• Proceedings of the Korean Society of Near Infrared Spectroscopy Conference
• /
• 2001.06a
• /
• pp.1253-1253
• /
• 2001

The ability to accurately assess wine quality is important during the wine making process, particularly when allocating batches of wines to styles determined by consumer requirements. Grape payments are often determined by the quality category of the wine that is produced from them. Wine quality, in terms of sensory characteristics, is normally a subjective measure, performed by experienced winemakers, wine competition judges or winetasting panellists. By nature, such assessments can be biased by individual preferences and may be subject to day-to-day variation. Taste and aroma compounds are often present in concentrations below the detection limit of near infrared (NIR) spectroscopy but the more abundant organic compounds offer potential for objective quality grading by this technique. Samples were drawn from one of Australia's major wine shows and from BRL Hardy's post-vintage wine quality allocation tastings. The samples were scanned in transmission mode with a FOSS NIR Systems 6500, over the wavelength range 400-2500 ㎚. Data analysis was performed with the Vision chemometrics package. With samples from the allocation tastings, the best correlations between NIR spectra and tasting data were obtained with dry red wines. These calibrations used loadings in the wavelengths related to anthocyanins, ethanol and possibly tannins. Anthocyanins are a group of compounds responsible for colour in red wines - restricting the wavelengths to those relating to anthocyanins produced calibrations of similar accuracy to those using the full wavelength range. This was particularly marked with Merlot, a variety that tends to have relatively lower anthocyanin levels than Cabernet Sauvignon and Shiraz. For dry white wines, calibrations appeared to be more dependent on ethanol characteristics of the spectrum, implying that quality correlated with fruit maturity. The correlations between NIR spectra and sensory data obtained using the wine show samples were less significant in general. This may be related to the fact that within most classes in the show, the samples may span vintages, glowing areas and winemaking styles, even though they may be made from only one grape variety. For dry red wines, the best calibrations were obtained with a class of Pinot Noir - a variety that tends to be produced in limited areas in Australia and would represent the least matrix variation. Good correlations were obtained with a tawny port class - these wines are sweet, fortified wines, that are aged for long periods in wooden barrels. During the ageing process Maillard browning compounds are formed and the water is lost through the barrels in preference to ethanol, producing “concentrated” darkly coloured wines with high alcohol content. These calibrations indicated heaviest loadings in the water regions of the spectrum, suggesting that “concentration” of the wines was important, whilst the visible and alcohol regions of the spectrum also featured as important factors. NIR calibrations based on sensory scores will always be difficult to obtain due to variation between individual winetasters. Nevertheless, these results warrant further investigation and may provide valuable Insight into the main parameters affecting wine quality.

• Journal of the Korean Society of Marine Environment & Safety
• /
• v.24 no.6
• /
• pp.726-734
• /
• 2018

The total number of Sea Area Utilization Consultation in the environment management sea areas reviewed from 2015 to 2017 were 60. The number of development projects in the environment conservation sea areas decreased steadily, but special management sea areas increased. Development types in environment management sea areas showed that artificial structure installation was the highest ratio, followed by fishery port development and construction of habor and coastal maintenance and sea water intake and draining. By comparing the trend of water quality changes using marine environment information system (MEIS) data in the environment management areas from 2006 to 2017, COD showed no significant changes but the environment conservation sea areas increased slightly, and the concentration of TN and TP decreased. Gwangyang and Masan bays in the special management sea areas and Gamak bay in the environment conservation sea areas displayed oxygen deficient mass in the summer. As the use of development projects of the environment management sea areas are performed continuously, an analysis of the status of sufficient water quality changes is necessary for environmental impact assessment (Sea Area Utilization Consultation) in the marine environment and should be evaluated mainly for management of contamination by diagnosing thoroughly water quality effects and the pollution of sediment. Especially, the water quality goal for the purpose of designation in each of the environment management sea areas is set clearly, connection with pollution source control and the total pollution load management system (TPLMS) should be proposed and measured to reduce the amount of contaminated water.

• Fire Science and Engineering
• /
• v.31 no.6
• /
• pp.107-111
• /
• 2017

The purpose of this study was to develop a Eco smoking booth that can effectively reduce hazardous pollutants generated during smoking and evaluate the efficiency and effectiveness of removing hazardous pollutants. The design and manufacture of an eco-friendly automatic smoking booth equipped with deodorizing facilities, such as inlet - HEPA filter - electrostatic precipitator (EP) - impregnated activated carbon - exhaust port, etc., and the efficiency of removing hazardous pollutants from inside and outside was measured and evaluated. The complex odor removal efficiency was 95.37% inside the smoking booth, and 97.38% at the exit of the preventive facility. The carbon monoxide removal efficiency was 94.25% in the inside and 98.32% in the outlet. In addition, the removal efficiency of particulate matter, (PM1, PM2.5, and PM10) inside the smoking booth was 98.59%, and 98.85% at the outlet. The total volatile organic compounds (TVOCs) decreased from $26,000{\mu}g/m^3$ to $5,203{\mu}g/m^3$ in the smoking booth, resulting in 79.99% removal efficiency. After the ventilator was operated, the measured effluent concentration was $5,019{\mu}g/m^3$, and the removal efficiency was 80.70%. Therefore, the smoking booth designed and manufactured through this study can be applied to the removal of harmful pollutants even in the small working environment in the future.

• Journal of Korean Society of Coastal and Ocean Engineers
• /
• v.17 no.4
• /
• pp.259-268
• /
• 2005

There has been a growing interest in the elimination of anoxic layer in the Youngsan River Estuarybecause the anoxic water mass caused mainly by the inflow of fresh water from the sea wall might cause the mass reduction of benthos during summer. An ocean outfall system to discharge treated wastewater into sea water may be used as one of the effective and economical ways to eliminate the anoxic layer. The suitable ocean outfall design is generally proposed for the prediction of the buoyant jet behavior in the near field. The parameters including CTD and current data are taken into account f3r more reliable buoyant jet behavior calculation. One of the numerical models, CORMIX 1, approved by EPA is used herein for the prediction of the trajectorial variation of the cross-sectional salinity and DO concentration distribution on the calculated buoyant jet boundary according to the tidal periods. On the basis of the results, it is suggested that the single port outfall is a useful system to eliminate the anoxic layer. Proper strategies are also proposed for achieving desirable ambient conditions.

• Journal of the Korean Society of Marine Environment & Safety
• /
• v.17 no.2
• /
• pp.105-121
• /
• 2011

The operation of tidal power facility may induce severe changes of water quality in Shihwa Lake. Current water quality data are quite important to water quality management policy of Shihwa Lake. Thus, the water quality data of Shihwa Lake and its adjacent sea in 2010 were presented to characterize the temporal and spatial changes of water parameters such as pH, SS, DO, COD, dissolved nutrients, chlorophyll-a, TN and TP. Highest levels of water quality parameters were observed near the Shihwa and Banweol industrial complexes and the levels of water quality parameters were on a decreasing trend to those near the water gate. It suggests that the horizontal distributions of water quality levels are mainly controlled by the supply of fresh water from streams and the inflow of outer seawater by operation of water gate. Although the higher concentrations of TN and TP were observed in the location being affected by Sorae port, the levels of water quality parameters in outer sea of Shihwa Lake were lower than those in Lake. In summer season, hypoxic condition was well developed in bottom water by strong stratification and active decomposition of organic matter. Thus, the vertical distributions of dissolved nutrient, TN and TP concentrations showed the concentrations to be higher in bottom seawater than those in surface seawater whereas the vertical distributions of chlorophyll-a, COD and POC concentrations showed the concentrations to be higher in surface seawater than those in bottom water. Results of Pearson's correlation matrix for surface seawater demonstrated that salinity showed negatively good correlation with not only dissolved nutrients except for ammonium but chlorophyll-a, COD and POC This result indicates that the supply of dissolved nutrients through several streams might significantly affect phytoplankton bloom and increase of COD concentration in surface seawater.

• Journal of Korean Tunnelling and Underground Space Association
• /
• v.19 no.6
• /
• pp.845-856
• /
• 2017

In the long railway tunnel, in order to secure safety in case of fire, it is required a emergency station. However, there is no standard or research results on smoke exhaust method and exhaust flow rate in emergency station, so it is necessary to study the smoke exhaust system for emergency station. In this study, we are created a numerical analysis model for emergency station where the evacuation cross passage connected to the service tunnel or the relative tunnel was installed at regular intervals (40 m intervals). And the fire analysis are carried out by varying the fire intensity (15, 30MW), the smoke exhaust method (only air supply, forced air supply and exhaust, forced air exhaust only), and the air flow rate (7, 14, $40m^3/s$). From the results of fire analysis, temperature and CO concentration are analyzed and ASET based on the limit temperature are compared at various condition. As a result, in the case with fire intensity of 15 MW, it is shown that a sufficiently safe evacuation environment can be ensured by applying forced air supply and exhaust method or forced air exhaust only method when the air flow rate is $7m^3/s$ above. In case of fire intensity of 30 MW, it is impossible to maintain the safety evacuation environment for more than 900 seconds when the exhaust air volume is below $14m^3/s$. And when the air flow rate is $40m^3/s$, the exhaust port is disposed at the side portion of the upper duct, which is most advantageous for securing the temperature-based safety.

• Analytical Science and Technology
• /
• v.34 no.1
• /
• pp.23-35
• /
• 2021

In order to measure the volatile organic compounds (VOCs) of a sample which is too large to use commercially available chamber, a stainless steel vacuum chamber (VC) (with an internal diameter of 205 mm and a height of 50 mm) was manufactured and the temperature of the chamber was controlled using an oven. After concentrating the volatiles of the sample in the chamber by helium gas, it was made possible to remove residual volatile substances present in the chamber under reduced pressure ((2 ± 1) × 10-2 mmHg). The chamber was connected to a purge & trap (P&T) using a 6 port valve to concentrate the VOCs, which were analyzed by gas chromatography-mass spectrometry (GC-MS) after thermal desorption (VC-P&T-GC-MS). Using toluene, the toluene recovery rate of this device was 85 ± 2 %, reproducibility was 5 ± 2 %, and the detection limit was 0.01 ng L-1. The method of removing VOCs remaining in the chamber with helium and the method of removing those with reduced pressure was compared using Korean drinking water regulation (KDWR) VOC Mix A (5 μL of 100 ㎍ mL-1) and butylated hydroxytoluene (BHT, 2 μL of 500 ㎍ mL-1). In case of using helium, which requires a large amount of gas and time, reduced pressure ((2 ± 1) × 10-2 mmHg) only during the GC-MS running time, could remove VOCs and BHT to less than 0.1 % of the original injection concentration. As a result of analyzing volatile substances using VC-P&T-GC-MS of six types of cell phone case, BHT was detected in four types and quantitatively analyzed. Maintaining the chamber at reduced pressure during the GC-MS analysis time eliminated memory effect and did not affect the next sample analysis. The volatile substances in a cell phone case were also analyzed by dynamic headspace (HT3) and GC-MS, and the results of the analysis were compared with those of VC-P&T-GC-MS. Considering the chamber volume and sample weight, the VC-P&T configuration was able to collect volatile substances more efficiently than the HT3. The VC-P&T-GC-MS system is believed to be useful for VOCs measurement of inhomogeneous large sample or devices used inside clean rooms.

• Analytical Science and Technology
• /
• v.19 no.5
• /
• pp.383-388
• /
• 2006

Simple post-wash method by ion chromatography (IC) was established for the rapid and precise determination of fluoride ion in wastewater from mine in fluorite mineralized area. High sulfate in sample was retained in a pre-column and less strongly held fluoride ion was transferred to the principal separation system using modified conventional IC with switching technique. An analytical column with high capacity (AS 9 HC) was used as a pre-column to retain the amount of high sulfate. A guard column (AG 14) as a separation column was used to increase the response of fluoride and reduce the system pressure. According to the recovery of fluoride ion with one detector and the observation of sulfate peak with another conductivity detector, the optimum switching time of 10-port chromatographic injector was 4.3 min. The limit of detection (S/N = 3) of fluoride in synthetic solution containing $500mg\;L^{-1}$ sulfate was $2.4{\mu}g/L$, with $25{\mu}L$ sample volume.

• Journal of Environmental Health Sciences
• /
• v.49 no.6
• /
• pp.344-352
• /
• 2023

Background: With its developed port and related industries, the concentration of fine dust is high in Busan compared to other cities in South Korea. Many studies have reported the health effects of fine dust, but there has been a lack of information regarding concentrations of volatile organic compounds among those who exposed to high levels of fine dust. Objectives: This study aimed to define an area with high concentrations of particulate matter and perform biomonitoring surveys among the residents of the area. Methods: Air quality data was collected and the mean level of each district in Busan was derived. We then defined the area with the highest concentrations of PM₁₀ as a target site. Urine samples were collected from the 400 participants and analyzed for VOCs metabolites - trans,trans-Muconic Acid (t,t-MA) and N-AcetylS-(benzyl)-L-cysteine (BMA). Interviews were conducted by trained investigators to examine demographic information. The levels of t,t-MA and BMA were compared with representative South Korean population data (Korean National Environmental Health Survey). The association of the VOC metabolites and fine dust were analyzed by general linear regression analysis. Results: The mean of PM₁₀ in the target site was 42.50 ㎍/m³ from 2018 to 2020. Among the 400 participants in the target site, 74.8% were female and the average age of the participants was 66 years. The geometric mean of t,t-MA was 71.15 ㎍/g creatinine and the BMA was 7.00 ㎍/g creatinine among the residents. The levels were higher than the geometric mean from the 4th KoNEHS. The levels of t,t-MA showed significance in BMI, smoking status, and household income. BMA showed significance in gender and age. Conclusions: Compared to the general population of South Korea, the target site's residents had higher biomonitoring levels. Based on this study, continuous screening for high risk areas, including the target site, and biomonitoring of the residents are required.

• Journal of Environmental Health Sciences
• /
• v.50 no.3
• /
• pp.181-190
• /
• 2024

Background: Air pollutants have been reported to have harmful effects on human health. Busan is a vulnerable area in terms of air quality due to the installation of various industrial complexes, particularly the port industry. However there is limited research data on the ambient air quality of residential areas near ports and industrial complexes. Objectives: This study aimed to determine the quarterly levels of air pollutants near industrial complexes and ports and to identify trends and characteristics of air pollutant exceedances. Methods: Air measurements were conducted quarterly. The measured air pollutants included O₃, SO₂, CO, NO₂, PM₁₀, and PM_2.5. PM₁₀ and PM_2.5 were measured using BAM-1020 equipment, while O₃, SO₂, CO, and NO₂ were measured using AP-370 Series equipment. The quarterly concentration levels of air pollutants were determined, and the influence of precipitation and commuting hours on fine particulate matter was examined. Analysis of variance (ANOVA) was conducted to determine if there was significance between the concentrations of fine particulate matter during commuting hours and non-commuting hours. Results: The concentrations of air pollutants were generally higher in the first and second quarters. Furthermore, the concentrations of PM₁₀ and PM_2.5 tended to decrease continuously following consecutive rainfall, with concentrations at the end of rainfall periods lower than those observed at the beginning. The frequency of exceeding average concentrations of PM₁₀ and PM_2.5 was higher on weekdays. Moreover, the average concentrations of PM₁₀ and PM_2.5 during weekday commuting hours were higher compared to non-commuting hours. Conclusions: The concentrations of air pollutants in the survey area were found to be higher than the overall average in Busan. Based on this study, continuous air quality monitoring is necessary for residential areas near industrial complexes and ports. For further research, health biomonitoring of residents in these areas should be conducted to assess their exposure levels.