• Computers and Concrete
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• v.4 no.4
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• pp.273-284
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• 2007

The paper considers a theoretical model for the study of the process of transfer of sulfate ions in saturated porous media - mineral composites. In its turn, the model treats diffusion of sulfate ions into cement based composites, accounting for simultaneous effects such as filling of micro-capillaries with ions and chemical products and liquid push out of them. The proposed numerical algorithm enables one to account for those simultaneous effects, as well as to model the diffusive behavior of separate sections of the considered volume, such as inert fillers. The cases studied illustrate the capabilities of the proposed model and those of the algorithm developed to study diffusion, considering the specimen complex configuration. Computations show that the theoretical assumptions enable one to qualitatively estimate the experimental evidence and the capabilities of the studied composite. The results found can be used to both assess the sulfate corrosion in saturated systems and predict and estimate damage of structures built of cement-based mineral composites.

• Journal of Integrative Natural Science
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• v.4 no.3
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• pp.192-196
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• 2011

New method to encode multiple photonic features of Bragg type reflector on silicon wafer has been investigated. Multiple bit encodes of distributed Bragg reflector features have been prepared by electrochemical etching of crystalline silicon by using various square wave current densities. Optical characterization of multi-encoding of distributed Bragg reflectors on porous silicon was achieved by Ocean optics 2000 spectrometer for the search of possible applications of multiple bit encoding of distributed Bragg reflectors such as multiplexed assays and chemical sensors. The morphology and cross-sectional structure of multi-encoded distributed Bragg reflectors was investigated by field emission scanning electron micrograph.

• Corrosion Science and Technology
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• v.16 no.5
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• pp.227-234
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• 2017

Reference electrodes are generally implemented for the purpose of monitoring the cathodic protection potentials of buried or immersed metallic structures. In the market, many types of reference electrodes are available for this purpose, such as saturated calomel, silver/silver chloride and copper/copper sulfate. These electrodes contain a porous ceramic junction plate situated in the cylindrical body bottom to permit ionic flux between the internal electrolyte (of the reference electrode) and the external electrolyte. In this work, the copper/copper sulfate reference electrode was modified by replacing the porous ceramic junction plate for a metallic platinum wire. The main purpose of this modification was to avoid the ion copper transport from coming from the inner reference electrode solution into the surrounding electrolyte, and to mitigate the copper plating on the coupon surfaces. Lab tests were performed in order to compare the performance of the two mentioned reference electrodes. We verified that the experimental errors associated with the measurements conducted with developed reference electrode would be negligible, as the platinum surface area exposed to the surrounding electrolyte and/or to the reference electrolyte are maintained as small as possible.

• Korea-Australia Rheology Journal
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• v.21 no.1
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• pp.71-79
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• 2009

The incomplete saturation and the void formation during the resin infiltration into fibrous porous media in the resin transfer molding process cause failure in the final product during its service. In order to better understand flow behavior during the filling process, a finite-element scheme for transient flow simulation across the micro-structured fibrous media is developed in the present work. A volume-of- fluid (VOF) method has been incorporated in the Eulerian frame to capture the evolution of flow front and the vertical periodic boundary condition has been combined to avoid unwanted wall effect. In the microscale simulation, we investigated the transient filling process in various fiber structures and discussed the mechanism leading to the flow fingering in the case of random fiber distribution. Effects of the filling pressure, the shear-thinning behavior of fluid and the volume fraction on the flow front have been investigated for both intra-tow and the inter-tow flows in dual-scale fiber tow models.

• Transactions on Electrical and Electronic Materials
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• v.11 no.5
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• pp.230-233
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• 2010

The authors investigated the anodization mechanism of aluminum in an oxalic acid solution, and the electrochemical reaction is very unique for pore formation via the dissolution process, which is very dependent on the surface geometry in nanoporous alumina templates. The cross-sectional nanochannels showed that the geometrical curvature of the initial surface can cause the branching of nanochannels to be adjusted in volume occupancy to be direct to the electric field normal to the surface. The nanoporous alumina with the crystalline $\gamma-Al_2O_3$ phase showed hexagonal ordering at a voltage of 40 V, with a nanohole distance of 102 nm from the charge density oscillation of the oxalic acid solution.

• Wind and Structures
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• v.27 no.1
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• pp.59-70
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• 2018

In this paper, geometrically non-linear analysis of a functionally graded simple supported beam is investigated with porosity effect. The material properties of the beam are assumed to vary though height direction according to a prescribed power-law distributions with different porosity models. In the nonlinear kinematic model of the beam, the total Lagrangian approach is used within Timoshenko beam theory. In the solution of the nonlinear problem, the finite element method is used in conjunction with the Newton-Raphson method. In the study, the effects of material distribution such as power-law exponents, porosity coefficients, nonlinear effects on the static behavior of functionally graded beams are examined and discussed with porosity effects. The difference between the geometrically linear and nonlinear analysis of functionally graded porous beam is investigated in detail. Also, the effects of the different porosity models on the functionally graded beams are investigated both linear and nonlinear cases.

• Journal of Integrative Natural Science
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• v.2 no.3
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• pp.207-210
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• 2009

Multiple rugate structures can be etched on a silicon wafer and placed in the same physical location, showing that many sharp spectral lines can be obtained in the optical reflectivity spectrum. Porous silicon samples were prepared by electrochemical etch of heavily doped p-type silicon wafers. The etching solution consisted of a 3:1 volume mixture of aqueous 48% hydrofluoric acid and absolute ethanol. Galvanostatic etch was carried out in a Teflon cell by using a two-electrode configuration with a Pt mesh counterelectrode. A sinusoidal current density waveform varying between 51.5 and $74.6mA/cm^2$ is applied. The anodization current was supplied by a Keithley 2420 high-precision constant current source which is controlled by a computer to allow the formation of PSi multilayer.

• Proceedings of the Computational Structural Engineering Institute Conference
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• 1992.10a
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• pp.168-173
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• 1992

In the design and construction of underground structures, it is essential to accurately predict the structural behavior of the fluid-saturated ground during and after excavation. Terzaghi and Biot established the theory for the behavior of such two phase material. For the purpose of analysing the saturated porous solid system, finite element procedure provides a powerful tool. In this paper, a finite element analysis procedure based upon Biot's theory is presented to evaluate the deformation of solid skeleton and pore pressure of entraped fluid. Teraghi's onf-dimensional and Gibson's two-dimensional problems are solved using Q4 and Q8 element to verify the program validity.

• Journal of the Korean institute of surface engineering
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• v.49 no.6
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• pp.486-489
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• 2016

In the present work, we investigate the anodization of Nb in a $K_2HPO_4$ containing glycerol electrolyte at elevated temperatures ($180^{\circ}C$). Under optimized conditions, uniformly over the entire anodized surface, self-organized porous $Nb_2O_5$ structures can be formed. The growth rate of highly ordered $Nb_2O_5$ is $1.7{\mu}m/min$ at beginning stage of anodization and the overall current efficiency is 70 %.

• The Korean Journal of Ceramics
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• v.5 no.2
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• pp.137-141
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• 1999

To increase the strength of high-purity porous mullite ceramics, ultra fine mullite precursor powders of about 10nm in diameter were deposited at point of contact between primary coarse mullite particles of about 60$\mu\textrm{m}$. The deposited and hetero coagulated structures of ultra fine mullite precursor powders were controlled by pH. The optimum pH condition to form a uniform deposition of mullite powders between coarse mullite particles was in the range from 7 to 8. Deposition of the ultra fine powders did not form at pH < 7 and pH > 10 irregular deposition was observed from pH 8 to 9.