50% of potassium hydroxide in ethanol and methanol respectively by weight of oil, as catalyst. The biodiesel was tested for biodegradability using E. coli. The percentage yield of the FAEE and FAME were 84.8% and 91.6% respectively. The biodegradability values of 81.4% and 86.2% were obtained for FAEE and FAME respectively after a period of 28 days. Other fuel quality parameters determined are the cetane index of 47.19 (FAEE) and 58.97 (FAME), flash point of $198^{\circ}C$ (FAEE) and $175^{\circ}C$ (FAME), kinematic viscosity at $40^{\circ}C$ of 5.21 $mm^2s^{-1}$ (FAEE) and 5.10 $mm^2s^{-1}$(FAME), pour point of $4^{\circ}C$ (FAEE) and $-2^{\circ}C$ (FAME) and a cloud point of $6^{\circ}C$ (FAEE) and $3^{\circ}C$ (FAME). Thus, Thevetia peruviana oil has a high potential for use in production of environmentally friendly biodiesel.

Manufacturing Large-scale SiNx EUV Pellicle with Water Bath (물중탕을 이용한 대면적 SiNx EUV 펠리클 제작)

  • Kim, Jung Hwan;Hong, Seongchul;Cho, Hanku;Ahn, Jinho
    • Journal of the Semiconductor & Display Technology
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    • v.15 no.1
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    • pp.17-21
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    • 2016
  • EUV (Extreme Ultraviolet) pellicle which protects a mask from contamination became a critical issue for the application of EUV lithography to high-volume manufacturing. However, researches of EUV pellicle are still delayed due to no typical manufacturing methods for large-scale EUV pellicle. In this study, EUV pellicle membrane manufacturing method using not only KOH (potassium hydroxide) wet etching process but also a water bath was suggested for uniform etchant temperature distribution. KOH wet etching rates according to KOH solution concentration and solution temperature were confirmed and proper etch condition was selected. After KOH wet etching condition was set, $5cm{\times}5cm$ SiNx (silicon nitride) pellicle membrane with 80% EUV transmittance was successfully manufactured. Transmittance results showed the feasibility of wet etching method with water bath as a large-scale EUV pellicle manufacturing method.

Comparison of Some Physicochemical Properties of Ginger Root and Cross-linked Corn Starches (생강 전분과 옥수수 가교 전분의 이화학적 성질 비교)

  • Hur, June;Kim, Sung-Kon
    • Korean Journal of Food Science and Technology
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    • v.16 no.2
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    • pp.201-205
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    • 1984
  • Some physicochemical properties of ginger root (Zingiber officinale) starch were compared with those of cross-linked corn starch. The ginger root starch that contained 23.5% amylose had a water-binding capacity of 99.1% and a B-type X-ray diffraction pattern. The optical transmittance of the ginger root starch suspension increased from $70^{\circ}C$ and showed a similar pattern to cross-linked corn starch. Solubility studies revealed that both ginger root and cross-linked corn starches had low swelling power and solubility in water up to $90^{\circ}C$, and reduced solubility in potassium hydroxide. Brabender amylograph data indicated that the ginger root starch (7%) had a relatively high initial pasting temperature $(81.5^{\circ}C)$ and was stable against heat and mechanical shear, which resembled to the cross-linked corn starch.

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Synthesis of Ba(Mg1/3Ta2/3)O3 Nanoparticles by a Hydrothermal Process (수열합성법에 의한 Ba(Mg1/3Ta2/3)O3 나노분말 합성)

  • Kim, Rak-Hee;Son, Jung-Hun;Bae, Dong-Sik
    • Korean Journal of Materials Research
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    • v.16 no.6
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    • pp.373-376
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    • 2006
  • [ $Ba(Mg_{1/3}Ta_{2/3})O_3$ ] nanoparticles were synthesized in water solution under mild temperature and pressure conditions by precipitation from $Ba(NO_3),\;Mg(NO_3)_2{\cdot}6H_2O\;and\;TaCl_5$ with aqueous potassium hydroxide. The average size and distribution of the synthesized $Ba(Mg_{1/3}Ta_{2/3})O_3$ nanoparticles were below 100 nm and broad, respectively. The phase of synthesized particles was crystalline reacted at $170^{\circ}C$ for 4 h. The characterization of $Ba(Mg_{1/3}Ta_{2/3})O_3$ nanoparticles were studied using XRD, SEM, and TEM.

Flocculation Characteristics of Microalgae Using Chemical Flocculants (화학응집제를 이용한 미세조류의 응집 특성)

  • Kwon, Do-Yeon;Jung, Chang-Kyou;Park, Kwang-Beom;Lee, Choul-Gyun;Lee, Jin-Won
    • KSBB Journal
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    • v.26 no.2
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    • pp.143-150
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    • 2011
  • The aim of the study was to optimize harvesting method for concentrating microalgae from microalgae mass culture. It is well known that the mass density of microalgae is usually very low and these are small size (5-20 ${\mu}m$) in the culture medium. It is essential that microalgae is harvested and concentrated economically for economical biodiesel production from microalgae. In this study, to determine optimized conditions for microalgae harvesting by chemical flocculation. Flocculation of three algae, Chlorella ellipsoidea, Dunaliella bardawil, and Dunaliella tertiolecta, was performed using various chemical flocculants, such as inorganic flocculants (aluminium sulfate, aluminium potassium sulfate, ferrous sulfate, ferric sulfate, ferric chloride, calcium hydroxide, sodium carbonate, sodium nitrite, and sodium aluminate), organic flocculant (polyacrylamide), and biopolymer flocculants (chitosan and starch). The results indicated that aluminium based inorganic flocculants is suitable for microalgae harvesting such as Chlorella ellipsoidea, Dunaliella bardawil, and Dunaliella tertiolecta. The results also recommended that flocculant doses, agitation speed, agitation time, sedimentation time for economical microalgae harvesting method using chemical flocculants.

The Optimum Condition of Anisotropic Bulk(10) Si Etching with KOH for High Selectivity and Low Surface Roughness

  • Lim, Hyung-Teak;Kim, Yong-Kweon;Lee, Seung-Ki
    • Journal of Electrical Engineering and information Science
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    • v.2 no.5
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    • pp.108-113
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    • 1997
  • In this paper, the optimum condition of (110) Si etching with the potassium hydroxide(KOH) etchant is presented. Although several researches on (110) Si anisotropic etching have been studied, there has been lack of effects of mask quality and etching conditions on the selectivity and the roughness o the etched surface. Three kinds of masks (film, emulsion and E-beam mask) were used in order to verify the effect of etching properties. Anisotropic bulk etching depends on the crystalline orientation and the concentration and temperature of the etchant. In order to investigate the effect of etching conditions on selectivity and the roughness of the etched surface, the concentration of the etchant was varied from 35 to 45 per cent in weight with increments by 5 per cent and the temperature was changed from 70 to 90$^{\circ}C$ with increments by 10$^{\circ}C$. The combination of the temperature of 70$^{\circ}C$ and the concentration of 40wt.% was found to be the optimum etching condition for high selectivity. Etched surfaces show minimum surfaces show minimum surface roughness at a temperature of 80$^{\circ}C$ and a concentation of 40wt.%. Comb structures with various comb widths were fabricated and the lengths of the combs wree measured with several etching time durations. A micro comb structure 525$\mu\textrm{m}$ high was fabricated for MEMS application.

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Optimization of Porous Silicon Reflectance for Multicrystalline Silicon Solar Cells (다공성 실리콘 반사방지막의 최적 반사율을 적용한 다결정 실리콘 태양전지)

  • Kwon, J.H.;Kim, D.S.;Lee, S.H.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.07a
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    • pp.146-149
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    • 2004
  • Porous silicon(PS) as an excellent light diffuser can be used as an antireflection layer without other antireflection coating(ARC) materials. PS layers were obtained by electrochemical etching(ECE) anodization of silicon wafers in hydrofluoric acid/ethanol/de-ionized(DI) water solution($HF/EtOH/H_2O$). This technique is based on the selective removal of Si atoms from the sample surface forming a layer of PS with adjustable optical, electrical, and mechanical properties. A PS layer with optimal ARC characteristics was obtained in charge density (Q) of 5.2 $C/cm^2$. The weighted reflectance is reduced from 33 % to 4 % in the wavelength between 400 and 1000 nm. The weighted reflectance with optimized PS layers is much less than that obtained with a commercial SiNx ARC on a potassium hydroxide(KOH) pre-textured multi-crystalline silicon(mc-Si) surface.

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