• Title/Summary/Keyword: Post-synthesis Technology

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Recent trends in advanced flight control

  • Kanai, Kimio
    • 제어로봇시스템학회:학술대회논문집
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    • 1996.10a
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    • pp.24.1-24
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    • 1996
  • The development of future aircraft that involves the expanded flight envelop will place increased performance requirements on the design of the flight control system. Maneuvering areas are expanding into flight envelopes characterized by significantly larger levels of modeling uncertainty than encountered in present flight control designs. Conventional flight control techniques that ignore the effects of large parameter variations, modeling uncertainties and nonlinearities, will likely produce designs with poor performance and robustness. Recent advances in modern control theories called advanced control theories, most notably the H$\_$.inf./ synthesis technique, adaptive control and neural network application, offer the promise of a design technique that can produce both high performance and robust controllers for next generation aircraft. This special lecture will survey the recent development in advanced flight control and review the possible application of advanced control theories.

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Effective Estimation Method of Routing Congestion at Floorplan Stage for 3D ICs

  • Ahn, Byung-Gyu;Kim, Jae-Hwan;Li, Wenrui;Chong, Jong-Wha
    • JSTS:Journal of Semiconductor Technology and Science
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    • v.11 no.4
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    • pp.344-350
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    • 2011
  • Higher integrated density in 3D ICs also brings the difficulties of routing, which can cause the routing failure or re-design from beginning. Hence, precise congestion estimation at the early physical design stage such as floorplan is beneficial to reduce the total design time cost. In this paper, an effective estimation method of routing congestion is proposed for 3D ICs at floorplan stage. This method uses synthesized virtual signal nets, power/ground network and clock network to achieve the estimation. During the synthesis, the TSV location is also under consideration. The experiments indicate that our proposed method had small difference with the estimation result got at the post-placement stage. Furthermore, the comparison of congestion maps obtained with our method and global router demonstrates that our estimation method is able to predict the congestion hot spots accurately.

Synthesis, Characterization and Determination of HOMO-LUMO of the Substituted 1,3,5-Triazine Molecule for the Applications of Organic Electronics

  • Pakkath, Rajeesh;Reddy, Eeda Koti;Kuriakose, Sheena;Saritha, C;Sajith, Ayyiliath M;Karuvalam, Ranjith Pakkath;Haridas, Karickal Raman
    • Journal of the Korean Chemical Society
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    • v.63 no.5
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    • pp.352-359
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    • 2019
  • The most important parameter of organic molecules for energy harvesting application focuses mainly on their band gap (HOMO-LUMO). In this report, we synthesized differently substituted 1,3,5-triazine based organic molecule which on future processing can be used in organic electronics like solar cells and OLED's. The energy gap of the synthesized novel analogue was calculated using cyclic voltammetry, UV-Visible spectroscopy and compared with density functional theory (DFT) studies.

Synthesis and Luminescence Characteristics of SrGa2S4:Eu Green Phosphor for Light Emitting Diodes by Solid-State Method (고상법을 이용한 LED용 SrGa2S4:Eu 녹색 형광체의 합성 및 발광특성)

  • Kim, Jae-Myung;Kim, Kyung-Nam;Park, Joung-Kyu;Kim, Chang-Hae;Jang, Ho-Gyeom
    • Journal of the Korean Chemical Society
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    • v.48 no.4
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    • pp.371-378
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    • 2004
  • The $SrGa_2S_4:Eu^{2+}$ green emitting phosphor has been studied as a luminous device for CRT (Cathode Ray Tube) or FED (Field Emission Display) and EL (Electroluminescence). This phosphor, also, is under noticed for LED (Lighting Emitting Diode) phosphor, which makes use of excitation characteristics of long wavelength region. The $SrGa_2S_4:Eu^{2+}$ phosphor was prepared generally conventional synthesis method using flux. However, this method needs high heat-treated temperature, long reaction time, complex process and harmful $H_2S$or $CS_2$ gas. In this works, therefore, we have synthesized $SrGa_2S_4:Eu^{2+}$ using SrS, $Ga_2S_3$, and EuS as starting materials, and the mixture gas of 5% H2/95% N2 was used to avoid the $H_2S$or $CS_2$. We investigated the luminescence characteristic of $SrGa_2S_4:Eu^{2+}$ phosphor prepared in various synthesis conditions, performed post-treatment and sieving process for application to LED.

The studies on synthesis of aluminum oxide and boron oxide co-doped zinc oxide(AZOB) powder by spray pyrolysis (분무열분해법(Spray Pyrolysis)에 의한 알루미늄 산화물과 보론 산화물이 함께 도핑된 산화아연(AZOB: $Al_2O_3$ and $B_2O_3$ Co-doped Zinc Oxide)의 분말 제조에 대한 연구)

  • Kim, Sang Hern
    • Journal of the Korean Applied Science and Technology
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    • v.31 no.4
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    • pp.731-739
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    • 2014
  • Aluminum and boron co-doped zinc-oxide(AZOB) powders as transparent conducting oxide(TCO) were prepared by spray pyrolysis at $900^{\circ}C$. The micron-sized AZOB particles were prepared by spray pyrolysis from aqueous precursor solutions for aluminium, boron, and zinc. The micron-sized AZOB particle after the spray pyrloysis underwent post-heat treatment at $700^{\circ}C$ for 2 hours and it was changed fully to nano-sized AZOB particle by ball milling for 24 hours. The size of primary AZOB particle by Debye-Scherrer Equation and surface resistance of AZOB pellet were measured.

Damage detection for beam structures using an angle-between-string-and-horizon flexibility matrix

  • Yan, Guirong;Duan, Zhongdong;Ou, Jinping
    • Structural Engineering and Mechanics
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    • v.36 no.5
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    • pp.643-667
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    • 2010
  • The classical flexibility difference method detects damage by observing the difference of conventional deflection flexibility matrices between pre- and post-damaged states of a structure. This method is not able to identify multiple damage scenarios, and its criteria to identify damage depend upon the boundary conditions of structures. The key point behind the inability and dependence is revealed in this study. A more feasible flexibility for damage detection, the Angle-between-String-and-Horizon (ASH) flexibility, is proposed. The physical meaning of the new flexibility is given, and synthesis of the new flexibility matrix by modal frequencies and translational mode shapes is formulated. The damage indicators are extracted from the difference of ASH flexibility matrices between the pre- and post-damaged structures. One feature of the ASH flexibility is that the components in the ASH flexibility matrix are associated with elements instead of Nodes or DOFs. Therefore, the damage indicators based on the ASH flexibility are mapped to structural elements directly, and thus they can pinpoint the damaged elements, which is appealing to damage detection for complex structures. In addition, the change in the ASH flexibility caused by damage is not affected by boundary conditions, which simplifies the criteria to identify damage. Moreover, the proposed method can determine relatively the damage severity. Because the proposed damage indicator of an element mainly reflects the deflection change within the element itself, which significantly reduces the influence of the damage in one element on the damage indicators of other damaged elements, the proposed method can identify multiple damage locations. The viability of the proposed approach has been demonstrated by numerical examples and experimental tests on a cantilever beam and a simply supported beam.

Donating Otx2 to support neighboring neuron survival

  • Kim, Hyoung-Tai;Prochiantz, Alain;Kim, Jin Woo
    • BMB Reports
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    • v.49 no.2
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    • pp.69-70
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    • 2016
  • Mutations of orthodentricle homeobox 2 (OTX2) in human and mice often cause retinal dystrophy and nyctalopia, suggesting a role of OTX2 in mature retina, in addition to its functions in the development of the eye and retina. In support of this, the number of bipolar cells in Otx2+/− post-natal mouse retina was found to be significantly lower than normal. Degeneration of the cells becomes greater as the mice age, leading to the loss of vision. Especially, the type-2 OFF-cone bipolar cells, which do not express Otx2 mRNA but carry Otx2 protein, are most sensitive to Otx2 haplodeficiency. Interestingly, this bipolar cell subpopulation imports Otx2 protein from photoreceptors to protect itself from glutamate excitotoxicity in the dark. Moreover, in the bipolar cells, the exogenous Otx2 relocates to the mitochondria to support mitochondrial ATP synthesis. This novel mitochondrial activity of exogenous Otx2 highlights the therapeutic potential of Otx2 protein transduction in retinal dystrophy.

Synthesis of Mixed Phase Vanadium Oxides Thin Films and Their Ethanol Gas Sensing Properties (혼합 상의 바나듐 산화물 박막 제작 및 에탄올 가스 감지 특성 연구)

  • Han, Soo Deok;Kang, Chong-Yun
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.31 no.1
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    • pp.29-33
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    • 2018
  • Using a vanadium dioxide ($VO_2$) source, highly pure and amorphous vanadium oxide (VO) thin films were deposited using an e-beam evaporator at room temperature and high vacuum (<$10^{-7}$ Torr). Then, by controlling the post-annealing conditions such as $N_2:O_2$ pressure ratio and annealing time, we could easily synthesize a homogeneous $VO_2$ thin film and also mixed-phase VO thin films, including $VO_2$, $V_2O_5$, $V_3O_7$, $V_5O_9$, and $V_6O_{13}$. The crystallinity and phase of these were characterized by X-ray diffraction, and the surface morphology by FE-SEM. Moreover, the electrical properties and ethanol sensing measurements of the VO thin films were analyzed as a function of temperature. In general, mixed-phases as a self-doping effect have enhanced electrical properties, with a high carrier density and an enhanced response to ethanol. In summary, we developed an easy, scalable, and reproducible fabrication process for VO thin films that is a promising candidate for many potential electrical and optical applications.

Synthesis and herbicidal activities of 2-[4-(6-chloro-2-benzoxazolyloxy)-phenoxy]propionamide derivatives (2-[4-(6-chloro-2-benzoxazolyloxy)phenoxy]-propionamide 유도체의 합성과 제초 활성)

  • Chang, Hae-Sung;Chung, Kun-Hoe;Ko, Young-Kwan;Ryu, Jae-Wook;Woo, Jae-Chun;Koo, Dong-Wan;Kang, Yong-Hee;Kim, Tae-Joon;Kim, Jin-Seog;Chung, Bong-Jin;Kwon, Oh-Yeon;Kim, Dae-Whang
    • The Korean Journal of Pesticide Science
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    • v.8 no.2
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    • pp.145-149
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    • 2004
  • A series of 2-[4-(6-chloro-2-benzoxazolyloxy)phenoxy]-propionamide were synthesized and evaluated for post herbicidal activity under upland condition. 2-[4-(6-chloro-2-benzoxazolyloxy)phenoxy]-N-(2-fluorophenyl)-N methyl propionamide showed high herbicidal activity against barnyardgrass with good selectivity on rice.

Preparation and Characteristics of Partially Fluorinated-Sulfonated Poly(biphenylene-co-sulfone)ether Membranes for Polymer Electrolyte Membrane Fuel Cell (고분자전해질 연료전지용 부분 불소계 설폰화 Poly(biphenylene-co-sulfone)ether 막의 제조와 특성)

  • Park, Jae-Wan;Chang, Bong-Jun;Kim, Jeong-Hoon;Lee, Yong-Taek
    • Polymer(Korea)
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    • v.34 no.2
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    • pp.137-143
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    • 2010
  • A series of partially fluorinated, sulfonated poly(biphenylene-co-sulfone)ether containing perfluorocyclobutane(PFCB) groups were prepared for fuel cell applications through three synthetic steps: synthesis of trifluorovinylether-terminated monomers, thermal cycloaddition and post-sulfonation. Two kinds of trifluorovinylether-terminated monomers were synthesized and statistically copolymerized via thermal cycloaddition to obtain a series of polymers containing 20-60 mol% of biphenyl units(PBS-X). The post-sulfonation of PBS-X was carried out using chlorosulfonic acid(CSA) to obtain copolymers with various sulfonation levels(SPBS-X). All the synthesized compounds, monomers and polymers were characterized by $^1H$-NMR, $^{19}F$-NMR and FT-IR. It was confirmed that the ion exchange capacity(IEC), water uptake and ion conductivity of SPBS-X increased with the increment of sulfonated biphenyl units. Particularly, SPBS-60 showed higher ion conductivity compared to Nafion$^{(R)}$-115 at 25~80 $^{\circ}C$.