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http://dx.doi.org/10.5012/jkcs.2019.63.5.352

Synthesis, Characterization and Determination of HOMO-LUMO of the Substituted 1,3,5-Triazine Molecule for the Applications of Organic Electronics  

Pakkath, Rajeesh (School of Chemical Sciences, Kannur University, Payyanur Campus)
Reddy, Eeda Koti (Division of Chemistry, Department of Science and Humanities, Vignan, Foundation for Science, Technology and Research University-VFSTRU (Vignan's University))
Kuriakose, Sheena (School of Chemical Sciences, Kannur University, Payyanur Campus)
Saritha, C (School of Chemical Sciences, Kannur University, Payyanur Campus)
Sajith, Ayyiliath M (Post Graduate and Research Department of Chemistry, Kasargod Govt. College, Kannur University)
Karuvalam, Ranjith Pakkath (School of Chemical Sciences, Kannur University, Payyanur Campus)
Haridas, Karickal Raman (School of Chemical Sciences, Kannur University, Payyanur Campus)
Publication Information
Journal of the Korean Chemical Society / v.63, no.5, 2019 , pp. 352-359 More about this Journal
Abstract
The most important parameter of organic molecules for energy harvesting application focuses mainly on their band gap (HOMO-LUMO). In this report, we synthesized differently substituted 1,3,5-triazine based organic molecule which on future processing can be used in organic electronics like solar cells and OLED's. The energy gap of the synthesized novel analogue was calculated using cyclic voltammetry, UV-Visible spectroscopy and compared with density functional theory (DFT) studies.
Keywords
Electroactive material; Bandgap; Organic solar cell; Cyclic voltammetry; Density functional theory;
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1 Shirota, Y. J. Mater. Chem. 2000, 10, 1.   DOI
2 Forrest, S. R.; Thompson, M. E. Chem. Rev. 2007, 107, 923.   DOI
3 Tessler, N.; Preezant, Y.; Rappaport, N.; Roichman, Y. Adv. Mater. 2009, 21, 2741.   DOI
4 Shirota, Y.; Kageyama, H. Chem. Rev. 2007, 107, 953.   DOI
5 Shirota, Y. J. Mater. Chem. 2005, 15, 75.   DOI
6 Berggren, M.; Nilsson, D.; Robinson, N. D. Nature Materials 2007, 6, 3.   DOI
7 Cicoira, F.; Santato, C.; Adv. Funct. Mater. 2007, 17, 3421.   DOI
8 Fink, R.; Frenz, C.; Thelakkat, M.; Schmidt, H.-W. Macromolecules 1997, 30, 8177.   DOI
9 Schmidt-Mende, L.; Fechtenkotter, A.; Mullen, K.; Moons, E.; Friend, R. H.; MacKenzie, J. D. Science 2001, 293, 1119.   DOI
10 Witte, G.; Woll, C. J. Mater. Res. 2004, 19, 1889.   DOI
11 Dimitrakopoulos, C. D. Advanced Semiconductor and Organic Nano-Techniques; Elsevier: 2003; pp 191-240.
12 Pron, A.; Gawrys, P.; Zagorska, M.; Djurado, D.; Demadrille, R. Chem. Soc. Rev. 2010, 39, 2577.   DOI
13 Etter, M. C. J. Phys. Chem. 1991, 95, 4601.   DOI
14 Chang, J.-F.; Sun, B.; Breiby, D. W.; Nielsen, M. M.; Solling, T. I.; Giles, M.; McCulloch, I.; Sirringhaus, H. Chem. Mater. 2004, 16, 4772.   DOI
15 Forrest, S. R. Nature 2004, 428, 911.   DOI
16 Kietzke, T. Adv. OptoElec. 2007.
17 Hoppe, H.; Sariciftci, N. S. J. Mater. Res. 2004, 19, 1924.   DOI
18 Al-Ibrahim, M.; Roth, H.-K.; Schroedner, M.; Konkin, A.; Zhokhavets, U.; Gobsch, G.; Scharff, P.; Sensfuss, S. Organic Electronics 2005, 6, 65.   DOI
19 Pommerehne, J.; Vestweber, H.; Guss, W.; Mahrt, R. F.; Bassler, H.; Porsch, M.; Daub, J. Adv. Mater. 1995, 7, 551.   DOI
20 Gagne, R. R.; Koval, C. A.; Lisensky, G. C. Inorg. Chem. 1980, 19, 2854.   DOI
21 Becke, A. D. J. Chem. Phys. 1993, 98, 5648.   DOI
22 Frisch, M. J.; Trucks, G. W.; Schlegel, H. B.; Scuseria, G. E.; Robb, M. A.; Cheeseman, J. R.; Scalmani, G.; Barone, V.; Mennucci, B.; Petersson, G. A.; Gaussian 09, Revision D.1; Gaussain Inc.: Wallingford, CT, 2009.
23 Scalmani, G.; Frisch, M. J. J. Chem. Phys. 2010, 132, 114110.   DOI
24 Hehre, W. J.; Ditchfield, R.; Pople, J. A. J. Chem. Phys. 1972, 56, 2257.   DOI